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At least 127 records · Page 7

Electrochemically driven carbon dioxide separation

This project explored the viability of a Ni(OH) 2 based hydroxide exchange membrane carbon capture (HEMCC) device for direct air capture. It is built off an H 2 fuel cell based HEMCC previously developed in the Yushan Yan group at University of Delaware. Taking the same membrane-based, electrochemically driven pH gradient concept, similar flux performance was able to be seen in the Ni(OH) 2 system as the H 2 system when using comparable current densities. The project produced two types of membrane electrode assemblies (MEA). The first was a traditional MEA with two electrodes and a membrane, the second was a flow-through membrane MEA. Consistent performance was achieved with the traditional MEA with an energy cost of 1.1 MWh∙ton -1 and flux of 82 kg∙m -2 ∙yr -1 . This was the most stable of the two designs. This project investigated strategies to improve performance with a flow-through membrane design. Two designs were made, one with a cast phase inversion membrane, and one with powdered membrane layer. The template phase inversion membrane achieved low pressure drop but had performance limitations due to a skin layer of membrane limiting CO 2 gas transport. The powdered membrane layer had better performance but higher pressure drop. Finally, using the powdered membrane, commercial battery materials were able to be used in order to achieve higher flux. This showed that the flow through membrane design does have the capability to overcome flux inefficiencies in the traditional MEA. Moreover, the process design of the system is proposed and given in this project. The process mass and energy balances were calculated for a reference plant of 1000 t/yr CO 2 capture, which contains several subsystems, e.g. air processing subsystem, electrical subsystem, and CO 2 purification and compression subsystem is designed and evaluated. Based on our calculation, When the power consumption for stack is 1 MWh t -1 CO 2 , Additional 382 kWh t -1 CO 2 will be consumed by other subsystem of the plant, i.e. The total power consumption of 1.38 MWh t -1 CO 2 , lower than the final milestone of 1.5 MWh t -1 CO 2 in this project.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

LIQUID AIR COMBINED CYCLE

Hybrid integration of thermal energy storage with gas turbines can provide compact, cost-effective, long-duration energy storage while reducing the fuel consumption of dispatchable resources needed for the reliability of renewable dominant electric grids. The Liquid Air Combined Cycle™ (LACC) is a hybrid energy storage system using cryogenic liquid air as an energy storage medium and gas turbine exhaust heat to extract stored energy. The storage tank is charged using liquefaction processes employing electric motor-driven compressors to pressurize the air, heat exchangers to reject heat of compression, and expanders to reduce the temperature and liquefy the air. Proven cryogenic refrigeration processes can be selected based on capital cost (per kg/s of liquid air produced), efficiency (kJ per kg of air produced), and operating factors including startup speed and load following capability. This paper presents results of studies undertaken for the U.S. Department of Energy to evaluate cost and performance tradeoffs for charge and discharge cycle components, optimize charge and discharge cycles, and assess the techno-economic potential of LACC technology.

Conlon, William↗

Low-GWP Refrigerants Status and Outlook

Refrigeration - including air conditioning (AC) – contributes substantially to the modern life of the 21st century and its economy. The food cold chain, air conditioning, healthcare and energy are examples of sectors for which refrigeration is indispensable. About 5 billion refrigeration systems – of different types and sizes– operate worldwide in different applications [1]. The dominant share of equipment providing refrigeration operate on the vapor-compression-cycle principle and use fluorocarbon refrigerants. Concerns about the environmental safety have become the driving force for refrigerant changes within the last 35 years. The phased-out schedule of stratospheric-ozone-depleting fluids was first formulated by the Montreal Protocol (MP) in 1987 and was made more stringent during the follow-up international meetings [2]. The affected chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) refrigerants were largely replaced by hydrofluorocarbons (HFCs).The 2016 Kigali Amendment to the MP [3] responses to the concerns about the Earth climate change. The refrigeration and AC sectors are attributed with about 7.8 % of global greenhouse gas emissions [4]. This contribution comes in the form of direct effect, which is related to refrigerant emissions from refrigeration systems (37 %), and in the form of indirect effect, which is related to CO2 emissions from fossil fuel power plants producing electricity to power refrigeration systems (63 %) [4]. The Kigali Amendment aims at reducing the direct effect. The effect a given molecule has on the climate change is quantified in a simplified manner by its Global Warming Potential (GWP), a relative index referencing the effect produced to that of the same mass of carbon dioxide released to the atmosphere. By definition, GWP of carbon dioxide is equal to one.While HFC refrigerants have on average a lower GWP than the CFCs and HCFCs they replaced, they are still potent greenhouse gases (GHGs). The Kigali Amendment phases down the use of HFCs by imposing a schedule for reducing a weighted GWP value to be implemented by a country through the year 2047 (Figure 1). It provides four paths depending on the country location and category assigned in the MP, and also prescribes a method for establishing the baseline consumption used for calculating GWP reductions. For developing countries, it is expected to bring the weighed GWP across all refrigeration applications down to about 300 from the baseline value of about 2000. The implementation of Kigali Amendment aims at reducing the future warming due to HFCs from the range of 0.3 °C to 0.5 °C to less than 0.1 °C [5]. While this reduction may seem to be small, it must be viewed in the context of the 2015 Paris Agreement [6], which calls for holding global warming to well below 2 °C and pursuing to limit global warming to 1.5 °C relative to pre-industrial levels [6]. Considering that average global temperatures reached 1 °C above pre-industrial levels for the first time in 2015 [7], the Earth is already within 1 °C of the “2 °C limit”.The low-GWP requirement narrows the pool of fluids that can be considered for application as a refrigerant [8]. This Informatory Note discusses low-GWP refrigerant options for major applications and presents their selection merits.

Yana Motta, Samuel↗

A Phenomenological Thermal Spray Wall Interaction Modeling Framework Applied to a High Temperature Ignition Assistant Device

Airborne compression ignition engines must operate with reliable ignition systems to achieve proper ignition at every cycle, particularly at high altitudes. Glow-plug-based ignition-assistant (IA) devices can provide the necessary energy to preheat the fuel and ensure ignitability of the fuel-air mixture. Ignitability of liquid sprays can be facilitated via direct impingement onto the hot IA surface, however this comes with adverse effects on the IA durability. Therefore, optimizing an IA’s design requires detailed understanding of the physics of fuel spray impingement of superheated surfaces. While spray impingement on relatively low wall temperatures has been extensively studied and appropriate numerical models have been proposed through the years, fundamental understanding of high-speed liquid spray impingement on superheated walls is still elusive. This work aims to formulate a phenomenological thermal spray-wall interaction framework for modeling the film-boiling-induced heat transfer, atomization, and dispersion of fuel spray droplets impinging onto a superheated IA device. A qualitative comparison of the new phenomenological model is performed against optical experiments from the literature of an F-24 fuel spray injected onto an IA device located 12 mm away from the injector tip. The temperature of the IA was set at 1400 K. The fuel injection pressure was 400 bar, while the ambient gas pressure and temperature were 30 bar and 800 K, respectively. The performance of the phenomenological model is evaluated in comparison with two other state-of-art models from the literature. A qualitative analysis of the different spray and fuel-air mixture characteristics is performed to outline the differences in the predictions offered by the new phenomenological model and the two state-of-art spray-wall interaction models.

droplet dispersion↗

An alternative method of changing the pulse duration in a stretcher-compressor pair by changing the gas pressure in the compressor

The relatively narrow bandwidth of neodymium glass requires a much larger stretch ratio of chirped-pulse amplification (CPA) systems. This factor, together with a large incident angle on the gratings, makes glass CPA systems extremely sensitive to the refractive index of the medium in the stretcher-compressor. High sensitivity of the stretcher-compressor pair for hybrid optical parametric chirped-pulse amplification and an Nd:glass laser to the refractive index was demonstrated in air, vacuum, and carbon dioxide, and a pulse duration close to the transform limit was reached. An alternative way to change the pulse duration was proposed. The pulse duration from the best compression of 500 fs to 30 ps was smoothly varied by changing the air pressure from 10 -6 Torr to 1 atm in the compressor and up to 52 ps in carbon dioxide, while the stretcher and compressor remained untouched. Finally, excellent agreement of the measured pulse duration with theoretical calculations was demonstrated.

47 OTHER INSTRUMENTATION↗

Liquid Air Combined Cycle TM for Power and Storage

Liquid Air Combined Cycle (LACC) is a hybrid liquid air energy storage (LAES) system combining energy storage with a combustion turbine to enable large-scale, long-duration energy storage (LDES) while reducing fuel intensity compared to the current state-of-the-art. The LACC technical approach employs proven equipment (cryogenic refrigeration, storage, tanks, pumps, gas turbines, exhaust heat recovery equipment, and turbines) to limit technical risk to a novel organic Rankine cycle (ORC), which was evaluated during this project and found to be feasible. Moreover, LACC storage is safe and relatively compact, to facilitate siting close to loads and within metropolitan regions. The air storage medium is freely available and eliminates supply chain constraints. LACC uses cryogenic air as a storage medium and a gas turbine as the source of heat to drive the discharge process. LACC is distinguished from other LAES technologies by several factors. The charge and discharge processes are decoupled so that cryogenic liquid air is the only storage medium. Other systems also store the higher temperature thermal energy from the liquefaction process in an additional medium. Subsequently, LACC focuses on maximization of the discharge energy and power. LACC also permits the use of commercially available cryogenic refrigeration and storage technologies to increase competition. This project identified product requirements to support market entry and commercialization of the LACC in modular units of approximately 117 MW, each drawing liquid air from customary cryogenic storage tanks capable of storing 75 GWh of dispatchable energy, more than pumped storage hydro or compressed air energy storage technologies. An economic analysis identified the specific liquid air consumption (quantity of liquid air per unit of discharge energy) as a critical parameter. Minimizing the air consumption reduces the specific capital cost ($\$ $/kW) for charging and discharging equipment by reducing the size of piping and turbomachinery. Likewise, the specific cost of energy capacity ($\$ $/kWh) is reduced by increasing the energy deliverable from a given size tank. The cycle was analyzed to identify the optimal equipment selection and operating conditions, which in turn were combined with quotes and cost estimates to calculate the cost of energy from an LACC system. A substantial effort was focused on the ORC, which draws low-temperature heat from the gas turbine exhaust and condenses at low temperature using the cryogenic liquid air as a heat sink. Alternative turbomachinery arrangements were evaluated for feasibility and cost. A technology maturation plan lays out a low-risk approach to development of the novel ORC components and demonstration of LACC technology at pilot scale.

25 ENERGY STORAGE↗

Next Gen High Efficiency Boosted Engine Development

This work represents an advanced engineering research project partially funded by the U.S. Department of Energy (DOE). Ford Motor Company, FEV North America, and Oak Ridge National Laboratory collaborated to develop a next generation boosted spark ignited engine concept. The project goals, specified by the DOE, were 23% improved fuel economy and 15% reduced weight relative to a 2015 or newer light-duty vehicle. The fuel economy goal was achieved by designing an engine incorporating high geometric compression ratio, high dilution tolerance, low pumping work, and low friction. The increased tendency for knock with high compression ratio was addressed using early intake valve closing (EIVC), cooled exhaust gas recirculation (EGR), an active pre-chamber ignition system, and careful management of the fresh charge temperature. Engine weight reduction measures were implemented throughout the engine system making use of composite materials, advanced manufacturing techniques, and architectural choices. This report outlines the analytical, design, fabrication, and test work conducted for the duration of the project. The combustion system stability, EGR tolerance, and knock resistance were validated on a single cylinder engine. An inline six-cylinder engine was then designed targeting application in the Ford F150. Multi-cylinder engines were produced and tested achieving the target vehicle fuel economy improvement of 23% assessed using measured engine fuel consumption combined with a vehicle drive cycle simulation. Actions were identified and designs were demonstrated to achieve the 15% weight reduction target. This project included items covering a range of technology readiness levels. Some of the technologies explored are production ready, while others were investigated to understand the limitations for what can be achieved in a stoichiometric, gasoline-fueled, spark-ignited internal combustion engine.

42 ENGINEERING↗

Energy Saving Analysis Using Energy Intensity Usage and Specific Energy Consumption Methods

This study presents the energy saving analysis reached through employing the energy intensity usage and specific energy consumption method. The energy analyses conducted in this study are used for implementing a new technology. However, they are additionally used to evaluate the latest concepts, techniques, processes, and uses for technologies, which are aimed at improvement of energy savings. This study shows the correlation between energy consumption, potential energy savings, and the impact of the energy assessment in different industrial sectors. The correlation is found by using two indicators: (1) the energy intensity usage (EIU) and (2) the specific energy consumption (SEC). The data analysis in this study considers the assessments for 67 industries from 2015 to 2019 and classifies those assessments using the Standard Industrial Classification (SIC) code. The results show that energy savings and energy consumption are linearly related. Also, the energy assessment improves energy performance in a more significant way for smaller companies than for larger industries. Furthermore, these results can be extrapolated by identifying the potential benefits of the energy management system (EMS) implementation.

24 POWER TRANSMISSION AND DISTRIBUTION↗

NLR HPC Facility Power Usage Effectiveness (PUE) Data

Timeseries of Energy Systems Integration Facility (ESIF) Data Center Power Usage Effectiveness (PUE) Data provided in Parquet and compressed CSV formats Power Metrics Timeseries Fields: ts: Timestamp cooling_kw: Cooling (kilowatts) - Captures the power used by fans and pipe trace heaters associated with outdoor cooling equipment. The dedicated tower filter pump power is also captured as cooling load. energy_reuse: Energy Reuse Effectiveness hvac_kw: Heating, ventilation, and air conditioning (kilowatts) - Captures fan walls, fan coils that support the data center electrical rooms, and the make-up air unit. it_power_kw: IT equipment (kilowatts) - Captures power used by the IT equipment on the data center floor. plug_and_light_kw: Lights and utility plugs (kilowatts) - Captures power associated with the data center and dedicated mechanical room. The crank-case heater for the emergency standby generator is also captured as light and plug load. pue: Power Usage Effectiveness pump_kw: Pumps (kilowatts) - Captures power from pumps that move water in the data center Energy Recover Water loop and the Tower Water loops, and also captures power used by the boost pumps that circulate water through the fan walls. Note: The tower filter pump runs constantly to filter water from the data center cooling tower system, so 2.67 kilowatts are attributed to this pump and that is not reflected in this data field. day: Day of month Outside Weather Station Timeseries Fields: ts: Timestamp outside_air_humidity: Outside air humidity - Relative humidity percent outside_air_temp: Outside air temperature - Degrees Fahrenheit day: Day of month More detail: High-Performance Computing Data Center Power Usage Effectiveness

97 MATHEMATICS AND COMPUTING↗

Thermal Stability of Silica for Application in Thermal Energy Storage

Thermal energy storage (TES) systems have enabled concentrating solar power (CSP) to remain competitive in the modern energy mix by providing economical load shifting grid services and firming up intermittent solar resource. Free from siting constraints, TES also shows promise as an economical alternative to traditional pumped-storage hydropower (PSH) and compressed air energy storage (CAES). As potential thermal energy storage media, some solid particles demonstrate stability over wide temperature ranges which allows for increased sensible energy storage density and is essential in achieving low-cost storage. Silica sand, in the form of a-quartz, is one such candidate. This work presents a brief review of relevant silica thermophysical properties and further investigates the thermal stability of silica particles as a candidate TES media by subjecting them to two different thermal tests: (1) a 500-hour thermal treatment at 1200 degrees C under varied atmospheres; and (2) cycling 25, 50, and 100 times between 300 degrees C and 1200 degrees C. For both tests, particle stability is examined by means of pre- and post-treatment Mie scattering. An additional XRD analysis is conducted for the 500-hour treatment in air. Results indicate limited changes in both particle distribution and crystallographic structure which is promising for the application as solid particle media for thermal energy storage.

concentrating solar power↗

Effective properties of semitransparent radiative cooling materials with spectrally variable properties

Radiative cooling is a promising solid-state, non-vapor-compression technology for passive refrigeration and air conditioning. Although this phenomenon occurs naturally, achieving a significant amount of cooling to make it a technically and economically viable technology requires highly engineered, spectrally selective radiative surfaces. These characteristics make radiative cooling difficult to estimate, particularly when it is integrated with other systems such as photovoltaic panels or building envelopes. The complexity further increases when the substrate also participates in the radiative cooling (along with the radiative coating). Energy estimation is becoming increasingly critical because of the recent focus on the semitransparent radiative coatings that transmit a variety of colors to enhance the aesthetic appeal of the system. In this work, we propose an iterative method to calculate the effective radiative properties, which provides the same net radiative cooling that would be observed using the spectral properties at both the coating and substrate surfaces. Compared to traditional methods that rely on either computationally expensive full spectral analysis or methods for averaging each radiative surface parameter locally, our proposed method focuses on calculating effective properties that provide the same the net cooling effect as a full spectral analysis by accounting the emissivity, absorptivity, and transmissivity collectively, thereby providing an overall estimation error of less than 0.2%. We believe that this study will be beneficial to the engineering communities that employ complex simulation codes and require lumped solar and thermal radiation related parameters.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Model-based predictive control of multi-stage air-source heat pumps integrated with phase change material-embedded ceilings

This paper presents a model-based predictive control strategy to optimize the operations of phase change material (PCM) ceiling panels coupled with a multi-stage air-source heat pump. A three-stage prototype heat pump unit has been built and tested in the laboratory, with the low and medium stages designed for space heating/cooling and the high compression stage dedicated to charging of the PCM energy storage. To facilitate optimal control of the integrated heat pump system, a mixed-integer linear programming formulation is derived through linearization of the heat pump model and a mixed-integer reformulation of the PCM dynamic governing equations. A predictive control strategy is synthesized based on the resultant control formulation and implemented in a receding horizon scheme that optimizes the PCM charging and the zone temperature schedules simultaneously to leverage both the passive (associated with building construction materials) and active (PCM) storage capacities of a building. The control strategy has been tested along with three benchmarking control scenarios using a co-simulation platform for a prototypical detached house in Atlanta, GA. In this study, test results showed that application of the proposed control strategy to the PCM-integrated heat pump could provide 27.1% electricity cost savings while a fine tuned rule-based control strategy could achieve cost savings of 20.4%, compared to a baseline case without PCM storage, under a time-of-use rate tariff.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Superconducting qubits in a flip-chip architecture

Flip-chip architectures have recently enabled significant scaling-up of multi-qubit circuits and have been used to assemble hybrid quantum systems that combine different substrates, for example, for quantum acoustics experiments. The standard flip-chip method uses superconducting galvanic connections between two substrates, typically implemented using sophisticated indium wafer-bonding systems, which give highly reliable and temperature-cyclable assemblies, but are expensive, somewhat inflexible in design, and require robust substrates that can sustain the large compressive forces required to cold-weld the indium bonds. A much simpler method is to assemble dies using very low-force contacts and air-dried adhesives, although this does not provide a galvanic contact between the dies. In this work, we demonstrate that the latter technique can be used to reliably couple superconducting qubit circuits, in which the qubits are on separate dies, without the need for a galvanic connection. We demonstrate full vector qubit control of each qubit on each of the two dies, with high-fidelity single-shot readout, and further demonstrate entanglement-generating excitation swaps as well as benchmark a controlled-Z entangling gate between the two qubits on the two dies. This exemplifies a simple and inexpensive assembly method for two-plus-one-dimensional quantum circuit integration that supports the use of delicate or unusually shaped substrates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Design and performance evaluation of a dual-circuit thermal energy storage module for air conditioners

We present experimental results and a validated numerical model of a dual-circuit phase-change thermal energy storage module for air conditioners. The module incorporates a phase-change material encapsulated in compressed expanded natural graphite foam. We used n-tetradecane as the PCM with a transition temperature (~4.5 °C) suitable for air-conditioning applications. Heat exchange to and from the module is accomplished through two fluid loops operating as a heat source and sink embedded inside multiple slabs of the composite material. This dual-circuit design enables easier integration with air-conditioning equipment and provides enhanced flexibility in system operation as compared to the state-of-the-art thermal storage systems. When integrated with an air-conditioner, this design will enable peak-load shaving and enhances operational efficiency. The thermal storage device was designed for a nominal storage capacity of ~ 3.5 kWh. We evaluated the heat transfer and energy storage performance of this device using standalone heat transfer experiments to estimate key thermal resistances and identify design improvements before integration with an air conditioner. The numerical model of the heat exchanger uses a combination of discretized and lumped parameter approaches to maintain a balance between accuracy and computational expense. Our analyses show that the geometric features and integration of fluid tubes are key contributors to the thermal contact resistance between the fluid and the thermal storage material, and consequently, to the overall performance of the thermal storage module. Our standalone experiments also identified important operating scenarios in which this thermal storage module can be used for air-conditioning in buildings.

25 ENERGY STORAGE↗

5.1.6 Demo #6: NanoStitch (NAWAStitch) Multifunctional Composites Trade Validation

The overall objective of the NanoStitch Multifunctional Composites Trade Validation Demonstration project was to determine the value proposition of adding NanoStitch to rapid-cure composite systems for structures used in the expanding sector of advanced air mobility (AAM) and specifically electric vertical take-off and landing (eVTOL) aircraft. The expected value proposition was stronger composite parts, with new multifunctional attributes, that are lower cost to fabricate and maintain. NanoStitch is a new composite innovation where a contiguous vertically aligned carbon nanotube (VACNT) forest is located between each ply of a laminate composite resulting in improved mechanical properties as well as other multifunctional properties such as enhanced thermal and electrical conductivity. NanoStitch was originally distributed by N12, later acquired by NAWA Technologies, now called NAWAStitch, and henceforth referred to in this document as NAWAStitch. Two significant evaluations were framed to help meet the overall objective. First, was Task 1 to evaluate the effects that adding NAWAStitch to a rapid cure material system would have on the mechanical and processing properties of the material. Second, was Task 2 to evaluate the workability of adding NAWAStitch to practical flight demonstration articles. From previous research, it was already known that the application of NAWAStitch to a composite structure can enhance the mechanical properties of that structure. However, this project will help the engineering community understand those benefits and the basic structural strength values to apply when incorporating NAWAStitch material into composite structure that utilizes a rapid-cure resin system, which is novel. Testing showed that by adding NAWAStitch to the prepreg, most material properties were improved because the VACNTs strengthened the resin to fiber interface, and the interface itself, between plies. For example compression strength improved by more than 20%, and erosion resistance by more than 50%. The UDRI team identified two flight demonstration articles through discussions with Aurora Flight Sciences (Aurora) and reviewing literature on air mobility and the eVTOL market. The demonstration articles were a thin skin honeycomb panel and a section from an eVTOL propeller blade. The manufacturing and testing trials of the demonstration articles were as follows: • NAWAStitch added no manufacturing complexity or detriment to the article physical qualities, while at the same time added multifunctional properties such as enhanced rain erosion and electrothermal de-icing besides enhanced mechanical properties • VACNTs did not increase or hurt the mechanical properties of the interface between honeycomb core materials and the thin skin face sheet • Demonstrated successful de-icing function in an eVTOL propeller meeting real-world specifications in uniformity and endurance • Multifunctional eVTOL propeller cost analysis showed a cost savings of at least 67 % for a single propeller blade with multifunctional de-icing capability and improved mechanical properties which equates to a potential savings of $10,116 per eVTOL aircraft with six three-bladed propellers Overall, the results of this project can provide additional tools for the composite industry to optimize energy efficiency through faster and stronger composite parts that are lower cost to fabricate and maintain. Additionally, the results of this effort can help US industry like NAWA America set the stage for rapid growth and establishment of a manufacturing facility in Ohio. The project has given NAWA America the basic understanding of how the addition of VACNTs to a composite structure can affect the mechanical properties and hence point them to potential commercial applications. The project has also provided Teijin Carbon US with another potential material application for their rapid cure materials that are manufactured at the Renegade facility in Miamisburg, OH.

36 MATERIALS SCIENCE↗

Performance Evaluation of Liquid-Cooled Open Stand-Alone Refrigerated Cases

This project is part of a joint effort between Commonwealth Edison Company (ComEd) and the National Renewable Energy Laboratory (NREL) to evaluate the energy and demand savings potential of emerging efficient buildings technologies. This project quantifies the energy efficiency benefits from retrofitting an air-cooled, constant-speed compression, self-contained medium-temperature open-vertical display case with a high efficiency water-cooled condensing unit. In addition to a water-cooled heat rejection mechanism, the high-efficiency condensing unit utilizes a variable-speed compressor, electronic expansion valve and advanced controls system. The focus of this project, however, was mainly on capturing the energy savings potentials of the water-cooled condenser, variable-speed compression and electronic expansion valve, and not on the advanced controls. The results of this evaluation will be considered by ComEd and CLEAResult for future energy efficiency rebate offerings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Techno-Economic Analysis of Compressed Air Energy Storage and Hydrogen Production from Variable Renewable Energy

This study presents the techno-economic analysis (TEA) results of integrating electrolysis hydrogen (H 2 ) production, compressed air energy storage (CAES), and H 2 -fired combustion turbines in a high variable renewable energy (VRE) market environment. The inconsistent nature of VRE creates challenges for power producers in maintaining a stable electrical grid as it is increasingly utilized. The mission of the National Energy Technology Laboratory (NETL) is driving innovation and delivering energy solutions, and a multiangle approach involving H 2 production, energy storage, and next-level H 2 -fired combustion turbine generator (CTG) technologies could provide one solution for the nation’s growing electrical grid issues with increasing VRE sources. The H 2 production and CAES concept were investigated due to its ability to provide utility-scale H 2 -fueled power generation with large-scale energy storage capabilities. Two facilities with CAES and natural gas-fired CTGs (in McIntosh, Alabama, and Huntorf, Germany) have been operating for decades. In contrast, this study investigates the potential to replace the natural gas fuel with H 2 fuel. This concept has been publicly presented by both Siemens Energy and Bechtel Global Engineering, Construction & Project Management (Bechtel) at two different power generating levels. The CAES and air expansion/combustion turbine power generation in this study are primarily based on the Siemens Energy system (Bailie, Aug. 10-11, 2021) (Scheller, Feb. 21, 2023). The inclusion of a H 2 turboexpander generator is from Bechtel (Gülen, Sep. 6, 2022). A block flow diagram of the proposed process is illustrated in Exhibit ES-1.

08 HYDROGEN↗

Techno-Economic Analysis of a Concentrating Solar Power Plant Using Redox-Active Metal Oxides as Heat Transfer Fluid and Storage Media

We present results for a one-dimensional quasi-steady-state thermodynamic model developed for a 111.7 MW e concentrating solar power (CSP) system using a redox-active metal oxide as the heat storage media and heat transfer agent integrated with a combined cycle air Brayton power block. In the energy charging and discharging processes, the metal oxide CaAl 0.2 Mn 0.8 O 2.9-δ (CAM28) undergoes a reversible, high temperature redox cycle including an endothermic oxygen-releasing reaction and exothermic oxygen-incorporation reaction. Concentrated solar radiation heats the redox-active oxide particles under partial vacuum to drive the reduction extent deeper for increased energy density at a fixed temperature, thereby increasing storage capacity while limiting the required on sun temperature. Direct counter-current contact of the reduced particles with compressed air from the Brayton compressor releases stored chemical and sensible energy, heating the air to 1,200°C at the turbine inlet while cooling and reoxidizing the particles. The cool oxidized particles recirculate through the solar receiver subsystem for another cycle of heating and reduction (oxygen release). We applied the techno-economic model to 1) size components, 2) examine intraday operation with varying solar insolation, 3) estimate annual performance characteristics over a simulated year, 4) estimate the levelized cost of electricity (LCOE), and 5) perform sensitivity analyses to evaluate factors that affect performance and cost. Simulations use hourly solar radiation data from Barstow, California to assess the performance of a 111.7 MW e system with solar multiples (SMs) varying from 1.2 to 2.4 and storage capacities of 6–14 h. The baseline system with 6 h storage and SM of 1.8 has a capacity factor of 54.2%, an increase from 32.3% capacity factor with no storage, and an average annual energy efficiency of 20.6%. Calculations show a system with an output of 710 GWh e net electricity per year, 12 h storage, and SM of 2.4 to have an installed cost of $329 million, and an LCOE of 5.98 ¢/kWh e . This value meets the U.S. Department of Energy’s SunShot 2020 target of 6.0 ¢/kWh e ( U. S Department of Energy, 2012 ), but falls just shy of the 5.0 ¢/kWh e 2030 CSP target for dispatchable electricity ( U. S Department of Energy, 2017 ). The cost and performance results are minimally sensitive to most design parameters. However, a one-point change in the weighted annual cost of capital from 8 to 7% (better understood as a 12.5% change) translates directly to an 11% decrease (0.66 ¢/kWhe) in the LCOE.

Gorman, Brandon T.↗