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Advanced Subsonic Combustion Rig

Researchers from the NASA Lewis Research Center have obtained the first combustion/emissions data under extreme future engine operating conditions. In Lewis' new world-class 60-atm combustor research facility--the Advanced Subsonic Combustion Rig (ASCR)--a flametube was used to conduct combustion experiments in environments as extreme as 900 psia and 3400 F. The greatest challenge for combustion researchers is the uncertainty of the effects of pressure on the formation of nitrogen oxides (NOx). Consequently, U.S. engine manufacturers are using these data to guide their future combustor designs. The flametube's metal housing has an inside diameter of 12 in. and a length of 10.5 in. The flametube can be used with a variety of different flow paths. Each flow path is lined with a high-temperature, castable refractory material (alumina) to minimize heat loss. Upstream of the flametube is the injector section, which has an inside diameter of 13 in. and a length of 0.5-in. It was designed to provide for quick changeovers. This flametube is being used to provide all U.S. engine manufacturers early assessments of advanced combustion concepts at full power conditions prior to engine production. To date, seven concepts from engine manufacturers have been evaluated and improved. This collaborated development can potentially give U.S. engine manufacturers the competitive advantage of being first in the market with advanced low-emission technologies.

Lee, Chi-Ming

User Guide for TROPICS Data Products

This document provides information for using the data products available from the “Time-Resolved Observations of Precipitation structure and storm Intensity with a Constellation of Smallsats” (TROPICS) mission. The TROPICS mission will produce a range of data products that will be available at the NASA Goddard Earth Sciences Data and Information Services Center (GES DISC). The data products will be produced at the TROPICS Data Processing Center (UW-M SSEC), and consist of Level-1 radiances (antenna and brightness temperatures), Level-2a unified resolution radiance, Level-2b Atmospheric Vertical Temperature Profiles (AVTP), Level-2b Atmospheric Vertical Moisture Profiles (AVMP), Level-2b Instantaneous Surface Rain Rate (ISRR), and Level-2b Tropical Cyclone (TC) intensity algorithms to estimate two primary variables: Minimum Sea Level Pressure (MSLP) and Maximum Sustained Winds (MSW). Two independent intensity estimation methods are included: 1) the Tropical Cyclone Intensity Estimate algorithm (TCIE) developed at the University of Wisconsin/CIMSS using native microwave brightness temperatures and 2) the Hurricane Intensity and Structure Algorithm (HISA) developed at Colorado State University/CIRA using microwave retrievals of temperature, moisture, and integrated quantities. In addition to MSW and MSLP, HISA also provides estimates of surface wind radii and 2D winds at standard pressure levels. TROPICS is adapting the NOAA STAR Microwave Integrated Retrieval System (MIRS) to retrieve the AVTP and AVMP data products. The ISRR algorithm uses the NASA Goddard Precipitation Retrieval and Profiling Scheme (PRPS).

TROPICS

Unalakleet Climate: Analyzing Permafrost Degradation and Drainage Networks in Unalakleet, Alaska

The coastal community of Unalakleet is currently the 8th most at-risk community in Alaska due to the adverse effects of climate change that include permafrost degradation, severe coastal erosion, and sea-level rise-induced flood inundation caused by increasingly frequent storm surges. In response, the community has started a managed relocation with support from the Native Village of Unalakleet (NVU) and the National Renewable Energy Lab (NREL)’s Alaska campus in Fairbanks. The Unalakleet Climate NASA DEVELOP team partnered with NREL to provide remote sensing support and analysis for resilience planning in Unalakleet, supporting their ongoing relocation efforts and guiding future expansion. The team utilized Sentinel-1 C-Synthetic Aperture Radar (SAR), WorldView-2, and WorldView-3 datasets from 2017 – 2023 to analyze seasonal summer subsidence and utilized a 2014 Ancillary USGS 5 m Alaska DEM to conduct drainage network analyses that included watershed delineation and Height Above Nearest Drainage (HAND) analysis. The team also used high-resolution WorldView images to locate stable reference points that served as quality control for the team’s analyses. The team’s end products included maps containing subsidence and drainage zones information at and surrounding the relocation site. The team’s products provide NREL with valuable data that enables them to better assist Unalakleet’s managed relocation and assists Unalakleet with adapting to the catastrophic effects of climate change and build resilience in a community on the front lines of climate change.

Ian Lee

State-Estimation Algorithm Based on Computer Vision

An algorithm and software to implement the algorithm are being developed as means to estimate the state (that is, the position and velocity) of an autonomous vehicle, relative to a visible nearby target object, to provide guidance for maneuvering the vehicle. In the original intended application, the autonomous vehicle would be a spacecraft and the nearby object would be a small astronomical body (typically, a comet or asteroid) to be explored by the spacecraft. The algorithm could also be used on Earth in analogous applications -- for example, for guiding underwater robots near such objects of interest as sunken ships, mineral deposits, or submerged mines. It is assumed that the robot would be equipped with a vision system that would include one or more electronic cameras, image-digitizing circuitry, and an imagedata- processing computer that would generate feature-recognition data products.

Bayard, David

Unlocking the potential: machine learning applications in electrocatalyst design for electrochemical hydrogen energy transformation

Machine learning (ML) is rapidly emerging as a pivotal tool in the hydrogen energy industry for the creation and optimization of electrocatalysts, which enhance key electrochemical reactions like the hydrogen evolution reaction (HER), the oxygen evolution reaction (OER), the hydrogen oxidation reaction (HOR), and the oxygen reduction reaction (ORR). This comprehensive review demonstrates how cutting-edge ML techniques are being leveraged in electrocatalyst design to overcome the time-consuming limitations of traditional approaches. ML methods, using experimental data from high-throughput experiments and computational data from simulations such as density functional theory (DFT), readily identify complex correlations between electrocatalyst performance and key material descriptors. Leveraging its unparalleled speed and accuracy, ML has facilitated the discovery of novel candidates and the improvement of known products through its pattern recognition capabilities. This review aims to provide a tailored breakdown of ML applications in a format that is readily accessible to materials scientists. Hence, we comprehensively organize ML-driven research by commonly studied material types for different electrochemical reactions to illustrate how ML adeptly navigates the complex landscape of descriptors for these scenarios. We further highlight ML's critical role in the future discovery and development of electrocatalysts for hydrogen energy transformation. Potential challenges and gaps to fill within this focused domain are also discussed. As a practical guide, we hope this work will bridge the gap between communities and encourage novel paradigms in electrocatalysis research, aiming for more effective and sustainable energy solutions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Information Management Platform for Data Analytics and Aggregation (IMPALA) System Design Document

The System Design document tracks the design activities that are performed to guide the integration, installation, verification, and acceptance testing of the IMPALA Platform. The inputs to the design document are derived from the activities recorded in Tasks 1 through 6 of the Statement of Work (SOW), with the proposed technical solution being the completion of Phase 1-A. With the documentation of the architecture of the IMPALA Platform and the installation steps taken, the SDD will be a living document, capturing the details about capability enhancements and system improvements to the IMPALA Platform to provide users in development of accurate and precise analytical models. The IMPALA Platform infrastructure team, data architecture team, system integration team, security management team, project manager, NASA data scientists and users are the intended audience of this document. The IMPALA Platform is an assembly of commercial-off-the-shelf (COTS) products installed on an Apache-Hadoop platform. User interface details for the COTS products will be sourced from the COTS tools vendor documentation. The SDD is a focused explanation of the inputs, design steps, and projected outcomes of every design activity for the IMPALA Platform through installation and validation.

Carnell, Andrew

Remote Sensing and Fluxes Upscaling for Real-world Impact (Workshop Report)

The "Remote Sensing and Fluxes Upscaling for Real-world Impact" workshop, held on July 9-10, 2024, at Lawrence Berkeley National Lab, was a collaborative effort led by the AmeriFlux Management Project, NEON, and the Carbon Dew Community of Practice. The event brought together over 200 registrants and approximately 100 attendees each day, including leading experts, researchers, and practitioners. The primary focus was on bridging the gap between cutting-edge research and practical applications in environmental monitoring by integrating remote sensing and flux data. Key themes included the importance of site-level measurements for validating remote sensing products, providing nature-based climate solutions, and addressing challenges such as instrument costs and the need for standardized methods. At the regional scale, discussions centered on addressing spatial heterogeneity and using high-resolution remote sensing and machine learning methods to enhance data interpretation. Global scale challenges included data consistency, gap filling, and accurate emission source identification, with opportunities for international collaboration and standardized practices to improve global carbon budget assessments. The workshop emphasized the critical need for integrating data across local, regional, and global scales through explicit scale-matching and developed a workflow for scaling flux data using "straight shot" and "explicit nesting" approaches. The event highlighted the importance of connecting scientific research with real-world applications in carbon, energy, and water management, ensuring that advancements translate into tangible societal benefits. These insights will guide future research, technology transfer, and collaboration, maximizing the potential of environmental fluxes to address real-world challenges.

97 MATHEMATICS AND COMPUTING

Drought Impacts on Agricultural Production and Land Fallowing in California's Central Valley in 2015

The ongoing drought in California substantially reduced surface water supplies for millions of acres of irrigated farmland in California's Central Valley. Rapid assessment of drought impacts on agricultural production can aid water managers in assessing mitigation options, and guide decision making with respect to mitigation of drought impacts. Satellite remote sensing offers an efficient way to provide quantitative assessments of drought impacts on agricultural production and increases in fallow acreage associated with reductions in water supply. A key advantage of satellite-based assessments is that they can provide a measure of land fallowing that is consistent across both space and time. We describe an approach for monthly and seasonal mapping of uncultivated agricultural acreage developed as part of a joint effort by USGS, USDA, NASA, and the California Department of Water Resources to provide timely assessments of land fallowing during drought events. This effort has used the Central Valley of California as a pilot region for development and testing of an operational approach. To provide quantitative measures of uncultivated agricultural acreage from satellite data early in the season, we developed a decision tree algorithm and applied it to time-series data from Landsat TM (Thematic Mapper), ETM+ (Enhanced Thematic Mapper Plus), OLI (Operational Land Imager), and MODIS (Moderate Resolution Imaging Spectroradiometer). Our effort has been focused on development of indicators of drought impacts in the March-August timeframe based on measures of crop development patterns relative to a reference period with average or above average rainfall. To assess the accuracy of the algorithms, monthly ground validation surveys were conducted across 650 fields from March-September in 2014 and 2015. We present the algorithm along with updated results from the accuracy assessment, and data and maps of land fallowing in the Central Valley in 2015.

Valleys

NASA-Modified Precipitation Products to Improve EPA Nonpoint Source Water Quality Modeling for the Chesapeake Bay

The Environmental Protection Agency (EPA) has estimated that over 20,000 water bodies within the United States do not meet water quality standards. Ninety percent of the impairments are typically caused by nonpoint sources. One of the regulations in the Clean Water Act of 1972 requires States to monitor the Total Maximum Daily Load (TMDL), or the amount of pollution that can be carried by a water body before it is determined to be "polluted", for any watershed in the U.S.. In response to this mandate, the EPA developed Better Assessment Science Integrating Nonpoint Sources (BASINS) as a Decision Support Tool (DST) for assessing pollution and to guide the decision making process for improving water quality. One of the models in BASINS, the Hydrological Simulation Program -- Fortran (HSPF), computes daily stream flow rates and pollutant concentration at each basin outlet. By design, precipitation and other meteorological data from weather stations serve as standard model input. In practice, these stations may be unable to capture the spatial heterogeneity of precipitation events especially if they are few and far between. An attempt was made to resolve this issue by substituting station data with NASA modified/NOAA precipitation data. Using these data within HSPF, stream flow was calculated for seven watersheds in the Chesapeake Bay Basin during low flow periods, convective storm periods, and annual flows. In almost every case, the modeling performance of HSPF increased when using the NASA-modified precipitation data, resulting in better stream flow statistics and, ultimately, in improved water quality assessment.

Nigro, Joseph

Transient Ejector Analysis (TEA) code user's guide

A FORTRAN computer program for the semi analytic prediction of unsteady thrust augmenting ejector performance has been developed, based on a theoretical analysis for ejectors. That analysis blends classic self-similar turbulent jet descriptions with control-volume mixing region elements. Division of the ejector into an inlet, diffuser, and mixing region allowed flexibility in the modeling of the physics for each region. In particular, the inlet and diffuser analyses are simplified by a quasi-steady-analysis, justified by the assumption that pressure is the forcing function in those regions. Only the mixing region is assumed to be dominated by viscous effects. The present work provides an overview of the code structure, a description of the required input and output data file formats, and the results for a test case. Since there are limitations to the code for applications outside the bounds of the test case, the user should consider TEA as a research code (not as a production code), designed specifically as an implementation of the proposed ejector theory. Program error flags are discussed, and some diagnostic routines are presented.

Drummond, Colin K.

Reuse metrics and measurement: A framework

The lessons learned and experience gleaned are described by those who have started to implement the reuse metrics and measurement framework used in controlling the development of common avionics and software for its affiliated aircraft programs. The framework was developed to permit the measurement of the long term cost/benefits resulting from the creation and use of Reusable Software Objects (RSOs). The framework also monitors the efficiency and effectiveness of the Software Reuse Library (SRL). The metrics and measurement framework is defined which was established to allow some determinations and findings to be made relative to software reuse. Seven criteria are discussed which were used to guide the establishment of the proposed reuse framework. Object recapture and creation metrics are explained along with their normalized use in effort, productivity, and quality determination. A single and multiple reuse instance version of a popular cost model is presented which uses these metrics and the measurement scheme proposed to predict the software effort and duration under various reuse assumptions. Studies in using this model to predict actuals taken from the RCI data base of over 1000 completed projects is discussed.

Reifer, Donald J.

Data for Selective Oxidation of 3-Hydroxypropionic Acid to Malonic Acid over Pd/C: Mechanistic and Kinetic Study

Malonic acid (MA) is a high-value dicarboxylic acid with strong industrial demand, yet its current production heavily relies on petrochemical feedstocks. Here, we report the first systematic study for the sustainable production of MA via oxidation of 3-hydroxypropionic acid (3-HP) with a Pd/Carbon catalyst. The effects of oxidant type (O2 and H2O2), pH, and temperature on the reaction chemistry were comprehensively evaluated. Guided by experimental observation and DFT-calculated thermochemical energetics, reaction networks for 3-HP oxidation with both oxidants are proposed and validated through kinetic modeling. MA was identified as the primary oxidation product, while further oxidation yields acetic acid and oxalic acid. The kinetic model validated the network, displaying excellent agreement (R2 > 0.95). Kinetic observations also enabled a direct comparison between O2 and H2O2 and revealed their distinct behaviors. The model was further developed into a temperature-time map, providing insight into conditions that maximize MA production. Malonic acid selectivity of 56.9 % and yield of 50.5 % were achieved at 3 bar oxygen, equimolar NaOH:3-HP ratio, and 50 °C.

Bioproducts

Terrain Relative Navigation for Guided Descent on Titan

Titan’s dense atmosphere, low gravity, and high winds at high altitudes create descent times of >90 minutes with standard entry/descent/landing (EDL) architectures and result in large unguided landing ellipses, with 99% values of 110x110 km and 149x72 km in recent Titan lander proposals. Enabling precision landing on Titan could increase science return for the types of missions proposed to date and make additional types of landing sites accessible, opening up new possibilities for science investigations. Precision landing on Titan has unique challenges, because the hazy atmosphere makes it difficult to see the surface and because it requires guided descent with divert ranges that are one to two orders of magnitude larger than needed for other target bodies, i.e. up to on the order of 100 km. It is conceivable that such a divert capability could be provided economically by a parafoil or other steerable aerodynamic decelerator deployed several 10s of km above the surface. The long descent times lead to large inertial navigation errors, hence a need for terrain relative navigation (TRN). This would require a TRN capability that can operate at such altitudes, despite challenges of seeing the surface sufficiently clearly and of depending on map products that are two orders of magnitude lower in spatial resolution than those for Mars and airless bodies. We then develop algorithms for map matching and feature tracking with descent images and test these with synthetic images created from Cassini/Huygens data sets and our radiative transfer model. We also introduce new possibilities for TRN based on the potential to discriminate some specific types of terrain onboard in descent imagery, such as lake vs adjacent ground and dune vs interdune. We use sensor measurement noise models in simulations of state estimation with an extended Kalman filter that includes coordinates of a set of tracked features in the state vector. Case studies were done for two notional landing sites, one in a site with only dry ground and one in a Titan lake district. In both cases, the filter error model shows 3 position error at touchdown on the order of 2 km. More work is needed to validate these results with higher fidelity camera models and larger data sets, but this is very promising.

Matthies, Larry

ThermoPI—an Online Tool to Calculate Heat Transfer Through Foam Insulation

Thermal insulation materials with ultra-low effective thermal conductivity are crucial for a multitude of applications. Over the years, a significant amount of experimental work has been dedicated to creating new insulation materials with low thermal conductivity. Similarly, substantial efforts have been made to enhance the theoretical understanding of thermal transport mechanisms in thermal insulation materials and to push the boundaries of lower thermal conductivity. However, ample room remains for enhancing the thermal resistivity of closed-cell foam insulations. To aid in the development of ultra-low effective thermal conductivity foam insulations, Oak Ridge National Laboratory has introduced a unique online tool, ThermoPI. This tool calculates not only the effective thermal conductivity but also the thermal conductivity components for porous materials, including gases, solids, and radiative, based on the materials’ structural information (e.g., porosity, pore size, gas species, pressure, solid species, pore geometry, and temperature).This tool collected and improved the existing theoretical models for thermal insulation materials’ gas, solid, and radiative thermal conductivity. These improved models have been validated with experimental data. Effective medium theory and sound velocity softening effects are considered for solid thermal conductivity. The built-in solid materials include polystyrene, polyurethane, polyethylene, and silica. Users are allowed to input new solid materials that are not built inside the tool. For gas thermal conductivity, the subcontinuum Knudsen effect is considered. In addition to several built-in gases, users can input new gases. For solid and radiative thermal conductivity calculations, several models are available to select, and the tool can determine the best model to choose based on the materials that users input. Users are also allowed to change selections manually. In addition, the tool can also calculate the effect of interfacial resistance on the overall thermal conductivity of layered materials. This work will elaborate on the tool and discuss how it can guide the development of new insulation products.

Shrestha, Som [ORNL] (ORCID:0000000183993797)

Micromechanics Analysis Code Post-Processing (MACPOST) User Guide

As advanced composite materials have gained wider usage. the need for analytical models and computer codes to predict the thermomechanical deformation response of these materials has increased significantly. Recently, a micromechanics technique called the generalized method of cells (GMC) has been developed, which has the capability to fulfill this -oal. Tc provide a framework for GMC, the Micromechanics Analysis Code with Generalized Method of Cells (MAC/GMC) has been developed. As MAC/GMC has been updated, significant improvements have been made to the post-processing capabilities of the code. Through the MACPOST program, which operates directly within the MSC/PATRAN graphical pre- and post-processing package, a direct link between the analysis capabilities of MAC/GMC and the post-processing capabilities of MSC/PATRAN has been established. MACPOST has simplified the production, printing. and exportation of results for unit cells analyzed by MAC/GMC. MACPOST allows different micro-level quantities to be plotted quickly and easily in contour plots. In addition, meaningful data for X-Y plots can be examined. MACPOST thus serves as an important analysis and visualization tool for the macro- and micro-level data generated by MAC/GMC. This report serves as the user's manual for the MACPOST program.

Goldberg, Robert K.

Data and code from: Selective oxidation of 3-hydroxypropionic acid to malonic acid over Pd/C: Mechanistic and kinetic study

Malonic acid (MA) is a high-value dicarboxylic acid with strong industrial demand, yet its current production heavily relies on petrochemical feedstocks. Here, we report the first systematic study for the sustainable production of MA via oxidation of 3-hydroxypropionic acid (3-HP) with a Pd/Carbon catalyst. The effects of oxidant type (O2 and H2O2), pH, and temperature on the reaction chemistry were comprehensively evaluated. Guided by experimental observation and DFT-calculated thermochemical energetics, reaction networks for 3-HP oxidation with both oxidants are proposed and validated through kinetic modeling. MA was identified as the primary oxidation product, while further oxidation yields acetic acid and oxalic acid. The kinetic model validated the network, displaying excellent agreement (R2 > 0.95). Kinetic observations also enabled a direct comparison between O2 and H2O2 and revealed their distinct behaviors. The model was further developed into a temperature-time map, providing insight into conditions that maximize MA production. Malonic acid selectivity of 56.9 % and yield of 50.5 % were achieved at 3 bar oxygen, equimolar NaOH:3-HP ratio, and 50 °C.

3-Hydroxypropionic Acid

Unlocking the Tight Oil Reservoirs of the Powder River Basin, Wyoming

The project focused on detailed geologic characterization, geomechanical studies, well completion optimization, stimulation monitoring, and field development strategies. A key aspect involved partnerships with industry and academic collaborators such as Occidental Petroleum, Southern Illinois University, Britt Rock Mechanics and Piri Technologies. Data acquisition included drilling, logging, coring, deployment of fiber optics, and microseismic monitoring. The project emphasized feedback loops for continuous model updating and integration of economic evaluations to guide development strategies.

02 PETROLEUM

Yield From Iowa's First Commercial Miscanthus Fields: Implications of Spatial Variability for Productivity and Sustainability Beyond Research Plots

The cultivation of sterile giant miscanthus (Miscanthus × giganteus, M × g) for bioenergy and bioproducts has expanded into grain-cropped land in the United States (US) as local markets developed for this high-yielding perennial grass (10–30 Mg DM ha −1 ). However, the magnitude of spatial and temporal variability in yield within US Corn Belt fields, along with impacts on economic return and sustainable land management, is poorly understood. This study established a diagnostic model relating remote sensing-derived vegetation indices to ground truth data from 105 hand-harvested stem biomass samples, which were strategically selected to represent the full range of vegetation index observations. The high-resolution satellite-sensed vegetation indices captured > 90% of the yield variation measured within fields. This model was then used to predict yield variability and assess economic performance across four of the first commercial M × g fields in the Corn Belt state of Iowa, US. Significant spatial variability in biomass dry matter (DM) yields (9.3–18.1 Mg DM ha −1 ) and net profits ($\$$83 to $\$$1211.5 ha −1 ) was observed. All fields were profitable in all site-years. When low profit occurred, it was explained by limited management experience of the crop in Iowa. The breakeven yield at a selling price of $\$$130 Mg −1 varied from 9.0–12.1 Mg ha −1 at 15% moisture content (7.6–10.3 Mg DM ha −1 ). Breakeven prices ranged from $\$$73 to $\$$122.4 Mg −1 , matching ranges used in the Department of Energy Billion Ton Report (US Department of Energy, 2023). Notably, M × g yield and profits were commensurate with grain crops particularly with favorable precipitation. This study provides insight on the M × g management “learning curve”, performance on marginal land and in drought conditions, and demonstrates that addressing yield gaps, reducing costs, and implementing precision agriculture strategies can enhance profitability. These findings emphasize the value of remote sensing technologies in guiding sustainable and competitive commercial-scale M × g production.

60 APPLIED LIFE SCIENCES