Unusual structural distortions induced by charge-transfer interactions through conjugated molecules - Crystal structures of NH2C6H4(C triple bond C)nC6H4NO2 (n = 0-3)
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Graham, Eva M.↗
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Collisions between H(+) and H2 at kilo-electron-volt energies - Absolute differential cross sections for small-angle direct, single-, and double-charge-transfer scattering
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Gao, R. S.↗
The Charge Transfer Efficiency and Calibration of WFPC2
A new determination of WFPC2 photometric corrections is presented, using HSTphot reduction of the WFPC2 Omega Centauri and NGC 2419 observations from January 1994 through March 2000 and a comparison with ground-based photometry. No evidence is seen for any position-independent photometric offsets (the "long-short anomaly"); all systematic errors appear to be corrected with the CTE and zero point solution. The CTE loss time dependence is determined to be very significant in the Y direction, causing time-independent CTE solutions to be valid only for a small range of times. On average, the present solution produces corrections similar to Whitmore, Heyer, & Casertano, although with an improved functional form that produces less scatter in the residuals and determined with roughly a year of additional data. In addition to the CTE loss characterization, zero point corrections are also determined as functions of chip, gain, filter, and temperature. Of interest, there are chip-to-chip differences of order 0.01 - 0.02 magnitudes relative to the Holtzman et al. calibrations, and the present study provides empirical zero point determinations for the non-standard filters such as the frequently-used F450W, F606W, and F702W.
Dolphin, Andrew E.↗
Comparison of the Proton-Induced Dark Current and Charge Transfer Efficiency Responses of N- and P-Channel CCDs
The proton-induced CTE behavior for the Lawrence Berkeley National Laboratory (LBNL) p-CCD (being developed for the Supernovae Acceleration Project (SNAP) and Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) n-CCDs were compared using 55Fe, EPER and FPR techniques. CTE performance of the p-CCD is about an order of magnitude better after a 63 MeV fluence of 2.5 x 10(sup 9)/sq cm, which is equivalent to 2.5 years in the shielded HST orbit. Notched n- and p-CCDs yielded factor of two improvement in CTE performance as compared to their un-notched versions. The introduction rate of hot pixels was greater in p-CCD as compared to n-CCD, and also greater in notched than un-notched devices.
Marshall, Cheryl↗
Synthesis of Charge Transfer Dyes for Use as Molecular Sensors in Biological Systems
This is a continuation of last year's project to synthesize tetraaryl substituted benzodifurans for use as molecular probes in biological systems. The project will involve the synthesis and chemical characterization of dyes and precursor molecules.
Christie, Joseph J.↗
Reversible non-volatile switch based on a TCNQ charge transfer complex
A solid-state synaptic memory matrix (10) having switchable weakly conductive connections at each node (24) whose resistances can be selectably increased or decreased over several orders of magnitude by control signals of opposite polarity, and which will remain stable after the signals are removed, comprises an insulated substrate (16), a set of electrical conductors (14) upon which is deposited a layer (18) of an organic conducting polymer, which changes from an insulator to a conductor upon the transfer of electrons, such as polymerized pyrrole doped with 7,7,8,8-tetracyanoquinodimethane (TCNQ), covered by a second set of conductors (20) laid at right angles to the first.
Nagasubramanian, Ganesan↗
The chemical evolution of molecular clouds
The nonequilibrium chemistry of dense molecular clouds (10,000 to 1 million hydrogen molecules per cu cm) is studied in the framework of a model that includes the latest published chemical data and most of the recent theoretical advances. In this model the only important external source of ionization is assumed to be high-energy cosmic-ray bombardment; standard charge-transfer reactions are taken into account as well as reactions that transfer charge from molecular ions to trace-metal atoms. Schemes are proposed for the synthesis of such species as NCO, HNCO, and CN. The role played by adsorption and condensation of molecules on the surface of dust grains is investigated, and effects on the chemical evolution of a dense molecular cloud are considered which result from varying the total density or the elemental abundances and from assuming negligible or severe condensation of gaseous species on dust grains. It is shown that the chemical-equilibrium time scale is given approximately by the depletion times of oxygen and nitrogen when the condensation efficiency is negligible; that this time scale is probably in the range from 1 to 4 million years, depending on the elemental composition and initial conditions in the cloud; and that this time scale is insensitive to variations in the total density.
Iglesias, E.↗
Opposite direction multiple-phase clocking in adjacent CCD shift registers
Parallelled charge transfer channels have multiple-phase-clocked gate electrodes overspanning them in one of a number of arrangements conditioning the transfer of charge packets in opposing directions in adjacent charge transfer channels. Three-phase, four-phase, five-phase and six-phase clocking arrangements constructed in three layers of polysilicon embody the invention.
Elabd, Hammam↗
An intracloud lightning parameterization scheme for a storm electrification model
The parameterization of an intracloud lightning discharge has been implemented in the present storm electrification model. The initiation, propagation direction, and termination of the discharge are computed using the magnitude and direction of the electric field vector as the determining criteria. The charge redistribution due to the lightning is approximated assuming the channel to be an isolated conductor with zero net charge over its entire length. Various simulations involving differing amounts of charge transferred and distribution of charges have been done. Values of charge transfer, dipole moment change, and electrical energy dissipation computed in the model are consistent with observations. The effects of the lightning-produced ions on the hydrometeor charges and electric field components depend strongly on the amount of charge transferred. A comparison between the measured electric field change of an actual intracloud flash and the field change due to the simulated discharge shows favorable agreement. Limitations of the parameterization scheme are discussed.
Helsdon, John H., Jr.↗
Monolithic InSb imaging arrays with charge-coupled device /CCD/ readout
The paper demonstrates the detection of infrared radiation and signal readout on a monolithic InSb charge coupled infrared imaging device. The device is a 20-element linear imager with MOS detectors coupled to a four-phase, surface-channel, charge transfer structure. The charge transfer device is p-channel and has planar ion implanted diode structures for zero input and charge readout. Sensitivity measurements on the MOS infrared detectors were determined for the 20-element array. Data are presented on the operational characteristics of the 20-element linear imager under various conditions of electrical and optical inputs in both multiplexed and a time delay and integration (TDI) mode. Plans are discussed for a monolithic InSb 100-element linear imager and a 20 x 16 TDI linear imager.
Miller, W. E.↗
A sub-nanosecond CCD
A 32-cell silicon n-channel PCCD was fabricated and tested for charge transfer efficiency versus transfer time. A charge transfer time of 550 picoseconds with a 0.9998 transfer efficiency was obtained when operated in the uni-phase mode. These conditions correspond to an operating rate of 900 MHz when operated as an analog data or digital device.
Chan, Y. T.↗
A predictive model for space-based X-ray CCD degradation
The first generation of X-ray telescopes to use Charge-Coupled Devices (CCDs) is being launched this decade. With a read noise of a few electrons, CCDs provide Fano-limited spectral resolution across the soft X-ray band (0.1 - 10 keV). However, degradation of resolution due to charge transfer losses becomes noticeable as Charge Transfer Inefficiency (CTI) increases to 10(exp -5). In this paper, we present a model which calculates the effects of radiation damage in low Earth orbit in order to predict CCD lifetimes over which good charge transfer is maintained. The model presented here considers damage mechanisms within the CCD, environmental conditions in which the CCD operates, and experiment shielding. We find that the predicted CTI approaches 10(exp -5) after a one to two year mission for the flight instruments considered here.
Antunes, Alex↗
Two-phase charge-coupled device
A charge-transfer efficiency of 99.99% per stage was achieved in the fat-zero mode of operation of 64- and 128-stage two-phase charge-coupled shift registers at 1.0-MHz clock frequency. The experimental two-phase charge-coupled shift registers were constructed in the form of polysilicon gates overlapped by aluminum gates. The unidirectional signal flow was accomplished by using n-type substrates with 0.5 to 1.0 ohm-cm resistivity in conjunction with a channel oxide thickness of 1000 A for the polysilicon gates and 3000 A for the aluminum gates. The operation of the tested shift registers with fat zero is in good agreement with the free-charge transfer characteristics expected for the tested structures. The charge-transfer losses observed when operating the experimental shift registers without the fat zero are attributed to fast interface state trapping. The analytical part of the report contains a review backed up by an extensive appendix of the free-charge transfer characteristics of CCD's in terms of thermal diffusion, self-induced drift, and fringing field drift. Also, a model was developed for the charge-transfer losses resulting from charge trapping by fast interface states. The proposed model was verified by the operation of the experimental two-phase charge-coupled shift registers.
Kosonocky, W. F.↗
Wire transfer of charge packets using a CCD-BBD structure for charge-domain signal processing
A structure for the virtual transfer of charge packets across metal wires is described theoretically and is experimentally verified. The structure is a hybrid of charge-coupled device (CCD) and bucket-brigade device (BBD) elements and permits the topological crossing of charge-domain signals in low power signal processing circuits. A test vehicle consisting of 8-, 32-, and 96-stage delay lines of various geometries implemented in a double-poly, double-metal foundry process is used to characterize the wire-transfer operation. Transfer efficiency ranging between 0.998 and 0.999 is obtained for surface n-channel devices with clock cycle times in the range from 40 ns to 0.3 ms. Transfer efficiency as high as 0.9999 is obtained for buried n-channel devices. Good agreement is found between experiment and simulation.
Fossum, Eric R.↗
Memory behavior of an MNS capacitor.
Metal-/Si nitride/-Si/MNS/ capacitor memory behavior due to high voltage pulses, discussing charge transfer, stored charge location and tunneling conduction
Oconnell, M.↗
Product distributions and rate constants for ion-molecule reactions in water, hydrogen sulfide, ammonia, and methane
The thermal energy, bimolecular ion-molecule reactions occurring in gaseous water, hydrogen sulfide, ammonia, and methane have been identified and their rate constants determined using ion cyclotron resonance methods. Absolute rate constants were determined for the disappearance of the primary ions by using the trapped ion method, and product distributions were determined for these reactions by using the cyclotron ejection method. Previous measurements are reviewed and compared with the results using the present methods. The relative rate constants for hydrogen-atom abstraction, proton transfer, and charge transfer are also determined for reactions of the parent ions.
Huntress, W. T., Jr.↗
Theoretical study of CO chemisorption on nickel and copper surfaces
A comparative study of the chemisorption of CO on Ni(001) and Cu(001) surfaces has been performed. The study is based on an analysis of the electronic structure of (M)5CO clusters obtained from self-consistent field X alpha scattered-wave calculations. The electron orbital formed principally by the 5 sigma orbital on CO was found to be mainly responsible for the bonding of the CO molecule to the metal surface for both the CO/Ni and CO/Cu systems. The different occupation of the antibonding 7 a sub 1 orbital in the two clusters is believed to be the major reason for the large difference observed in the measured heats of adsorption of CO on Ni and Cu surfaces. It was found also that metal atoms transfer electronic charge to the antibonding pi(asterisk)-like orbital of CO. A possible correlation between the amount of the charge transfered and the relative ease of dissociation of CO molecules on metal surfaces is discussed.
Yu, H. L.↗
Thermal and electrical interaction of tantalum with a low temperature chemically active plasma flow
The paper deals with an experimental study of radiative heat transfer and charge transfer processes from the surface of tantalum plates under conditions of unsteady high-temperature heating and oxidation. It is shown that at plate temperatures of 1800 K, the heat flux may be as high as 400 kW/sq m. Heating is shown to stimulate the emissivity of tantalum and the temperature of the free electrons which surface, through a gas boundary layer, from the plasma onto the metal.
Zake, M. V.↗