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At least 127 records · Page 7

Chronic Lunar Dust Exposure on Rat Cornea: Evaluation by Gene Expression Profiling

Lunar dust is capable of entering habitats and vehicle compartments by sticking to spacesuits or other objects that are transferred into the spacecraft from the lunar surface and has been reported to cause irritation upon exposure. During the Apollo missions, crewmembers reported irritation specifically to the skin and eyes after contamination of the lunar and service modules. It has since been hypothesized that ocular irritation and abrasion might occur as a result of such exposure, impairing crew vision. Recent work has shown that both ultrafine and unground lunar dust exhibited minimal irritancy of the ocular surface (i.e., cornea); however, the assessment of the severity of ocular damage resulting from contact of lunar dust particles to the cornea has focused only on macroscopic signs of mechanical irritancy and cytotoxicity. Given the chemical reactive properties of lunar dust, exposure of the cornea may contribute to detrimental effects at the molecular level including but not limited to oxidative damage. Additionally, low level chronic exposures may confound any results obtained in previous acute studies. We report here preliminary results from a tissue sharing effort using 10‐week‐old Fischer 344 male rats chronically exposed to filtered air or jet milled lunar dust collected during Apollo 14 using a Jaeger‐NYU nose‐only chamber for a total of 120 hours (6 hours daily, 5 days a week) over a 4‐week period. RNA was isolated from corneas collected from rats at 1 day and 7 days after being exposed to concentrations of 0, 20, and 60 mg/m3 of lunar dust. Microarray analysis was performed using the Affymetrix GeneChip Rat Genome 230 2.0 Array with Affymetrix Expression Console and Transcriptome Analysis Console used for normalization and secondary analysis. An Ingenuity iReport"TM" was then generated for canonical pathway identification. The number of differentially expressed genes identified increases with dose compared to controls suggesting a more severe response to the lunar dust insult at higher levels. Pathways of interests that have been identified in all exposed samples include oxidative stress response, mitochondrial dysfunction, fibrosis, epithelial healing, TGF-Beta signaling, and extracellular matrix remodeling. Several biological processes related to cell migration, cellular proliferation, and eye development were also identified to be altered by exposure to lunar dust. Our preliminary results suggest that even a chronic insult of lunar dust as low as 20 mg/m(exp 3) elicits a molecular response in cornea tissue. Lunar dust on the surface of the moon would have the added properties of ionization and activation potentially leading to further damage to the cornea and greater sensitivity to any other environmental insult such as exposure to radiation. Additional studies are required to fully assess the risk of vision impairment and the mechanistic responses initiated in cornea exposed to lunar dust as well as the potential for long‐term effects to astronaut health

Theriot, C. A.↗

Assessment of MODIS On-Orbit Calibration Using a Deep Convective Cloud Technique

The MODerate Resolution Imaging Spectroradiometer (MODIS) sensors onboard Terra and Aqua satellites are calibrated on-orbit with a solar diffuser (SD) for the reflective solar bands (RSB). The MODIS sensors are operating beyond their designed lifetime and hence present a major challenge to maintain the calibration accuracy. The degradation of the onboard SD is tracked by a solar diffuser stability monitor (SDSM) over a wavelength range from 0.41 to 0.94 micrometers. Therefore, any degradation of the SD beyond 0.94 micrometers cannot be captured by the SDSM. The uncharacterized degradation at wavelengths beyond this limit could adversely affect the Level 1B (L1B) product. To reduce the calibration uncertainties caused by the SD degradation, invariant Earth-scene targets are used to monitor and calibrate the MODIS L1B product. The use of deep convective clouds (DCCs) is one such method and particularly significant for the short-wave infrared (SWIR) bands in assessing their long-term calibration stability. In this study, we use the DCC technique to assess the performance of the Terra and Aqua MODIS Collection-6 L1B for RSB 1 3- 7, and 26, with spectral coverage from 0.47 to 2.13 micrometers. Results show relatively stable trends in Terra and Aqua MODIS reflectance for most bands. Careful attention needs to be paid to Aqua band 1, Terra bands 3 and 26 as their trends are larger than 1% during the study time period. We check the feasibility of using the DCC technique to assess the stability in MODIS bands 17-19. The assessment test on response versus scan angle (RVS) calibration shows substantial trend difference for Aqua band 1between different angles of incidence (AOIs). The DCC technique can be used to improve the RVS calibration in the future.

Mu, Qiaozhen↗

Assessing the Calibration Differences in the Reflective Solar Bands of Terra MODIS and Landsat-7 Enhanced Thematic Mapper Plus

Long-term data records obtained from Earth observing sensors depend not only onthe calibration accuracy of individual sensors but also on the consistency across instruments andplatforms. Hence, sensor calibration intercomparison plays a vital role for a better understandingof various science products. The Moderate Resolution Imaging Spectroradiometer (MODIS)and enhanced thematic mapper plus (ETM+) on the Terra and Landsat 7 platforms have operatedsuccessfully since their launch, collecting measurements in the reflective solar and infrared partsof the spectrum. Terra MODIS has employed a reflectance-based calibration since beginning itsmission. In the case of ETM+, a radiance-based calibration was employed until recent years,when a reflectance-based calibration was introduced. Being in the AM constellation with lessthan 30 min difference in overpass times, near-simultaneous Earth scene measurements can beeffectively used to assess the calibration differences between the spectrally matching bands ofthese two instruments. The pseudoinvariant calibration sites (PICS) in the North African desertare widely used for on-orbit calibration and validation of satellite sensors. Four PICS from thisregion have been employed to assess the multitemporal reflectance differences. Correction forbidirectional reflectance, spectral response function mismatch, and impacts of atmosphericwater-vapor have been incorporated to provide an assessment of the long-term stability ofeach spectral band and reflectance differences amongst them. Results indicate that the spectralbands of both instruments show a long-term stability to within 2% from 2000 to 2017. Thetop-of-atmosphere reflectances between the two instruments postcorrection agree to within 4%.Also included in this paper is a detailed discussion of various parameters contributing to theuncertainties of this cross-calibration. The techniques presented in this paper can be furtherextended to perform similar intercomparison between Landsat 8 Operational Land Imager, AquaMODIS, and Suomi-NPP VIIRS.

Angal, Amit↗

An Analysis of Spatio-Temporal Relationship between Satellite-Based Land Surface Temperature and Station-Based Near-Surface Air Temperature over Brazil

A better understanding of the relationship between land surface temperature (Ts) and near-surface air temperature (Ta) is crucial for improving the simulation accuracy of climate models, developing retrieval schemes for soil and vegetation moisture, and estimating large-scale Ta from satellite-based Ts observations. In this study, we investigated the relationship between multiple satellite-based Ts products, derived from the Atmospheric Infrared Sounder (AIRS) and the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard Aqua satellite, and Ta from 204 meteorological stations over Brazil during 2003–2016. Monthly satellite-based Ts products used in this study include: (1) AIRS Version 6 with 1° spatial resolution, (2) AIRS Version 7 with 1° spatial resolution, (3) MODIS Collection 6 with 0.05° spatial resolution, and (4) MODIS Collection 6 with 1° spatial resolution re-sampled from (3) for a direct comparison with AIRS products. We found that satellite-based Ts is lower than Ta over the forest area, but higher than Ta over the non-forest area. Nevertheless, the correlation coefficients (R) between monthly Ta and four Ts products during 2003–2016 are greater than 0.8 over most stations. The long-term trend analysis shows a general warming trend in temperatures, particularly over the central and eastern parts of Brazil. The satellite products could also observe the increasing Ts over the deforestation region. Furthermore, we examined the temperature anomalies during three drought events in the dry season of 2005, 2010, and 2015. All products show similar spatio-temporal patterns, with positive temperature anomalies expanding in areal coverage and magnitude from the 2005 to 2015 event. The above results show that satellite-based Ts is sensitive in reflecting environmental changes such as deforestation and extreme climatic events, and can be used as an alternative to Ta for climatological studies. Moreover, the observed differences between Ts and Ta may inform how thermal assumptions can be improved in satellite-based retrievals of soil and vegetation moisture or evapotranspiration.

land surface temperature↗

Organic Matter Concentration and Composition in November 2021 and April 2022 from 12 Streams Impacted by the 2020 Holiday Farm Fire (v2)

This dataset represents results from a field study aiming to understand storm induced transport of pyrogenic materials to streams impacted by varying degrees of burn severity. Time series samples were collected at 5 sites within the McKenzie River Watershed (Oregon, USA) whose catchment were each completely engulfed by the 2020 Holiday Farm Fire. An additional 7 sites were sampled once during the storm. The samples were collected during storm events in November 2020, January 2021, November 2021, and April 2022. Samples were characterized for benezenepolycarboxylic acids (BPCA), ultra-high resolution mass spectrometry, dissolved organic carbon and optics (absorbance and fluorescence). Fourier-transform ion cyclotron resonance mass spectrometry (FTICR) and dissolved organic carbon data from the November 2020 (referred to as “EWEB_2020”) sampling can be found in a separate data package (doi: 10.15485/1869708). NOTE: The 2020 samples were run on FTICR-MS in two unique instances. The first run can be found in the previous data package (EWEB_2020). The second run is included in this data package. These samples were run for a second time so that the data were more directly interoperable with the other samples in this data package. We have not done any investigation into the differences/similarities between these datasets and the previously ran/published data in the other data package. This data package was originally published in November 2024. It was updated in April 2025 (v2; new and modified files). See the change history section below for more details. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. This dataset contains (1) file-level metadata; (2) data dictionary; (3) data package readme; (4) metadata; (5) methods information; (6) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data; (7) excitation emission matrix (EEM) methods; and (8) a sub-folder with processed EEM data (9) benzene polycarboxylic acid (BPCA) concentration data; (10) Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) methods; and (11) folder of high-resolution characterization of organic matter via 12 Tesla FTICR-MS generated through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory). The EEMs sub-folder contains two additional folders; the Absorbance and Fluorescence folders which contain the processed EEMs absorbance and fluorescence data respectively. This package contains the following file types: csv, xml, pdf.

54 ENVIRONMENTAL SCIENCES↗

Structural Investigation of Six Quinary Sulfides Synthesized via the Flux-Assisted Boron-Chalcogen Mixture (BCM) Method: Eu 2+ Containing Members of the RE 3 MTQ 7 (M and T = Transition or Main Group Metals, Q = Chalcogens) Family

For this work, a series of six quinary rare-earth sulfides Ce 4+ 1.85 Eu 2+ 1.15 Na 0.30 SiS 7 , Ce 4+ 1.91 Eu 2+ 1.09 K 0.18 SiS 7 , Ce 4+ 1.96 Eu 2+ 1.04 Rb 0.08 SiS 7 , Ce 4+ 1.98 Eu 2+ 1.02 Cs 0.05 SiS 7 , Ce 4+ 1.97 Eu 2+ 1.03 Ag 0.06 SiS 7 , and Ce 4+ 1.50 Eu 2+ 1.50 CuSiS 7 were obtained in an alkali iodide flux using the boron-chalcogen mixture (BCM) method. Single crystal X-ray diffraction was used to determine the structures of the high quality single crystals that were grown; their elemental compositions were confirmed by energy-dispersive spectroscopy (EDS). The compounds crystallize in the hexagonal crystal system in the noncentrosymmetric space group P63. The crystal structure consists of a three-dimensional network composed of mixed cerium and europium bicapped trigonal prisms, isolated SiS4 tetrahedra, and monovalent metals (Na, K, Rb, Cs, Ag, and Cu) located in cavities created by linked Ce/EuS 8 polyhedra. The structures are charge-balanced when Ce and Eu are in their +4 and +2 oxidation states, respectively. The effective magnetic moment of Ce 1.50 4+ Eu 1.50 2+ CuSiS 7 determined from the temperature dependence of the magnetic susceptibility data is consistent with the presence of Ce 4+ and Eu 2+ . Clear correlations between the alkali ion site occupancy, the ionic radius of the alkali cations, and the average bond length of Ce 4+ /Eu 2+ –S, were established. UV–vis diffuse reflectance data were collected for Ce 1.50 4+ Eu 1.50 2+ CuSiS 7 and a band gap of 1.9(1) eV was established.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Alpha-particle sensitive test SRAMs

A bench-level test is being developed to evaluate memory-cell upsets in a test SRAM designed with a cell offset voltage. This offset voltage controls the critical charge needed to upset the cell. The effect is demonstrated using a specially designed 2-micron n-well CMOS 4-kb test SRAM and a Po-208 5.1-MeV 0.61-LET alpha-particle source. This test SRAM has been made sensitive to alpha particles through the use of a cell offset voltage, and this has allowed a bench-level characterization in a laboratory setting. The experimental data are linked to a alpha-particle interaction physics and to SPICE circuit simulations through the alpha-particle collection depth. The collection depth is determined by two methods and found to be about 7 micron. In addition, alpha particles that struck outside the bloated drain were able to flip the SRAM cells. This lateral charge collection was observed to be more than 6 micron.

Buehler, M. G.↗

Very High Cycle Fatigue Testing of AMS 6308 Steel

Lightweight and reliable gearboxes are required for helicopters and future electrical vertical take-off and landing aircraft. Mechanical gears in these applications experience more than 10 7 million fatigue cycles over their operating life and between maintenance intervals. Fatigue data for gear steels above 10 7 cycles is rare due to the testing time required to reach these cycle counts with traditional methods. In this paper, ultrasonic fatigue testing is used to collect mechanical fatigue data on AMS 6308 steel in the 10 7 to 1010 cycle regime.

Thomas Tallerico↗

Review of top quark mass measurements in CMS

The top quark mass is one of the most intriguing parameters of the standard model (SM). Its value indicates a Yukawa coupling close to unity, and the resulting strong ties to Higgs physics make the top quark mass a crucial ingredient for understanding essential aspects of the electroweak sector of the SM. This review offers the first comprehensive overview of the top quark mass measurements performed by the CMS Collaboration using the data collected at centre-of-mass energies of 7, 8, and 13 TeV. Moreover, a detailed description of the top quark event reconstruction is provided and dedicated studies of the dominant uncertainties in the modelling of the signal processes are discussed. The interpretation of the experimental results on the top quark mass in terms of the SM Lagrangian parameter is challenging and is a focus of an ongoing discussion in the theory community. The CMS Collaboration has performed two main types of top quark mass measurements, addressing this challenge from different perspectives: highly precise ‘direct’ measurements, based on reconstructed top quark decay products and relying exclusively on Monte-Carlo simulations, as well as ‘indirect’ measurements, where the simulations are employed to determine parton-level cross sections that are compared to fixed-order perturbative calculations. Recent mass extractions using Lorentz-boosted top quarks open a new avenue of measurements based on top quark decay products contained in a single particle jet, with promising prospects for accurate theoretical interpretations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Solvation Structure of 237 Np 4+ in a Noncomplexing Environment

Here, the solvation structure of an Np 4+ ion in an aqueous, noncomplexing and nonoxidizing environment of trifluoromethanesulfonic (triflic) acid was investigated with X-ray absorption spectroscopy (XAS) combined with ab initio molecular dynamics (AIMD) and time-dependent density functional theory (TDDFT) calculations. Np L III -edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) data were collected for Np 4+ in 1, 3, and 7 M triflic acid using a laboratory-scale spectrometer and separately at a synchrotron facility, producing data sets in excellent agreement. TDDFT calculations revealed a weak pre-edge feature not previously reported for Np L III -edge XANES. AIMD modeling results showed differences in the hydration shell of the Np 4+ ion at different concentrations of triflic acid; these results are supported by the experiment. EXAFS fit models to the experiment resulted in similar coordination of Np 4+ in noncomplexing aqueous media as reported in the literature for 1 M perchloric acid but, together with calculations, revealed more than one distance between Np and O atoms in 7 M triflic acid. These results imply monodentate coordination with sulfonate groups in 7 M triflic acid and suggest the possibility of proto-neptunyl species in relatively low-concentration Np 4+ acid solutions.

Boglaienko, Daria V. [Pacific Northwest National L↗

Centaur zero gravity coast and engine restart demonstration on the Titan/Centaur (TC-2) extended mission

The Centaur propellant management and thermal control techniques required for zero gravity coasting were successfully demonstrated during an extended mission following spacecraft separation on the TC-2 flight. As part of the demonstration, two successful engine starts were accomplished. The first engine start followed a one-hour zero gravity coast, and the second engine start followed a three-hour zero gravity coast. All of the Centaur systems performed satisfactorily, the design parameters for zero gravity coasting were verified, and no significant problems were encountered. The flight results showed that the propellant location and behavior, propellant heating, and tank pressure rise rates observed during the zero-gravity coasts were less severe than expected. Consequently, the majority of the propellants remained at the tank bottom, the propellant collection times were very short, and more than 7 hours of coast could have been achieved before a tank venting was required. The tank pressurization prior to the engine starts provided boost pump Net Positive Suction Head values well in excess of the values required. The LO2 tank pressurization was accomplished by a new bubbler method that greatly reduced the helium usage.

Lacovic, R. F.↗

Seasonal variations of the microwave scattering properties of deciduous trees as measured in the 1-18 GHz spectral range

The author has identified the following significant results. Employing two FM-CW radar spectrometers, scattering data were acquired from stands of deciduous trees during the spring and autumn. The data suggest that the trees act as a volume scatter target particularly in the 7-18 GHz region. A comparison of data collected in spring and autumn indicates that the radar scattering coefficient, sigma deg, as measured in spring can be substantially larger (as much as 10 dB) than sigma deg as measured in the autumn.

Ulaby, F. T.↗

Regolith reworking at Shorty Crater

Nuclear track densities in olivine grains from seventeen different locations within the top 7 cm of the double drive 74002-74001 collected at Shorty Crater were obtained. The track densities indicate significant reworking of the soil only to a depth of 4 cm. Allowing for 2 cms of missing material (Fruchter et al., 1978), this corresponds to a 6 cm reworking depth during the last 10 m.y. (when the material was presumably emplaced).

Crozaz, G.↗

Asteroid 2008 TC3 Breakup and Meteorite Fractions

The recovery of meteorites from the impact of asteroid 2008 TC3 in the Nubian Desert of Sudan on October 7, 2008, marked the first time meteorites were collected from an asteroid observed in space by astronomical techniques before impacting. Search teams from the University of Khartoum traced the location of the strewn field and collected about 660 meteorites in four expeditions to the fall region, all of which have known fall coordinates. Upon further study, the Almahata Sitta meteorites proved to be a mixed bag of mostly ureilites (course grained, fine grained, and sulfide-metal assemblages), enstatite chondrites (EL3-6, EH3, EH5, breccias) and ordinary chondrites (H5-6, L4-5). One bencubbinite-like carbonaceous chondrite was identified, as well as one unique Rumuruti-like chondrite and an Enstatite achondrite. New analysis: The analysed meteorites so far suggest a high 30-40 percent fraction of non-ureilites among the recovered samples, but that high fraction does not appear to be in agreement with the meteorites in the University of Khartoum (UoK) collection. Ureilites dominate the meteorites that were recovered by the Sudanese teams. To better understand the fraction of recovered materials that fell to Earth, a program has been initiated to type the meteorites in the UoK collection in defined search areas. At this meeting, we will present some preliminary results from that investigation.

Goodrich, C.↗

Insights From Routine Microbiological Monitoring of Air in Astromaterials Curation Cleanrooms

NASA maintains nine separate cleanrooms at the Johnson Space Center to curate and preserve astromaterials samples. Routine microbial monitoring of the surfaces in these cleanrooms began in 20181. Until recently, materials compatibility requirements prevented monitoring airborne biological particles in all but one of these cleanrooms. New astromaterials collections from carbon rich asteroids are more susceptible to biological degradation than previous collections. Therefore, it is important to monitor the bioburden in the air and on surfaces in these labs. Establishing a comprehensive microbial monitoring program will help inform the monitoring and curation plans for Mars sample return which will include samples that are extremely biologically sensitive. In April of 2022 we began routinely collecting air samples in seven of the nine curation cleanrooms (Meteorite ISO 7 equivalent, Lunar ISO 6 equivalent, Stardust, Hayabusa2, OSIRIS-REx ISO 5 equivalent, and Genesis ISO 4 equivalent) using a sampling device that collects airborne biological particles on an electret filter instead conventional sampler that collect cells in a liquid media or onto organic rich Petri dishes. Electret is a generic term for electrostatically charged media. The charge on these materials increases particle trapping when compared to non-charged filters of similar thickness. N95 respirators also use electret filters. This dry sample collection method allows us to meet materials requirements for all the curation labs and reduces the risk of inadvertently introducing contamination as part of our monitoring effort. This method also allows us to preserve a portion of each sample for DNA extraction and next generation sequencing. DNA sequencing helps us to characterize the portion of the cleanroom microbiome that we cannot culture. We will present the results of our first 8 months of monitoring, compare these results to particle counts in the labs and to measurements made directly onto Petri dishes when possible. We will also make recommendations for modifications to the sampling method to improve sampling efficiency and preserve diversity.

A. B. Regberg↗

All Sky Search for Gravitational-Wave Bursts in the Second Joint LIGO-Virgo Run

We present results from a search for gravitational-wave bursts in the data collected by the LIGO and Virgo detectors between July 7, 2009 and October 20, 2010: data are analyzed when at least two of the three LIGO-Virgo detectors are in coincident operation, with a total observation time of 207 days. The analysis searches for transients of duration approx. < 1 s over the frequency band 64-5000 Hz, without other assumptions on the signal wa.veform, polarization, direction or occurrence time. All identified events are c.onsistent with the expected accidental background. We set frequentist upper limits on the rate of gravitational-wave bursts by combining this search with the previous LIGOVirgo search on the data collected "between November 2005 and October 2007. The upper limit on the rate of strong gravita.tional-wave bursts at the Earth is 1.3 events per year at 90% confidence. We also present upper limits on source rate density per yea.r and Mpc3 for sample popula.tions of standard-candle sources. As in the previous joint run, typical sensitivities of the search in terms of the root-sum-squared strain amplitude for these waveforms lie in the range approx 5 x 10(exp -22 Hz(exp-1/2) approx 1 X 10(exp -20) Hz(exp -1/2) . The combination of the two joint runs entails the most sensitive all-sky search for generic gravitational-wave bursts and synthesizes the results achieved by the initial generation of interferometric detectors.

Abadie, J.↗

Earth Resources Technology Satellite Operations Control Center (OCC). ERTS-B flight activation plan

Included in this plan are general objectives through Day 7, operational guidelines and restraints. Following the activation of all subsystems (through Day 3), special series of payload operations were performed to obtain data samples for the different combinations of exposure/gain settings. This took place from Day 4 through Day 7. The Orbit Adjust was employed to perform vernier corrections after the orbit had been defined. The orbit data was collected through Day 3, with the corrections being made from Day 4 through Day 7. ERTS command auxiliary memory (ECAM) was turned on in Day 3 and the memory dumped to a narrow band tape recorder. A verification of memory was done in the off line mode. ECAM was not used in a payload support mode until Day 7.

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