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At least 127 records · Page 7

Compositional dispersions in lunar and terrestrial basalts

The dispersions in composition observed among samples of terrestrial basalts with known field relationships are compared with those of various subgroups of lunar mare basalts. The comparison indicates that there are no substantial reasons based on trace-element data to require that large numbers of different basalts were sampled at each Apollo site. The Apollo 15 olivine and quartz normative basalts and the Apollo 12 ilmenite and olivine basalts show compositional variations which are no more pronounced than those found within single terrestrial flows, whose inhomogeneity in horizontal section has been demonstrated. The inhomogeneities of the parent rocks in the case of the Apollo 12 and 15 basalts on a scale of centimeters overshadow any differences which might exist among different general regions of the lava flows from which these samples might have derived.

Haskin, L. A.↗

Evidence for a ubiquitous, sub-microscopic 'magnetite-like' constituent in the lunar soils

Electron spin resonance (ESR) has been employed in a study of the ferromagnetic constituents of a wide variety of soils from six sampled regions of the moon as well as glasses made to simulate lunar compositions. A significant result has been that magnetite-like phases (magnetic iron spinel) precipitated in and on simulated lunar glasses as a result of sub-solidus oxidation yield room-temperature ESR spectra virtually identical with the line shape predicted for spherical, single domain particles of metallic Fe. It is shown that such magnetite-like phases can nevertheless be distinguished from metallic iron on the basis of the temperature dependence of the ESR intensity.

Griscom, D. L.↗

Sintering, crystallization, and breccia formation

The process of breccia formation by viscous sintering in the absence of pressure, advanced by Simonds (1973), is examined in detail. The limitations on the standard model for such sintering are considered. The competing process of crystallization is analyzed kinetically in terms of time-temperature-transformation curves corresponding to various degrees of crystallinity. The analysis is applied to Lunar Composition 15418 to illustrate the approach. The results indicate that close constraints can be placed on the thermal histories of lunar breccias, particularly breccias with modest degrees of crystallinity, from microstructural observations and kinetic measurements.

Uhlmann, D. R.↗

REE Partitioning in Lunar Minerals

Rare earth elements (REE) are an extremely useful tool in modeling lunar magmatic processes. Here we present the first experimentally derived plagioclase/melt partition coefficients in lunar compositions covering the entire suite of REE. Positive europium anomalies are ubiquitous in the plagioclase-rich rocks of the lunar highlands, and complementary negative Eu anomalies are found in most lunar basalts. These features are taken as evidence of a large-scale differentiation event, with crystallization of a global-scale lunar magma ocean (LMO) resulting in a plagioclase flotation crust and a mafic lunar interior from which mare basalts were subsequently derived. However, the extent of the Eu anomaly in lunar rocks is variable. Fagan and Neal [1] reported highly anorthitic plagioclase grains in lunar impact melt rock 60635,19 that displayed negative Eu anomalies as well as the more usual positive anomalies. Indeed some grains in the sample are reported to display both positive and negative anomalies. Judging from cathodoluminescence images, these anomalies do not appear to be associated with crystal overgrowths or zones.

Rapp, J. F.↗

Thermal histories and crystal distributions in partly devitrified lunar glasses cooled by radiation

Calculations of the expected crystallization behavior of selected lunar compositions (60095 and 14259) are presented. Knowledge of this behavior combined with measurements of the state of crystallinity in partially devitrified lunar samples permits the determination of the thermal history of the samples. The state of crystallinity of a specimen is described by a statistical crystal distribution function psi. The heat flow problems of a plate of opaque glass quenched on an aluminum block and of a semi-transparent glass sphere cooling by radiation are analyzed. The results are combined with laboratory measurements of the crystal growth velocity and the viscosity, and with theoretical expressions for the nucleation frequency (homogeneous and heterogeneous) to obtain psi. It is found that the calculated psi is much too large in comparison with laboratory experiments on lunar samples. Possible reasons for the discrepancy are discussed, and the most likely cause is that the assumed nucleation barrier is too small. It also appears likely that these materials have relatively few nucleating heterogeneities.

Hopper, R. W.↗

GRAIL Refinements to Lunar Seismic Structure

Joint interpretation of disparate geophysical datasets helps reduce drawbacks that can result from analyzing them individually. The Apollo seismic network was situated on the lunar nearside surface in a roughly equilateral triangle having sides approximately 1000 km long, with stations 12/14 nearly co-located at one corner. Due to this limited geographical extent, near-surface ray coverage from moonquakes is low, but increases with depth. In comparison, gravity surveys and their resulting gravity anomaly maps have traditionally offered optimal resolution at crustal depths. Gravimetric maps and seismic data sets are therefore well suited to joint inversion, since the complementary information reduces inherent model ambiguity. Previous joint inversions of the Apollo seismic data (seismic phase arrival times) and Clementine- or Lunar Prospector-derived gravity data (mass and moment of inertia) attempted to recover the subsurface structure of the Moon by focusing on hypothetical lunar compositions that explored the density/velocity relationship. These efforts typically searched for the best fitting thermodynamically calculated velocity/density model, and allowed variables like core size, velocity, and/or composition to vary freely. Seismic velocity profiles derived from the Apollo seismic data through travel time inversion vary both in the depth of the crust and mantle layers, and the seismic velocities and densities assigned to those layers. The lunar mass and moment of inertia likewise only constrain gross variations in the density profile beyond that of a uniform density sphere. As a result, composition and structure models previously obtained by jointly inverting these data retain the original uncertainties inherent in the input data sets. We perform a joint inversion of Apollo seismic delay times and gravity data collected by the GRAIL lunar gravity mission, in order to recover seismic velocity and density as a function of latitude, longitude, and depth within the Moon. We relate density (p) to seismic velocity (v) using a depth-dependent linear relationship. The corresponding coefficient (B) can reflect a variety of material properties, including temperature and composition. The inversion seeks to recover the set of p, v, and B perturbations that minimize (in a least-squares sense) the difference between the observed and calculated data.

Weber, Renee C.↗

GRAIL Refinements to Lunar Seismic Structure

Joint interpretation of disparate geophysical datasets helps to reduce drawbacks that can result from analyzing them individually. The Apollo seismic network was situated on the lunar nearside surface in a roughly equilateral triangle having sides approximately 1000 km long, with stations 12/14 nearly co‐located at one corner. Due to this limited geographical extent, near‐surface ray coverage from moonquakes is low, but increases with depth. In comparison, gravity surveys and their resulting gravity anomaly maps have traditionally offered optimal resolution at crustal depths. Gravimetric maps and seismic data sets are therefore well suited to joint inversion, since the complementary information reduces inherent model ambiguity. Previous joint inversions of the Apollo seismic data (seismic phase arrival times) and Clementine‐ or Lunar Prospector‐derived gravity data (mass and moment of inertia) attempted to recover the subsurface structure of the Moon by focusing on hypothetical lunar compositions that explore the density/velocity relationship. These efforts typically search for the best fitting thermodynamically calculated velocity/density model, allowing variables like core size, velocity, and/or composition to vary freely. Seismic velocity profiles previously derived from the Apollo seismic data through inversion of travel times vary both in the depth of the crust and mantle layers, and the seismic velocities and densities assigned to those layers. The lunar mass and moment of inertia likewise only constrain gross variations in the density profile beyond that of a uniform density sphere. As a result, composition and structure models previously obtained by jointly inverting these data retain the original uncertainties inherent in the input data sets. We will perform a joint inversion of Apollo seismic delay times and gravity data collected by the GRAIL lunar gravity mission, in order to recover seismic velocities and density as a function of latitude, longitude, and depth within the Moon. We will relate density to seismic velocity using a linear relationship that is allowed to be depth‐dependent. The corresponding coefficient (B) can reflect a variety of material properties that vary with depth, including temperature and composition. The inversion seeks to recover the set of density, velocity, and B‐coefficient perturbations that minimize (in a least‐squares sense) the difference between the observed and calculated data.

Weber, Renee C.↗

Apollo 17 petrology and experimental determination of differentiation sequences in model moon compositions

Experimental studies of model moon compositions are discussed, taking into account questions related to the differentiation of the outer layer of the moon. Phase relations for a series of proposed lunar compositions have been determined and a petrographic and electron microprobe study was conducted on four Apollo 17 samples. Two of the samples consist of high-titanium mare basalts, one includes crushed anorthosite and gabbro, and another contains blue-gray breccia.

Hodges, F. N.↗

Pyroxene stability and the composition of the lunar magma ocean

Data on the liquidus stability fields of pyroxene phases in lunar-like systems are used to predict the crystallization sequence and residual liquid composition of lunar magma oceans. Fractional and equilibrium crystallization of major and trace elements are modeled quantitatively through use of analytical expressions for liquidus phase boundaries. According to the model, a magma ocean that differentiated chiefly at low pressure and contained 6-8 wt% A1203 and a subchondritic Ca/Al ratio probably formed the lunar crust. The chondrite-normalized pattern of heavy REE depletion in the magma ocean could have developed by self-contamination of extensively fractionated liquids, or could have been imparted during accretion.

Longhi, J.↗

Olivine cooling speedometers

Several kinetic models of zoning in olivines are discussed at length. The effects on predicted cooling rates of various assumptions used in the analyses are evaluated. It is concluded that the models of Walker et al. (1977) and Taylor et al. (1977) both provide underestimates of the cooling rate required to preserve a given compositional profile, and that both models as well as the model of Taylor et al. (1978) can be used to provide order-of-magnitude estimates of cooling rates. A new model is described which considers diffusion in both solid and liquid during crystallization as well as diffusion in the solid after crystallization is complete. The model provides a description of the compositional gradients which develop during crystallization as well as after cooling at various rates. Applied to olivine crystals nucleated at 1272 C in a high-iron analogue to Lunar Composition 15555, the model predicts only slight compositional gradients - in accord with electron beam microprobe measurements on crystals grown isothermally at this temperature.

Onorato, P. I. K.↗

Remote Sensing Information Applied to Geological Study of Planets

The Planetary Geology and Geophysics tasks under this grant have concentrated on the development and testing of tools for remote compositional analyses for the Moon and other airless bodies (especially asteroids). The grant has supported the PI and her students. Detailed analyses of space-weathering analogs were undertaken. Lunar research included development of models for regolith evolution and redistribution of materials across the Moon, with particular emphasis on the interior of South Pole-Aitken Basin. Lunar compositional analyses identified general rock types using Clementine data and mapped their distribution globally and locally based on the type of mafic mineralogy present (or lack thereof). Progress in these areas has been extensively discussed in the literature and in proposals submitted to the PGG program in 2003 and 2004.

Pieters, Carle M.↗

Lunar UV-visible-IR mapping interferometric spectrometer

Ultraviolet-visible-infrared mapping digital array scanned interferometers for lunar compositional surveys was developed. The research has defined a no-moving-parts, low-weight and low-power, high-throughput, and electronically adaptable digital array scanned interferometer that achieves measurement objectives encompassing and improving upon all the requirements defined by the LEXSWIG for lunar mineralogical investigation. In addition, LUMIS provides a new, important, ultraviolet spectral mapping, high-spatial-resolution line scan camera, and multispectral camera capabilities. An instrument configuration optimized for spectral mapping and imaging of the lunar surface and provide spectral results in support of the instrument design are described.

Smith, W. Hayden↗

In-situ Lunar Launch and Landing Pad Construction with Regolith-Thermoset Polymer Composite Materials

Lunar launch and landing pads are necessary to mitigate risks to lander/ascent vehicles and surrounding surface assets from rocket plume ejected regolith. The current state of the art of landing and launching from the lunar surface is to land/launch on unprepared regolith surfaces. Though this has been a relatively successful approach, significant risks exist for the Artemis Program due to higher thrust levels leading to increased ejecta and cratering, presence of co-located assets in the ejecta path, and potential strict surface levelness requirements. Regolith-thermoset polymer composite materials were developed and evaluated for off Earth launch and landing pad applications. Performance under hot fire conditions was assessed for two simulated Starship lunar launch/landing environments, one targeting thermal conditions and the second targeting pressure conditions. Paver test articles were prepared at 20% and 11% polymer mass fractions. Sintered paver test articles were prepared with 20% polymer grouting filling the seams between pavers. Though significant erosion was experienced during the more extreme thermal testing conditions, all test articles successfully mitigated regolith ejecta from plume effects. A concept for preparing and emplacing the materials was developed and tested in laboratory conditions. The testing evaluated the feasibility of using twin and single screw extruder technology to mix, convey and deposit materials. Both the twin and single screw extruders were capable of processing and extruding the composite with a maximum of 90% mass fraction of regolith achieved by the twin screw extruder.A primary risk for application of regolith-thermoset polymer composites as lunar launch/landingpad is the mass of polymer required to be landed on the moon. Calculations were performed that show that a 100 m diameter, 0.025 m thick pad with polymer mass fraction of 15% will require a payload mass of 72 mt to the Lunar surface. This is below the planned Starship payload capacity to the lunar surface of 100 mt. The regolith-thermoset polymer composite based construction approach proved feasibility in three critical areas: performance under launch/landing conditions, demonstration of a mixing and depositing strategy, and fitting within the planned lunar payload capacity. It is recommended that materials and systems be developed to TRL 6 for a small-scale lunar demonstration of emplacement of a launch/landing pad via a CLPS mission to support Artemis Program roadmap gap closure activities.

ISRU↗

Studies related to the surfaces of the moon and planets

A variety of glasses of lunar composition were prepared with different amounts of Fe and Ti under both reducing and oxidizing conditions, and also by sputter-deposition and thermal evaporation and condensation. These materials were analyzed by wet chemical, electron microprobe, ESR, Mossbauer and magnetic methods. The effects of darkening processes on surface soils of airless bodies are discussed along with the effects of vapor phase deposition processes on the optical, chemical, and magnetic properties of the lunar regolith.

Hapke, B.↗

Space Program

Solar phenomena, planetary and lunar compositions, plasmas, interplanetary particles, satellite probes, animal neurophysiology, engineering structures, and related space activities

NEUROPHYSIOLOGY↗