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At least 127 records · Page 7

Molecular and mass spectroscopic analysis of isotopically labeled organic residues

Experimental studies aimed at understanding the evolution of complex organic molecules on interstellar grains were performed. The photolysis of frozen gas mixtures of various compositions containing H2O, CO, NH3, and CH4 was studied. These species were chosen because of their astrophysical importance as deducted from observational as well as theoretical studies of ice mantles on interstellar grains. These ultraviolet photolyzed ices were warmed up in order to produce refractory organic molecules like the ones formed in molecular clouds when the icy mantles are being irradiated and warmed up either by a nearby stellar source or impulsive heating. The laboratory studies give estimates of the efficiency of production of such organic material under interstellar conditions. It is shown that the gradual carbonization of organic mantles in the diffuse cloud phase leads to higher and higher visual absorptivity - yellow residues become brown in the laboratory. The obtained results can be applied to explaining the organic components of comets and their relevance to the origin of life.

Mendoza-Gomez, Celia X.

An experimental investigation of boundary layer transition in an adverse pressure gradient

The evolution of a small perturbation introduced periodically into a boundary layer with a moderately strong adverse pressure gradient (APG) was investigated experimentally using the hot-wire method. The magnitude of the disturbance is found to decay with the streamwise distance in the APG before undergoing rapid growth and triggering transition in a very repetitive manner. The evidence suggests that the laminar layer separates and that the transition mechanism is an inviscid shear-layer type of instability. Contours of spanwise vorticity in the plane of the disturbance show the formation of roll-ups in the initial stages. Subsequent interaction with the wall leads to the formation of large-scale vortex loops which merge into a single vortex loop further downstream.

Watmuff, Jonathan H.

A new technique for in situ measurement of the composition of neutral gas in interplanetary space

Neutral atoms in interplanetary space play an important role in many processes relevant to the formation and evolution of the Solar System. An experimental approach is proposed for in situ atom detection based on the conversion of neutral atoms to negative ions at a specially prepared sensitive surface. Negative ions are subsequently analyzed and detected in an essentially noise-free mode. The use of the technique for in situ study of the composition of neutral interstellar atoms is considered. It is shown that interstellar H, D, and O atoms and possibly H2 molecules can be measured by the proposed technique. The experiment can be performed from a high-apogee Earth-orbiting satellite or from a deep space probe. Possible applications of the technique are discussed.

Gruntman, Michael A.

On the Environmental Realizability of Algebraically Growing Disturbances and Their Relation to Klebanoff Modes

A theoretical explanation of some experimentally observed phenomena associated with the so-called Klebanoff modes is obtained by analyzing the flow over a finite thickness flat plate resulting from a small-amplitude distortion imposed on the upstream mean flow. The analysis shows (among other things) how the stretching of the vortex lines around the plate leads to streamwise vorticity at the plate surface, which then produces a streamwise velocity perturbation within the boundary layer that can be related to the experimentally observed Klebanoff mode. The complete evolution of this flow must be found by solving the boundary-region equations of Kemp (1951) and Davis and Rubin (1980), but a limiting analytical solution can also be obtained. Since the initial growth of the boundary-layer disturbance is nearly algebraic, our results demonstrate how the algebraically growing disturbances promoted by Landahl and others can be generated by a realistic external-disturbance environment. The relationship between these results and various bypass transition mechanisms is discussed.

Goldstein, Marvin E.

On the Environmental Realizability of Algebraically Growing Disturbances and Their Relation to Klebanoff Modes

A theoretical explanation of some experimentally observed phenomena associated with the so-called Klebanoff modes is obtained by analyzing the flow over a finite thickness flat plate resulting from a small-amplitude distortion imposed on the upstream mean flow. The analysis shows (among other things) how the stretching of the vortex lines around the plate leads to streamwise vorticity at the plate surface, which then produces a streamwise velocity perturbation within the boundary layer that can be related to the experimentally observed Klebanoff mode. The complete evolution of this flow must be found by solving the boundary-region equations of Kemp (1951) and Davis and Rubin (1980), but a limiting analytical solution can also be obtained. Since the initial growth of the boundary-layer disturbance is nearly algebraic, our results demonstrate how the algebraically growing disturbances promoted by Landahl and others can be generated by a realistic external-disturbance environment. The relationship between these results and various bypass transition mechanisms is discussed.

Goldstein, M. E.

Evaluation of Production Cross Sections of Li, Be, B in CR

Accurate evaluation of the production cross section of light elements is important for models of cosmic ray (CR) propagation, galactic chemical evolution, and cosmological studies. However, the experimental spallation cross section data are scarce and often unavailable to CR community while semi-empirical systematics are frequently wrong by a significant factor. Running sophisticated nuclear codes is not an option of choice for everyone either. We use the Los Alamos versions of the Quark-Gluon String Model code LAQGSM and the improved Cascade-Exciton Model code CEM2k together with all available data from Los Alamos Nuclear Laboratory (LANL) nuclear database to produce evaluated production cross sections of isotopes of Li, Be, and B suitable for astrophysical applications. The LAQGSM and CEM2k models have been shown to reproduce well nuclear reactions and hadronic data in the range 0.01-800 GeV/nucleon.

Moskalenko, I. V.

Lunar and Planetary Science XXXVI, Part 4

Contents include the following: High-Resolution Electron Energy-Loss Spectroscopy (HREELS) Using a Monochromated TEM/STEM. Dynamical Evolution of Planets in Open Clusters. Experimental Petrology of the Basaltic Shergottite Yamato 980459: Implications for the Thermal Structure of the Martian Mantle. Cryogenic Reflectance Spectroscopy of Highly Hydrated Sulfur-bearing Salts. Implications for Core Formation of the Earth from High Pressure-Temperature Au Partitioning Experiments. Uranium-Thorium Cosmochronology. Protracted Core Differentiation in Asteroids from 182Hf-182W Systematics in the Eagle Station Pallasite. Maximizing Mission Science Return Through Use of Spacecraft Autonomy: Active Volcanism and the Autonomous Sciencecraft Experiment. Classification of Volcanic Eruptions on Io and Earth Using Low-Resolution Remote Sensing Data. Isotopic Mass Fractionation Laws and the Initial Solar System (sup26)Al/(sup27)Al Ratio. Catastrophic Disruption of Porous and Solid Ice Bodies (sup187)Re-(sup187)Os Isotope Disturbance in LaPaz Mare Basalt Meteorites. Comparative Petrology and Geochemistry of the LaPaz Mare Basalt Meteorites. A Comparison of the Structure and Bonding of Carbon in Apex Chert Kerogenous Material and Fischer-Tropsch-Type Carbons. Broad Spectrum Characterization of Returned Samples: Orientation Constraints of Small Samples on X-Ray and Other Spectroscopies. Apollo 14 High-Ti Picritic Glass: Oxidation/Reduction by Condensation of Alkali Metals. New Lunar Meteorites from Oman: Dhofar 925, 960 and 961. The First Six Months of Iapetus Observations by the Cassini ISS Camera. First Imaging Results from the Iapetus B/C Flyby of the Cassini Spacecraft. Radiative Transfer Calculations for the Atmosphere of Mars in the 200-900 nm Range. Geomorphologic Map of the Atlantis Basin, Terra Sirenum, Mars. The Meaning of Iron 60: A Nearby Supernova Injected Short-lived Radionuclides into Our Protoplanetary Disk.

Source record

Development and Characterization of a Rate-Dependent Three-Dimensional Macroscopic Plasticity Model Suitable for Use in Composite Impact Problems

Several key capabilities have been identified by the aerospace community as lacking in the material/models for composite materials currently available within commercial transient dynamic finite element codes such as LS-DYNA. Some of the specific desired features that have been identified include the incorporation of both plasticity and damage within the material model, the capability of using the material model to analyze the response of both three-dimensional solid elements and two dimensional shell elements, and the ability to simulate the response of composites composed with a variety of composite architectures, including laminates, weaves and braids. In addition, a need has been expressed to have a material model that utilizes tabulated experimentally based input to define the evolution of plasticity and damage as opposed to utilizing discrete input parameters (such as modulus and strength) and analytical functions based on curve fitting. To begin to address these needs, an orthotropic macroscopic plasticity based model suitable for implementation within LS-DYNA has been developed. Specifically, the Tsai-Wu composite failure model has been generalized and extended to a strain-hardening based orthotropic plasticity model with a non-associative flow rule. The coefficients in the yield function are determined based on tabulated stress-strain curves in the various normal and shear directions, along with selected off-axis curves. Incorporating rate dependence into the yield function is achieved by using a series of tabluated input curves, each at a different constant strain rate. The non-associative flow-rule is used to compute the evolution of the effective plastic strain. Systematic procedures have been developed to determine the values of the various coefficients in the yield function and the flow rule based on the tabulated input data. An algorithm based on the radial return method has been developed to facilitate the numerical implementation of the material model. The presented paper will present in detail the development of the orthotropic plasticity model and the procedures used to obtain the required material parameters. Methods in which a combination of actual testing and selective numerical testing can be combined to yield the appropriate input data for the model will be described. A specific laminated polymer matrix composite will be examined to demonstrate the application of the model.

Impact

Modeling the Crystallization of Martian Igneous Compositions

The martian crust is dominated by basalts and ultramafic rocks [1]. Understanding the crystallization sequence of martian igneous rocks is critical for constraining the petrologic and geochemical evolution of the crust and mantle. Experimental studies have investigated the parental liquid compositions and crystallization behavior using martian meteorite compositions [2-7], as well as compositions measured by rovers on the martian surface [8,9]. While experiments deliver crucial results, they are often limited by time and resources. Therefore, modeling approaches are an ideal tool to complement experimental results. The application of the MELTS software package [10, 11], to calculate the crystallization of martian compositions, reproduces important compositional details of magma crystallization but significant uncertainties regarding the pressure of the olivine-pyroxene multiple saturation point have been reported [12], and in the temperatures of initial crystallization [12, 13]. Recently, a new melting model, MAGMARS, has been shown to reproduce martian primary melts more accurately [14]. Here, we constrain the applicability of Gibbs free energy minimization software Perple_X [15] for martian compositions by comparing our modeled results to experimentally derived crystallization paths for two martian compositions.

J Semprich

Exploration of Rayleigh-Taylor seeding mechanisms in laser- and pulsed-power-driven inertial fusion

The ubiquitous Rayleigh-Taylor instability (RTI) has been observed in fluids and plasmas in a wide range of parameter regimes from astrophysical to laboratory plasmas. In high-energy-density (HED) laboratory plasmas, such as laser-driven inertial confinement fusion (ICF) plasmas, the RTI can have a detrimental impact on achieving fusion ignition through the generation of hydrodynamic mix. Hence, an understanding of the seeding mechanisms that produce the RTI and identifying ways to mitigate hydrodynamic mix is of critical importance. Appropriately aligned magnetic fields have been known to stabilize short-wavelength RTI. A number of numerical and experimental studies have demonstrated the benefits of using imposed magnetic fields in laser-driven ICF to achieve higher ion temeratures, higher neutron yields, and a relaxation of the ignition criteria. This work addresses seeding mechanisms in laser-driven implosions to understand critical early-stage physics that ultimately leads to substantial growth of the RTI along with mechanisms for mitigation of this growth. Surface perturbations due to machining tolerances and single-feature seeds (for example due to fill tubes) can produce substantial RTI growth in the ignition-relevant high-convergence ratio targets for laser- driven ICF implosions. RTI growth from single-feature seeding in laser-based implosions has the potential to be mitigated through appropriately aligned externally applied magnetic fields and the goal of this work has been to quantify that numerically and experimentally. Resistive-magnetohydrodynamic (MHD) simu- lations are used to study the seeding and evolution of the RTI leveraging previous support from the DOE HEDLP program. Furthermore, experimental data has been obtained and applied towards code validation of unmagnetized and magnetized evolution of single-feature seeded RTI growth.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

A numerical cloud model for the support of laboratory experimentation

A numerical cloud model is presented which can describe the evolution of a cloud starting from moist aerosol-laden air through the diffusional growth regime. The model is designed for the direct support of cloud chamber laboratory experimentation, i.e., experiment preparation, real-time control and data analysis. In the model the thermodynamics is uncoupled from the droplet growth processes. Analytic solutions for the cloud droplet growth equations are developed which can be applied in most laboratory situations. The model is applied to a variety of representative experiments.

Hagen, D. E.

Non-Genomic Origins of Proteins and Metabolism

It is proposed that evolution of inanimate matter to cells endowed with a nucleic acid- based coding of genetic information was preceded by an evolutionary phase, in which peptides not coded by nucleic acids were able to self-organize into networks capable of evolution towards increasing metabolic complexity. Recent findings that truly different, simple peptides (Keefe and Szostak, 2001) can perform the same function (such as ATP binding) provide experimental support for this mechanism of early protobiological evolution. The central concept underlying this mechanism is that the reproduction of cellular functions alone was sufficient for self-maintenance of protocells, and that self- replication of macromolecules was not required at this stage of evolution. The precise transfer of information between successive generations of the earliest protocells was unnecessary and, possibly, undesirable. The key requirement in the initial stage of protocellular evolution was an ability to rapidly explore a large number of protein sequences in order to discover a set of molecules capable of supporting self- maintenance and growth of protocells. Undoubtedly, the essential protocellular functions were carried out by molecules not nearly as efficient or as specific as contemporary proteins. Many, potentially unrelated sequences could have performed each of these functions at an evolutionarily acceptable level. As evolution progressed, however proteins must have performed their functions with increasing efficiency and specificity. This, in turn, put additional constraints on protein sequences and the fraction of proteins capable of performing their functions at the required level decreased. At some point, the likelihood of generating a sufficiently efficient set of proteins through a non-coded synthesis was so small that further evolution was not possible without storing information about the sequences of these proteins. Beyond this point, further evolution required coupling between proteins and informational polymers that is characteristic to all known forms of life. The emergence of such coupling must be postulated in any scenario of the origin of life, no matter whether it starts with RNA or proteins. To examine the evolutionary potential of non-genomic systems, a simple, computationally tractable model, which is still capable of capturing the essential features of the real system, has been studied computationally. Both constructive and destructive processes have been introduced into the model in a stochastic manner. Instead of assuming random reaction sets, only a suite of protobiologically plausible reactions has been considered. Peptides have been explicitly considered as protoenzymes and their catalytic efficiencies have been assigned on the basis of biochemical principles and experimental estimates. Simulations have been carried out using a novel approach (The Next Reaction Method) that is appropriate even for very low concentrations of reactants. Studies have focused on global autocatalytic processes and their diversity.

Pohorille, Andrew

Global- to Micro-Scale Evolution of the Pinatubo Aerosol: Using Composite Data Sets to Build the Picture and Assess Consistency of Different Measurements

This paper brings together experimental. evidence required to build realistic models of the global evolution of physical, chemical, and optical properties of the aerosol resulting from the 1991 Pinatubo volcanic eruption. Such models are needed to compute the effects of the aerosol on atmospheric chemistry, dynamics, radiation, and temperature. Whereas there is now a large and growing body of post-Pinatubo measurements by a variety of techniques, some results are in conflict, and a self-consistent, unified picture is needed, along with an assessment of remaining uncertainties. This paper examines data from photometers, radiometers, impactors, optical counters/sizers, and lidars operated on the ground, aircraft, balloons, and spacecraft.

Russell, P. B.

2D kinetic-ion simulations of inverted corona fusion targets

Laser-driven “inverted corona” fusion targets have attracted interest as a low-convergence neutron source and platform for studying kinetic physics. The scheme consists of a hollow or gas-filled spherical shell made of deuterated plastic. The shell has one or more laser entrance holes (LEH), resembling a spherical hohlraum. The laser passes through the LEH’s and illuminates the interior surface of the shell, ablating a plasma that travels inward towards the target center. Long ion mean free paths in the converging plasma can lead to significant interpenetration, atomic mix, and other kinetic effects. Here, in this work we report on numerical simulations of inverted corona targets using the kinetic-ion, fluid–electron hybrid particle-in-cell (PIC) approach in 2D RZ geometry. 2D simulations suggest that shape effects do not have a significant impact on plasma evolution and observed yield trends are primarily the result of 1D kinetic mix mechanisms. Simulations are also compared against available experimental data recorded at the OMEGA laser facility. In particular, synthetic x-ray emission images show good qualitative agreement with experimental results, albeit with an apparent timing discrepancy for the two-sided vacuum target. More generally, we demonstrate the potential of hybrid-PIC simulations for full-system modeling and experimental design, including collisional absorption of laser energy, plasma evolution, mix, and fusion burn.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Experimental studies of crystal-melt differentiation in planetary basalt compositions

An important process that controls the evolution of magmas on and within planetary bodies is crystal-melt differentiation. Experimental studies of silicate melt solidification were performed on several planetary and terrestrial melt compositions, and experiments on one of these compositions in the microgravity environment of the space station would provide an opportunity to understand the factors that control crystal growth and crystal-melt exchange processes at crystal-melt interfaces during solidification. Experimental requirements are presented.

Grove, T. L.

Coarse-Grained Simulations of Polyrotaxane Hydrogels under Quiescent and Shear Conditions

Cyclodextrin-based polyrotaxanes (PR) form hydrogels in water through cyclodextrin (CD) aggregation and crystallization. These networks can break under shear flows, making them versatile platforms for extrusion-based 3D printing. To optimize the material properties of 3D-printed PR gels, a microscopic understanding of the structural evolution during 3D printing is necessary. Here, we employ coarse-grained (CG) simulations to reveal the PR assembly process at the molecular level. Our simulations reproduce the experimental crystal morphologies of PR at varying concentrations and chain lengths under quiescent conditions. Using nonequilibrium simulations, we show shear flow ruptures crystalline domain connectivity in PR gels and stacks the lamellae in the gradient direction, allowing the materials to flow during 3D printing. After the cessation of flow, the anisotropic crystal alignment and absence of available dangling PR diminish the intercrystal connectivity. The printed materials are therefore mechanically weaker than the pristine hydrogels, in agreement with experimental results. Nonetheless, by relating the microscopic structural evolution with viscoelastic properties of PR gels and solutions, we elucidate how flow conditions and sample composition affect the 3D printing performance of PR hydrogels.

Smith, Cameron D. [Dartmouth College, Hanover, NH

Pinatubo Aerosol Evolution: Using Composite Data Sets to Build the Global- To Micro-Scale Picture and Assess Consistency of Different Measurements

This paper brings together experimental evidence required to build realistic models of the global evolution of physical, chemical, and optical properties of the aerosol resulting from the 1991 Pinatubo volcanic eruption. Such models are needed to compute the effects of the aerosol on atmospheric chemistry, dynamics, radiation, and temperature. Whereas there is now a large and crowing body of post-Pinatubo measurements by a variety of techniques, some results are in conflict, and a self-consistent, unified picture is needed, along with an assessment of remaining uncertainties. This paper examines, data from photometers, radiometers, impactors, optical counter/sizers, and lidars operated on the ground, aircraft, balloons, and spacecraft. Example data sources include: (1) Tracking sunphotometers and lidars at Mauna Loa Observatory (MLO) and on the DC-8. (2) Particle spectrometers and wire impactors on the ER-2 and DC-8. (3) Dustsondes (particle counter/sizers on balloons). and (3) SAGE II, SAM II, AVHRR, CLAES, and ISAMS sensors on a variety of satellites. We assess the mutual consistency of these disparate data sets and recommend 'consensus' properties and uncertainties in the process of developing a composite data set. Recommended properties include the spatial and temporal evolution of particle chemical composition, shape, wavelength-and temperature-dependent refractive index, size distribution, and optical depth spectra. Supporting references are cited and representative data shown.

Russell, Philip B.

Pinatubo Aerosol Evolution: Using Composite Data Sets to Build the Global- to Micro-Scale Picture and Assess Consistency of Different Measurements

This paper brings together experimental evidence required to build realistic models of the global evolution of physical, chemical, and optical properties of the aerosol resulting from the 1991 Pinatubo volcanic eruption. Such models are needed to compute the effects of the aerosol on atmospheric chemistry, dynamics, radiation, and temperature. Whereas there is now a large and growing body of post-Pinatubo measurements by a variety of techniques, some results are in conflict, and a self-consistent, unified picture is needed, along with an assessment of remaining uncertainties. This paper examines data from photometers, radiometers, impactors, optical counters/sizers, and lidars operated on the ground, aircraft, balloons, and spacecraft. Example data sources include: - Tracking sunphotometers and lidars at Mauna Loa Observatory (MLO) and on the DC-8 - Particle spectrometers and wire impactors on the ER-2 and DC-8 - Dustsondes (particle counters/sizers on balloons) - SAGE II, SAM II, AVHRR, CLAES, and ISAMS sensors on a variety of satellites. We assess the mutual consistency of these disparate data sets and recommend 'consensus" properties and uncertainties in the process of developing a composite data set. Recommended properties include the spatial and temporal evolution of particle chemical composition, shape, wavelength and temperature-dependent refractive index, size distribution, and optical depth spectra. Supporting references are cited and representative data shown.

Russell, P. B.