Search NASA⌕ Search

SEARCH · Search NASA

Results for “Chemical Plant”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7

Expert-System Consultant To Operating Personnel

Artificial intelligence aids engineers and technicians in controlling and monitoring complicated systems. Operations Analyst for Distributed Systems (OPERA) software is developmental suite of expert-system computer programs helping engineers and technicians operating from number of computer workstations to control and monitor spacecraft during prelaunch and launch phases of operation. OPERA designed to serve as consultant to operating engineers and technicians. It preprocesses incoming data, using expertise collected from conglomerate of specialists in design and operation of various parts of system. Driven by menus and mouse-activated commands. Modified versions of OPERA used in chemical-processing plants, factories, banks, and other enterprises in which there are distributed-computer systems including computers that monitor or control other computers.

Heard, Astrid E.↗

Fiber-Optic System Would Detect Leaking Liquid H2

Proposed instrument based on optical time-domain reflectometry measures both locations and sizes of leaks in tanks and plumbing storing and transferring liquid hydrogen. Conceived for use in detecting leaks of hydrogen from propulsion system of Space Shuttle, concept applicable to detection of flammable and/or poisonous fumes in chemical-processing plants, fuel-distributing equipment, and other terrestrial applications.

Grove, Charles H.↗

Reflection-Type Oil-Film Skin-Friction Meter

Oil-film skin-friction meter for both flight and wind-tunnel applications uses internal reflection and is self-contained, compact unit. Contained in palm-sized housing, in which source of light, mirrors, and sensor mounted rigidly in alignment. Entire unit mounted rigidly under skin of aircraft or wind tunnel, eliminating any relative vibration between optical elements and skin of aircraft or wind tunnel. Meter primarily applicable to flight and wind-tunnel tests, also used in chemical-processing plants.

Bandyopadhyay, Promode R.↗

Improved Hidden-Markov-Model Method Of Detecting Faults

Method of automated, continuous monitoring to detect faults in complicated dynamic system based on hidden-Markov-model (HMM) approach. Simpler than another, recently proposed HMM method, but retains advantages of that method, including low susceptibility to false alarms, no need for mathematical model of dynamics of system under normal or faulty conditions, and ability to detect subtle changes in characteristics of monitored signals. Examples of systems monitored by use of this method include motors, turbines, and pumps critical in their applications; chemical-processing plants; powerplants; and biomedical systems.

Smyth, Padhraic J.↗

System Measures Loads In Bolts

Improved technique for ultrasonic nondestructive measurement of loads in bolts involves use of pulsed phase-locked loop interferometer. Provides for correction of errors and for automatic readout of loads in bolts. Actual bolt load measured, using transducers rebonded after bolts tightened. Calibration block and thermometer added. Technique applicable to critical fasteners in aerospace applications, nuclear reactors, petroleum and other chemical processing plants, steel bridges, and other structures.

Allison, Sidney G.↗

Hydrogen Annealing Of Single-Crystal Superalloys

Annealing at temperature equal to or greater than 2,200 degrees F in atmosphere of hydrogen found to increase ability of single-crystal superalloys to resist oxidation when subsequently exposed to oxidizing atmospheres at temperatures almost as high. Supperalloys in question are principal constituents of hot-stage airfoils (blades) in aircraft and ground-based turbine engines; also used in other high-temperature applications like chemical-processing plants, coal-gasification plants, petrochemical refineries, and boilers. Hydrogen anneal provides resistance to oxidation without decreasing fatigue strength and without need for coating or reactive sulfur-gettering constituents. In comparison with coating, hydrogen annealing costs less. Benefits extend to stainless steels, nickel/chromium, and nickel-base alloys, subject to same scale-adhesion and oxidation-resistance considerations, except that scale is chromia instead of alumina.

Smialek, James L.↗

Improved Program For Calculation Of Heat-Load Multiplier

PRM1940 computer program computes heat-load multiplier for use in Power Balance Model (PBM) computer program which calculates hundreds of operating parameters of main engine of space shuttle from relatively few measurement data. PRM1940 is stand-alone program which incorporates only those PBM calculations necessary to compute heat-load multiplier. Developed to accelerate and partly automate calculation of heat-load multiplier. Although programs specific to space shuttle application, also of interest to engineers concerned with monitoring of conditions in turbines, chemical-processing plants, and other high-temperature flow machinery.

D'Valentine, Mark↗

Separation and Conditioning of Mars Atmospheric Gases via TSA

Space and planetary exploration almost always presents interesting and unusual engineering challenges. Separations engineering for chemical processes that are critical to humans working in space is no exception. The challenges are becoming clearer as we make the transition from concepts and planning to hardware development, and as we understand better the constraints and environments in which the processes must perform. The coming decade will see a robotic Mars exploration program that has recovered from recent setbacks and is building a knowledge and technology base for human exploration. One of the missions will carry a small chemical pilot plant for demonstrating the manufacture of rocket propellants and life support consumables from the low-pressure (0.01 atm) Martian atmosphere. By manufacturing and storing the fuel and consumables needed for human-return missions in situ, launch mass and landed mass are reduced by tons and missions become far less expensive. The front-end to the pilot plant is a solid-state atmosphere acquisition and separation unit based on temperature-swing adsorption (TSA). The unit produces purified and pressurized (to 1.0 atm) carbon dioxide to downstream reactors that will make methane and oxygen. The unit also produces a nitrogen-argon mixture as a valuable by-product for life support, inflatable structures, and propellant pressurization. With nighttime temperatures falling to -100 degrees C, power availability restricted to a few watts, and flawless operation critical to success, the dusty Martian surface is a difficult place to operate a remote plant. This talk will focus on how this TSA separation process is designed and implemented for this application, and how it might be used in the more distant future for human exploration.

Finn, John E.↗

Exhaustive Thresholds and Resistance Checkpoints

Once deployed, all intricate systems that operate for a long time (such as an airplane or chemical processing plant) experience degraded performance during operational lifetime. These can result from losses of integrity in subsystems and parts that generally do not materially impact the operation of the vehicle (e.g., the light behind the button that opens the sliding door of the minivan). Or it can result from loss of more critical parts or subsystems. Such losses need to be handled quickly in order to avoid loss of personnel, mission, or part of the system itself. In order to manage degraded systems, knowledge of its potential problem areas and the means by which these problems are detected should be developed during the initial development of the system. Once determined, a web of sensors is employed and their outputs are monitored with other system parameters while the system is in preparation or operation. Just gathering the data is only part of the story. The interpretation of the data itself and the response of the system must be carefully developed as well to avoid a mishap. Typically, systems use a test-threshold-response paradigm to process potential system faults. However, such processing sub-systems can suffer from errors and oversights of a consistent type, causing system aberrant behavior instead of expected system and recovery operations. In our study, we developed a complete checklist for determining the completeness of a fault system and its robustness to common processing and response difficulties.

Easton, Charles↗

Miniature Distillation Column for Producing LOX From Air

The figure shows components of a distillation column intended for use as part of a system that produces high-purity liquid oxygen (LOX) from air by distillation. (The column could be easily modified to produce high-purity liquid nitrogen.) Whereas typical industrial distillation columns for producing high-purity liquid oxygen and/or nitrogen are hundreds of feet tall, this distillation column is less than 3 ft (less than about 0.9 m) tall. This column was developed to trickle-charge a LOX-based emergency oxygen system (EOS) for a large commercial aircraft. A description of the industrial production of liquid oxygen and liquid nitrogen by distillation is prerequisite to a meaningful description of the present miniaturized distillation column. Typically, such industrial production takes place in a chemical processing plant in which large quantities of high-pressure air are expanded in a turboexpander to (1) recover a portion of the electrical power required to compress the air and (2) partially liquefy the air. The resulting two-phase flow of air is sent to the middle of a distillation column. The liquid phase is oxygen-rich, and its oxygen purity increases as it flows down the column. The vapor phase is nitrogen-rich and its nitrogen purity increases as it flows up the column. A heater or heat exchanger, commonly denoted a reboiler, is at the bottom of the column. The reboiler is so named because its role is to reboil some of the liquid oxygen collected at the bottom of the column to provide a flow of oxygen-rich vapor. As the oxygen-rich vapor flows up the column, it absorbs the nitrogen in the down-flowing liquid by mass transfer. Once the vapor leaves the lower portion of the column, it interacts with down-flowing nitrogen liquid that has been condensed in a heat exchanger, commonly denoted a condenser, at the top of the column. Liquid oxygen and liquid nitrogen products are obtained by draining some of the purified product at the bottom and top of the column, respectively. Because distillation is a mass-transfer process, the purity of the product(s) can be increased by increasing the effectiveness of the mass-transfer process (increasing the mass-transfer coefficient) and/or by increasing the available surface area for mass transfer through increased column height. The diameter of a distillation column is fixed by pressure-drop and mass-flow requirements. The approach taken in designing the present distillation column to be short yet capable of yielding a product of acceptably high purity was to pay careful attention to design details that affect mass-transfer processes.

Rozzi, Jay C.↗

Integrated Optoelectronics for Parallel Microbioanalysis

Miniature, relatively inexpensive microbioanalytical systems ("laboratory-on-achip" devices) have been proposed for the detection of hazardous microbes and toxic chemicals. Each system of this type would include optoelectronic sensors and sensor-output-processing circuitry that would simultaneously look for the optical change, fluorescence, delayed fluorescence, or phosphorescence signatures from multiple redundant sites that have interacted with the test biomolecules in order to detect which one(s) was present in a given situation. These systems could be used in a variety of settings that could include doctors offices, hospitals, hazardous-material laboratories, biological-research laboratories, military operations, and chemical-processing plants.

Stirbl, Robert↗

Domestic and International Standards for Nuclear Criticality Safety – Overview and Status

The domestic and international consensus standards for nuclear criticality safety (NCS) have provided guidance for staff performing hands-on work in operations with fissionable materials. These consensus standards have contributed directly to the significant reduction in the rate of criticality accidents in process facilities since the 1940s. The last known criticality accident inside the United States was in 1978 (nearly 43 years ago) at the Idaho Chemical Processing Plant, and outside the United States, an accident occurred at Tokai-mura, Japan, in 1999 (23 years ago). The domestic consensus standards for NCS include the American Nuclear Society (ANS) standards. The ANS Standards Board, the NCS Consensus Committee, and the ANS-8 Subcommittee oversee the development and maintenance of these standards. There are currently eighteen standards in the ANS-8 series. Currently, there are six ANS-8 standards in revision mode and eleven in a maintenance mode with one new standard under development. The international consensus standards for NCS calculations, procedures, and practices are maintained and developed within the International Organization for Standardization (ISO), Technical Committee 85 on Nuclear Energy, Subcommittee 5 on Nuclear Fuel Technology, and Working Group 8, “Nuclear Criticality Safety.” Eleven standards are currently available, three standards are in revision mode, and two standards are development. This paper provides the NCS community with an overview and status report of domestic and international NCS consensus standards to stimulate interest and to support their continued development.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Domestic and International Standards for Nuclear Criticality Safety - Overview & Status [Abstract]

The domestic and international consensus standards for nuclear criticality safety (NCS) have provided guidance for staff performing hands-on work in operations with fissionable materials. These consensus standards have contributed directly to the significant reduction in the rate of criticality accidents in process facilities since the 1940s. The last known criticality accident inside the United States was in 1978 (nearly 43 years ago) at the Idaho Chemical Processing Plant, and outside the United States, an accident occurred at Tokai-mura, Japan, in 1999 (22 years ago). The domestic consensus standards for NCS include the American Nuclear Society (ANS) standards. The ANS Standards Board, the NCS Consensus Committee, and the ANS-8 Subcommittee oversee the development and maintenance of these standards. There are currently eighteen standards in the ANS-8 series. Currently, there are six ANS-8 standards in re- vision mode and eleven in a maintenance mode with one new standard under development. The international consensus standards for NCS calculations, procedures, and practices are maintained and developed within the International Organization for Standardization, Technical Committee 85 on Nuclear Energy, Subcommittee 5 on Nuclear Fuel Technology, and Working Group 8, “Nuclear Criticality Safety.” Eleven standards are currently available, three standards are in revision mode, and two standards are development. This paper provides the NCS community with an overview and status report of domestic and international NCS consensus standards to stimulate interest and to support their continued development.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Domestic and International Consensus Standards for Nuclear Criticality Safety - Overview & Status

The domestic and international consensus standards for nuclear criticality safety (NCS) were developed based on the lessons-learned from process criticality accidents. These consensus standards were developed to reduce the rate of process criticality accidents in facilities that process, store, handle, or transport fissionable materials by hand. After a significant increase in criticality accidents through the mid-1960s, the rate of criticality accidents decreased as a result of these standards, and the criticality accident rate is extremely low from an industrial safety perspective. The last known criticality accident inside the United States was in 1978 (nearly 47 years ago) at the Idaho Chemical Processing Plant, and outside the United States, an accident occurred at Tokai-mura, Japan, in 1999 (almost 26 years ago). The domestic consensus standards for NCS include the American National Standards (ANS) that are prepared and published by the American Nuclear Society and approved by the American National Standards Institute (ANSI). The ANS Standards Board, the NCS Consensus Committee, and the ANS-8 Subcommittee oversee the development and maintenance of these standards. There are currently 18 standards in the ANS-8 series. Nine ANS-8 standards are either in revision mode or planned for revision. A new standard for the use of nondestructive assay measurements (ANSI/ANS-8.28-2024) for NCS was approved in March of 2024. The international consensus standards for NCS calculations, procedures, and practices are maintained and developed within the International Organization for Standardization, Technical Committee 85 “Nuclear Energy,” Subcommittee 5, “Nuclear Fuel Technology,” and Working Group 8, “Nuclear Criticality Safety.” Eleven standards are currently available, four standards are proposed for revision, and four standards are at various stages of development. This paper provides the NCS community with a high-level overview and status report of domestic and international NCS consensus standards to stimulate interest and to support their continued development.

Bowen, Douglas G [ORNL] (ORCID:0000000212460026)↗

Integrating Cybersecurity Risk Assessment with Process Safety in Chemical Process Industries

This dissertation bridges the gap between industrial cybersecurity and traditional process safety by introducing an integrated Cyber-LOPA framework that combines the Purdue Enterprise Reference Architecture, Cyber Kill Chain, and CVSS v4.0 metrics. Demonstrated on a High-Density Polyethylene slurry process, the work illustrates how cyber threats targeting automation systems can bypass physical protection layers, proving the necessity of unified risk assessments to prevent cyber-induced physical incidents in chemical manufacturing plants.

Cyber-LOPA (CLOPA)↗

Final Report – Cooperative Research and Development Agreement between National Energy Technology Laboratory and Praxair, Inc.

Praxair and DOE-NETL entered into a collaborative research and development agreement (CRADA) in March 2019 to evaluate economic viability of chemical looping processes for hydrogen, CO, and syngas production in comparison to state-of-the-art conventional processes. Praxair had developed process configurations for producing hydrogen and CO using chemical looping processes. NETL had modeling and system design experience for the chemical looping reactor system. The goal for NETL is to provide performance and design information regarding the chemical looping portion of a potential commercial plant. Praxair’s goal is to evaluate chemical looping processes and try to identify a process that can be commercially relevant within a few years. A key to success for the program will be to develop a chemical looping reactor system that enables significant capital cost reduction and performance improvement for the overall process. This report describes chemical looping-based CO production process, chemical looping reactor system and oxygen carrier material as well as summary of technoeconomic analysis results. Also included in the report are a list of assumptions that were used for designing the chemical looping plant and a list of areas for further study required to validate some of these assumptions in future efforts. The initial goal was to design two chemical looping plants. Case 1 would produce 1 MM scfd Hydrogen from NG, and Case 2 would co-produce hydrogen and 5 MM scfd CO from NG. However, later in the collaboration, it was decided to drop Case 1 as Case 2 process already included hydrogen production.

Bayham, Samuel↗

Application of a reversible chemical reaction system to solar thermal power plants

Three distributed dish solar thermal power systems using various applications of SO2/SO3 chemical energy storage and transport technology were comparatively assessed. Each system features various roles for the chemical system: (1) energy storage only, (2) energy transport, or (3) energy transport and storage. These three systems were also compared with the dish-Stirling, using electrical transport and battery storage, and the central receiver Rankine system, with thermal storage, to determine the relative merit of plants employing a thermochemical system. As an assessment criterion, the busbar energy costs were compared. Separate but comparable solar energy cost computer codes were used for distributed receiver and central receiver systems. Calculations were performed for capacity factors ranging from 0.4 to 0.8. The results indicate that SO2/SO3 technology has the potential to be more cost effective in transporting the collected energy than in storing the energy for the storage capacity range studied (2-15 hours)

Hanseth, E. J.↗

10 MWE CDCL Large Pilot Plant – pre-FEED Study (Final Report)

The Following Document is the Final Technical Scientific Report for the project tittle “10 MWE CDCL Large Pilot Plant – pre-FEED Study” performed by The Babcock & Wilcox Company in collaboration with The Ohio State University, Johnson & Matthey, The Electric Power Research Institute, and the Dover Light & Power Municipal Power Plant. The project Team performed a pre-Front End Engineering Design study of a 10 MWe Coal-Direct Chemical Looping power plant to be hosted at the Dover Light & Power Municipal Plant. As part of the pre-FEED study, the project Team performed multiple pilot test campaigns to obtain design and performance information at the 250 kWth CDCL pilot facility at the Babcock & Wilcox Company’s Research Center. The Techno-Economic analysis was updated based on the FEED study and the pilot tests results. The study shows that the CDCL process is a promising carbon-friendly technology capable of producing electricity with a high efficiency with a cost of electricity of $83.3 / MWh, which corresponded to less than 30% increase in cost of electricity compared to the cost of electricity of a base case study of a supercritical PC boiler.

01 COAL, LIGNITE, AND PEAT↗