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At least 127 records · Page 7

Moisture-Induced Delayed Spallation and Interfacial Hydrogen Embrittlement of Alumina Scales

While interfacial sulfur is the primary chemical factor affecting Al2O3 scale adhesion, moisture-induced delayed spallation appears as a secondary, but impressive, mechanistic detail. Similarities with bulk metallic phenomena suggest that hydrogen embrittlement from ambient humidity, resulting from the reaction Al(sub alloy)+3(H2O)(sub air) = Al(OH)(-) (sub 3) +3H(+) may be the operative mechanism. This proposal was tested on pre-oxidized Rene N5 by standard cathodic hydrogen charging in 1N H2SO4, as monitored by weight change, induced current, and microstructure. Cathodic polarization at -2.0 V abruptly stripped mature Al2O3 scales at the oxide-metal interface. Anodic polarization at +2.0 V, however, produced alloy dissolution. Finally, with no applied voltage, the acid electrolyte produced neither scale spallation nor alloy dissolution. Thus, hydrogen charging was detrimental to alumina scale adhesion. Moisture-induced interfacial hydrogen embrittlement is concluded to be the cause of delayed scale spallation and desktop thermal barrier coating failures.

Smialek, James L.↗

Cellular specificity of the gravitropic motor response in roots

A number of features of the gravitropic response of roots are not readily accounted for by the classical Cholodny-Went theory. These include the observations that (i) in the later stages of the response the growth gradient is reversed with no evident reversal of the auxin gradient; (ii) a major component of the acceleration of growth along the upper side occurs in the distal elongation zone (DEZ), a group of cells located between the meristem and the main elongation, not within the central elongation zone; and (iii) the initiation of differential growth in the DEZ appears to be independent of the establishment of auxin asymmetry. Alternative candidates for mediation of differential growth in the DEZ include calcium ions and protons. Gravi-induced curvature is accompanied by polar movement of calcium toward the lower side of the maize root tip and the DEZ is shown to be particularly sensitive to growth inhibition by calcium. Also, gravistimulation of maize roots causes enhanced acid efflux from the upper side of the DEZ. Evidence for gravi-induced modification of ion movements in the root tip includes changes in intracellular potentials and current flow. It is clear that there is more than one motor region in the root with regard to gravitropic responses and there is evidence that the DEZ itself consists of more than one class of responding cells. In order to gain a more complete understanding of the mechanism of gravitropic curvature, the physiological properties of the sub-zones of the root apex need to be thoroughly characterized with regard to their sensitivity to hormones, calcium, acid pH and electrical perturbations.

NASA Discipline Plant Biology↗

Augmentation of maneuver performance by spanwise blowing

A generalized wind tunnel model was tested to investigate new component concepts utilizing spanwise blowing to provide improved maneuver characteristics for advanced fighter aircraft. Primary emphasis was placed on high angle of attack performance, stability, and control at subsonic speeds. Spanwise blowing on a 44 deg swept trapezoidal wing resulted in leading edge vortex enhancement with subsequent large vortex-induced lift increments and drag polar improvements at the higher angles of attack. Small deflections of a leading edge flap delayed these lift and drag benefits to higher angles of attack. In addition, blowing was more effective at higher Mach numbers. Spanwise blowing in conjunction with a deflected trailing edge flap resulted in lift and drag benefits that exceeded the summation of the effects of each high lift device acting alone. Asymmetric blowing was an effective lateral control device at the higher angles of attack. Spanwise blowing on the wing reduced horizontal tail loading and improved the lateral-directional stability characteristics of a wing-horizontal tail-vertical tail configuration.

Erickson, G. E.↗

Improvement of maneuver aerodynamics by spanwise blowing

Spanwise blowing was used to test a generalized wind-tunnel model to investigate component concepts in order to provide improved maneuver characteristics for advanced fighter aircraft. Primary emphasis was placed on performance, stability, and control at high angles of attack and subsonic speeds. Test data were obtained in the Langley high speed 7 by 10 foot tunnel at free stream Mach numbers up to 0.50 for a range of model angles of attack, jet momentum coefficients, and leading and trailing edge flap deflection angles. Spanwise blowing on a 44 deg swept trapezoidal wing resulted in leading edge vortex enhancement with subsequent large vortex induced lift increments and drag polar improvements at the higher angles of attack. Small deflections of a leading edge flap delayed these lift and drag benefits to higher angles of attack. In addition, blowing was more effective at higher Mach numbers. Spanwise blowing in conjunction with a deflected trailing edge flap resulted in lift and drag benefits that exceeded the summation of the effects of each high lift device acting alone. Asymmetric blowing was an effective lateral control device at the higher angles of attack.

Erickson, G. E.↗

The phase of the crosspolarized signal generated by millimeter wave propagation through rain

Proposed schemes for cancelling rain-induced crosstalk in dual-polarized communications systems depend upon the phase relationships between the wanted and unwanted signals. This report investigates the phase relationship of the rain-generated crosspolarized signal relative to the copolarized signal. Theoretical results obtained from a commonly accepted propagation model are presented. Experimental data from the Communications Technology Satellite beacon and from the Comstar beacon are presented and the correlation between theory and data is discussed. An inexpensive semi-adaptive cancellation system is proposed and its performance expectations are presented. The implications of phase variations on a cancellation system are also discussed.

Overstreet, W. P.↗

Ion confinement and transport in a toroidal plasma with externally imposed radial electric fields

Strong electric fields were imposed along the minor radius of the toroidal plasma by biasing it with electrodes maintained at kilovolt potentials. Coherent, low-frequency disturbances characteristic of various magnetohydrodynamic instabilities were absent in the high-density, well-confined regime. High, direct-current radial electric fields with magnitudes up to 135 volts per centimeter penetrated inward to at least one-half the plasma radius. When the electric field pointed radially toward, the ion transport was inward against a strong local density gradient; and the plasma density and confinement time were significantly enhanced. The radial transport along the electric field appeared to be consistent with fluctuation-induced transport. With negative electrode polarity the particle confinement was consistent with a balance of two processes: a radial infusion of ions, in those sectors of the plasma not containing electrodes, that resulted from the radially inward fields; and ion losses to the electrodes, each of the which acted as a sink and drew ions out of the plasma. A simple model of particle confinement was proposed in which the particle confinement time is proportional to the plasma volume. The scaling predicted by this model was consistent with experimental measurements.

Roth, J. R.↗

Zonal wind observations during a geomagnetic storm

In situ measurements taken by the Wind and Temperature Spectrometer (WATS) onboard the Dynamics Explorer 2 spacecraft during a geomagnetic storm display zonal wind velocities that are reduced in the corotational direction as the storm intensifies. The data were taken within the altitudes 275 to 475 km in the dusk local time sector equatorward of the auroral region. Characteristic variations in the value of the Dst index of horizontal geomagnetic field strength are used to monitor the storm evolution. The detected global rise in atmospheric gas temperature indicates the development of thermospheric heating. Concurrent with that heating, reductions in corotational wind velocities were measured equatorward of the auroral region. Just after the sudden commencement, while thermospheric heating is intense in both hemispheres, eastward wind velocities in the northern hemisphere show reductions ranging from 500 m/s over high latitudes to 30 m/s over the geomagnetic equator. After 10 hours storm time, while northern thermospheric heating is diminishing, wind velocity reductions, distinct from those initially observed, begin to develop over southern latitudes. In the latter case, velocity reductions range from 300 m/s over the highest southern latitudes to 150 m/s over the geomagnetic equator and extend into the Northern Hemisphere. The observations highlight the interhemispheric asymmetry in the development of storm effects detected as enhanced gas temperatures and reduced eastward wind velocities. Zonal wind reductions over high latitudes can be attributed to the storm induced equatorward spread of westward polar cap plasma convection and the resulting plasma-neutral collisions. However, those collisions are less significant over low latitudes; so zonal wind reductions over low latitudes must be attributed to an equatorward extension of a thermospheric circulation pattern disrupted by high latitude collisions between neutrals transported via eastward winds and ions convecting westward.

Miller, N. J.↗

Carbon-Based Compounds and Exobiology

The Committee for Planetary and Lunar Explorations (COMPLEX) posed questions related to exobiological exploration of Mars and the possibility of a population of carbonaceous materials in cometary nuclei to be addressed by future space missions. The scientific objectives for such missions are translated into a series of measurements and/or observations to be performed by Martian landers. These are: (1) A detailed mineralogical, chemical, and textural assessment of rock diversity at a landing site; (2) Chemical characterization of the materials at a local site; (3) Abundance of Hydrogen at any accessible sites; (4) Identification of specific minerals that would be diagnostic of aqueous processes; (5) Textual examination of lithologies thought to be formed by aqueous activity; (6) Search for minerals that might have been produced as a result of biological processes; (7) Mapping the distribution, in three dimensions, of the oxidant(s) identified on the Martian surface by the Viking mission; (8) Definition of the local chemical environment; (9) Determination of stable-isotopic ratios for the biogenic elements in surface mineral deposits; (10) Quantitative analysis of organic (non-carbonate) carbon; (11) Elemental and isotopic composition of bulk organic material; (12) Search for specific organic compounds that would yield information about synthetic mechanisms, in the case of prebiotic evolution, and about possible bio-markers, in the case of extinct or extant life; (13) and Coring, sampling, and detection of entrained gases and cosmic-ray induced reaction products at the polar ice cap. A discussion of measurements and/or observations required for cometary landers is included as well.

Kerridge, John↗

Solar Wind Induced Waves in the Skies of Mars: Ionospheric Compression, Energization, and Escape Resulting from the Impact of Ultralow Frequency Magnetosonic Waves Generated Upstream of the Martian Bow Shock

Using data from the National Aeronautics and Space Administration Mars Atmosphere and Voltatile EvolutioN and the European Space Agency Mars Express spacecraft, we show that transient phenomena in the foreshock and solar wind can directly inject energy into the ionosphere of Mars. We demonstrate that the impact of compressive ultralow frequency waves in the solar wind on the induced magnetospheres drive compressional, linearly polarized, magnetosonic ultralow frequency waves in the ionosphere, and a localized electromagnetic "ringing" at the local proton gyro frequency. The pulsations heat and energize Ionospheric plasmas. A preliminary survey of events shows that no special upstream conditions are required in the interplanetary magnetic field or solar wind. Elevated ion densities and temperatures in the solar wind near to Mars are consistent with the presence of an additional population of Martian ions, leading to ion-ion instabilities, associated wave-particle interactions, and heating of the solar wind. The phenomenon was found to be seasonal, occurring when Mars is near perihelion. Finally, we present simultaneous multipoint observations of the phenomenon, with the Mars Express observing the waves upstream, and Mars Atmosphere and Voltatile EvolutioN observing the response in the ionosphere. When these new observations are combined with decades of previous studies, they collectively provide strong evidence for a previously undemonstrated atmospheric loss process at unmagnetized planets: ionospheric escape driven by the direct impact of transient phenomena from the foreshock and solar wind.

Collinson, Glyn↗

Effect of polarization on superfluidity in low density neutron matter

The singlet-state quasi-particle interaction in neutron matter is examined on the basis of results of a detailed evaluation of the Landau Fermi-liquid parameters for pure neutron effects, including polarization effects. This means that the interaction induced by exchange of density and spin-density excitations is taken into account. It is shown that polarization actually works to suppress the pairing matrix elements, owing to the spin dependence of the quasi-particle interaction and, ultimately, the balance of attraction, repulsion, and spin dependence in the fundamental two-neutron interaction. Since the isotropic energy gap and the condensation energy in low-density neutron-star matter are extremely sensitive functions of the pairing matrix elements, they will also be suppressed by the polarizability of the neutron medium.

Clark, J. W.↗

Characterization of root agravitropism induced by genetic, chemical, and developmental constraints

The patterns and rates of organelle redistribution in columella (i.e., putative statocyte) cells of agravitropic agt mutants of Zea mays are not significantly different from those of columella cells in graviresponsive roots. Graviresponsive roots of Z. mays are characterized by a strongly polar movement of 45Ca2+ across the root tip from the upper to the lower side. Horizontally-oriented roots of agt mutants exhibit only a minimal polar transport of 45Ca2+. Exogenously-induced asymmetries of Ca result in curvature of agt roots toward the Ca source. A similar curvature can be induced by a Ca asymmetry in normally nongraviresponsive (i.e., lateral) roots of Phaseolus vulgaris. Similarly, root curvature can be induced by placing the roots perpendicular to an electric field. This electrotropism increased with 1) currents between 8-35 mA, and 2) time between 1-9 hr when the current is constant. Electrotropism is reduced significantly by treating roots with triiodobenzoic acid (TIBA), an inhibitor of auxin transport. These results suggest that 1) if graviperception occurs via the sedimentation of amyloplasts in columella cells, then nongraviresponsive roots apparently sense gravity as do graviresponsive roots, 2) exogenously-induced asymmetries of a gravitropic effector (i.e., Ca) can induce curvature of normally nongraviresponsive roots, 3) the gravity-induced downward movement of exogenously-applied 45Ca2+ across tips of graviresponsive roots does not occur in nongraviresponsive roots, 4) placing roots in an electrical field (i.e., one favoring the movement of ions such as Ca2+) induces root curvature, and 5) electrically-induced curvature is apparently dependent on auxin transport. These results are discussed relative to a model to account for the lack of graviresponsiveness by these roots.

NASA Discipline Number 40-10↗

Moisture-Induced Spallation and Interfacial Hydrogen Embrittlement of Alumina Scales

Thermal expansion mismatch stresses and interfacial sulfur activity are the major factors producing primary Al2O3 scale spallation on high temperature alloys. However, moisture-induced delayed spallation appears as a secondary, but often dramatic, illustration of an additional mechanistic detail. A historical review of delayed failure of alumina scales and TBC s on superalloys is presented herein. Similarities with metallic phenomena suggest that hydrogen embrittlement from ambient humidity, resulting from the reaction Al+3H2O=Al(OH)3+3H(+)+3e(-), is the operative mechanism. This proposal was tested by standard cathodic hydrogen charging in 1N H2SO4, applied to Rene N5 pre-oxidized at 1150 C for 1000 1-hr cycles, and monitored by weight change, induced current, and microstructure. Here cathodic polarization at -2.0 V abruptly stripped mature Al2O3 scales at the oxide-metal interface. Anodic polarization at +2.0 V, however, produced alloy dissolution. Finally, with no applied voltage, the electrolyte alone produced neither scale spallation nor alloy dissolution. These experiments thus highlight the detrimental effects of hydrogen charging on alumina scale adhesion. It is proposed that interfacial hydrogen embrittlement is produced by moist air and is the root cause of both moisture-induced, delayed scale spallation and desktop TBC failures.

Smialek, James L.↗

Northern Late Winter Planetary Waves: MRO/MARCI Observations and Mars Climate Model Simulations

As does Earth, Mars presents pronounced global atmospheric circulation patterns. Solar differential heating drives mean meridional overturning (Hadley) circulations which are deep and intense, are hemispherically asymmetric, and where a cross-equatorial single cell dominates. Within middle and high latitudes, thermally indirect eddy-driven (Ferrel) circulation cells have been indicated. Differently, however, large-amplitude orography on planetary and continental scales on Mars can force very non-Earth-like hemispheric circulation patterns. Recent observations from the Mars Reconnaissance Orbiter, "Mars Color Imager" (MARCI) instrument are utilized that emphasize water ice clouds in ultra-violet (UV) wavelengths, and these measurements have been binned into "daily global maps" (DGMs) of water-ice cloud optical depth. The presence of large-scale, extratropical quasi-stationary atmospheric wave disturbances in middle and late winter of the northern hemisphere have been found to be present in such DGMs. In combination with such observations, a full-physics Mars global climate model (NASA ARC marsgcm 2.1) is applied to place the observations into context. During late northern winter, it is found that strong, forced Rossby modes (i.e., planetary waves) exist, and with direct correlation to columnintegrated cloud opacity undulating spatial patterns. At this season, zonal wavenumber s = 2 dominates (in contrast to wavenumber s = 1), consistent with MGS/TES analyses at this particular season (Banfield et al., 2003). Large-scale, planetary waves dictate the "coherence" of the northern polar vortex. Fundamentally, such forced planetary waves influence the polar vortex's impermeability (wave-induced) to tracer transport (e.g., dust and water-ice aerosol) and temporal mean water vapor spatial variations. The large-scale dynamical features of such planetary waves will be highlighted and discussed.

Northern polar vortex↗

Wind transport near the poles of Mars: Timescales of changes in deposition and erosion

Movement of sediment into and out of polar deposits is closely linked to the polar volatile budget and to changes in wind systems over the course of astronomically induced climate cycles. The present observations of the morphology of polar layered deposits, mantling sediments, dune fields, and variable surface features are the basis of inferences on the efficacy of polar sediment transport mechanisms. The time scales of formation of these features vary from days to perhaps 10(exp 6) yr, and latitudinal banding of dune fields near the poles may have been formed on timescales of 10(exp 7) yr. Orientations of intracrater dunes, dune crests, and wind streaks have been measured for latitudes -45 to -90 to compare features of likely different timescales of formation with models of wind flow from the south polar region. There is a complex variation with latitude of the indicated wind directions and of the efficacy of the resultant winds in orienting dune fields that suggests influence of frost cover on the ability of winds to move sediment in the spring and fall. Because of changes in the relative effectiveness of spring and fall winds expected with progression of the season of perihelion, the latitudinal variation in transport efficiency may mean that sediments at different latitudes dominantly respond to wind erosion and transport at different times during the perihelion cycle.

Thomas, Peter C.↗

Thermal- and plasma-induced molecular redistribution on the icy satellites

The molecular transport of condensed gas species across the surfaces of the icy satellites of Jupiter and Saturn is examined with the view of describing, in part, certain gross visual features associated with these bodies. Molecular redistribution induced by thermal sublimation and magnetospheric plasma-ion impact on satellites with negligible atmospheres is calculated by assuming that the molecules follow ballistic trajectories and by statistically selecting initial molecular velocities and points of origin. Erosion/deposition profiles so calculated are compared for a variety of satellite sizes and environments in order to understand the relative importance of sublimation and cold corotating plasma-ion- and fast plasma-ion-induced transport. The erosion/deposition profiles are used to discuss the appearance of a polar frost on Ganymede. A balance of magnetospheric-ion implantation and ion-induced molecular redistribution is used to discuss the observation of embedded SO2 and the darkening of the trailing side on Europa. Ion-induced molecular transport may also limit the deposition of SO2 frost in the polar regions of Io and may be a source of heavy particles in the Jovian and Saturnian magnetospheres.

Sieveka, E. M.↗

Twisting of the geomagnetic tail

Theory and models indicate that the IMF causes the magnetotail to produce an observable twist, predicting that the torque should bring the north lobe south of the GSM xy plane on one flank of the magnetotail, and the south lobe north of the plane on the other flank. In this paper, ISEE-3 geotail observations are compared with simultaneously made IMP 8 IMF observations supplemented by inferred IMF B(y) polarities to demonstrate the IMF-induced magnetotail twist. The results indicate that twisting is the single most important factor accounting for observations of the north lobe south of the GSM xy plane and the south lobe north of the plane. The value of the observed magnetotail twist about its aberrated axis is about 18 deg.

Sibeck, D. G.↗

An application of the WKBJ technique to the on-surface radiation condition

The on-surface radiation-condition method and the WKBJ method for approximating solutions to differential equations are used to derive an analytic formula for the surface currents on a two-dimensional perfectly conducting convex target. The currents are induced by an incident TE-polarized plane wave. The case of a circular cylinder is used to demonstrate the usefulness of the combined methods. It is shown that a two-term expansion yields good results for the surface currents and excellent results for the ensuing bistatic radar cross section.

Moore, Thomas G.↗