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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Evaluation of Gas-Cooled Pressurized Phosphoric Acid Fuel Cells for Electric Utility Power Generation

Gas cooling is a more reliable, less expensive and a more simple alternative to conventional liquid cooling for heat removal from the phosphoric acid fuel cell (PAFC). The feasibility of gas-cooling was already demonstrated in atmospheric pressure stacks. Theoretical and experimental investigations of gas-cooling for pressurized PAFC are presented. Two approaches to gas cooling, Distributed Gas-Cooling (DIGAS) and Separated Gas-Cooling (SGC) were considered, and a theoretical comparison on the basis of cell performance indicated SGC to be superior to DIGAS. The feasibility of SGC was experimentally demonstrated by operating a 45-cell stack for 700 hours at pressure, and determining thermal response and the effect of other related parameters.

Faroque, M.↗

Improved Gas Seal for Electrolytic Cells

Breakage by differential thermal expansion reduced. Cells for hot electrolysis of gases improved by design that reduces vulnerability of gas seals to breakage at operating temperature of about 1000 degrees C.

Richter, R.↗

Helium glow detector experiment, MA-088

Of the two 584 A channels in the helium glow detector, channel #1 appeared to provide data with erratic count rates and undue susceptibility to dayglow and solar contamination possibly because of filter fatigue or failure. Channel #3 data appear normal and of high quality. For this reason only data from this last channel was analyzed and used for detailed comparison with theory. Reduction and fitting techniques are described, as well as applications of the data in the study of nighttime and daytime Hel 584 A emission. A hot model of the interstellar medium is presented. Topics covered in the appendix include: observations of interstellar helium with a gas absorption cell: implications for the structure of the local interstellar medium; EUV dayglow observations with a helium gas absorption cell; and EUV scattering from local interstellar helium at nonzero temperatures: implications for the derivations of interstellar medium parameters.

Bowyer, C. S.↗

Thinner, More-Efficient Oxygen-Separation Cells

Better gas-distribution plates fabricated more easily. Oxygen-separation cell redesigned to make it more efficient, smaller, lighter, and easier to manufacture. Potential applications include use as gas separators, filters, and fuel cells.

Clark, Douglas J.↗

Techniques for in situ collection and measurement of volatiles released during hypervelocity impact

The capability of the gas capture cell to collect particles and semivolatile species which were released during impact is examined. The proposed Comet Coma Sample Return (CCSR) payload contains a variety of instrumentation for characterizing and collecting cometary dust. In this suite of instruments the Gas Capture Cell (GCC) is unique in that it not only collects the vaporization products resulting from the dust particle impacts, but also provides chemical characterization information prior to return of the dust particles for analysis on Earth. The GCC provides near real-time characterization of the volatile species, such as low- and medium-molecular-weight organic compounds that evolve from dust particles on impact with metal targets. Instrument sensitivity is sufficient for analyzing the volatile impact products resulting from single, individual dust particles. This capability will enable characterization of near-pristine dust particles, including the CHON particles, to be performed at a level not previously possible. Its design concept, operation and performance are detailed.

Heppner, R. A.↗

Heat pump processes induced by laser radiation

A carbon dioxide laser system was constructed for the demonstration of heat pump processes induced by laser radiation. The system consisted of a frequency doubling stage, a gas reaction cell with its vacuum and high purity gas supply system, and provisions to measure the temperature changes by pressure, or alternatively, by density changes. The theoretical considerations for the choice of designs and components are dicussed.

Garbuny, M.↗

Optically Driven Deformable Mirrors

Optically driven deformable mirrors may eventually supplant electrically driven deformable mirrors in some adaptive-optics and active-optics applications. Traditionally, the mirror facets in electrically driven deformable mirrors are actuated, variously, by means of piezoelectric, electrostrictive, microelectromechanical, liquid-crystal, or thermal devices. At least one such device must be dedicated to each facet, and there must be at least one wire carrying a control or drive signal to the device. If a deformable mirror comprises many (e.g., thousands) of facets, then wiring becomes a major problem for design, and the problem is compounded in cases of piezoelectric or other actuators for which high drive voltages are required. In contrast, in optically driven mirrors, the wiring problem is eliminated. The basic principle of actuation of an optically driven deformable mirror is to use a laser beam to actuate a material. For example, a laser beam can be used to heat a material to make the material thermally expand to displace a mirror facet. In an experiment to demonstrate this principle, the actuator was a Golay cell having a diameter of approximately equal to 6 mm and a length of approximately equal to 10 mm. The beam from a laser diode was aimed at an absorber in the cell, thereby heating the gas in the cell. A mirror mounted on a 12.5-micron-thick polyethylene terephthalate diaphragm at one end of the cell became displaced as the gas expanded against the diaphragm. In one representative pair of experiments at a laser beam power of 0.23 W, the beam was mechanically chopped at frequencies of 1 and 5 Hz. The mirror exhibited corresponding oscillating displacements having amplitudes of 373 and 83 micron, respectively

Hemmati, Hamid↗

Miniaturized Hollow-Waveguide Gas Correlation Radiometer (GCR) for Trace Gas Detection in the Martian Atmosphere

Gas correlation radiometry (GCR) has been shown to be a sensitive and versatile method for detecting trace gases in Earth's atmosphere. Here, we present a miniaturized and simplified version of this instrument capable of mapping multiple trace gases and identifying active regions on the Mars surface. Reduction of the size and mass of the GCR instrument has been achieved by implementing a lightweight, 1 mm inner diameter hollow-core optical fiber (hollow waveguide) for the gas correlation cell. Based on a comparison with an Earth orbiting CO2 gas correlation instrument, replacement of the 10 meter mUltipass cell with hollow waveguide of equivalent pathlength reduces the cell mass from approx 150 kg to approx 0.5 kg, and reduces the volume from 1.9 m x 1.3 m x 0.86 m to a small bundle of fiber coils approximately I meter in diameter by 0.05 m in height (mass and volume reductions of >99%). This modular instrument technique can be expanded to include measurements of additional species of interest including nitrous oxide (N2O), hydrogen sulfide (H2S), methanol (CH3OH), and sulfur dioxide (SO2), as well as carbon dioxide (CO2) for a simultaneous measure of mass balance.

Wilson, Emily L.↗

13CO2/12CO2 isotopic ratio measurements using a difference frequency-based sensor operating at 4.35 micrometers

A portable modular gas sensor for measuring the 13C/12C isotopic ratio in CO2 with a precision of 0.8%(+/-1 sigma) was developed for volcanic gas emission studies. This sensor employed a difference frequency generation (DFG)-based spectroscopic source operating at 4.35 micrometers (approximately 2300 cm-1) in combination with a dual-chamber gas absorption cell. Direct absorption spectroscopy using this specially designed cell permitted rapid comparisons of isotopic ratios of a gas sample and a reference standard for appropriately selected CO2 absorption lines. Special attention was given to minimizing undesirable precision degrading effects, in particular temperature and pressure fluctuations.

NASA Discipline Life Sciences Technologies↗

Systems analysis of electricity production from coal using fuel cells

Gasifiers, heat transfer, gas stability, quench, water-gas shift reaction, reforming-methanation, other catalytic reactions, compressors and expanders, acid-gas removal, the fuel cell, and catalytic combustors are described. System pressure drops, efficiency of rotating power equipment, heat exchangers, chemical reactions, steam systems, and the fuel cell subsystems are discussed.

Fleming, D. K.↗

Extreme ultraviolet photometer for observations of helium in interplanetary space

A four-channel photometer sensitive to two solar EUV lines which are resonantly scattered by helium gas was developed for flight on the Apollo-Soyuz Test Project. Two channels observed the 58.4-nm line of He I and used helium gas resonant absorption cells to determine the intensities of the center and wings of that line. The other two channels observed the 30.4-nm line of He II. The instrument surveyed much of the celestial sphere during a series of slow rolling maneuvers by the Apollo spacecraft. The experiment operated properly, and usable data were obtained. Study of the distributions of flux seen, and of the ratio 58.4-nm fluxes seen with gas cells full and empty, will refine current understanding of several poorly known properties of the local interstellar medium. Study of the 30.4-nm flux distribution will refine present knowledge of the structure of the earth's plasmasphere.

Bowyer, S.↗

Bipolar Ag-Zn battery

The silver-zinc (AgZn) battery system has been unique in its ability to safely satisfy high power demand applications with low mass and volume. However, a new generation of defense, aerospace, and commercial applications will impose even higher power demands. These new power demands can be satisfied by the development of a bipolar battery design. In this configuration the power consuming, interelectrode current conductors are eliminated while the current is then conducted via the large cross-section electrode substrate. Negative and positive active materials are applied to opposite sides of a solid silver foil substrate. In addition to reducing the weight and volume required for a specified power level, the output voltage performance is also improved as follows. Reduced weight through: elimination of the plastic cell container; elimination of plate leads and intercell connector; and elimination of internal plate current collector. Increased voltage through: elimination of resistance of current collector; elimination of resistance of plate lead; and elimination of resistance of intercell connector. EPI worked previously on development of a secondary bipolar silver zinc battery. This development demonstrated the electrical capability of the system and manufacturing techniques. One difficulty with this development was mechanical problems with the seals. However, recent improvements in plastics and adhesives should eliminate the major problem of maintaining a seal around the periphery of the bipolar module. The seal problem is not as significant for a primary battery application or for a requirement for only a few discharge cycles. A second difficulty encountered was with activation (introducing electrolyte into the cell) and with venting gas from the cell without loss of electrolyte. During previous work, the following projections for energy density were made from test data for a high power system which demonstrated in excess of 50 discharge/charge cycles. Projected system power = 100 kilowatts; discharge time = 30 seconds; discharge current density = 1.75 amps/sq in.; system weight = 86 lbs (9.7 WH/lb); and system volume = 1071 cu. in. (.78 WH/cu. in.). EPI is currently working on a development program to produce a bipolar silver-zinc battery design for NASA. The potential application would be to power electromechanical actuators for space launch vehicles.

Giltner, L. John↗

Applications study of advanced power generation systems utilizing coal-derived fuels. Volume 1: Executive summary

The technology status of phosphoric acid and molten carbon fuel cells, combined gas and steam turbine cycles, and magnetohydrodynamic energy conversion systems was assessed and the power performance of these systems when operating with medium-Btu fuel gas whether delivered by pipeline to the power plant or in an integrated mode in which the coal gasification process and power system are closely coupled as an overall power plant was evaluated. Commercially available combined-cycle gas turbine systems can reach projected required performance levels for advanced systems using currently available technology. The phosphoric acid fuel cell appears to be the next most likely candidate for commercialization. On pipeline delivery, the systems efficiency ranges from 40.9% for the phosphoric acid fuel cell to 63% for the molten carbonate fuel cell system. The efficiencies of the integrated power plants vary from approximately 39-40% for the combined cycle to 46-47% for the molden carbonate fuel cell systems. Conventional coal-fired steam stations with flue-gas desulfurization have only 33-35% efficiency.

Robson, F. L.↗

Gas-Particle Interactions in a Microgravity Flow Cell

We are developing a microgravity flow cell in which to study the interaction of a flowing gas with relatively massive particles that collide with each other and with the moving boundaries of the cell. The absence of gravity makes possible the independent control of the relative motion of the boundaries and the flow of the gas. The cell will permit gas-particle interactions to be studied over the entire range of flow conditions over which the mixture is not turbulent. Within this range, we shall characterize the viscous dissipation of the energy of the particle fluctuations, measure the influence of particle-phase viscosity on the pressure drop along the cell, and observe the development of localized inhomogeneities that are likely to be associated with the onset of clusters. These measurements and observations should contribute to an understanding of the essential physics of pneumatic transport.

Louge, Michel↗

Large-Flow-Area Flow-Selective Liquid/Gas Separator

This liquid/gas separator provides the basis for a first stage of a fuel cell product water/oxygen gas phase separator. It can separate liquid and gas in bulk in multiple gravity environments. The system separates fuel cell product water entrained with circulating oxygen gas from the outlet of a fuel cell stack before allowing the gas to return to the fuel cell stack inlet. Additional makeup oxygen gas is added either before or after the separator to account for the gas consumed in the fuel cell power plant. A large volume is provided upstream of porous material in the separator to allow for the collection of water that does not exit the separator with the outgoing oxygen gas. The water then can be removed as it continues to collect, so that the accumulation of water does not impede the separating action of the device. The system is designed with a series of tubes of the porous material configured into a shell-and-tube heat exchanger configuration. The two-phase fluid stream to be separated enters the shell-side portion of the device. Gas flows to the center passages of the tubes through the porous material and is then routed to a common volume at the end of the tubes by simple pressure difference from a pumping device. Gas flows through the porous material of the tubes with greater ease as a function of the ratio of the dynamic viscosity of the water and gas. By careful selection of the dimensions of the tubes (wall thickness, porosity, diameter, length of the tubes, number of the tubes, and tube-to-tube spacing in the shell volume) a suitable design can be made to match the magnitude of water and gas flow, developed pressures from the oxygen reactant pumping device, and required residual water inventory for the shellside volume.

Vasquez, Arturo↗

Phase-Modulation Gas-Correlation Spectroscopy

Electro-optic phase-modulation gas-correlation spectroscopy demonstrated in laboratory tests promising candidate technique for remote sensing of gases, temperatures, and wind velocities in atmosphere. In technique radiation emitted by sample atmosphere passed through electro-optic phase modulator, and modulated and unmodulated versions of spectrum alternately passed through reference absorption cell containing gas to be detected. Radiation emerging from reference cell band-pass filtered and detected. Correlation signal is difference in intensity between phase-modulated and unmodulated detected signals.

Rider, David M.↗