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DOE OSTI2020

LandRAY Final Report

The overarching Project objective is to demonstrate the feasibility of using an innovative Power Take-Off (PTO) Module, to be used in the Columbia Power Technologies, Inc. (C·Power) utility-scale wave energy converter (WEC). The PTO Module uniquely combines a large-diameter, direct-drive, rotary permanent magnet generator; a patent-pending rail-bearing system; and a corrosion-resistant fiber-reinforced-plastic structure. The rail bearing system allows for: • A flexible non-rigid and low-cost generator frame as compared to conventional machines. • A reduction of air gap and consequently lower cost electromagnetic design • Ability to reduce costs by increasing diameter to much larger dimensions, while maintaining the small air gap. • A direct drive electro-mechanical solution that is the fastest and most precise approach for responding to the dynamic variability of forces from wave energy. The land-based test of the PTO Module (DDP1) will provide an important risk reduction phase, to demonstrate the reliability and feasibility of a large-diameter, small air-gap generator that is capable of delivering high efficiency, fault-tolerance and relatively simple "at-sea" maintenance capabilities – qualities that are essential for cost-effective wave energy devices. This is the first known test of such a system.

16 TIDAL AND WAVE POWER↗

NASA NTRS2017

Milli-Watt Radioisotope Power to Enable Small, Long-Term Robotic “Probe” Space Exploration

Milli-watt Radioisotope Power Systems (RPS) based on Radioisotope Heater Units (RHUs) could be an ideal power source for certain spacecraft that cannot use solar power due to large distances from the sun, or other environmental constraints, and where they enable or significantly enhance the ability of a mission to meet its scientific or operational goals. Various modular, compact RHU-based thermoelectric (TE) generator concepts developed or derived from current NASA Small Business Innovation Research (SBIR) projects satisfying this need have been investigated. These modular, compact and low mass power systems could support small, highly-mobile robotic exploration packages, and could be incorporated into different robotic package concepts, spacecraft or satellites. Current modular RPS design concepts with 40mW, 80mW and 120mW power levels use RHUs and Bi2Te3 TE converters. Skutterudites materials could be used in the future if new higher thermal energy output and higher temperature miniature heat sources were developed, for example, using technologies currently in the General Purpose Heat Source (GPHS) used in higher electric power output RTGs. Small (a.k.a., “mice-like”) robotic packages could effectively utilize these RHU-driven power levels to accommodate crawling, climbing, monitoring, taking measurements, and communicating during long-term planetary missions aimed at gathering environmental and geologic data (i.e., over multiple decades). Waste heat from the cold side of the TE converter could also be directed toward the electronics and / or energy storage (e.g. batteries) to keep them within design temperature ranges. In addition to power generation and electronics / battery heating, the RHU / TE configuration could be designed to survive an external 500°C bake out procedure for critical spacecraft sterilization, environmental certification and planetary protection. Analytical studies have been performed to optimize various design configurations for power, mass, volume and robotic mobility. Specific power (mW/kg) and volumetric specific power (mW/cm3) characteristics of various design configurations will be presented and key conceptual design tradeoffs will be discussed. Hot- and cold-side thermal interfaces required to meet power and mass goals and associated design sensitivities will also be discussed. RHU / TE systems must overcome critical design challenges to survive high-g loadings in some robotic applications and we will examine the mass impacts required to satisfy various dynamic loading environments up to 10,000 g’s. Power can be generated for a minimum of 30 years or more using plutonium-238 dioxide heat sources (given that Pu-238 has an 87.7 year half-life) with some reduction in power as the heat source naturally degrades.

Bahrami, Poyan↗

NASA NTRS1979

Hydrogen as the solar energy translator

Many concepts are being investigated to convert sunlight to workable energy forms with emphasis on electricity and thermal energy. The electrical alternatives include direct conversion of photons to electricity via photovoltaic solar cells and solar/thermal production of electricity via heat-energy cycles. Solar cells, when commercialized, are expected to have efficiencies of about 12 to 14 percent. The cells would be active about eight hours per day. However, solar-operated water-splitting process research, initiated through JPL, shows promise for direct production of hydrogen from sunlight with efficiencies of up to 35 to 40 percent. The hydrogen, a valuable commodity in itself, can also serve as a storable energy form, easily and efficiently converted to electricity by fuel cells and other advanced-technology devices on a 24-hour basis or on demand with an overall efficiency of 25 to 30 percent. Thus, hydrogen serves as the fundamental translator of energy from its solar form to electrical form more effectively, and possibly more efficiently, than direct conversion. Hydrogen also can produce other chemical energy forms using solar energy.

Kelley, J. H.↗

DOE OSTI2024

Photosynthetic biohybrid systems for solar fuels catalysis

Photosynthetic reaction center (RC) proteins are finely tuned molecular systems optimized for solar energy conversion. RCs effectively capture and convert sunlight with near unity quantum efficiency utilizing light-induced directional electron transfer through a series of molecular cofactors embedded within the protein core to generate a long-lived charge separated state with a useable electrochemical potential. Of current interest are new strategies that couple RC chemistry to the direct synthesis of energy-rich compounds. This Feature Article highlights recent work from our lab on RC and RC-inspired hybrid systems that capture the Sun's energy and convert it to chemical energy in the form of H2, a carbon-neutral energy source derived from water. Further, biohybrids made from the Photosystem I (PSI) RC are among the best photocatalytic H2-producing protein hybrids to date. Targeted self-assembly strategies that couple abiotic catalysts to PSI translate to catalyst incorporation at intrinsic PSI sites within thylakoid membranes to achieve complete solar water-splitting systems. RC-inspired biohybrids interface synthetic photosensitizers and molecular catalysts with small proteins to create photocatalytic systems and enable the spectroscopic discernment of the structural features and electron transfer processes that underpin solar-driven proton reduction. In total, these studies showcase the incredible scientific opportunities photosynthetic biohybrid research provides for harnessing the optimal qualities of both artificial and natural photosynthetic systems and developing materials that capture, convert, and store solar energy as a fuel.

14 SOLAR ENERGY↗

NASA NTRS1971

Pulsed electromagnetic gas acceleration

Experimental data were combined with one-dimensional conservation relations to yield information on the energy deposition ratio in a parallel-plate accelerator, where the downstream flow was confined to a constant area channel. Approximately 70% of the total input power was detected in the exhaust flow, of which only about 20% appeared as directed kinetic energy, thus implying that a downstream expansion to convert chamber enthalpy into kinetic energy must be an important aspect of conventional high power MPD arcs. Spectroscopic experiments on a quasi-steady MPD argon accelerator verified the presence of A(III) and the absence of A(I), and indicated an azimuthal structure in the jet related to the mass injection locations. Measurements of pressure in the arc chamber and impact pressure in the exhaust jet using a piezocrystal backed by a Plexiglas rod were in good agreement with the electromagnetic thrust model.

Jahn, R. G.↗

NASA NTRS2000

Thermal Considerations of Space Solar Power Concepts with 3.5 GW RF Output

This paper presents the thermal challenge of the Space Solar Power (SSP) design concepts with a 3.5 GW radio-frequency (RF) output. High efficiency klystrons are thermally more favored than solid state (butterstick) to convert direct current (DC) electricity to radio-frequency (RF) energy at the transmitters in these concepts. Using klystrons, the heat dissipation is 0.72 GW. Using solid state, the heat dissipation is 2.33 GW. The heat dissipation of the klystrons is 85% at 500C, 10% at 300C, and 5% at 125C. All the heat dissipation of the solid state is at 100C. Using klystrons, the radiator area is 74,500 square m Using solid state, the radiator area is 2,362,200 square m Space constructable heat pipe radiators are assumed in the thermal analysis. Also, to make the SSP concepts feasible, the mass of the heat transport system must be minimized. The heat transport distance from the transmitters to the radiators must be minimized. It can be accomplished by dividing the radiator into a cluster of small radiators, so that the heat transport distances between the klystrons and radiators can be minimized. The area of each small radiator is on the order of 1 square m. Two concepts for accommodating a cluster of small radiators are presented. If the distance between the transmitters and radiators is 1.5 m or less, constant conductance heat pipes (CCHPs) are acceptable for heat transport. If the distance exceeds 1.5 m, loop heat pipes (LHPs) are needed.

Choi, Michael K.↗

NASA NTRS2018

Dual-mode Propulsion System Enabling Cubesat Exploration of the Solar System

It is apparent the cost of planetary exploration is rising as mission budgets are declining. Currently small scientific beds geared to performing limited tasks are being developed and launched into low earth orbit (LEO) in the form of small-scale satellite units, i.e., CubeSats. These micro- and nano-satellites are gaining popularity among the university and science communities due to their relatively low cost and design flexibility. To date these small units have been limited to performing tasks in LEO utilizing solar-based power. If a reasonable propulsion system could be developed, these CubeSat platforms could perform exploration of various extra-terrestrial bodies within the solar system engaging a broader range of researchers. Additionally, being mindful of mass, smaller cheaper launch vehicles (~1,000 kg to LEO) can be targeted. This, in effect, allows for beneficial exploration to be conducted within limited budgets.Researchers at the Center for Space Nuclear Research (CSNR) are proposing a low mass, radioisotope-based, dual-mode propulsion system capable of extending the exploration realm of these CubeSats out of LEO.The proposed radioisotope-based system would leverage the high specific energies [J/kg] associated with radioisotope materials and enhance their inherent low specific powers [W/g]. This is accomplished by accumulating thermal energy from nuclear decay within a central core over time. This allows for significant amounts of power to be transferred to a flowing gas over short periods of time. In the proposed configuration the stored energy can be utilized in two ways: (1) with direct propellant injection to the core, the energy can be converted into thrust through the use of a converging-diverging nozzle and (2) by flowing a working fluid through the core and subsequent Brayton engine, energy within the core can be converted to electrical energy. The first scenario achieves moderate ranges of thrust, but at a higher Isp than traditional chemical-based systems. The second scenario allows for the production of electrical power, which is then available for electric-based propulsion. Additionally, once at location the production of electrical power can be dedicated to the payload's communication system for data transfer. Ultimately, the proposed dual-mode propulsion platform capitalizes on the benefits of two types of propulsion methods the thrust of thermal propulsion ideal for quick orbital maneuvers and the specific impulse of electric propulsion ideal for efficient interplanetary travel. Overall, the system is functioning as a radioisotope thermal rocket (RTR).In this study the RTR concept is being developed as an in-space propulsion system to deliver a 6U CubeSat payload to the orbit of the Saturnian moon - Enceladus. Additionally, this study will develop an entire mission architecture for Enceladus targeting a total allowable launch mass of 1,000 kg.

Cubesats↗

DOE OSTI2022

Integrated energy harvesting transceivers and transmitters with dual-antenna architecture for miniaturized implants and electrochemical sensors

Systems and methods for utilizing a small form-factor, wirelessly powered transceiver are disclosed. In one embodiment, a wireless powered transceiver includes a receive antenna configured to receive a receive signal, a transmit antenna configured to transmit a transmit signal, a power harvesting system including a rectifier circuit configured convert radio frequency energy from the receive signal into DC (direct current) voltage, and a power management unit (PMU) configured to set the operating mode and biasing condition of the receive and transmit circuitry blocks and provide DC voltage from the receive circuitry block to the transmit circuitry block to maintain a minimum voltage, a receiver circuitry block configured to provide energy from the receive signal to the power harvesting system, and a transmitter circuitry block including a data modulator circuit, the data modulator circuit configured to generate the transmit signal using DC voltage received from the power management unit.

Babakhani, Aydin↗

DOE OSTI2024

Integrated energy harvesting transceivers and transmitters with dual-antenna architecture for miniaturized implants and electrochemical sensors

Babakhani, Aydin↗

DOE OSTI2024

Integrated Process for Direct Air Capture of CO 2 and Electrochemical Conversion to Ethanol

This Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and Reactwell, L.L.C. aimed to facilitate the development of an energy-efficient and cost-effective technology that captures carbon dioxide (CO 2 ) from ambient air and converts it electrochemically to ethanol. Direct air capture (DAC) of CO 2 offers the prospect of permanently lowering the atmospheric CO 2 concentration, providing economic and energy-efficient technologies can be developed and deployed at a large scale. DAC has the potential for high-capacity atmospheric CO 2 capture, the flexibility of placement anywhere on earth, and the generation of high-purity CO 2 streams. The most significant technical challenge with DAC is the very low atmospheric concentration of CO 2 , thereby requiring sorbents that bind CO 2 quickly, strongly, and selectively against other components in the air. Integrating DAC with CO 2 conversion into useful chemicals, fuels, or materials can provide an economically feasible solution for mitigating climate change. As long as the carbon contained in these products is taken from the atmosphere and no additional carbon emissions result from their production, processing, and transportation, they can be considered carbon-neutral products. This CRADA facilitated the development of a new net-zero emission technology that closes the carbon cycle by combining DAC with the catalytic electrochemical conversion of CO 2 into ethanol.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Feed-Forward Compensation for Model Predictive Control in Tri-port Current-Source Medium-Voltage String Inverters for PV-Plus-Storage Farms

The novel tri-port current-source medium-voltage string inverter (TCS-MVSI) is a promising candidate for large-scale PV-plus-storage (PVS) farms owing to its galvanic isolation, easy storage integration, soft-switching capability across entire load range, controlled low dv/dt and EMI, benign fault tolerance, etc. Due to its low inertia feature, traditional PI-based control cannot manage large transients effectively. Instead, a model-based predictive control (MPC) is proposed to achieve robust and stable operation. As is well known, the control performance of MPC is compromised by the sampling and computational delay during implementation significantly, if not well addressed. This paper analyzed and quantified these delays and then proposes feed-forward compensation (FFC) for the MPC method to compensate the delays and the large parameter variations due to the low-inertia nature. In addition, this method also compensates for the high dc-link ripple within each switching cycle, a unique issue for low-inertia converters. Here, the proposed method requires low computational effort, allowing it to be extended for multiple ports. The effectiveness of the proposed method has been validated in experiments. In 10 kW test, the proposed method decreases the average dc-link current by 17%, leading to ~20% conduction losses and ~0.5% increase in converter efficiency. In addition, the peak dc-link current also decreases by 15%, resulting in reduced transformer size. As a result, an increased power density can be achieved with the proposed method. Similar improvements have been observed across the power range from 2 kW to 10 kW.

30 DIRECT ENERGY CONVERSION↗

DOE OSTI2021

Moving from scientific research to consenting guidance for MRE environmental risk

Potential environmental effects from tidal and wave devices are of concern to regulators, advisors, and other stakeholders in many nations. Monitoring results from early deployments and the first commercial arrays, coupled with targeted research studies, are providing a growing base of knowledge of how components of tidal turbines and wave energy converters might interact with marine animals and habitats. Efforts are underway to organize and direct these findings towards facilitating consenting that allays concerns and allows the marine renewable energy (MRE) industry to move forward. The OES-Environmental international initiative has developed scientific evidence bases for several key interactions from MRE devices, organized around stressors (portions of MRE systems that may cause injury or stress to the marine ecosystem), and receptors (the animals, habitats, and ecosystem processes that may be affected). This paper summarizes the evidence bases for four stressors (underwater noise, electromagnetic fields, habitat change, and changes in oceanographic systems) and presents the process of moving from the scientific knowledge into guidance documents to support the regulatory process. The guidance documents will serve as a broad guide that can be used internationally to look at stressor-receptor interactions of interest within a regulatory context. The evidence bases and guidance documents aim to assist MRE developers, regulators, and advisors with project scoping, consenting, and licensing processes.

Copping, Andrea E.↗

DOE OSTI2023

Active SOC Balancing for a Multi-Chemistry Battery Pack with Reduced Number of Converters

In energy storage systems using second-life or multi-chemistry cells, an active state of charge (SOC) balancing system can prolong pack life and enhance performance by utilizing the healthier cells more than those which are heavily degraded. However, the high cost of the active balancing system, particularly in converter-based solutions, prevents their widespread usage. Considering this, existing research has proposed numerous balancing systems utilizing only one converter. However, such systems may compromise the balancing speed too much. Therefore, this work proposes two active balancing systems with a reduced number of converters for 14-16 series-connected cells. One system uses two converters for direct cell-to-cell balancing. The other uses a time-multiplexed approach to exchange energy via an auxiliary low-voltage (LV) bus using four converters. The proposed balancing systems are compared to two baseline systems, a single converter cell-to-cell balancing system, and a 14 converter balancing system with an auxiliary LV bus.

battery pack↗

DOE OSTI2023

Active SOC Balancing for a Multi-Chemistry Battery Pack with Reduced Number of Converters: Preprint

battery pack↗

DOE OSTI2022

A Fast-Response High-Accuracy Overvoltage Protection Circuit for Soft-Switching Current-Source Converters

Although voltage-source converters (VSCs) have been a focus of research for decades and are widely applied in numerous applications, they face great challenges in short-circuit failures, high dv/dt and electromagnetic interference (EMI), especially using wide bandgap devices. Instead, current-source converters (CSCs) are attracting increasing attention in recent years owing to their friendliness to short-circuit faults, improved EMI, etc. For CSCs, overvoltage is the most catastrophic failure since the semiconductor devices can hardly withstand an overvoltage for a short pulse. In this paper, a fast-response high-accuracy overvoltage protection (OVP) circuit is proposed to protect CSCs from overvoltage damage. It also features a small form factor, good noise-immunity, friendly retrofit capability, and no need for active switches. In this paper, the operating principle and design guideline of the proposed OVP circuit is introduced. Its effectiveness is validated in soft-switching solid-state transformer (S4T) at 500 V. In experiments, the voltage detection error of less than 5% and a propagation delay of fewer than 400 ns have been achieved.

30 DIRECT ENERGY CONVERSION↗

DOE OSTI2021

Hydrodynamic-dissipation relation for characterizing flow stagnation

Hydrodynamic stagnation converts flow energy into internal energy. Here we develop a technique to directly analyze this hydrodynamic-dissipation process, which also yields a lengthscale associated with the conversion of flow energy to internal energy. We demonstrate the usefulness of this analysis for finding and comparing the hydrodynamic-stagnation dynamics of implosions theoretically, and in a test application to Z-pinch implosion data.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1992

Coronal loops - Current-based heating processes

Based on new observations, a theoretical model of magnetic-field related heating processes in the solar corona is given. In this model, field-aligned currents are induced along coronal loops in thin current sheaths. Excitation of instabilities involving magnetic reconnection converts the energy associated with the current-related magnetic field directly into particle energy, where the heating process proceeds via short bursts corresponding to an intermittent disruption of the current sheath configuration. Because of the relatively low transverse thermal conduction, only a small fraction of the loop volume is heated to a much higher temperature than the average value. This is consistent with experimental observations of low filling factors of hot plasmas in coronal loops. Thus the model involves a repeated sequence of dynamic events taking into account the observed loop topology, the differential emission measure distribution in the 10 exp 6 - 10 exp 7 K range, the energy balance requirements in the loop, and the probable duty cycles involved in the heating processes.

Beaufume, P.↗

DOE OSTI2026

Scalable, low-cost ink-based processing of high-performance silver selenide thermoelectrics

The growing global energy demand and its accelerating contribution to climate change emphasize the urgent need for sustainable energy conversion/harvesting technologies. Thermoelectric (TE) devices offer a compelling route to directly convert waste heat into electricity and enable solid-state cooling without moving parts or harmful refrigerants. Achieving their full potential requires not only higher TE performance (zT) but also scalable, low-cost manufacturing processes. Here, we introduce a transformative ink-based processing approach for scalable manufacturing of high-performance silver selenide-based TE materials and devices. Using a simple, high-throughput ink-mixing and blade coating strategy, our Ag 2 Se-based materials under the optimized composition and processing conditions yield an ultrahigh room-temperature power factor of 2.8 mW m −1 K −2 , over 100% higher than baseline samples and a reproducible figure of merit zT of 1 at room temperature. A thermoelectric generator (TEG) achieves a very competitive power density of 112 mW cm −2 at a 90 °C temperature difference between the hot and cold sides of the device, which is among the highest reported for silver selenide-based TE devices to date. This facile, scalable ink-based processing establishes a practical pathway toward industrial-scale manufacturing and widespread adoption of thermoelectric devices, advancing sustainable energy technologies.

Bappy, Md. Omarsany [University of Notre Dame, IN ↗