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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Evidence for aqueous alteration in a carbonaceous xenolith from the Plainview /H5/ chondrite

The compositions of the mineral components of two inclusions within a CM-like clast in the Plainview (H5) chondrite are determined. The inclusions have the morphologies of an Allende-like, coarse-grained CAI and an amoeboid olivine inclusion, respectively. Major constituents of the altered inclusions are found to be calcite, Mg-Fe-rich phyllosilicates, Fe-Ti oxides, and an Al-rich phyllosilicate, and it is suggested that the alteration process would have required transport of Ne, Cl, H2O, CO2, and FeO. Liquid water appears to be the medium in which the alterations took place, due to the presence of hydrous phases and significant quantities of iron required to produce the mineral assemblages now present from the inferred starting materials.

Nozette, S.↗
NASA NTRS1984

Minor elements and cathodoluminescence of Mg-rich olivines from Murchison and Allende carbonaceous meteorites

The morphology and inclusions of individual Mg rich olivine grains from C2 chondrites provide disputed evidence for origin either from a liquid or a vapor. Olivine grains from Murchison (C2) and Allende (C3) meteorites were examined to extend data on Belgica 7904 (C2. Cathodoluminescence revealed the relation of chemical zoning to external shape and inclusions. High precision electron probe analyses of selected spots for Na, Al, P, Ca, Ti, Cr and Mn provided chemical constraints on the source material. From several possible explanations tentative suggestions are for at least two stages: (1) growth of the blue core from a vapor enriched in refractory elements (hence lack of inclusions); and (2) growth of red/dark rim from an unenriched liquid which entrapped the blue core. Mechanical transfer may be involved. The channels and networks are puzzling at this time. Whatever the true explanation, a complex history is needed for a simple mineral, and further study should provide additional restraints on formation of carbonaceous meteorites.

Steele, I. M.↗
NASA NTRS1993

Martian crater degradation by eolian processes: Analogy with the Rio Cuarto Crater Field, Argentina

Numerous degraded and rimless craters occur across broad areas of the Martian surface that are mantled by thick, unconformable deposits. These regions include Arabia, Mesogaea, Electris, Tempe, the interior and surface to the northwest of Isidis Basin, southern Ismenius Lacus, and the polar layered terrains. Occurrence of the deposits and low regional thermal inertias indicate that at least some accumulated fine-grained sediment (effective particle diameters of 0.1-0.5 mm or coarse silt to medium sand) to a thickness of 100's to 1000's of meters. Most unconformable deposits experienced some eolian modification that may be recent in some locales. Despite the presence of these deposits, simple eolian deposition appears incapable of creating the numerous degraded and rimless craters occurring within their limits. Nevertheless, terrestrial analyses of the Rio Cuario craters formed into loessoid deposits demonstrates that eolian redistribution of fine-grained sediment in and around craters produces degraded morphologies that are analogous to some found in mantled regions on Mars.

Grant, J. A.↗
NASA NTRS1993

Ion-Implanted Diamond Films and Their Tribological Properties

This paper reports the physical characterization and tribological evaluation of ion-implanted diamond films. Diamond films were produced by microwave plasma, chemical vapor deposition technique. Diamond films with various grain sizes (0.3 and 3 microns) and roughness (9.1 and 92.1 nm r.m.s. respectively) were implanted with C(+) (m/e = 12) at an ion energy of 160 eV and a fluence of 6.72 x 10(exp 17) ions/sq cm. Unidirectional sliding friction experiments were conducted in ultrahigh vacuum (6.6 x 10(exp -7)Pa), dry nitrogen and humid air (40% RH) environments. The effects of C(+) ion bombardment on fine and coarse-grained diamond films are as follows: the surface morphology of the diamond films did not change; the surface roughness increased (16.3 and 135.3 nm r.m.s.); the diamond structures were damaged and formed a thin layer of amorphous non-diamond carbon; the friction coefficients dramatically decreased in the ultrahigh vacuum (0.1 and 0.4); the friction coefficients decreased slightly in the dry nitrogen and humid air environments.

Wu, Richard L. C.↗
NASA NTRS1998

Real-Time X-Ray Microscopy of Al-Cu Eutectic Solidification

Recent improvements in the resolution of the X-ray Transmission Microscope (XTM) for Solidification Studies provide microstructure feature detectability down to 5 micrometers during solidification. This presentation will show the recent results from observations made in real-time of the solid-liquid interfacial morphologies of the Al-CuAI2 eutectic alloy. Lamellar dimensions and spacings, transitions of morphology caused by growth rate changes, and eutectic grain structures are open to measurements. A unique vantage point viewing the face of the interface isotherm is possible for the first time with the XTM due to its infinite depth of field. A video of the solid-liquid interfaces seen in-situ and in real-time will be shown.

Kaukler, William F.↗
NASA NTRS1999

Surface Texture and Structure of ZnO Films Synthesized by Off-Axis Sputtering Deposition

Morphology and structure of ZnO films deposited on (0001) sapphire and glass substrates by off-axis sputtering are investigated at various temperatures and pressures. All films show highly textured structures on glass substrates and epitaxial growth on sapphire substrates. The full width at half maximum of theta rocking curves for epitaxial films is less than 0.5 degrees. In textured films, it rises to several degrees. The trend of surface textures in films grown at low pressures is similar to those grown at high temperatures. A morphology transition from large well-defined hexagonal grains to flat surface was observed at a pressure of 50 mtorr and temperature of 550 C. The experiment results are explained by the transport behavior of depositing species.

Zhu, Shen↗
NASA NTRS1980

The relative stress-corrosion-cracking susceptibility of candidate aluminum-lithium alloys for aerospace structural applications

The microstructure and tensile properties of two powder metallurgy processed aluminum-lithium alloys were determined. Strength properties of 480 MPa yield and 550 MPa ultimate tensile strength with 5% strain to fracture were attained. Very little reduction in area was observed and fracture characteristics were brittle. The magnesium bearing alloy exhibited the highest strength and ductility, but fracture was intergranular. Recrystallization and grain growth, as well as coarse grain boundary precipitation, occurred in Alloy 2. The fracture morphology of the two alloys differed. Alloy 1 fractured along a plane of maximum shear stress, while Alloy 2 fractured along a plane of maximum tensile stress. It is found that a fixed orientation relationship exists between the shear fracture plane and the rolling direction which suggests that the PM alloys are strongly textured.

Pizzo, P. P.↗
NASA NTRS2008

The Large-Grained Dust Coma of 174P/Echeclus

On 2005 December 30, Y.-J. Choi and P. R. Weissman discovered that the formerly dormant Centaur 2000 EC98 was in strong outburst. Previous observations by P. Rousselot et al. spanning a 3-year period indicated a lack of coma down to the 27 mag arcsec 2 level.We present Spitzer Space Telescope MIPS observations of this newly active Centaur--now known as 174P/Echeclus (2000 EC98)--or 60558 Echeclus--taken in 2006 late February. The images show strong signal at both the 24 and 70 micron bands and reveal an extended coma about 2' in diameter. Analyses yield estimates of the coma signal contribution that are in excess of 90% of the total signal in the 24 micron band. Dust production estimates ranging from 1.7-4 x 10(exp 2) kg/s are on the order of 30 times that seen in other Centaurs. Simultaneous visible-wavelength observations were also obtained with Palomar Observatory's 200-inch telescope, the 1.8-m Vatican Advanced Technology Telescope, the Bohyunsan Optical Astronomy Observatory (BOAO) 1.8-m telescope, and Table Mountain Observatory's 0.6-m telescope, revealing a coma morphology nearly identical to the mid-IR observations. The grain size distribution derived from the data yields a log particle mass power-law with slope parameter (alpha) = -0.87 +/- 0.07, and is consistent with steady cometary-activity, such as that observed during the Stardust spacecraft's encounter at 81P/Wild 2, and not with an impact driven event, such as that caused by the Deep Impact experiment.

Bauer, James M.↗
NASA NTRS1982

High temperature low cycle fatigue mechanisms for nickel base and a copper base alloy

Damage mechanisms were studied in Rene' 95 and NARloy Z, using optical, scanning and transmission in microscopy. In necklace Rene' 95, crack initiation was mainly associated with cracking of surface MC carbides, except for hold time tests at higher strain ranges where initiation was associated more with a grain boundary mechanism. A mixed mode of propagation with a faceted fracture morphology was typical for all cycle characters. The dependence of life on maximum tensile stress can be demonstrated by the data falling onto three lines corresponding to the three tensile hold times, in the life against maximum tensile stress plot. In NARloy Z, crack initiation was always at the grain boundaries. The mode of crack propagation depended on the cycle character. The life decreased with decreasing strain rate and with tensile holds. In terms of damage mode, different life prediction laws may be applicable to different cycle characters.

Shih, C. I.↗
NASA NTRSDate not supplied

Evaluating Surface Exposure Timescales Derived From Solar Energetic Particle Track Densities for Grains From Apollo 17 Core Sample 73002

Space weathering causes the surface soils of airless bodies like the Moon to be morphologically, microstructurally, and chemically altered due to micrometeoroid bombardment and solar wind exposure. These processes produce a multitude of microstructural and chemical changes that accumulate on individual soil grains that are continuously exposed on the surface. One characteristic is the formation of solar wind damaged rims on grains which develop from low energy solar wind particles penetrating <100 nm in depth. Also present are solar energetic particle (SEP) tracks, which are nanoscale streaks of irradiation damage in grain interiors formed by heavy, high energy ions (predominantly Fe group nuclei) originating from solar energetic particles (SEPs) that penetrate millimeters below the surface.

J. A. McFadden↗
NASA NTRS1992

U-Pb isotopic results for single shocked and polycrystalline zircons record 550-65.5-Ma ages for a K-T target site and 2700-1850-Ma ages for the Sudbury impact event

The refractory mineral zircon develops distinct morphological features during shock metamorphism and retains these features under conditions that would anneal them in other minerals. In addition, weakly shocked zircon grains give primary ages for the impact site, while highly reconstituted (polycrystalline) single grains give ages that approach the age of the impact event. Data for a series of originally coeval grains will define a mixing line that gives both of these ages providing that no subsequent geological disturbances have overprinted the isotopic systematics. In this study, we have shown that the three zircon grain types described by Bohor, from both K-T distal ejecta (Fireball layer, Raton Basin, Colorado) and the Onaping Formation, represent a progressive increase in impact-related morphological change that coincides with a progressive increase in isotopic resetting in zircons from the ejecta and basement rocks. Unshocked grains are least affected by isotopic resetting while polycrystalline grains are most affected. U-Pb isotopic results for 12 of 14 single zircon grains from the Fireball layer plot on or close to a line recording a primary age of 550 +/- 10 Ma and a secondary age of 65.5 +/- 3 Ma. Data for the least and most shocked grains plot closest to the primary and secondary ages respectively. The two other grains each give ages between 300 and 350 Ma. This implies that the target ejecta was dominated by 550-Ma rocks and that the recrystallization features of the zircon were superimposed during the impact event at 65.5 Ma. A predominant age of 550 Ma for zircons from the Fireball layer provides an excellent opportunity to identify the impact site and to test the hypothesis that multiple impacts occurred at this time. A volcanic origin for the Fireball layer is ruled out by shock-related morphological changes in zircon and the fact that the least shocked grains are old. Basement Levack gneisses north of the Sudbury structure have a primary age of 2711 Ma. Data for three single zircons from this rock, which record a progressive increase in shock features, are displaced 24, 36, and 45 percent along a Pb-loss line toward the 1850 +/- 1 Ma minimum age for the impact as defined by the age of the norite. Southeast of the structure three shocked grains from the Murray granite record a primary age of 2468 Ma and are displaced 24, 41, and 56 percent toward the 1853 +/- 4 Ma even as defined by coexisting titanite.

Krogh, T. E.↗
NASA NTRSDate not supplied

Mineralogical, Elemental and Tomographic Reconnaissance Investigation for CLPS (“METRIC”)

METRIC comprises a suite of two instruments in a Lunar lander that perform X-ray diffraction (XRD) for mineral structure, X-ray fluorescence (XRF) for elemental composition, and X-ray Micro Computed Tomography (XCT) for 3D internal micromorphology. The instruments are accompanied by optical-near IR cameras to provide local geologic context. The Honeybee Robotics PlanetVac pneumatic sampling and transfer system [1],positioned on a lander footpad, will deliver sieved regolith to the X-ray instruments for analysis. The instrument suite is intended for delivery to the lunar surface on a Commercial Lunar Payload Services (CLPS) lander. The METRICXRD/F instrument draws on heritage from the Mars Science Laboratory CheMin instrument [2] and improves upon the design in multiple ways [3]. Like CheMin, Rietveld refinement and full-pattern fitting of METRIC XRD data can identify minerals at a detection limit of ~1 wt.%, quantify their abundances when present at >3 wt.%, and determine mineral composition (e.g., Fo#in olivine) from lattice parameters for minerals present at >5 wt.%[4,5]. An optimized XRF geometry provides for improved detection and quantification of major, minor and trace elements. The METRIC XCT instrument is a miniaturized X-ray Computed Tomography scanner[6]. Lunar regolith is delivered to a 3 mm diameter, 10 mm long graphite tube inside the instrument. The tube is rotated through 360°in 0.9deg.incrementsand a divergent point source X-ray beam is directed through the material. A Charge Coupled Device (CCD)records attenuation images whose brightness and contrast area function of average atomic number and density. Quantitative data, including particle and void sizes, 3D particle shape parameters, modal volumes and pore geometry can be derived from the resulting 3D reconstructions(voxel resolution: 30 μm). Crystal morphologies derived from METRIC XCT data complement the bulk mineralogy determined by the METRIC XRD/F and provide a measure of grain size distribution for the different phases. Taken together, the METRIC instrument suite determines crystal structure, elemental composition and morphology, three principal characteristics of geological materials that are highly useful in determining the origin and subsequent processing of lunar regolith.

Moon↗
NASA NTRS1986

The evolution and growth of Al2O3 scales on beta-NiAl

The formation and growth of Al2O3 scales on (beta)-NiAl were studied using electron microscopy and other analytical techniques to gain an understanding of the oxidation properties of (beta)-NiAl and of alumina-forming alloys, in general. The transient and mature stages of oxidation were studied as well as the transformation stage during which the oxide scale transforms from metastable Al2O3 phases to the thermodynamically stable alpha-Al2O3 phase. The transient oxidation stages were studied at 800 deg C and for short times at 1100C. At 800C, the scales consist predominantly of delta-Al2O3 which forms by cation vacancy ordering in the defective spinel lattice of gamma-Al2O3. At 1100C, a fast-growth morphology of theta-Al2O3 forms as a surface layer over delta-Al2O3. For both oxidation temperatures, the scales are often epitaxially oriented with respect to the metal. The transient scales grow by outward cation diffusion as evidenced by surface growth morphologies. The transformation to alpha-Al2O3 occurs within 1 hour at 1100C by a nucleation and radial growth process. The large volume decrease associated with the transformation results in a highly strained alpha-Al2O3 microstructure. A change in scale growth mechanism from outward cation to inward anion diffusion allows transient surface morphologies to be smoothed by surface diffusion. The mature stage of oxidation involves the growth of an alpha-Al2O3 scale having the lacey morphology formed as a result of the gamma yields alpha transformation. Growth of the scale occurs by counterdiffusion along grain boundaries resulting in ridges formed by impingement of alpha-Al2O3 nuclei during the transformation stage. Also scale growth occurs by inward oxygen diffusion through healed cracks; the cracks result from transformation stresses. The measured growth rates of scales having the lacey morphology are an order of magnitude less than fine-grained alpha-Al2O3 scales. Metal orientations were found to have a large effect on oxide morpholoies during all stages of oxidation.

Doychak, J. K.↗
NASA NTRS1985

High temperature oxidation of beta-NiAl

The oxidation of single crystal beta-NiAl has been studied primarily using electron microscopy. Oriented metastable Al2O3 phases form during transient oxidation at 800 C. Specific orientation relationships exist on all metal orientations studied and are a result of the small mismatch along aligned close-packed directions in the cation sublattices of the metal and oxide. Transformation of the metastable Al2O3 phases at 1100 C results in an oxide morphology described as the 'lacey' structure of alpha-Al2O3 scales. This structure results from impingement of oriented patches of alpha-Al2O3 as the transformation initiates and moves radially parallel to the surface. Scale growth occurs by diffusion along high angle grain boundaries. A drastic reduction in oxidation rate accompanies the change in oxide morphology.

Koychak, J. K.↗
NASA NTRS1989

From interstellar dust to comets

The bulk and microstructure of comet nuclei are derived from the morphological structure and chemical composition of submicron sized interstellar dust grains which have undergone cold aggregation in the pre-solar nebula. The evolutionary picture of dust which is emerging is a cyclic one in which the particles, before being destroyed or going into solar system bodies, find themselves during their 5 billion year lifetime alternately in diffuse clouds and in molecular clouds. A small silicate core captured within a molecular cloud accretes various ices and gradually builds up an inner mantle of organic refractory material which has been produced by photoprocessing of the volatile ices. Clumps of grains form, and then clumps of clumps, and so on, until finally we reach the size of the comet nucleus.

Greenberg, J. M.↗
NASA NTRS2007

Infrared and X-Ray Evidence for Circumstellar Grain Destruction by the Blast Wave of Supernova 1987A

Multiwavelength observations of supernova remnant (SNR) 1987A show that its morphology and luminosity are rapidly changing at X-ray, optical, infrared, and radio wavelengths as the blast wave from the explosion expands into the circumstellar equatorial ring, produced by mass loss from the progenitor star. The observed infrared (IR) radiation arises from the interaction of dust grains that formed in mass outflow with the soft X-ray emitting plasma component of the shocked gas. Spitzer IRS spectra at 5 - 30 microns taken on day 6190 since the explosion show that the emission arises from approx. 1.1 x 10(exp -6) solar mass of silicate grains radiating at a temperature of approx. 180+/-(15-20) K. Subsequent observations on day 7137 show that the IR flux had increased by a factor of 2 while maintaining an almost identical spectral shape. The observed IR-to-X-ray flux ratio (IRX) is consistent with that of a dusty plasma with standard LMC dust abundances. This flux ratio has decreased by a factor of approx. 2 between days 6190 and 7137, providing the first direct observation of the ongoing destruction of dust in an expanding SN blast wave on dynamic time scales. Detailed models consistent with the observed dust temperature, the ionization fluence of the soft X-ray emission component, and the evolution of IRX suggest that the radiating si1icate grains are immersed in a 3.5 x 10(exp 6) K plasma with a density of (0.3 - 1) x 10(exp 4)/cu cm, and have a size distribution that is confined to a narrow range of radii between 0.02 and 0.2 microns. Smaller grains may have been evaporated by the initial UV flash from the supernova.

Dwek, Eliahu↗
NASA NTRS2003

Pristine Presolar Silicon Carbide

In this talk we discuss a simple physical disaggregation technique coupled with an X-ray mapping procedure used to locate 81 micrometer-sized presolar SiC grains from the Murchison carbonaceous chondrite, that preserves them in their pristine state. We then describe pristine SiC surface characteristics and overall morphologies determined by high resolution field emission scanning electron microscopy (FESEM), and compare these features to those of presolar SiC grains that have been prepared using chemical dissolution techniques.

Bernatowicz, T. J.↗