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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Residential Battery Modeling for Control-Oriented Techno-Economic Studies: Preprint

Electrochemical batteries, which serve as electric energy storage devices, are becoming increasingly popular among residential buildings that incorporate solar photovoltaic (PV) systems to help meet their energy needs. Battery economics are affected by performance degradation over time, and managing this degradation can help extend the battery's lifespan. The tradeoff between operational costs/benefits and managing battery degradation is of significant research interest. One of the key factors for assessing battery degradation is the dispatch strategy used to control the charging and discharging of the battery. Conventional dispatch strategies typically use simple rule-based methods, and these overly aggressive charging/discharging cycles can significantly reduce a battery’s life span. Our research seeks to develop optimized dispatch strategies for grid-connected PV homes with a goal of extending battery life while simultaneously taking into consideration utility costs and occupant comfort. To achieve this goal, we adapted lithium-ion battery life- and cyclic-degradation models for use in high-fidelity building simulations, so whole-building and grid-interactive controllers can dispatch the batteries along with other flexible loads. With the help of a co-simulation platform, we performed a simulation study to compute the optimized dispatch strategies for relevant operating conditions brought about by changing geographical locations, weather conditions, and utility pricing. Comparing the optimized strategies with the conventional strategies resulted in a >50% decrease in capacity degradation and >10% average reduction in operational costs during the months of January and July in Fort Collins, Colorado; Phoenix, Arizona; and Portland, Oregon.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2020

Variability and origins of grain boundary electric potential detected by electron holography and atom-probe tomography

A number of grain boundary phenomena in ionic materials, in particular, anomalous (either depressed or enhanced) charge transport, have been attributed to space charge effects. Developing effective strategies to manipulate transport behaviour requires deep knowledge of the origins of the interfacial charge, as well as its variability within a polycrystalline sample with millions of unique grain boundaries. Electron holography is a powerful technique uniquely suited for studying the electric potential profile at individual grain boundaries, whereas atom-probe tomography provides access to the chemical identify of essentially every atom at individual grain boundaries. Using these two techniques, we show in this paper that the space charge potential at grain boundaries in lightly doped, high-purity ceria can vary by almost an order of magnitude. We further find that trace impurities (<25 ppm), rather than inherent thermodynamic factors, may be the ultimate source of grain boundary charge. These insights suggest chemical tunability of grain boundary transport properties. A number of grain boundary phenomena in ionic materials, such as anomalous charge transport, have been attributed to space charge effects. Space charge potential at grain boundaries in lightly doped, high-purity ceria is now shown to vary by almost an order of magnitude.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Generalizing Reversible Triplet–Triplet Energy Transfer as a Strategy to Increase Excited-State Lifetime in Copper(I) Charge-Transfer Chromophores

In this work, we generalize reversible triplet–triplet energy transfer (TTET) as a strategy to achieve long (μs range) excited-state lifetimes in copper(I) photosensitizers of the general formula Cu(RNacNac)(CN-Ar) (RNacNac is a substituted β-diketiminate and CN-Ar is an aryl isocyanide). Six new complexes are presented where the isocyanide is substituted with a triplet–acceptor moiety─anthracene, naphthalene, or phenanthrene. In-depth photophysical analysis reveals that energetic matching of the charge-transfer ( 3 CT) and acceptor-localized 3 (π→π*) states is key to achieving long triplet excited-state lifetimes via reversible TTET. With 2-isocyanoanthracene as the acceptor ligand, 3 CT and 3(π→π*) are not energetically proximate, and irreversible quenching of 3 CT occurs. With a small 0.1–0.2 eV gap between the two triplet states, luminescence originates from the 3 CT state with a moderate excited-state lifetime of 250 or 283 ns observed. As key to the success of this approach, we demonstrate that altering the N-substituent on the RNacNac ligand modulates the energy of the 3 CT state, giving three complexes where the 3 CT and 3 (π→π*) energies are perfectly matched and the excited-state lifetimes are much longer, spanning 1.9–2.7 μs. As such, the key lesson of this work is that long triplet-state lifetimes in these compounds can be achieved by proper “mixing and matching” of the RNacNac ligand, which influences the 3 CT energy, and the triplet acceptor group which dictates the energy of the 3 (π→π*) state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

A Control Strategy for Improving Resiliency of an DC Fast Charging EV System

As DC fast charging electric vehicle (EV) infrastructure continues to expand, potential challenges loom. One issue is the potential for EV charger outages due to electrical grid voltage transients. Today, EV chargers are expected to disconnect under a severe voltage sag (below 70%) which reduces electric vehicle charging infrastructure resilience. This work proposes a droop-control solution to ride-through voltage sags and maintain operation. The control solution is presented in a controller hardware in the loop platform.

Starke, Michael↗
DOE OSTI2024

Discovery of a Peptoid-Based Nanoparticle Platform for Therapeutic mRNA Delivery via Diverse Library Clustering and Structural Parametrization

Nanoparticle-mediated mRNA delivery has emerged as a promising therapeutic modality, but its growth is still limited by the discovery and optimization of effective and well-tolerated delivery strategies. Lipid nanoparticles containing charged or ionizable lipids are an emerging standard for in vivo mRNA delivery, so creating facile, tunable strategies to synthesize these key lipid-like molecules is essential to advance the field. Here, we generate a library of N-substituted glycine oligomers, peptoids, and undertake a multistage down-selection process to identify lead candidate peptoids as the ionizable component in our Nutshell nanoparticle platform. First, we identify a promising peptoid structural motif by clustering a library of >200 molecules based on predicted physical properties and evaluate members of each cluster for reporter gene expression in vivo. Then, the lead peptoid motif is optimized using design of experiments methodology to explore variations on the charged and lipophilic portions of the peptoid, facilitating the discovery of trends between structural elements and nanoparticle properties. We further demonstrate that peptoid-based Nutshells leads to expression of therapeutically relevant levels of an anti-respiratory syncytial virus antibody in mice with minimal tolerability concerns or induced immune responses compared to benchmark ionizable lipid, DLin-MC3-DMA. Through this work, we present peptoid-based nanoparticles as a tunable delivery platform that can be optimized toward a range of therapeutic programs.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Electric Vehicle Charging Management in Smart Energy Communities to Increase Renewable Energy Hosting Capacity

Abnormal climates due to global warming have emerged as a big concern in the global community. To mitigate climate change and achieve sustainability, distributed energy resources (DERs), including solar and wind, have been recently deployed in power systems. As the penetration level of DERs has increased, however, it caused a multitude of issues in the power systems, such as voltage fluctuation in the distribution network limiting renewable hosting capacity. On the other hand, the electric vehicle (EV) industry is rapidly growing to facilitate the transition to a carbon-neutral community, illuminating the potential of EVs as a flexible grid asset to mitigate some of the issues and improve grid operation, if properly exploited. To explore the potential of EVs, this paper proposes an EV scheduling strategy. By using an optimal EV charging scheduling proposed, distribution system operators (DSOs) can minimize their operating costs and stably operate the system with a high level of DERs. To validate the method, a modified IEEE 33-bus system with DERs is developed. The case study shows the proposed scheduling strategizes EV charging to reduce the cost of PV curtailment. In the study, the method outperforms the renewable-only case with curtailment by 4.97% in DSO cost. It also demonstrates its potential to increase the renewable hosting capacity by harmonizing EV charging with renewables.

ADVANCED PROPULSION SYSTEMS,POWER TRANSMISSION AND↗
DOE OSTI2022

Insights into the Enhanced Reversibility of Graphite Anode Upon Fast Charging Through Li Reservoir

Increasing the charging rate and reducing the charging time for Li-ion batteries are crucial to realize the mainstream of electric vehicles. However, it is formidable to avoid the Li plating on graphite anode upon fast charging. Despite the tremendous progress in Li detection techniques, the fundamental mechanism of Li plating and its chemical/electrochemical responses upon cycling still remains elusive. Herein, we present a comprehensive electrochemical method to investigate the fast charging behavior of graphite electrode. A detailed analysis is directed toward understanding the changes in phase, composition, and morphology of the fast-charged graphite. By applying a resting process, we scrutinize the further reactions of the plated Li, which readily transforms into irreversible (dead) Li. We further develop a modified graphite electrode with a thin Ag coating as the Li reservoir. The plated Li can be "absorbed" by the Ag layer to form the Li-Ag solid solution that suppresses the formation of dead Li and provides structural stability, thus promoting the further lithiation of graphite and enhancing the reversibility. Here this work not only provides additional insights into the fast charging behavior of graphite electrode but also demonstrates a potential strategy to improve the fast charging performance of graphite anode.

25 ENERGY STORAGE↗
DOE OSTI2024

Final Physics Design of Proton Improvement Plan-II at Fermilab

This paper presents the final physics design of the Proton Improvement Plan-II (PIP-II) at Fermilab, focusing on the linear accelerator (Linac) and its beam transfer line. We address the challenges in longitudinal and transverse lattice design, specifically targeting collective effects, parametric resonances, and space charge nonlinearities that impact beam stability and emittance control. The strategies implemented effectively mitigate space charge complexities, resulting in significant improvements in beam quality—evidenced by reduced emittance growth, lower beam halo, decreased loss, and better energy spread management. This comprehensive study is pivotal for the PIP-II project's success, providing valuable insights and approaches for future accelerator designs, especially in managing nonlinearities and enhancing beam dynamics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Final Physics Design of Proton Improvement Plan-II At Fermilab

This paper presents the final physics design of the Proton Improvement Plan-II (PIP-II) at Fermilab, focusing on the linear accelerator (Linac) and its beam transfer line. We address the challenges in longitudinal and transverse lattice design, specifically targeting collective effects, parametric resonances, and space charge nonlinearities that impact beam stability and emittance control. The strategies implemented effectively mitigate space charge complexities, resulting in significant improvements in beam quality -- evidenced by reduced emittance growth, lower beam halo, decreased loss, and better energy spread management. This comprehensive study is pivotal for the PIP-II project's success, providing valuable insights and approaches for future accelerator designs, especially in managing nonlinearities and enhancing beam dynamics.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

The need for ion-exchange membranes with high charge densities

Ion-exchange membranes (IEMs) are essential for controlling ion transport in electrochemical membrane-based technologies for water purification, energy generation, and energy storage. In general, IEMs must exhibit high ionic conductivity and selectivity, both of which are significantly influenced by the charge and water content of the hydrated membrane. In this perspective, we compiled the charge and water contents of approximately 1,000 IEMs reported over the past several decades to assess their range and variability, as well as to reveal gaps and set clear targets for future membrane design. We compared the charge and water content of negatively and positively charged membranes, as well as membranes developed for desalination and energy applications. The majority of IEMs, regardless of structure or intended application, have volumetric charge densities below 3 mol/L[membrane]. This narrow range of charge densities limits the performance of IEMs and contributes to the observed tradeoff between ion throughput and selectivity. It is critical to develop IEMs with higher charge densities to overcome this performance limitation. Further, we highlighted several design strategies that yielded IEMs with fixed charge densities higher than 3 mol/L[membrane]. These strategies provide valuable insights and can guide the design of next-generation IEMs with high charge densities.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Space charge studies on strong hadron cooler energy recovery linac

An Energy Recovery Linac (ERL) based cooler, using Coherent electron Cooling (CeC) is being designed for cooling hadron beams of the Electron-Ion Collider (EIC). The ERL design utilizes highcurrent, high-brightness electron beams with low emittance and a uniform longitudinal distribution for efficient hadron cooling. This is designed to operate in two modes to accommodate cooling requirements for hadron bunches at 100 GeV and 275 GeV, each with an average current of 100 mA and 1 nC bunch charge. With these parameters, the space charge effects become significant in this ERL design due to the low beam energy and high beam current. In this paper, we discuss strategies for including space charge effects in the optics design and implementation of an interface for space charge dominated and non-dominated regions of this ERL lattice.

Accelerator Physics↗
DOE OSTI2024

Tailoring-Orientated Deposition of Li 2 S for Extreme Fast-Charging Lithium–Sulfur Batteries

Precipitation/dissolution of insulating Li 2 S has long been recognized as the rate-determining step in lithium-sulfur (Li-S) batteries, which dramatically undermines sulfur utilization at elevated charging rates. Herein, we present an orientated Li 2 S deposition strategy to achieve extreme fast charging (XFC, ≤15 min) through synergistic control of porosity, electronic conductivity, and anchoring sites of electrode substrate. Via magnesiothermic reduction of a zeolitic imidazolate framework, a nitrogen-doped and hierarchical porous carbon with highly graphitic phase was developed. This design effectively reduces interfacial resistance and ensures efficient sequestration of polysulfides during deposition, leading to (110)-preferred growth of Li 2 S nanocrystalline between (002)-dominated graphitic layers. Our approach directs an alternative Li 2 S deposition pathway to the commonly reported lateral growth and 3D thickening growth mode, ameliorating the electrode passivation. Therefore, a Li-S cell capable of charging/discharging at 5C (12 min) while maintaining excellent cycling stability (82% capacity retention) for 1000 cycles is demonstrated. In conclusion, even under high S loading (8.3 mg cm -2 ) and low electrolyte/sulfur ratio (3.8 mL mg -1 ), the sulfur cathode still delivers a high areal capacity of >7 mAh cm -2 for 80 cycles.

25 ENERGY STORAGE↗
DOE OSTI2025

Photocatalytic Overall Water Splitting at the Integrated Rh–MoRhO x Cluster Heterostructure on InGaN/GaN Nanowires

The quest for efficient solar-driven water splitting, a promising avenue for clean fuel production, faces challenges due to limited solar energy conversion efficiency. Traditional approaches study the overall water splitting as two spatially separate half reactions on two unrelated sites, hindering full utilization of photogenerated charge and water molecules. To overcome these limitations, an integrated cluster heterostructure catalyst on InGaN/GaN semiconductor nanowires is proposed for the effective utilization of photogenerated charge carriers and water molecules on the same redox localization. By establishing the fast charge extraction kinetics based on InGaN/GaN nanowires, the integration of Rh and MoRhOx clusters on the nanowire surface enables simultaneous and fast hydrogen/oxygen evolution reactions at the cluster heterostructure. Furthermore, the integrated strategy can enhance the charge redistribution across the heterostructure between the two clusters, further optimizing adsorption of reaction intermediates on each cluster for boosted photocatalytic water splitting activity. Consequently, the integrated heterostructure triggers a 40-fold increased hydrogen production efficiency in an artificial leaf system. This study provides valuable insights for the rational design of advanced heterostructured photocatalysts for water splitting and beyond.

GaN nanowire↗
DOE OSTI2025

(NH 3 (CH 2 ) 7 NH 3 ) 2 Sn 3 I 10 , a Vacancy-Ordered Three-Dimensional Tin(II) Perovskite-Derived Semiconductor

Ordering vacancies in hybrid Sn(II) halide semiconductors provides a strategy for preventing uncontrolled oxidation and formation of mobile holes. In this study, we report the structure and optical and electronic properties of (NH 3 (CH 2 ) 7 NH 3 ) 2 Sn 3 I 10 , a vacancy-ordered perovskite derivative with three-dimensional inorganic connectivity. The crystal structure resembles that of a Dion–Jacobson layered perovskite derivative, but with [SnI 5 ] square pyramids bridging the layers. UV–vis diffuse reflectance spectroscopy reveals a sharp onset of light absorption at 1.86(1) eV with the photoluminescence emission maximum at 1.90(1) eV. However, the maximum excitation occurs from 3.42 to 3.81 eV (325 to 370 nm), revealing a significant Stokes shift of 1.3 eV. The electronic properties determined from dark and time-resolved microwave conductivity measurements reveal a minimum carrier mobility of 4.3 × 10 –2 cm 2 V –1 s –1 and a maximum carrier density of 5.96 × 10 16 cm –3 , a uniquely low value for a hybrid Sn(II) halide semiconductor. The transport behavior in combination with first-principles calculations of the electronic band structure and dielectric permittivity suggest polaron-mediated electronic transport, yet the photogenerated carriers have a fast and fluence-dependent nonradiative recombination rate, suggestive of localized “defect-like” states at the band edge. The observed photoluminescence is most consistent with single-ion-like behavior of an asymmetric Sn(II) environment. Together, these results suggest that defect ordering presents a strategy for the reduction of mobile charge carriers at equilibrium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Strategies on How to Manage Battery Heat Under Fast Charge Conditions

Improvements to battery design often focus on the energy density of the active material and/or utilization of the available active material. Optimizing thermal management design at the cell-level and/or the pack level is key to accomplishing mission-relevant battery design. Measurement of heat signatures at each level helps inform manufacturing at the design, production, and characterization phases. Understanding thermal limitations allows end users to make well-informed decisions on design of durable and safe battery packs.

battery↗
DOE OSTI2021

Grid Voltage Control Analysis for Heavy-Duty Electric Vehicle Charging Stations

This paper presents an analysis of grid voltage control strategies for heavy-duty electric vehicle charging stations. The performance of three voltage control approaches—including power factor control, standardized volt-volt ampere reactive (VAR) curve control, and customized volt-VAR curve control—are investigated and evaluated for three different sizes of charging stations, including a single-port charging station, a midsized three-port charging station, and six-port travel center. The charging stations are placed on multiple locations of four different types of distribution systems to obtain a comprehensive performance analysis of the voltage control approaches under different scenarios. To quantitively compare the performance of the three voltage control approaches, a series of metrics are designed to quantify the performance and contribute to the comprehensive analysis.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Grid Voltage Control Analysis for Heavy-Duty Electric Vehicle Charging Stations: Preprint

This paper presents an analysis of voltage control strategies for heavy duty electric vehicle (EV) charging stations. The performance of three voltage control approaches including power factor control, preset volt-var curve control, and customized volt-var curve control, have been investigated and evaluated for three different sizes of charging stations, including single-port small charging station, three-port middle size charging station, and 6-port travel center. The charging stations have been placed on various locations of four different types of distribution systems, to obtain a comprehensive performance analysis of the three voltage control approaches under different scenarios. To quantitively compare the performance of the three voltage control approaches, a series of metrics have been designed to quantify the performance and contribute to the comprehensive analysis summary.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Long-lived charge separation in two-dimensional ligand-perovskite heterostructures

Rational design of heterojunctions using nanostructured materials is a useful strategy for achieving efficient interfacial charge separation in photovoltaics. Heterojunctions can be constructed between organic ligands and inorganic layer in two-dimensional (2D) perovskites, taking advantage of their highly programmable structures. We investigate electron and hole transfer at the interface between the thiophene-based semiconducting ligands and the lead halide inorganic sublattices using time-resolved photoluminescence and transient reflection spectroscopy in single 2D perovskite crystals. Here, these measurements demonstrate charge transfer time of ~ 10 ps and long-lived charge-separated state over the nanosecond timescale in 2D ligand-perovskite heterostructures. The efficient charge transfer processes with slow charge recombination suggest the potential for improving exciton dissociation and charge transport in 2D perovskite solar cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗