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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Direct detection of C4H2 photochemical products - Possible routes to complex hydrocarbons in planetary atmospheres

The photochemistry of diacetylene (C4H2), the largest hydrocarbon to be unambiguously identified in planetary atmospheres, is of considerable importance to understanding the mechanisms by which complex molecules are formed in the solar system. In this work, the primary products of C4H2's ultraviolet photochemistry were determined in a two-laser pump-probe scheme in which the products of C4H2 photoexcitation are detected by vacuum ultraviolet photoionization in a time-of-flight mass spectrometer. Three larger hydrocarbon primary products were observed with good yield in the C4H2 + C4H2 reaction: C6H2, C8H2, and C8H3. Neither C6H2 or C8H3 is anticipated by current photochemical models of the atmospheres of Titan, Uranus, Neptune, Pluto, and Triton. The free hydrogen atoms that are released during the formation of the C8H3 and C8H2 products also may partially offset the role of C4H2 in catalyzing the recombination of free hydrogen atoms in the planetary atmospheres.

Bandy, Ralph E.↗

Comparison of electron and electronic temperatures in recombining nozzle flow of ionized nitrogen-hydrogen mixture. I, II.

Relaxation of the population distribution of electronic states is studied theoretically for a highly ionized nitrogen-hydrogen mixture expanding through a nozzle wherein the hydrogen content is less than 0.1%. The analysis incorporates quantum-mechanical rate coefficients, and considers the effects of wall cooling and absorption of radiation. Calculations are carried out for a condition produced experimentally. Visible and infrared line radiations from nitrogen and hydrogen were measured with a spectrograph. The geometry and stagnation conditions were those calculated theoretically. The experiment confirms quantitatively the predictions that the electronic excitation temperatures of hydrogen and (3P) core states of nitrogen are higher than the electron temperature, and that (3P) excitation temperatures exhibit maxima within the nozzle.

Park, C.↗

Storage and recombination of atomic H in solid H2

A phenomenological rate process theory is developed for the storage and rapid recombination of atomic hydrogen free radicals in a crystalline molecular hydrogen solid at temperatures in the range of about 0.1-4 K. It is shown that such a theory can account quantitatively for the recently observed dependence of the storage time on the storage temperature, for the maximum concentration of trapped H atoms, and for the time duration of the energy release in the tritium decay experiments of Webeler. The theory predicts that maximum atomic hydrogen concentrations of the order 10 to the 20th per cu cm are realizable for storage temperatures in the vicinity of 0.14 K.

Rosen, G.↗

Spectroscopy of the B-gamma line in the Galactic center

Spectra of the B-gamma recombination line of hydrogen in the Galactic center show that the line has central velocities and shapes similar to those reported previously for the Ne II line. Observations are made at 10 positions within the infrared cluster of the Galactic center with a circular diaphragm of diameter 5 arcsec and with a spectral resolution of approximately 85 km/sec. The spectra confirm that the ionized gas in the Galactic center is distributed in discrete clouds.

Nadeau, D.↗

Infrared imaging spectroscopy of the Galactic center - Distribution and motions of the ionized gas

High spatial spectral resolution IR images of the Galactic center in the Br-gamma recombination line of hydrogen were taken. A coherent filament of gas extending from north of IRS 1, curving around IRS 16/Sgr A complex, and continuing to the southwest, is seen. Nine stellar sources have associated Br-gamma emission. The total Br-gamma line flux in the filament is approximately 3 x 10 exp -15 W/sq m. The distribution and kinematics of the northern arm suggest orbital motion; the observations are accordingly fit with elliptical orbits in the field of a central point of mass.

Herbst, T. M.↗

Hubble Space Telescope images of the Seyfert galaxies NGC 5929 and MCG 8-11-11

We present the initial results of a program to obtain high resolution images of Seyfert galaxies with the Planetary Camera aboard the Hubble Space Telescope (HST). In this paper we discuss the images of the type 2 Seyfert NGC 5929 and the type 1.5 Seyfert MCG 8-11-11 (= UGC 3374). The images were obtained in the emission lines of (O III) lambda lambda 4959 and 5007 A and H alpha + (N II) lambda lambda 6548 and 6583 A and their adjacent continua. The high-excitation gas in the narrow line region (NLR) of NGC 5929 is resolved into individual clouds in the central 1 sec .5. Although the (O III) emission is clearly not spherically symmetric with respect to the nucleus, it does not define a distinct 'bicone' morphology, as observed by the HST in a few other Seyfert galaxies. We find no direct evidence for the reddening and/or obscuration effects characteristic of a dusty torus, which, in the context of 'unified models', is expected to obscure the active galactic nucleus (AGN) in type 2 Seyfert galaxies. The correspondence between the emission line gas and the radio morphology suggests that the structure of the NLR in NGC 5929 is governed by matter ejected from the AGN. A comparison of the recombination rate of hydrogen in the brightest emission line cloud with an upper limit on the ionizing luminosity emitted toward Earth provides no evidence that the central ionizing source radiates anisotropically. The images of MCG 8-11-11 show only an unresolved nuclear source. No emission line gas associated with the extended radio source is detected. We estimate upper limits on the intensity of extended line emission in this galaxy and examine their significance.

Bower, Gary A.↗

Evolution of Iron K Alpha Line Emission in the Black Hole Candidate GX 339-4

GX 339-4 was regularly monitored with the Rossi X-Ray Timing Explorer during a period (in 1999) when its X-ray flux decreased significantly (from 4.26 x 10(exp -10) to 7.6 x 10(exp -12) ergs in the 3-20 keV band), as the source settled into the 'off state.' Our spectral analysis revealed the presence of a prominent iron K alpha line in the observed spectrum of the source for all observations. The line shows an interesting evolution: it is centered at approx. 6.4 keV when the measured flux is above 5 x 10(exp -1) ergs per sq cm/s but is shifted to approx. 6.7 keV at lower fluxes. The equivalent width of the line appears to increase significantly toward lower fluxes, although it is likely to be sensitive to calibration uncertainties. While the fluorescent emission of neutral or mildly ionized iron atoms in the accretion disk can perhaps account for the 6.4 keV line, as is often invoked for black hole candidates, it seems difficult to understand the 6.7 keV line with this mechanism because the disk should be less ionized at lower fluxes (unless its density changes drastically). On the other hand, the 6.7 keV line might be due to a recombination cascade of hydrogen- or helium-like iron ions in an optically thin, highly ionized plasma. We discuss the results in the context of proposed accretion models.

Feng, Y. X.↗

Near-infrared spectroscopy of the proto-planetary nebula CRL 618 and the origin of the hydrocarbon dust component in the interstellar medium

A new 2.8-3.8 micrometers spectrum of the carbon-rich protoplanetary nebula CRL 618 confirms the previous detection of a circumstellar 3.4 micrometers absorption feature in this object (Lequeux & Jourdain de Muizon). The high resolution and high signal-to-noise ratio of our spectrum allow us to derive the detailed profile of this absorption feature, which is very similar to that observed in the spectrum of the Galactic center and also resembles the strong 3.4 micrometers emission feature in some post-asymptotic giant branch stars. A weak 3.3 micrometers unidentified infrared band, marginally detected in the CRL 618 spectrum of Lequeux & Jourdain de Muizon, is present in our spectrum. The existence of the 3.4 micrometers feature implies the presence of relatively short-chained, aliphatic hydrocarbon materials (-CH2-/-CH3 approximately = 2-2.5) in the circumstellar environment around CRL 618. It also implies that the carriers of the interstellar 3.4 micrometers feature are produced at least in part in circumstellar material, and it calls into question whether any are produced by the processing of interstellar ices in dense interstellar clouds, as has been previously proposed. Other features in the spectrum are recombination lines of hydrogen, rotational and vibration-rotation lines of molecular hydrogen, and a broad absorption probably due to a blend of HCN and C2H2 bands.

Spectroscopy, Near-Infrared↗

Multiphysics Analysis of a Solid-Core Nuclear Thermal Engine Thrust Chamber

The objective of this effort is to develop an efficient and accurate thermo-fluid computational methodology to predict environments for a hypothetical solid-core, nuclear thermal engine thrust chamber. The computational methodology is based on an unstructured-grid, pressure-based computational fluid dynamics methodology. Formulations for heat transfer in solids and porous media were implemented and anchored. A two-pronged approach was employed in this effort: A detailed thermo-fluid analysis on a multi-channel flow element for mid-section corrosion investigation; and a global modeling of the thrust chamber to understand the effect of hydrogen dissociation and recombination on heat transfer and thrust performance. The formulations and preliminary results on both aspects are presented.

Wang, Ten-See↗

Lyman-Alpha Comes of Age

The Lyman-alpha (Lyα) line is the strongest recombination line of hydrogen, which constitutes the dominant share of normal matter in the Universe. Fifty-one years ago, it was predicted that Lyα emission should appear prominently in the spectra of young primordial galaxies. For the next 30 years, this prediction was tested by many surveys, but none found the predicted galaxies at the predicted luminosities. The blame for these non-detections was squarely cast on the resonant nature of the Lyα line, which requires Lyα photons to scatter off many hydrogen atoms before escaping from a galaxy. This can hugely increase the path that they traverse, and consequently also the probability that they will be absorbed by dust. This remained the dominant explanation of the missing high-redshift lines for decades, despite some dissenting opinions about the effect of dust. The spectra of nearby galaxies from the International Ultraviolet Explorer are inconclusive about what allows galaxies to be Lyα emitters. The ‘missing’ lines were finally detected 20 years ago, at flux levels much below the original predictions - a difference that we understand to be predominantly due to the hierarchical growth of galaxies, such that star-forming objects at high redshift are much less massive than anticipated in the original prediction. The discovery and study of Lyα galaxies has blossomed into an invaluable method for understanding the youngest stages of galaxy formation, the circumgalactic medium, and ultimately the epoch of reionization. The high equivalent widths of Lyα galaxies from the earliest high-redshift surveys show that they are low-mass galaxies dominated by young stellar populations. The Sakura CLAW workshop (which used the Twitter hashtag #SakuraCLAW) gathered more than 110 participants (Fig. 1) who showcased progress that pushed the frontiers of Lyα galaxy science in sample size, sensitivity, redshifts and physical understanding..

Malhotra, Sangeeta↗

Dielectronic recombination rates, ionization equilibrium, and radiative energy-loss rates for neon, magnesium, and sulfur ions in low-density plasmas

Results of detailed and systematic calculations are presented for the total dielectronic recombination rate coefficients for the ions of Ne, Mg, and S in a low-density predominantly hydrogen plasma. The new recombination rates are used to calculate solar corona ionization-equilibrium distributions of the ions. The most important effect of dielectronic recombination for ions in corona equilibrium is found to be a shift in the maximum-abundance temperatures toward higher temperatures, which are in some cases reduced from those predicted on the basis of the simple Burgess formula.

Jacobs, V. L.↗

Multiple jets from the young star IRAS 21334 + 5039

The source IRAS 21334 + 5039, a young stellar object (YSO) with broad CO outflow velocity profiles, was imaged in the 1-2 micron region with broad-band J, H, and K filters, and with a Fabry-Perot set to the molecular hydorgen v = 1-0 S(1) line, the hydrogen Br-gamma recombination line, and the neighboring continua. At 2 microns the source has an elongated continuum emission structure centered on the star. The structure has very blue tips, with a weak VLA 6 cm continuum source coincident with one of them. Strong molecular hydrogen emission appears as bow-shaped arcs oriented along an axis perpendicular to the continuum emission, and as a weaker structure aligned with it. Both the continuum and the molecular hydrogen emission are most likely produced by jets, possibly emanating in multiple directions from the central source at large angles to each other. While jets are a common feature of young stars, this source provides solid evidence for multiple jet structures.

Smith, Howard A.↗

Fast molecular shocks. II - Emission from fast dissociative shocks

The line radiations emitted in the cooling gas behind a fast dissociative shock are studied. The intensities emitted in high rotational transitions of the neutral molecules CO, SiO, HCN, CN, NO, and SO are estimated, as well as in rovibrational transitions of the molecular ions HeH(+) and OH(+) in radio recombination lines of atomic hydrogen and in fine-structure transitions of C, C(+), O, and Si(+). The predictions are compared with the observed intensities of line emission from the Orion-KL region. For Orion-KL the observations do not exclude, but probably do not require, the presence of a fast dissociative shock. Emission from SiO in high-J rotational states and from vibrationally excited OH(+), HeH(+), HeH(+), and SO(+) may be detectable from dissociative shocks under suitable conditions of preshock density and shock velocity; such emission may prove to be a useful diagnostic probe of fast shock activity.

Neufeld, David A.↗