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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Vertical Gradients in Fluidized Sand Columns

This study evaluated the influence of diameter and grain size on the initiation and continuation phase of piping erosion. Twelve tests were performed in a laboratory setting in which sand was fluidized in a controlled setting and hydraulic gradients within the sand, flow rates through the sand, and expansion of the sand columns were measured as the sand was fluidized. This study was conducted to improve the understanding of the resistance a vertical column of sand offers to piping erosion. From the fluidization tests conducted in two permeameters with different diameters, it cannot be concluded that permeameter diameter has a significant influence on a specimen’s resistance to piping erosion. Although one test conducted in the smaller diameter permeameter did record hydraulic gradients lower than those recorded in tests conducted in the larger diameter permeameter, this was not a consistent observation for all tests run in the smaller diameter permeameter. Further analysis ought to involve more tests run in each permeameter as well as incorporating additional permeameters with both larger and smaller diameters than those used in this study. From the fluidization tests conducted using the well-graded, coarse-, medium-, and fine-grained sands, it appears that resistance to piping is dependent on grain size and grain size distribution. The coarse-grained sand offered the most resistance to piping, the fine-grained sand offered the least, and the medium-grained and well-graded sands offered similar resistances between those of the coarse-grained and fine-grained sands. Gradients at which sand boils were observed, maximum gradients reached before the sand fluidized, and the minimum gradients reached at the conclusion of each test also appear to be influenced by grain size and grain size distribution. Tests conducted on the coarse-grained sand recorded the highest and most closely spaced sand boil, maximum, and minimum gradients, indicating that it offered the highest and most constant resistance to piping, while the fine-grained sand tests recorded the lowest sand boil, maximum, and minimum gradients, indicating that it offered the least resistance to piping and that resistance decreased as the tests progressed. The medium-grained sand tests recorded sand boil, maximum, and minimum gradients between those of the coarse-grained and fine-grained sands. The well-graded sand tests recorded the lowest sand boil gradient, which could be indicative of the occurrence of suffusion erosion occurring in conjunction with piping erosion, whereby the finer particles were washed out of the sand matrix at relatively low gradients, forming sand boils while the relatively coarser matrix remained resistant to piping. All tests recorded maximum gradients that were lower than the theoretical critical gradients calculated using Equation 4. This is likely due to the changes in the internal configuration of the sand as the piping process 33 initiates. In order to better understand the influence of gradation on resistance to piping, more sand gradations should be tested in future work. Measured hydraulic gradients in the lower portion of the fluidized sands were higher than those measured in higher portions. This could be explained if the density of the fluidized sand was not uniform, with more material near the base of the column than near the top, which is contrary to the findings of Sellmeijer. Furthermore, the tests were terminated when the maximum height of the upstream reservoir was reached but did not give any evidence that gradients had leveled off to a uniform “final gradient”. It is likely that gradients would have continued to dissipate had more hydraulic head been applied to the upstream reservoir. In order to better understand this, additional testing should be conducted using an upstream reservoir capable of simulating higher hydraulic heads.

13 HYDRO ENERGY↗
DOE OSTI2017

The lateral variation of P n velocity gradient under Eurasia

We report that mantle lid P wave velocity gradient, or P n velocity gradient, reflects the depth and lateral variations of thermal and rheological state of the uppermost mantle. Mapping the P n velocity gradient and its lateral variation helps us gain insight into the temperature, composition, and dynamics of the uppermost mantle. In addition, because P n velocity gradient has profound influence on P n propagation behavior, an accurate mapping of P n velocity gradient also improves the modeling and prediction of P n travel times and amplitudes. In this study, I used measured P n travel times to derive path-specific P n velocity gradients. I then inverted these velocity gradients for two-dimensional (2-D) P n velocity-gradient models for Eurasia based on the assumption that a path-specific Pn velocity gradient is the mean of laterally varying P n velocity gradients along the P n path. Result from a Monte Carlo simulation indicates that the assumption is appropriate. The 2-D velocity-gradient models show that most of Eurasia has positive velocity gradients. High velocity gradients exist mainly in tectonically active regions. Most tectonically stable regions show low and more uniform velocity gradients. In conclusion, strong velocity-gradient variations occur largely along convergent plate boundaries, particularly under overriding plates.

58 GEOSCIENCES↗
DOE OSTI2021

The dependence of the gradients of oxygen and nitrogen-to-oxygen on stellar age in MaNGA galaxies

For this work, we derived the oxygen abundance (O/H), the nitrogen-to-oxygen (N/O) abundance ratio, and their corresponding radial gradients for a sample of 1431 galaxies from the MaNGA DR15 survey using two different realisations of the strong line method: empirical R calibration and the Bayesian model-based HII-CHI-MISTRY (HCM) code. We find that both abundance calculation methods reveal a correlation between the O/H gradient and the stellar mass of a galaxy. This relation is non-linear, with the steepest average gradients in the intermediate mass range and flatter average gradients for high- and low-mass galaxies. The relation between the N/O gradient and the stellar mass is, on average, non-linear with the steepest gradients in the intermediate mass range (log(M/M ⊙ )~10), flatter gradients for high-mass galaxies, and the flattest gradients for low-mass galaxies. However, the general trend of steepening N/O gradients for higher masses, as reported in previous studies, remains evident. We find a dependence between the O/H and N/O gradients and the galaxy mean stellar age traced by the D(4000) index. For galaxies of lower masses, both gradients are, generally, steeper for intermediate values of D(4000) and flatter for low and high values of D(4000). Only the most massive galaxies do not show this correlation. We interpret this behaviour as an evolution of the metallicity gradients with the age of stellar population. Though the galaxies with a positive slope of the D(4000) radial gradient tend to have flatter O/H and N/O gradients, as compared to those with a negative D(4000) gradient.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2002

Shadowgraph Study of Gradient Driven Fluctuations

A fluid or fluid mixture, subjected to a vertical temperature and/or concentration gradient in a gravitational field, exhibits greatly enhanced light scattering at small angles. This effect is caused by coupling between the vertical velocity fluctuations due to thermal energy and the vertically varying refractive index. Physically, small upward or downward moving regions will be displaced into fluid having a refractive index different from that of the moving region, thus giving rise to the enhanced scattering. The scattered intensity is predicted to vary with scattering wave vector q, as q(sup -4), for sufficiently large q, but the divergence is quenched by gravity at small q. In the absence of gravity, the long wavelength fluctuations responsible for the enhanced scattering are predicted to grow until limited by the sample dimensions. It is thus of interest to measure the mean-squared amplitude of such fluctuations in the microgravity environment for comparison with existing theory and ground based measurements. The relevant wave vectors are extremely small, making traditional low-angle light scattering difficult or impossible because of stray elastically scattered light generated by optical surfaces. An alternative technique is offered by the shadowgraph method, which is normally used to visualize fluid flows, but which can also serve as a quantitative tool to measure fluctuations. A somewhat novel shadowgraph apparatus and the necessary data analysis methods will be described. The apparatus uses a spatially coherent, but temporally incoherent, light source consisting of a super-luminescent diode coupled to a single-mode optical fiber in order to achieve extremely high spatial resolution, while avoiding effects caused by interference of light reflected from the various optical surfaces that are present when using laser sources. Results obtained for a critical mixture of aniline and cyclohexane subjected to a vertical temperature gradient will be presented. The sample was confined between two horizontal parallel sapphire plates with a vertical spacing of 1 mm. The temperatures of the sapphire plates were controlled by independent circulating water loops that used Peltier devices to add or remove heat from the room air as required. For a mixture with a temperature gradient, two effects are involved in generating the vertical refractive index gradient, namely thermal expansion and the Soret effect, which generates a concentration gradient in response to the applied temperature gradient. For the aniline/cyclohexane system, the denser component (aniline) migrates toward the colder surface. Consequently, when heating from above, both effects result in the sample density decreasing with altitude and are stabilizing in the sense that no convective motion occurs regardless of the magnitude of the applied temperature gradient. The Soret effect is strong near a binary liquid critical point, and thus the dominant effect is due to the induced concentration gradient. The results clearly show the divergence at low q and the predicted gravitational quenching. Results obtained for different applied temperature gradients at varying temperature differences from the critical temperature, clearly demonstrate the predicted divergence of the thermal diffusion ratio. Thus, the more closely the critical point is approached, the smaller becomes the temperature gradient required to generate the same signal. Two different methods have been used to generate pure concentration gradients. In the first, a sample cell was filled with a single fluid, ethylene glycol, and a denser miscible fluid, water, was added from below thus establishing a sharp interface to begin the experiment. As time went on the two fluids diffused into each other, and large amplitude fluctuations were clearly observed at low q. The effects of gravitational quenching were also evident. In the second method, the aniline/cyclohexane sample was used, and after applying a vertical temperature gradient for several hours, the top and bottom temperatures were set equal and the thermal gradient died on a time scale of seconds, leaving the Soret induced concentration gradient in place. Again, large-scale fluctuations were observed and died away slowly in amplitude as diffusion destroyed the initial concentration gradient.

Cannell, David↗
DOE OSTI2022

Colour gradients of low-redshift galaxies in the DESI Legacy Imaging Survey

ABSTRACT Radial colour gradients within galaxies arise from gradients of stellar age, metallicity, and dust reddening. Large samples of colour gradients from wide-area imaging surveys can complement smaller integral-field spectroscopy data sets and can be used to constrain galaxy formation models. Here, we measure colour gradients for low-redshift galaxies (z < 0.1) using photometry from the DESI Legacy Imaging Survey DR9. Our sample comprises ∼93 000 galaxies with spectroscopic redshifts and ∼574 000 galaxies with photometric redshifts. We focus on gradients across a radial range 0.5Reff to Reff, which corresponds to the inner disc of typical late-type systems at low redshift. This region has been the focus of previous statistical studies of colour gradients and has recently been explored by spectroscopic surveys such as MaNGA. We find that the colour gradients of most galaxies in our sample are negative (redder towards the centre), consistent with the literature. We investigate empirical relationships between colour gradient, average g − r and r − z colour, Mr, M⋆, and sSFR. Trends of gradient strength with Mr (M⋆) show an inflection around Mr ∼ −21 ($\log _{10} \, M_\star /\mathrm{M_\odot }\sim 10.5$). Below this mass, colour gradients become steeper with increasing M⋆, whereas colour gradients in more massive galaxies become shallower. We find that positive gradients (bluer stars at smaller radii) are typical for galaxies of $M_{\star }\sim 10^{8}\, \mathrm{M_\odot }$. We compare our results to age and metallicity gradients in two data sets derived from fits of different stellar population libraries to MaNGA spectra, but find no clear consensus explanation for the trends we observe. Both MaNGA data sets seem to imply a significant contribution from dust reddening, in particular, to explain the flatness of colour gradients along the red sequence.

Astronomy & Astrophysics↗
NASA NTRS1995

Effects of pressure gradients on turbulent premixed flames

The influence of a constant acceleration on a turbulent premixed flame is studied by direct numerical simulation. This acceleration induces a mean pressure gradient across the flame brush, leading to a modification of the turbulent flame structure due to differential buoyancy mechanisms between heavy cold fresh and light hot burnt gases. Such a pressure gradient may be encountered in practical applications in ducted flames. A favorable pressure gradient, i.e. the pressure decreases from unburnt to burnt gases, is found to decrease the flame wrinkling, the flame brush thickness, and the turbulent flame speed. A favorable pressure gradient also promotes counter-gradient turbulent transport. On the other hand, adverse pressure gradients tend to increase the flame brush thickness and turbulent flame speed, and promote classical gradient turbulent transport. The balance equation for the turbulent flux of the Favre averaged progress variable is also analyzed. The first results show that the fluctuating pressure term, cannot be neglected as generally assumed in models. Simple models assuming that a high mean pressure gradient may only be balanced by the cross-dissipation term seem too approximate. This analysis has to be continued to compare simulation data and closure schemes proposed for the transport equation. The analysis developed by Veynante et al.(1995) has been extended to imposed acceleration and mean pressure gradients. A simple model for the turbulent flux is proposed and validated from simulation data. Then, a modified criterion is derived to delineate between counter-gradient and gradient turbulent diffusion. In fact, counter-gradient diffusion may occur in most practical applications, especially for ducted flames.

Veynante, D.↗
DOE OSTI2022

The half-mass radius of MaNGA galaxies: effect of IMF gradients

Gradients in the stellar populations (SP) of galaxies – e.g. in age, metallicity, stellar initial mass function (IMF) – can result in gradients in the stellar-mass-to-light ratio, M * / L . Such gradients imply that the distribution of the stellar mass and light is different. For old SPs, e.g. in early-type galaxies at z ∼ 0, the M * / L gradients are weak if driven by variations in age and metallicity, but significantly larger if driven by the IMF. A gradient which has larger M * / L in the centre increases the estimated total stellar mass ( M * ) and reduces the scale which contains half this mass ( R e,* ), compared to when the gradient is ignored. For the IMF gradients inferred from fitting MILES simple SP models to the H β, 〈Fe〉, [MgFe], and TiO 2SDSS absorption lines measured in spatially resolved spectra of early-type galaxies in the MaNGA survey, the fractional change in R e,* can be significantly larger than that in M * , especially when the light is more centrally concentrated. The R e,* – M * correlation which results from accounting for IMF gradients is offset to smaller sizes by 0.3 dex compared to when these gradients are ignored. Comparisons with ‘quiescent’ galaxies at higher z must account for evolution in SP gradients (especially age and IMF) and in the light profile before drawing conclusions about how R e,* and M * evolve. Here, the implied merging between higher z and the present is less contrived if R e,* / R e at z ∼ 0 is closer to our IMF-driven gradient calibration than to unity.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Gradient-based surface nuclear magnetic resonance for groundwater investigation

In medical magnetic resonance imaging, spatial localization (imaging) is based upon the application of controlled magnetic field gradients on top of the main magnetic field to spatially modulate the frequency and/or phase of the nuclear magnetic resonance (NMR) signal across the volume of investigation. In this work, we have applied similar physical principles to produce controlled magnetic field gradients during surface NMR-based groundwater investigations. In this approach, a gradient pulse of variable amplitude or duration is applied immediately after the excitation pulse to cause predictable phase encoding of the NMR signal as a function of depth. This approach is also applicable to emerging surface NMR detection methods that use a prepolarization field with fast nonadiabatic turn-off to generate detectable NMR signals from the shallow subsurface. In this case, the gradient pulse is applied after terminating the prepolarization field and provides a heretofore unavailable means of localizing the NMR response as a function of depth. The application of gradients can also be combined with tip-angle-based modulation to yield higher imaging resolution than can be achieved through either gradient- or tip-angle-based imaging alone. We implemented this new gradient-based capability into a surface NMR gradient generation accessory that is compatible with the GMR-Flex instrument and developed surface NMR-specific forward modeling and linear inverse models. We validated the accuracy of this novel gradient-based sNMR technology using computer simulations, experiments using a small pool filled with a discrete layer of bulk water, and field experiments at well-characterized groundwater test sites along Ebey Island, WA, and Larned, KS. The gradient-based sNMR imaging observations were compared with high-resolution direct push NMR results observed at these sites. The results of computer simulations and field experiments indicate improvements in both the detection (signal-to-noise ratio) and spatial resolution of shallow subsurface water content using gradient-based surface NMR, compared with traditional surface NMR imaging methods.

Geochemistry & Geophysics↗
NASA NTRS1996

A Study of the Development of Steady and Periodic Unsteady Turbulent Wakes Through Curved Channels at Positive, Zero, and Negative Streamwise Pressure Gradients, Part 1

The turbomachinery wake flow development is largely influenced by streamline curvature and streamwise pressure gradient. The objective of this investigation is to study the development of the wake under the influence of streamline curvature and streamwise pressure gradient. The experimental investigation is carried out in two phases. The first phase involves the study of the wake behind a stationary circular cylinder (steady wake) in curved channels at positive, zero, and negative streamwise pressure gradients. The mean velocity and Reynolds stress components are measured using a X-hot-film probe. The measured quantities obtained in probe coordinates are transformed to a curvilinear coordinate system along the wake centerline and are presented in similarity coordinates. The results of the steady wakes suggest strong asymmetry in velocity and Reynolds stress components. However, the velocity defect profiles in similarity coordinates are almost symmetrical and follow the same distribution as the zero pressure gradient straight wake. The results of Reynolds stress distributions show higher values on the inner side of the wake than the outer side. Other quantities, including the decay of maximum velocity defect, growth of wake width, and wake integral parameters, are also presented for the three different pressure gradient cases of steady wake. The decay rate of velocity defect is fastest for the negative streamwise pressure gradient case and slowest for the positive pressure gradient case. Conversely, the growth of the wake width is fastest for the positive streamwise pressure gradient case and slowest for the negative streamwise pressure gradient. The second phase studies the development of periodic unsteady wakes generated by the circular cylinders of the rotating wake generator in a curved channel at zero streamwise pressure gradient. Instantaneous velocity components of the periodic unsteady wakes, measured with a stationary X-hot-film probe, are analyzed by the phase averaging techniques. The temporal distribution of velocity and Reynolds stress components obtained in a stationary frame of reference are transformed to a spatial distribution in a relative frame of reference. Profiles of phase-averaged velocity and Reynolds stress distributions in the relative frame of reference and similarity coordinates are presented. The velocity defect and Reynolds stress distributions agree with the results of the wake development behind a stationary cylinder in the curved channel at zero streamwise pressure gradient. The phase-averaged third-order correlations, presented in the relative frame of reference and similarity coordinates, show pronounced asymmetric features.

Schobeiri, M. T.↗
DOE OSTI2026

Strong gradient neoclassical transport in the plateau regime

Strong gradient regions in tokamaks such as the pedestal or internal transport barriers are regions of reduced turbulence where neoclassical transport can play a dominant role. In pedestals, gradient lengths comparable to the ion poloidal gyroradius have been measured. Standard neoclassical theory can miss important strong gradient effects in these regions because it assumes that the gradient length scales of density, temperature and potential are larger than the ion poloidal gyroradius. We extend plateau regime neoclassical theory into regions of gradients of the order of the ion poloidal gyroradius to capture strong gradient effects on transport processes in the pedestal and internal transport barriers. The fundamental idea behind our new framework is to keep a scale separation between the orbit widths and the gradient length scales by performing a large aspect ratio expansion. In the plateau regime, strong gradients cause poloidal variation that is in–out as well as up–down asymmetric. We study two different test cases assuming either radial force balance or the absence of turbulence and show that strong gradient effects can enhance or reduce standard neoclassical theory predictions in the plateau regime in strong gradient regions.

fusion plasma↗
DOE OSTI2017

Nonlinear verification of a linear critical gradient model for energetic particle transport by Alfven eigenmodes

Here, a “stiff transport” critical gradient model of energetic particle (EP) transport by EPdriven Alfven eigenmodes (AEs) is verified against local nonlinear gyrokinetic simulations of a well-studied beam-heated DIII-D discharge 146102. A greatly simplifying linear “recipe” for the limiting EP-density gradient (critical gradient) is considered here. In this recipe, the critical gradient occurs when the AE linear growth rate, driven mainly by the EP gradient, exceeds the ion temperature gradient (ITG) or trapped electron mode (TEM) growth rate, driven by the thermal plasma gradient, at the same toroidal mode number (n) as the AE peak growth, well below the ITG/TEM peak n. This linear recipe for the critical gradient is validated against the critical gradient determined from far more expensive local nonlinear simulations in the gyrokinetic code GYRO, as identified by the point of transport runaway when all driving gradients are held fixed. The reduced linear model is extended to include the stabilization from equilibrium E×B velocity shear. The nonlinear verification unambiguously endorses one of two alternative recipes proposed in Ref. 1: the EP-driven AE growth rate should be determined with rather than without added thermal plasma drive.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1977

Gradients of meteorological parameters in convective and nonconvective areas

Horizontal gradients of geopotential height, temperature, and wind speed were computed at the 850-, 700-, 500-, and 200-mb levels. Mixing ratio gradients also were computed, but only for the 850-, 700-, and 500-mb levels. Rawinsonde data was provided at 3- to 6-h intervals. Cumulative frequency distributions and statistical parameters showed that the variability and magnitude of the gradients decreased as the gradients were computed over progressively longer distances. Most frequency distributions were positively skewed, and the standard deviations of the gradient distributions were roughly half as large as the means. An examination of the differences of gradients observed in convective and nonconvective areas was made after convective areas were determined objectively using Manually Digitized Radar data. The gradients of height, wind speed, and mixing ratio at 850 mb were larger in convective than nonconvective areas. No general relationship held for the meteorological variables at other levels. Intensive examination of the gradients observed near squall lines revealed typical gradient patterns and trends in the magnitudes of the gradients associated with convective systems.

Mccown, M. S.↗
NASA NTRS1994

Induced population gradients in galaxy merger remnants

We use numerical models to investigate the nature of induced population gradients in merger remnants. As noted by White, we find that the population mixing in stellar-dynamical mergers is rather moderate, leading to metallicity gradients in the remnant that are closely tied to gradients in the progenitor galaxies. Furthermore, the resultant metallicity gradients are poorly fitted by power laws, showing significant nonlinearities within an effective radius. If constant metallicity bulges are added to the progenitor disks, the strong relation between final and initial metallicity gradients is diluted, but the final gradients are still not well fitted by power laws. Detailed studies of the shape of the metallicity gradients in elliptical galaxies should help determine the degree to which stellar-dynamical mergers have contributed to the population of present-day ellipticals. We also consider the effects of centrally concentrated starbursts on metallicity gradients. Using simple models for metallicity enhancement, we find that addition of a metal-rich starburst population can reproduce the magnitude and shape of metallicity gradients observed in elliptical galaxies. However, even in such cases the metallicity gradients in the merger remnant should steepen significantly beyond an effective radius. Modelling such merger-induced starbursts with population synthesis techniques, we find that if the starburst is characterized by solar metallicity, it should be detectable as a bluing of the nuclear regions for several Gyr. However, if the starburst is metal-rich, the reddening effects of higher metallicity makes the broad-band signature of the starburst much more difficult to detect.

Mihos, J. Christopher↗
DOE OSTI2021

Gradient-Informed Design Optimization of Select Nuclear Systems

In this work, we present a gradient-informed design optimization of nuclear reactor core components based on neutronics objectives with both continuous and discrete materials. The main argument in favor of using gradient-informed design optimization is that it scales well with increasing dimensionality of the design space. First, a challenge problem with 121 free parameters is solved with a gradient-informed method and then with a genetic algorithm. Then, a challenge problem to optimize the flux profile of a simplified assembly with eight axial zones is solved. Both challenge problems are solved using directly calculated derivatives from Tools for Sensitivity and Uncertainty Analysis Methodology Implementation (TSUNAMI) in the SCALE package. Furthermore, we demonstrate how a discrete optimization problem—selection of materials for 121 voxels—can be lifted into a continuous problem with mixed materials. In the continuous space, adjoint-based gradients are well-defined, and gradient descent is applicable. Then, a forcing function is introduced that with the selection of an appropriately sized hyperparameter can be used to guide the optimized continuous solution back into a discrete solution. This paper presents an account of the challenges that were faced when applying a gradient-informed optimization algorithm using a Monte Carlo calculation to estimate the gradient information and compares a gradient descent optimization method to a genetic algorithm optimization of the same geometry. Overall, this work demonstrates the potential use of adjoint-based gradient calculations in design optimization of nuclear systems.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2019

Synergetic Strengthening of Grain Refinement and Texture in Gradient Zircaloy-4 by Surface Mechanical Rolling Treatment

A Zircaloy-4 rod was subjected to surface mechanical rolling treatment (SMRT) to form a gradient structure, and the evolution of the resulting sub-grain-boundary property and texture across the gradient structure was characterized using electron backscattered diffraction. Dual-gradient structures in grain size and orientation were formed; the grain size was refined from several microns at the center to approximately 400 nm at the topmost surface. Texture analysis revealed that the c-axis gradually tilted from a random orientation toward the parallel-to-radial direction on the radial–tangential plane. The SMRT-induced formation of the dual-gradient microstructure is attributed to the formation of gradient distributions of stress and strain, which resulted in various deformation mechanisms (twinning and dislocation) being active at different depths. During the SMRT process, twinning and dislocations were activated to refine the grains. When the dual-gradient microstructure formed, twinning was mainly activated at the subsurface near the matrix, whereas dislocations were activated across the entire gradient. The geometrically necessary dislocation density increased with decreasing depth and then slightly decreased near the surface. The synergetic strengthening of the dual-gradient microstructure resulted in a gradient distribution of the microhardness near the surface. Thus, the Zircaloy-4 rod exhibited a good combination of strength and ductility.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Binary Electroosmotic-Pump Nanoflow Gradient Generator for Miniaturized High-Performance Liquid Chromatography

High-performance liquid chromatography (HPLC) plays an important role in biotechnology, and a majority of chromatographic separations use gradient elution. While gradient generators can be built in different formats, binary pumps or quaternary pumps are most frequently used for gradient generator constructions. We have recently developed a high-pressure electroosmotic pump (EOP); the pump can be manufactured at a cost of a few hundred dollars. However, it is challenging to use this pump to deliver a gradient eluent directly. In this study, we first improve the monolith preparation by applying a pressure to the monomer solution during polymerization. We assemble a binary EOP gradient generator and discuss the relationship between the gradient profile and voltage applied to the EOP. Here we demonstrate the feasibility of the binary EOP gradient generator for generating a smooth and reproducible nanoflow gradient. After integration of the gradient generator into a miniaturized HPLC system, we use the HPLC system for separating peptide mixtures from trypsin-digested proteins. Lastly, the performance comparison between the above miniaturized HPLC system and an Agilent 1200 HPLC system exhibits comparable efficiencies, resolutions, and peak capacities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

TU-F-CAMPUS-I-04: Head-Only Asymmetric Gradient System Evaluation: ACR Image Quality and Acoustic Noise

Purpose: A high-performance head-only magnetic resonance imaging gradient system with an acquisition volume of 26 cm employing an asymmetric design for the transverse coils has been developed. It is able to reach a magnitude of 85 mT/m at a slew rate of 700 T/m/s, but operated at 80 mT/m and 500 T/m/s for this test. A challenge resulting from this asymmetric design is that the gradient nonlinearly exhibits both odd- and even-ordered terms, and as the full imaging field of view is often used, the nonlinearity is pronounced. The purpose of this work is to show the system can produce clinically useful images after an on-site gradient nonlinearity calibration and correction, and show that acoustic noise levels fall within non-significant risk (NSR) limits for standard clinical pulse sequences. Methods: The head-only gradient system was inserted into a standard 3T wide-bore scanner without acoustic damping. The ACR phantom was scanned in an 8-channel receive-only head coil and the standard American College of Radiology (ACR) MRI quality control (QC) test was performed. Acoustic noise levels were measured for several standard pulse sequences. Results: Images acquired with the head-only gradient system passed all ACR MR image quality tests; Both even and odd-order gradient distortion correction terms were required for the asymmetric gradients to pass. Acoustic noise measurements were within FDA NSR guidelines of 99 dBA (with assumed 20 dBA hearing protection) A-weighted and 140 dB for peak for all but one sequence. Note the gradient system was installed without any shroud or acoustic batting. We expect final system integration to greatly reduce noise experienced by the patient. Conclusion: A high-performance head-only asymmetric gradient system operating at 80 mT/m and 500 T/m/s conforms to FDA acoustic noise limits in all but one case, and passes all the ACR MR image quality control tests. This work was supported in part by the NIH grant 5R01EB010065.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Examination of stiff ion temperature gradient mode physics in simulations of DIII-D H-mode transport

A systematic evaluation of gyrokinetic and gyrofluid model predictions of ion temperature gradient (ITG) stability and transport using parameters from DIII-D high confinement mode (H-mode) plasmas has been performed. The nonlinear CGYRO code is used to make the gyrokinetic predictions, and the quasilinear TGLF model for the corresponding gyrofluid predictions. The assessments are made at three radii (normalized toroidal flux ρtor = 0.4, 0.55, and 0.7) in three different plasma scenarios with varying levels of neutral beam heating and torque. For each of the nine cases (3 radii × 3 scenarios) considered, ITG turbulence is found to be the dominant long-wavelength instability and transport mechanism. The inclusions of both transverse magnetic fluctuations and dynamic fast beam ions are stabilizing for all cases considered, with strongest effects seen at ρor = 0.4 where the fast ion population and normalized plasma pressure β = 2μ0nT/B2 are highest. The further inclusion of parallel magnetic fluctuations does not have a meaningful impact on the ITG turbulence in these scenarios, but does destabilize (in combination with fast ions) new high-frequency instabilities at ρtor = 0.4 in the high power scenarios. In each case the linear and nonlinear ITG critical gradients are predicted to be lower than the measured ITG scale lengths and their associated uncertainties. Inclusion of equilibrium flow shear in the transport predictions generally leads to an upshift in effective critical gradient rather than a qualitative change in the predicted stiffness, with stronger responses typically seen in the gyrokinetic predictions than in the gyrofluid results. However, in most cases these upshifted gradients still remain below the measured values and their uncertainties. Although the predicted critical gradients are below the measured gradients, both models predicted flux-matching gradients consistent with measured values in six of the nine cases considered, with no clear systematic over- or underprediction. Thus, while the experimental ion temperature profiles do not appear to be closely pinned to the ITG critical gradient, both gyrokinetic and gyrofluid models are able to accurately match the measured gradients reasonably well in most cases.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗