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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Gas Generation in Lithium Cells with High-Nickel Cathodes and Localized High-Concentration Electrolytes

High-nickel layered-oxide cathodes (LiNi x Mn y Co 1-x-y O 2 , x ≥ 0.8) exhibit high capacities, but also experience rapid capacity fade during cycling, and are susceptible to heat generation and gas release. Advanced electrolytes, such as localized high-concentration electrolytes (LHCE), substantially stabilize the cathode during cycling and have lower flammability than conventional electrolytes, but gas generation with these electrolytes is yet to be assessed. We demonstrate here that gas generation from a high-nickel cathode in an LHCE is half as much as in a conventional electrolyte at 4.4 V. The gas generation in LHCE is further reduced at 4.3 V, but the LHCE generates a similar amount of gas as the conventional electrolyte at 4.6 V. Neither electrolyte can prevent gas generation after cycling; cathodes after 200 cycles generate similar amounts of gas as pristine cathodes during high-voltage hold. Finally, it is shown that in both electrolytes, oxygen from the cathode lattice plays a critical role in gas generation.

25 ENERGY STORAGE↗
DOE OSTI2013

Architecture, implementation, and testing of a multiple-shell gas injection system for high current implosions on the Z accelerator

Tests are ongoing to conduct {approx}20 MA z-pinch implosions on the Z accelerator at Sandia National Laboratory using Ar, Kr, and D{sub 2} gas puffs as the imploding loads. The relatively high cost of operations on a machine of this scale imposes stringent requirements on the functionality, reliability, and safety of gas puff hardware. Here we describe the development of a prototype gas puff system including the multiple-shell nozzles, electromagnetic drivers for each nozzle's valve, a UV pre-ionizer, and an inductive isolator to isolate the {approx}2.4 MV machine voltage pulse present at the gas load from the necessary electrical and fluid connections made to the puff system from outside the Z vacuum chamber. This paper shows how the assembly couples to the overall Z system and presents data taken to validate the functionality of the overall system.

42 ENGINEERING↗
DOE OSTI2018

Characterization of temporal variations and feedback timescales of exhaust gas recirculation gas properties using high-speed diode laser absorption spectroscopy for next-cycle control of cyclic variability

Dilute combustion offers efficiency gains in boosted gasoline direct injection engines both through knock-limit extension and thermodynamic advantages (i.e. the effect of γ on cycle efficiency), but is limited by cyclic variability at high dilution levels. Past studies have shown that the cycle-to-cycle dynamics are a combination of deterministic and stochastic effects. The deterministic causes of cyclic variations, which arise from feedback due to exhaust gas recirculation, imply the possibility of using active control strategies for dilution limit extension. While internal exhaust gas recirculation will largely provide a next-cycle effect (short-timescale feedback), the feedback of external exhaust gas recirculation will have an effect after a delay of several cycles (long timescale). Therefore, control strategies aiming to improve engine stability at dilution limit may have to account for both short- and long-timescale feedback pathways. This study shows the results of a study examining the extent to which variations in exhaust gas recirculation composition are preserved along the exhaust gas recirculation flow path and thus the relative importance and information content of the long-timescale feedback pathway. To characterize the filtering or retention of cycle-resolved feedback information, high-speed (1–5 kHz) CO 2 concentration measurements were performed simultaneously at three different locations along the low-pressure external exhaust gas recirculation loop of a four-cylinder General Motors gasoline direct injection engine using a multiplexed two-color diode laser absorption spectroscopy sensor system during steady-state and transient engine operation at various exhaust gas recirculation levels. It was determined that cycle-resolved feedback propagates through internal residual gases but is filtered out by the low-pressure exhaust gas recirculation flow system and do not reach the intake manifold. Intermediate variations driven by flow rate and compositional changes are also distinguished and identified.

Dilute combustion↗
DOE OSTI2015

A gas-loading system for LANL two-stage gas guns

A novel gas loading system was designed for the specific application of remotely loading high purity gases into targets for gas-gun driven plate impact experiments. The high purity gases are loaded into well-defined target configurations to obtain Hugoniot states in the gas phase at greater than ambient pressures.The small volume of the gas samples is challenging, as slight changing in the ambient temperature result in measurable pressure changes. Therefore, the ability to load a gas gun target and continually monitor the sample pressure prior to firing provides the most stable and reliable target fielding approach. We present the design and evaluation of a gas loading system built for the LANL 50 mm bore two-stage light gas gun. Targets for the gun are made of 6061 Al or OFHC Cu, and assembled to form a gas containment cell with a volume of approximately 1.38 cc. The compatibility of materials was a major consideration in the design of the system, particularly for its use with corrosive gases. Piping and valves are stainless steel with wetted seals made from Kalrez® and Teflon®. Preliminary testing was completed to ensure proper flow rate and that the proper safety controls were in place. The system has been used to successfully load Ar, Kr, Xe, and anhydrous ammonia with purities of up to 99.999 percent. The design of the system and example data from the plate impact experiments will be shown.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

CO 2 capture from natural gas power plants using selective exhaust gas recycle membrane designs

This paper describes membrane processes to capture the CO 2 produced by combustion gas turbines in natural gas combined cycle power plants. Because combustion turbines typically use a large excess of air, the resulting turbine exhaust gas is relatively dilute (only 3–4% CO 2 ), making subsequent CO 2 capture difficult and costly. Previously, we’ve shown that a membrane process can be used to selectively recycle CO 2 to the combustion step, which significantly increases the CO 2 content in the exhaust gas. In this way, selective exhaust gas recycle (S-EGR) makes CO 2 capture energetically easier. Here, various membrane design concepts incorporating S-EGR are described and compared. Furthermore, a combination of S-EGR with non-selective exhaust gas recycle (EGR) is shown to offer advantages in reduced capital, while retaining most of the energy benefits of S-EGR alone. For all of the membrane designs analyzed, the energy and cost of capture vary with the capture rate. Generally, if flue gas compression is not used, the lowest capture cost ($\$$/tonne CO 2 ) for membranes occurs at partial capture rates of 60–70%. Of the process designs studied, the lowest cost of capture (~$44/t) is achieved by an integrated turbine/membrane design that would require changes to existing turbines.

03 NATURAL GAS↗
DOE OSTI2012

Numerical simulations of depressurization-induced gas production from gas hydrate reservoirs at the Walker Ridge 312 site, northern Gulf of Mexico

In 2009, the Gulf of Mexico (GOM) Gas Hydrates Joint-Industry-Project (JIP) Leg II drilling program confirmed that gas hydrate occurs at high saturations within reservoir-quality sands in the GOM. A comprehensive logging-while-drilling dataset was collected from seven wells at three sites, including two wells at the Walker Ridge 313 site. By constraining the saturations and thicknesses of hydrate-bearing sands using logging-while-drilling data, two-dimensional (2D), cylindrical, r-z and three-dimensional (3D) reservoir models were simulated. The gas hydrate occurrences inferred from seismic analysis are used to delineate the areal extent of the 3D reservoir models. Numerical simulations of gas production from the Walker Ridge reservoirs were conducted using the depressurization method at a constant bottomhole pressure. Results of these simulations indicate that these hydrate deposits are readily produced, owing to high intrinsic reservoir-quality and their proximity to the base of hydrate stability. The elevated in situ reservoir temperatures contribute to high (5–40 MMscf/day) predicted production rates. The production rates obtained from the 2D and 3D models are in close agreement. To evaluate the effect of spatial dimensions, the 2D reservoir domains were simulated at two outer radii. The results showed increased potential for formation of secondary hydrate and appearance of lag time for production rates as reservoir size increases. Similar phenomena were observed in the 3D reservoir models. The results also suggest that interbedded gas hydrate accumulations might be preferable targets for gas production in comparison with massive deposits. Hydrate in such accumulations can be readily dissociated due to heat supply from surrounding hydrate-free zones. Special cases were considered to evaluate the effect of overburden and underburden permeability on production. The obtained data show that production can be significantly degraded in comparison with a case using impermeable boundaries. The main reason for the reduced productivity is water influx from the surrounding strata; a secondary cause is gas escape into the overburden. The results dictate that in order to reliably estimate production potential, permeability of the surroundings has to be included in a model.

2D and 3D reservoir simulations↗
DOE OSTI2015

Modeling impacts of changes in temperature and water table on C gas fluxes in an Alaskan peatland: Modeling C Gas Fluxes in Peatland

Northern peatlands have accumulated a large amount of organic carbon (C) in their thick peat profile. Climate change and associated variations in soil environments are expected to have significant impacts on the C balance of these ecosystems, but the magnitude is still highly uncertain. Verifying and understanding the influences of changes in environmental factors on C gas fluxes in biogeochemical models are essential for forecasting feedbacks between C gas fluxes and climate change. In this study, we applied a biogeochemical model, DeNitrification-DeComposition (DNDC), to assess impacts of air temperature (T A ) and water table (WT) on C gas fluxes in an Alaskan peatland. DNDC was validated against field measurements of net ecosystem exchange of CO 2 (NEE) and CH 4 fluxes under manipulated surface soil temperature and WT conditions in a moderate rich fen. The validation demonstrates that DNDC was able to capture the observed impacts of the manipulations in soil environments on C gas fluxes. To investigate responses of C gas fluxes to changes in T A and soil water condition, we conducted a series of simulations with varying T A and WT. The results demonstrate that (1) uptake rates of CO 2 at the site were reduced by either too colder or warmer temperatures and generally increased with increasing soil moisture; (2) CH 4 emissions showed an increasing trend as TA increased or WT rose toward the peat surface; and (3) the site could shift from a net greenhouse gas (GHG) sink into a net GHG source under some warm and/or dry conditions. A sensitivity analysis evaluated the relative importance of T A and WT to C gas fluxes. The results indicate that both T A and WT played important roles in regulating NEE and CH 4 emissions and that within the investigated ranges of the variations in T A and WT, changes in WT showed a greater impact than changes in T A on NEE, CH 4 fluxes, and net C gas fluxes at the study fen.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Transport and Fate of Natural Gas and Brine Escaping from a Hydrocarbon Reservoir Through a Failed Deepwater Well in the Oceanic Subsurface of the Gulf of Mexico

The possibility of broaching, or the release of fluids at the seafloor due to a damaged or faulty well, is a hazard that must be assessed in the well permitting process. Here, this paper describes a numerical simulation study of a real-life scenario where a complex, permeable sandy formation, connected to the seafloor via known chimneys/seeps, is intersected by a damaged production well that drains another deeper, gas-bearing formation. The objective of the study is to determine the transport and fate of hydrocarbon reservoir fluids (gas and brines) escaping into the sandy formation through the casing shoe of the failed well, and to determine the time it takes for these contaminants to reach the ocean floor. We conducted a detailed simulation study to represent the conditions, properties, and behavior of the system under such failure conditions, and we investigated the migration of gas and brine for a range of reservoir and chimney properties. A key conclusion is that, for such complex systems, modeling the three-dimensional geometry of the system in detail is the key to describing transport and assessing the time and magnitude of potential releases. For the system studied here, transport times range from under 2 years (highest permeabilities) to many decades, ensuring significant time to respond to potential broaching hazards. Lastly, under the conditions investigated in this study, we also determine that gas-dominated releases associated with low rates of water flow into the sandy formation are likely to cause hydrate formation that can reduce permeabilities in the colder, upper regions of the chimneys and possibly mitigate releases.

58 GEOSCIENCES↗
DOE OSTI2018

The future of natural gas infrastructure development in the United states

Changes in the natural gas market have spawned the need for pipeline infrastructure planning. Previous studies have analyzed natural gas infrastructure development largely independent of the interactions of the natural gas sector with the broader economy. However, natural gas infrastructure development is strongly influenced by broader domestic and international socioeconomic conditions. We couple a global Human-Earth system model with state-level detail in the United States (GCAM-USA) that provides the broader socioeconomic context for natural gas supply and demand with a natural gas infrastructure investment model (NANGAM) to examine interstate natural gas pipeline infrastructure development in the U.S. under a range of socioeconomic scenarios. Here we show that existing pipeline infrastructure in the U.S. is insufficient to satisfy the increasing demand for natural gas and investments in pipeline capacity will be required. However, the geographic distribution of investments within the U.S. is heterogeneous and depends on the capacity of existing infrastructure as well as the magnitude of increase in demand. Our results also illustrate the risks of under-utilization of pipeline capacity, in particular, under a scenario characterized by long-term systemic transitions toward a low-carbon economy. More broadly, our study highlights the value of integrated approaches to facilitate informed decision-making.

Feijoo, Felipe↗
DOE OSTI2020

Defect cluster and nonequilibrium gas bubble associated growth in irradiated UMo fuels – a cluster dynamics and phase field model

Irradiation examination shows that gas bubble swelling kinetics is much faster after irradiation-induced recrystallization than that prior recrystallization in UMo fuels. It implies that gas bubbles in coarse grains and small recrystallized grains have different growth behavior. In this work, a phase-field model of gas bubble evolution integrating microstructure dependent cluster dynamics has been developed, for the first time, to study the gas bubble swelling behavior in the recrystallization zone of UMo fuels. Generation, diffusion, reaction, sink, emission and clustering of vacancies and interstitials are described by the cluster dynamics model while a phase-field model is used to describe the evolution of non-equilibrium gas bubbles including nucleation and growth. With the coupled model, the effect of defect generation rate, clustering rate, interstitial emission and sink rates on grain boundaries on the gas bubble evolution are systematically simulated. A set of model parameters (defect generation rate, clustering rate, interstitial emission and sink rates) is determined by comparing measured and simulated gas bubble swelling kinetics. The results demonstrate that interstitial clustering is one of the important physical mechanisms which results in a fast gas bubble swelling kinetics in the recrystallization zone. The developed model can also be extended to study the associated growth of defect and second phase precipitates often observed in irradiated materials.

Hu, Shenyang↗
DOE OSTI2026

Consolidation and Permeability of the B1 and D1 Gas Hydrate Bearing Sands and Associated Seal Sediments of the Extended-Duration Gas Production Test Site on the Alaska North Slope

Gas hydrate, a solid combination of gas (mostly methane in nature) and water molecules stable at low temperatures and elevated pressures, occurs naturally in marine and permafrost-associated environments. Gas hydrate reservoirs, such as those in the Alaska North Slope, have been considered potential energy resources for gas production. To understand the petrophysical and geo-mechanical characteristics of the reservoir, core samples retrieved from the site of the JOGMEC-DOE-USGS collaborative gas hydrate R&D project have been analyzed in the laboratory for their hydraulic and mechanical properties. This paper focuses on both seal and reservoir samples associated with the B1 and D1 sands, which are evaluated for index properties (including porosity, grain size distribution, liquid and plastic limits, specific surface area, and specific gravity), consolidation, permeability, and water retention. Furthermore, the reservoir core samples were tested with pore-filling, laboratory-grown tetrahydrofuran hydrate, in order to assess reservoir behavior during gas production from hydrates. Under simulated in situ stress conditions, the seal and hydrate-free reservoir cores had a permeability anisotropy ratio of k h /k v = 3.0−5.0, and k h /k v = 2.4−3.0 for the reservoir tetrahydrofuran hydrate-bearing cores. The data suggest that depressurizing the reservoir to induce hydrate dissociation alters the reservoir effective permeability in three ways: permeabilities decrease due to porosity lost (e.g., the initial reservoir thickness can decrease by up to 5% upon 7 MPa depressurization), permeability increases due to the loss of solid hydrate in the pore space, and permeability anisotropy k h /k v decreases in response to the evolving pore-space geometry. We show that given the simulated in situ gas hydrate saturations (i.e., S h = 32% in core 7P-2E and S h = 21% in core 20P-4), gas production from the dissociation of tetrahydrofuran hydrate in the two tested cores results in a net increase in effective permeability and a decrease in k h /k v . This study highlights the importance of investigating seal and reservoir sediments and the impacts of depressurization on the porosity and permeability responses during production.

Geological materials↗
DOE OSTI2014

Gas cell for in situ soft X-ray transmission-absorption spectroscopy of materials

A simple gas cell design, constructed primarily from commercially available components, enables in situ soft X-ray transmission-absorption spectroscopy of materials in contact with gas at ambient temperature. The cell has a minimum X-ray path length of 1 mm and can hold gas pressures up to ~300 Torr, and could support higher pressures with simple modifications. The design enables cycling between vacuum and gas environments without interrupting the X-ray beam, and can be fully sealed to allow for measurements of air-sensitive samples. The cell can attach to the downstream port of any appropriate synchrotron beamline, and offers a robust and versatile method for in situ measurements of certain materials. The construction and operation of the cell are discussed, as well as sample preparation and proper spectral analysis, illustrated by examples of spectral measurements. Potential areas for improvement and modification for specialized applications are also mentioned.

47 OTHER INSTRUMENTATION↗
DOE OSTI2014

Development of the CD Symcap platform to study gas-shell mix in implosions at the National Ignition Facility

Surrogate implosions play an important role at the National Ignition Facility (NIF) for isolating aspects of the complex physical processes associated with fully integrated ignition experiments. The newly developed CD Symcap platform has been designed to study gas-shell mix in indirectly driven, pure T{sub 2}-gas filled CH-shell implosions equipped with 4 μm thick CD layers. This configuration provides a direct nuclear signature of mix as the DT yield (above a characterized D contamination background) is produced by D from the CD layer in the shell, mixing into the T-gas core. The CD layer can be placed at different locations within the CH shell to probe the depth and extent of mix. CD layers placed flush with the gas-shell interface and recessed up to 8 μm have shown that most of the mix occurs at the inner-shell surface. In addition, time-gated x-ray images of the hotspot show large brightly radiating objects traversing through the hotspot around bang-time, which are likely chunks of CH/CD plastic. This platform is a powerful new capability at the NIF for understanding mix, one of the key performance issues for ignition experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Design and fabrication of a window for the gas Cherenkov detector 3

The gas Cherenkov detector 3 was designed at Los Alamos National Laboratory for use in inertial confinement fusion experiments at both the Omega Laser Facility and the National Ignition Facility. This instrument uses a low-Z gamma-to-electron convertor plate and high pressure gas to convert MeV gammas into UV/visible Cherenkov photons for fast optical detection. This is a follow-on diagnostic from previous versions, with two notable differences: the pressure of the gas is four times higher, and it allows the use of fluorinated gas, requiring metal seals. These changes force significant changes in the window component, having a unique set of requirements and footprint limitations. The selected solution for this component, a sapphire window brazed into a stainless steel flange housing, is described.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2014

COLD MOLECULAR GAS IN MERGER REMNANTS. I. FORMATION OF MOLECULAR GAS DISKS

We present the ≲1 kpc resolution {sup 12}CO imaging study of 37 optically selected local merger remnants using new and archival interferometric maps obtained with ALMA, CARMA, the Submillimeter Array, and the Plateau de Bure Interferometer. We supplement a sub-sample with single-dish measurements obtained at the Nobeyama Radio Observatory 45 m telescope for estimating the molecular gas mass (10{sup 7} {sup –} {sup 11} M {sub ☉}) and evaluating the missing flux of the interferometric measurements. Among the sources with robust CO detections, we find that 80% (24/30) of the sample show kinematical signatures of rotating molecular gas disks (including nuclear rings) in their velocity fields, and the sizes of these disks vary significantly from 1.1 kpc to 9.3 kpc. The size of the molecular gas disks in 54% of the sources is more compact than the K-band effective radius. These small gas disks may have formed from a past gas inflow that was triggered by a dynamical instability during a potential merging event. On the other hand, the rest (46%) of the sources have gas disks that are extended relative to the stellar component, possibly forming a late-type galaxy with a central stellar bulge. Our new compilation of observational data suggests that nuclear and extended molecular gas disks are common in the final stages of mergers. This finding is consistent with recent major-merger simulations of gas-rich progenitor disks. Finally, we suggest that some of the rotation-supported turbulent disks observed at high redshifts may result from galaxies that have experienced a recent major merger.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Dust in and around galaxies: dust in cluster environments and its impact on gas cooling

Simulating the dust content of galaxies and their surrounding gas is challenging due to the wide range of physical processes affecting the dust evolution. Here we present cosmological hydrodynamical simulations of a cluster of galaxies, M 200,crit = 6×10 14 M ⊙ , including a novel dust model for the moving mesh code AREPO. This model includes dust production, growth, supernova-shock-driven destruction, ion-collision-driven thermal sputtering, and high-temperature dust cooling through far-infrared reradiation of collisionally deposited electron energies. Adopting a rather low thermal sputtering rate, we find, consistent with observations, a present-day overall dust-to-gas ratio of ~2 × 10 -5 , a total dust mass of ~2×10 9 M ⊙ , and a dust mass fraction of ~3 × 10 -6 . The typical thermal sputtering time-scales within ~100 kpc are around ~10 Myr, and increase towards the outer parts of the cluster to ~10 3 Myr at a cluster-centric distance of 1 Mpc. The condensation of gas-phase metals into dust grains reduces high-temperature metal-line cooling, but also leads to additional dust infrared cooling. The additional infrared cooling changes the overall cooling rate in the outer parts of the cluster, beyond ~1 Mpc, by factors of a few. This results in noticeable changes of the entropy, temperature, and density profiles of cluster gas once dust formation is included. The emitted dust infrared emission due to dust cooling is consistent with observational constraints.

79 ASTRONOMY AND ASTROPHYSICS↗