EPR study of electron irradiated LiF
Electron paramagnetic resonance detection of electron bombarded lithium fluoride
Fryburg, G. C.↗
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Optical coatings for space astronomy
Magnesium fluoride- and lithium fluoride-optical coatings for aluminum mirror in space astronomy
Osantowski, J. F.↗
Design and fabrication of brayton cycle solar heat receiver
A detail design and fabrication of a solar heat receiver using lithium fluoride as the heat storage material was completed. A gas flow analysis was performed to achieve uniform flow distribution within overall pressure drop limitations. Structural analyses and allowable design criteria were developed for anticipated environments such as launch, pressure containment, and thermal cycling. A complete heat receiver assembly was fabricated almost entirely from the refractory alloy, niobium-1% zirconium.
Mendelson, I.↗
Measured performance of a 1089 K (1500 deg F) heat storage device for sun-shade orbital missions
Tubes designed for a solar heat receiver to serve as an energy source for a Brayton power system were tested for 2002 hours and 1251 sun-shade cycles. The tubes were designed to transfer a constant thermal input to the Brayton system during an orbit. Excess solar energy during a sun period is stored as heat of fusion of lithium fluoride. The niobium - 1% zirconium tubes accommodate the 23 percent volume decrease of LiF during freezing. Test results showed slight, local distortions. The gas discharge temperature varied from 16 K (29 F) below to 28 K (50 F) above the nominal value of 1089 K (1500 F). The tube surface temperatures ranged from 1039 K (1410 F) to 1183 K (1670 F).
Namkoong, D.↗
Preliminary design of a solar heat receiver for a Brayton cycle space power system
The preliminary design of a solar heat receiver for use as a heat source for an earth-orbiting 11-kWe Brayton-cycle engine is described. The result was a cavity heat receiver having the shape of a frustum of a cone. The wall of the cone is formed by 48 heat-transfer tubes, each tube containing pockets of lithium fluoride for storing heat for as much as 38 minutes of fullpower operation in the shade. Doors are provided in order to dump excess heat especially during operation in orbits with full sun exposure. The receiver material is predominantly columbium - 1-percent-zironium (Cb-1Zr) alloy. Full-scale testing of three heat-transfer tubes for more than 2000 hours and 1250 sun-shade cycles verified the design concept.
Cameron, H. M.↗
Thermoluminescent dosimetry for the Apollo 16 microbial response to space environment experiment (M191)
Lithium fluoride thermoluminescent chips were used to provide an integrated dose from the broad spectrum of ionizing radiation to the Microbial Response to Space Environment Experiment (M191). The chips were positioned in the flight hardware to provide data on ionizing radiation within specific volume segments. A uniform radiation dose of 4.8 x 0.001 plus or minus 2 x 0.0001 joule/kg resulted.
Brown, R. D.↗
Development of fine diameter mullite fiber
Results are presented of a program to develop and evaluate mullite fiber with a mean diameter under two microns. The two micron fiber is produced by a blowing process at room temperature from a low viscosity (10-25 poise) solution. The blown fiber was evaluated for dimensional stability in thermal cycling to 1371 C, and was equivalent to the 5 micron spun B and W mullite fiber. An additive study was conducted to evaluate substitutes for the boron. Three levels of chromium, lithium fluoride, and magnesium were added to the standard composition in place of boron and the fiber produced was evaluated for chemical and dimensional stability in thermal cycling to 1371 C. The magnesium was the most chemically stable, but the chrome additive imparted the best dimensional stability.
Long, W. G.↗
An ellipsometer with variable angle of incidence for studies in ultrahigh vacuum
The windows for the vacuum chamber are incorporated into the optical bench system by means of flexible bellows which allow measurements to be made over a large range of angle of incidence, one of which is chosen so that maximum sensitivity is obtained. The principal angle of incidence was determined, and straightforward corrections for strain birefringence of vacuum chamber windows were made. Atomically clean surfaces of sodium chloride and lithium fluoride were investigated to verify the performance of the system. Submonolayer and monolayer coverage of water on these surfaces could be detected. On cleavage planes of NaCl, a first monolayer of adsorbed water is complete at about one torr only.
Walter, H. U.↗
Thermoluminescence and lattice defects in LiF
The principal effect of thermal and optical treatments in an ionic solid is to alter the lattice defect equilibrium, including the concentration and arrangement of ion vacancies, impurities, impurity-vacancy associates, and assorted electrons and holes which may be associated with such defects. This paper examines the relationship between these defects and thermoluminescence in the case of lithium fluoride at and above room temperature. The discussion focuses on lattice defect equilibrium, thermoluminescent trapping centers, the relationship between recombination and luminescence, the supralinearity and sensitization of the dosimetry grade of LiF and activation energy parameters.
Stoebe, T. G.↗
Cleaving machine for hard crystals
Hard crystalline materials such as lithium fluoride (LiF) are cleaved in thin sections by semiautomatic machine. Yield of undistorted LiF crystals is almost 100 percent, even when cleaved section is only 1/32 inch thick. Machine contains spring-activated hammer that limits penetration of blade and controls shock that cleaves crystal. Fixture with spring-loaded clamps precisely locates and holds crystal, restraining it in ideal position for cleaving. Crystal then splays apart.
Benedicto, J. S. J.↗
Crystal cleaving machine
A machine is disclosed for cleaving hard crystals. A typical example of which is lithium fluoride, with prcision and uniformity and includes vertical axis positioning control means for an adjustable spring tension guided hammer mechanism employed to strike an anvil. A crystal cleaving shock wave transmitted to a cleaving blade is generated having an angulated cleaving edge in contact with one corner of the crystal. Connection between the anvil and the blade is by means of a pair of vertical shafts held in substantially friction free engagement by two pairs of adjustable linear bearings. An underlying crystal holding fixture with horizontal position control means includes a zero reference stop face for the crystal and opposing spring-loaded clamping and vertical positioning elements which are precisely guided.
Hallberg, F. C.↗
Wideband comet camera lens design
A quarter-meter diameter, modified Ritchey-Chretien camera is described for spacecraft-based observation of Halley's Comet. The system will operate over an unusually broad spectral region, from 0.1216 micron (the hydrogen Lyman-alpha line) to 1.1 microns using reflective primary and secondary mirror optics and a thin UV-grade lithium fluoride refractive element as a field corrector near the image plane. The f/12, 3000 mm focal length camera has a 0.4 deg full field of view for operation with a 15 x 15 mm charge-coupled device detector array. The UV-enhanced silicon CCD detector is a 1000 x 1000 array of 15 micron pixels which establishes the system resolution requirement. The optical design and performance are discussed, with an emphasis on the image analysis with respect to pixel resolution elements used for viewing extended objects such as comets.
Huber, E. D.↗
Positioning Vise for Crystal Cleavage
Vise manipulates brittle crystals, such as lithium fluoride, so they are in proper position for cleaving. Vise allows crystals as thin as 2 millimeters or less positioned so that cleaved without breakage. Vise holds workpiece firmly but gently. Bushings, shafts and adjusting screw designed to move jaws smoothly and uniformly with great tactile sensitivity.
Hallberg, F. C.↗
Workpiece positioning vise
A pair of jaw assemblies simultaneously driven in opposed reciprocation by a single shaft has oppositely threaded sections to automatically center delicate or brittle workpieces such as lithium fluoride crystal beneath the blade of a crystal cleaving machine. Both jaw assemblies are suspended above the vise bed by a pair of parallel guide shafts attached to the vise bed. Linear rolling bearings, fitted around the guide shafts and firmly held by opposite ends of the jaw assemblies, provide rolling friction between the guide shafts and the jaw assemblies. A belleville washer at one end of the drive shaft and thrust bearings at both drive shaft ends hold the shaft in compression between the vise bed, thereby preventing wobble of the jaw assemblies due to wear between the shaft and vise bed.
Hallberg, F. C.↗
Impact of thermal energy storage properties on solar dynamic space power conversion system mass
A 16 parameter solar concentrator/heat receiver mass model is used in conjunction with Stirling and Brayton Power Conversion System (PCS) performance and mass computer codes to determine the effect of thermal energy storage (TES) material property changes on overall PCS mass as a function of steady state electrical power output. Included in the PCS mass model are component masses as a function of thermal power for: concentrator, heat receiver, heat exchangers (source unless integral with heat receiver, heat sink, regenerator), heat engine units with optional parallel redundancy, power conditioning and control (PC and C), PC and C radiator, main radiator, and structure. Critical TES properties are: melting temperature, heat of fusion, density of the liquid phase, and the ratio of solid-to-liquid density. Preliminary results indicate that even though overalll system efficiency increases with TES melting temperature up to 1400 K for concentrator surface accuracies of 1 mrad or better, reductions in the overall system mass beyond that achievable with lithium fluoride (LiF) can be accomplished only if the heat of fusion is at least 800 kJ/kg and the liquid density is comparable to that of LiF (1880 kg/cu m.
Juhasz, Albert J.↗
Compact Ho:YLF Laser
Longitudinal pumping by laser diodes increases efficiency. Improved holmium:yttrium lithium fluoride laser radiates as much as 56 mW of power at wavelength of 2.1 micrometer. New Ho:YLF laser more compact and efficient than older, more powerful devices of this type. Compact, efficient Ho:YLF laser based on recent successes in use of diode lasers to pump other types of solid-state lasers.
Hemmati, H.↗
Impact of thermal energy storage properties on solar dynamic space power conversion system mass
A 16 parameter solar concentrator/heat receiver mass model is used in conjunction with Stirling and Brayton Power Conversion System (PCS) performance and mass computer codes to determine the effect of thermal energy storage (TES) material property changes on overall PCS mass as a function of steady state electrical power output. Included in the PCS mass model are component masses as a function of thermal power for: concentrator, heat receiver, heat exchangers (source unless integral with heat receiver, heat sink, regenerator), heat engine units with optional parallel redundancy, power conditioning and control (PC and C), PC and C radiator, main radiator, and structure. Critical TES properties are: melting temperature, heat of fusion, density of the liquid phase, and the ratio of solid-to-liquid density. Preliminary results indicate that even though overall system efficiency increases with TES melting temperature up to 1400 K for concentrator surface accuracies of 1 mrad or better, reductions in the overall system mass beyond that achievable with lithium fluoride (LiF) can be accomplished only if the heat of fusion is at least 800 kJ/kg and the liquid density is comparable to that of LiF (1800 kg/cu m).
Juhasz, Albert J.↗
Compatibility of molten salts with advanced solar dynamic receiver materials
Metal-coated graphite fibers are being considered as a thermal conductivity enhancement filler material for molten salts in solar dynamic thermal energy storage systems. The successful metal coating chosen for this application must exhibit acceptable wettability and must be compatible with the molten salt environment. Contact angle values between molten lithium fluoride and several metal, metal fluoride, and metal oxide substrates have been determined at 892 C using a modification of the Wilhelmy plate technique. Reproducible contact angles with repeated exposure to the molten LiF indicated compatibility.
Jaworske, D. A.↗