Search NASA⌕ Search

SEARCH · Search NASA

Results for “Lead recovery”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7

Effect of an Additional, Parallel Capacitor on Pulsed Inductive Plasma Accelerator Performance

A model of pulsed inductive plasma thrusters consisting of a set of coupled circuit equations and a one-dimensional momentum equation has been used to study the effects of adding a second, parallel capacitor into the system. The equations were nondimensionalized, permitting the recovery of several already-known scaling parameters and leading to the identification of a parameter that is unique to the particular topology studied. The current rise rate through the inductive acceleration coil was used as a proxy measurement of the effectiveness of inductive propellant ionization since higher rise rates produce stronger, potentially better ionizing electric fields at the coil face. Contour plots representing thruster performance (exhaust velocity and efficiency) and current rise rate in the coil were generated numerically as a function of the scaling parameters. The analysis reveals that when the value of the second capacitor is much less than the first capacitor, the performance of the two-capacitor system approaches that of the single-capacitor system. In addition, as the second capacitor is decreased in value the current rise rate can grow to be twice as great as the rise rate attained in the single capacitor case.

Polzin, Kurt A.↗

Grid-Forming and -Following Background, Future, and Strategies

This paper reviews current grid forming (GFM) and grid following (GFL) inverter control strategies and explores the optimized ratio between these assets in high-penetration inverter-based resource (IBR) grids. Two case studies demonstrate that an insufficient GFM ratio leads to instability, while increasing GFM participation improves fault recovery, voltage stability, and frequency regulation.

14 - SOLAR ENERGY↗

Recovery of the UCAS asteroids

The astrometric measurements of the original 1981 UCAS survey plates were computed, leading to a grand total of 1252 orbits for newly discovered asteroids ranging in absolute magnitude from H = 10.5 to 19.5. New programs were created and existing computer routines were revised at Lowell Observatory, which has streamlined the process of correctly identifying asteroid images on archival photographic plates. The recovery and accurate measurements were made of 130 UCAS asteroids at other oppositions on plates taken by C. T. Kowal at Palomar Mountain in 1978 and 1979. When added to the 90 other UCAS objects identified by other investigators, this brings the total of multiple-opposition orbits to 220. Of the 56 UCAS asteroids known to be planet crossing, 11 were recovered at second oppositions. The recovery and accurate measurements of about 20 non-UCAS asteroids identified on the plates were examined.

Shoemaker, E. M.↗

Preliminary Wind-Tunnel Investigation of the Performance of Republic F-105 Wing-Root Inlet Configurations at Various Angles of Attack and a Mach Number of 2.01

A 1/13-scale model of the forebody of the Republic F-105 with twin-duct wing-root inlets was tested in the Langley 4- by 4-foot supersonic pressure tunnel through a range of angle of attack from -4 deg to 15 deg at a Mach number of 2.01 and a Reynolds number of approximately 3.4 x 10(exp 6) per foot. The tests were made with four configurations which incorporated varying amounts of sweep and stagger of the inlet leading edges, modifications to the areas of the boundary-layer diverter floor plate, and modifications to the area of the boundary-layer diverter bleed slots. The highest overall pressure recovery at an angle of attack of 0 deg (average total-pressure recovery, 0.84 mass-flow ratio, 0.98) was achieved with configuration having an inlet leading-edge sweep angle of 58 deg with no leading-edge stagger. Stagger was found to improve the angle-of- attack performance, but at a sacrifice in inlet efficiency for an angle of attack of 0 deg. The boundary-layer diverter floor height, of the order of one boundary-layer thickness, was satisfactory for bypassing the fuselage boundary layer. The boundary-layer diverter-plate bleed slots were effective in increasing the total-pressure recovery of the inlet. The total-pressure-recovery contour plots, taken at the compressor-face station, indicate the existence of high-velocity "cores" throughout the inlet operating range.

Kouyoumjian, W. L.↗

Robust Chemiresistive Behavior in Conductive Polymer/MOF Composites

Metal-organic frameworks (MOFs) are promising materials for gas sensing but are often limited to single-use detection. A hybridization strategy is demonstrated synergistically deploying conductive MOFs (cMOFs) and conductive polymers (cPs) as two complementary mixed ionic-electronic conductors in high-performing stand-alone chemiresistors. This work presents significant improvement in i) sensor recovery kinetics, ii) cycling stability, and iii) dynamic range at room temperature. The effect of hybridization across well-studied cMOFs is demonstrated based on 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and 2,3,6,7,10,11-hexaiminotriphenylene (HITP) ligands with varied metal nodes (Co, Cu, Ni). A comprehensive mechanistic study is conducted to relate energy band alignments at the heterojunctions between the MOFs and the polymer with sensing thermodynamics and binding kinetics. The findings reveal that hole enrichment of the cMOF component upon hybridization leads to selective enhancement in desorption kinetics, enabling significantly improved sensor recovery at room temperature, and thus long-term response retention. This mechanism is further supported by density functional theory calculations on sorbate–analyte interactions. It is also found that alloying cPs and cMOFs enables facile thin film co-processing and device integration, potentially unlocking the use of these hybrid conductors in diverse electronic applications.

36 MATERIALS SCIENCE↗

The status of measurement technologies concerning micrometer and submicrometer space articulate matter capture, recovery, velocity and trajectory

The return of a pristine sample from a comet would lead to greater understanding of cometary structures, as well as offering insights into exobiology. The paper presented at the Discovery Program Workshop outlined a set of measurements for what was identified as a SOCCER-like interplanetary mission. Several experiments comprised the total instrumentation. This paper presents a summary of CCSR with an overview of three of the four major instruments. Details of the major dust dynamics experiment including trajectory are given in this paper. The instrument proposed here offers the opportunity for the return of cometary dust particles gathered in situ. The capture process has been employed aboard the space shuttle with successful results in returning samples to Earth for laboratory analysis. In addition, the sensors will measure the charge, mass, velocity, and size of cometary dust grains during the encounter. This data will help our understanding of dusty plasmas.

Alexander, W. M.↗

ISS Ammonia Pump Failure, Recovery, and Lesson Learned A Hydrodynamic Bearing Perspective

The design, development, and operation of long duration spaceflight hardware has become an evolutionary process in which meticulous attention to details and lessons learned from previous experiences play a critical role. Invaluable to this process is the ability to retrieve and examine spaceflight hardware that has experienced a premature failure. While these situations are rare and unfortunate, the failure investigation and recovery from the event serve a valuable purpose in advancing future space mechanism development. Such a scenario began on July 31, 2010 with the premature failure of an ammonia pump on the external active thermal control system of the International Space Station. The ground-based inspections of the returned pump and ensuing failure investigation revealed five potential bearing forces that were un-accounted for in the design phase and qualification testing of the pump. These forces could combine in a number of random orientations to overload the pump bearings leading to solid-surface contact, wear, and premature failure. The recovery plan identified one of these five forces as being related to the square of the operating speed of the pump and this fact was used to recover design life through a change in flight rules for the operation of the pump module. Through the course of the failure investigation, recovery, and follow-on assessment of pump wear life, design guidance has been developed to improve the life of future mechanically pumped thermal control systems for both human and robotic exploration missions.

Bruckner, Robert J.↗

Microfluidic Investigation of Salinity-Induced Oil Recovery in Porous Media during Chemical Flooding

High and low salinity water flooding are common oil recovery processes performed in the oil fields for extracting crude oil from the reservoir. These processes are often performed sequentially, naturally establishing non-uniform salinity in the porous subsurface. In this article, we investigate oil transport in porous media induced by salinity change upon flooding with high and low salinity water. As we observe a large number of impervious dead-ends from three-dimensional imaging of the actual reservoir, we identify that these areas play an important role in oil recovery where the oil transport is governed by the salinity change rather than hydrodynamics. The salinity gradients induced upon high salinity water flooding provide pathways to enhance the transport of oil drops trapped in the dead-end regions via non-equilibrium effects. However, above a critical salinity, we observe a rapid aggregation of drops that lead to the complete blockage of the pore space, thereby inhibiting oil recovery. We also find that, at an intermediate salinity where the drop aggregation is modest, the aggregation rather promotes the oil recovery. Furthermore, our observations suggest that there exist optimal salinity conditions for maximizing oil recovery during chemical flooding.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Design of Multi-Stage Solvent Extraction Process for Separation of Rare Earth Elements

Flowsheet design and stage determination for the separation of rare earth elements (REEs) using solvent extraction (SX) is a challenging task because of the chemical similarity of the REEs. Low separation factors between the elements and complex equilibrium chemistry provide unique challenges to designing an efficient flowsheet for the separation of elements. The multi-stage nature of the SX process adds further complexity, making the assessment of products for a proposed design and stage combination difficult. Therefore, to develop a SX flowsheet, it is essential to quantify the performance for various design and separation conditions. This paper attempts to address the challenge by utilizing an equilibrium and process modeling approach. Results from a bench-scale study performed on a 10 g/L rare earth salt mixture were used in studying the extraction/stripping behavior and developing equilibrium models. DEHPA with TBP as a phase modifier was used as an extractant, while hydrochloric acid was utilized as a stripping agent. The results obtained were used in developing extraction/stripping models, which were integrated into a process framework of a SX train in a Matlab/Simulink environment. The models were programmed as a function block routine and used for developing a flowsheet, which was simulated for differing separation and design conditions. To identify optimum stage combinations, a particle swarm optimization (PSO) routine was developed and implemented for each SX train. Recovery and purity of elements of interest were used as objective function criteria. The stage combination leading to the minimization of the objective function was used to identify the optimum stage combination for a series of SX trains to attempt a balance of purity and recovery. The models and optimization method were implemented to separate a feed mixture containing REEs, which indicated that 99.52 and 85.41 percent purity is achievable for Yttrium and Lanthanum separation using 8-12-3 and 10-3-5 stage combination for loading, scrubbing, and striping. The model also indicated difficult separability between neodymium, praseodymium, and cerium.

Srivastava, Vaibhav (ORCID:0000000212645987)↗

Updated PSC Climatology Based on Caliop Measurements From 2006-2023

After more than three decades of research, the roles of polar stratospheric clouds (PSCs) in stratospheric ozone depletion are well established. Heterogeneous reactions on PSCs convert the stable chlorine reservoirs HCl and ClONO2 to chlorine radicals that destroy ozone catalytically. PSCs also prolong ozone depletion by delaying chlorine deactivation through the removal of gas-phase HNO3 and H2O by sedimentation of large nitric acid trihydrate (NAT) and ice particles. A substantial recovery of the ozone layer is expected by the middle of this century with reduced global production of ozone depleting substances in accordance with the Montreal Protocol and subsequent amendments. But as climate changes, leading to a colder and perhaps wetter stratosphere and upper troposphere, reliable model predictions of recovery of the Antarctic ozone hole and of potentially more severe ozone depletion in the Arctic are challenging. This is due both to a lack of detailed understanding of the underlying physics and the fact that many global models use simple parameterizations that do not accurately represent PSC processes. A more complete picture of PSC processes on vortex-wide scales has emerged from the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) instrument on the CALIPSO satellite that has been observing PSCs at latitudes up to 82 degrees in both hemispheres since June 2006. The CALIOP Version 2.0 (v2) PSC algorithm was recently developed to address known deficiencies in previous algorithms and includes additional refinements to increase the robustness of the inferred PSC composition. In this paper, we present an updated PSC reference data record and comprehensive climatology constructed by applying the v2 algorithm to the more than 17-year CALIOP spaceborne lidar dataset. In addition, we will examine the potential impact of aerosol and water vapor injections into the stratosphere from the January 2022 Hunga Tonga eruption on PSC occurrence in both the Arctic and Antarctic regions.

polar stratospheric clouds↗

Impact of Ring Current Ions on Electromagnetic Ion Cyclotron Wave Dispersion Relation

Effect of the ring current ions in the real part of electromagnetic ion Cyclotron wave dispersion relation is studied on global scale. Recent Cluster observations by Engebretson et al. showed that although the temperature anisotropy of is energetic (> 10 keV) ring current protons was high during the entire 22 November 2003 perigee pass, electromagnetic ion cyclotron waves were observed only in conjunction with intensification of the ion fluxes below 1 keV by over an order of magnitude. To study the effect of the ring current ions on the wave dispersive properties and the corresponding global wave redistribution, we use a self-consistent model of interacting ring current and electromagnetic ion cyclotron waves, and simulate the May 1998 storm. The main findings of our simulation can be summarized as follows: First, the plasma density enhancement in the night MLT sector during the main and recovery storm phases is mostly caused by injection of suprathermal plasma sheet H + (approximately < 1 keV), which dominate the thermal plasma density. Second, during the recovery storm phases, the ring current modification of the wave dispersion relation leads to a qualitative change of the wave patterns in the postmidnight-dawn sector for L > 4.75. This "new" wave activity is well organized by outward edges of dense suprathermal ring current spots, and the waves are not observed if the ring current ions are not included in the real part of dispersion relation. Third, the most intense wave-induced ring current precipitation is located in the night MLT sector and caused by modification of the wave dispersion relation. The strongest precipitating fluxes of about 8 X 10(exp 6)/ (cm(exp 2) - s X st) are found near L=5.75, MLT=2 during the early recovery phase on 4 May. Finally, the nightside precipitation is more intense than the dayside fluxes, even if there are less intense waves, because the convection field moves ring current ions into the loss cone on the nightside, but drives them out of the loss cone on the dayside. So convection and wave scattering reinforce each other in the nightside, but interfere in the dayside sector.

Khazanov, G. V.↗

Reversible Phase Transformation of Colloidal 2D Lead Halide Perovskite Platelets under Photoirradiation

The photostability of lead halide perovskites is an important criterion for their utilization in light harvesting applications. Colloidal two-dimensional mixed halide perovskites offer a convenient approach to probe photoinduced transformations using spectroscopy tools. We employed suspensions of colloidal 2D methylammonium lead halide perovskite platelets with butylammonium and octylammonium as organic spacer cations. Upon irradiation of the mixed halide perovskite (BAOAMAPb 2 (Br 3.5 I 3.5 )) colloidal platelet suspension, we observe a phase transformation, as seen from the formation of bromide rich domains (BAOAMAPb 2 Br 7 ) and an iodide complex (PbI 3 – ). Unlike in the case of 3D mixed halide films, we did not observe the formation of iodide rich domains as part of the photoinduced phase segregation process. Instead, we observed the dissociation of the BAOAMAPb 2 I 7 to form an iodide complex, PbI 3 – . Interestingly, this photoinduced phase transformation was reversible, as the products which were confined in the colloidal core restored the original mixed halide phase upon storage in dark. The spectroscopic measurements that characterize excited states of different colloidal methylammonium lead halide perovskites and kinetics of photoinduced transformation and their dark recovery are presented. Furthermore, these new phototransformations of colloidal perovskite platelets provide new insights into the processes that dictate their overall photostability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Process innovations to enable viable enzymatic poly(ethylene terephthalate) recycling

Enzymatic depolymerization of poly(ethylene terephthalate) (PET) has received considerable attention for closed-loop polyester recycling. However, current approaches for enzymatic PET recycling face challenges to achieve commercial viability with lower environmental impacts compared with virgin polyester manufacturing. Here, in this study, we present multiple process innovations for enzymatic PET recycling that enable economic and environmental feasibility. We show that substrate amorphization through extrusion and quenching is energy-efficient and enables near-quantitative enzymatic conversion in 50 h. Using ammonium hydroxide for pH control and thermolysis of the isolated diammonium terephthalate salt reduces the acid and base consumption by >99%, lowering annual operating expenses by 74%. Fed-batch processing increased ethylene glycol concentration, leading to a 65% reduction in energy consumption for ethylene glycol recovery. These improvements were modeled in an optimal process, with recycled PET estimated to be US$\$$1.51 kg -1 relative to US domestic virgin PET at US$\$$1.87 kg -1 and eliminating key life cycle obstacles to scale this technology.

36 MATERIALS SCIENCE↗

Non-parametric Lagrangian biasing from the insights of neural nets

We present a Lagrangian model of galaxy clustering bias in which we train a neural net using the local properties of the smoothed initial density field to predict the late-time mass-weighted halo field.By fitting the mass-weighted halo field in the AbacusSummit simulations at z = 0.5, we find that including three coarsely spaced smoothing scales gives the best recovery of the halo power spectrum. Adding more smoothing scales may lead to 2–5% underestimation of the large-scale power and can cause the neural net to overfit.We find that the fitted halo-to-mass ratio can be well described by two directions in the original high-dimension feature space.Projecting the original features into these two principal components and re-training the neural net either reproduces the original training result, or outperforms it with a better match of the halo power spectrum. The elements of the principal components are unlikely to be assigned physical meanings, partly owing to the features being highly correlated between different smoothing scales.Our work illustrates a potential need to include multiple smoothing scales when studying galaxy bias, and this can be done easily with machine-learning methods that can take in high dimensional input feature space.

79 ASTRONOMY AND ASTROPHYSICS↗

Investigation of Inlet Concepts for Maneuver Improvement at Transonic Speeds

A 15 percent scale lightweight fighter type inlet forebody was tested in the Ames 14 foot transonic wind tunnel at Mach numbers of 0.7, 0.9, and 1.04. The inlet was a two dimensional horizontal ramp system designed for a Mach number of 2.2. Four inlet devices designed to prevent or delay cowl-lip boundary layer separation or to improve the inlet internal flow characteristics at high angles of attack were investigated. The devices used to control cowl-lip separation consisted of cowl leading edge flaps, slotted flaps, and tangential blowing. To improve the internal flow characteristics, discrete jet nozzle flows were directed downstream and parallel to the duct surface in the subsonic diffuser to energize the wall boundary layer. The discrete jets used in the subsonic diffuser were also tested in combination with each of the cowl leading edge devices. Test measurements included engine-face total pressure recovery, steady state distortion, dynamic distortion, duct boundary layer profiles, and duct-surface static pressures.

Latham, E.↗

Experimental investigation of a 0.15-scale model of an underfuselage normal-shock inlet

A 0.15 scale model of an underfuselage inlet designed for a single-engine fighter airplane was tested. The inlet was a fixed-geometry, normal-shock configuration designed to operate at flight speeds up to Mach 2.0. Peformance data for the basic inlet and several configuration variations are presented as a function of angle of attack, angle of sideslip, and airflow in the 0.6 to 2.0 Mach number range. The configuration variations included boundary-layer diverter height, cowl and splitter-plate modifications, and inlet bleed system variations. Flow-field characteristics at the simulated engine face, at the inlet throat, at the splitter-plate leading edge, and forward of the inlet are presented. The pressure recovery of the inlet is approximately equal to the product of theoretical normal-shock and duct pressure recoverable at cruise angle of attack. Very good performance at high angle of attack was obtained. Pressure distortion and turbulence at the engine face were low, and the inlet remained stable at all engine airflows over the flight maneuver envelope of the aircraft for which the inlet was designed.

Leamer, P. C.↗

Boundary-layer transition effects on airplane stability and control

Surface contamination of laminar-flow airfoils can significantly modify the location of transition from laminar-to-turbulent boundary-layer flow. The contamination can be the result of insect debris, environmental effects such as ice crystals and moisture due to mist or rain, surface damage, or other contamination adhering to the surface. Location and mode of transition have a dominant effect on the lift-and-drag characteristics of a lifting surface. The influences of laminar boundary-layer flow behavior on airplane stability and control are examined through theoretical results and experimental (wind-tunnel and free-flight) data. For certain airfoils with a relatively steep pressure recovery it is shown that loss of laminar flow near the leading edge can result in premature separation of the turbulent boundary layer and, consequently, in loss of lift and control effectiveness. Aerodynamic modifications which minimize boundary-layer transition effects on airplane stability and control are also discussed.

Van Dam, C. P.↗

DEVELOPMENT OF AN INFLIGHT COUNTERMEASURE TO MITIGATE POSTFLIGHT GAIT DYSFUNCTION

Following spaceflight crewmembers experience gait and postural instabilities due to inflight adaptive alterations in sensorimotor function. These changes can pose a risk to crew safety if nominal or emergency vehicle egress is required immediately following long-duration spaceflight. At present, no operational countermeasure is available to mitigate postflight locomotor disturbances. Therefore, the goal of this study is to develop an inflight training regimen that facilitates the recovery of locomotor function after long-duration spaceflight. The countermeasure we are developing is based on the concept of variable practice. During this type of training the subject gains experience producing the appropriate adaptive motor behavior under a variety of sensory conditions and response constraints. This countermeasure is built around current ISS treadmill exercise activities. Crewmembers will conduct their nominal inflight treadmill exercise while being exposed to variations in visual flow patterns. These variations will challenge the postural and locomotor systems repeatedly, thereby promoting adaptive reorganization in locomotor behavior. As a result of this training a subject learns to solve a class of motor problems, rather than a specific motor solution to one problem, Le., the subject learns response generalizability or the ability to "learn to learn" under a variety of environmental constraints. We anticipate that this training will accelerate recovery of postural and locomotor function during readaptation to gravitational environments following spaceflight facilitating neural adaptation to unit (Earth) and partial (Mars) gravity after long-duration spaceflight. The study calls for one group of subjects to perform the inflight treadmill training regimen while a control group of subjects performs only the nominal exercise procedures. Locomotor function in both groups is assessed before and after spaceflight using two tests of gait function: The Integrated Treadmill Locomotion Test (ITLT) and the Functional Mobility Test (FMT). The ITLT characterizes alterations in the integrated function of multiple sensorimotor subsystems responsible for the control of locomotion. This test calls for subjects to walk on a motorized treadmill while we assess changes in dynamic postural stability, head-trunk coordination, short-latency head stabilization responses, dynamic visual acuity, lower limb coordination strategies and gait cycle timing. To make these assessments we measure the following parameters while subjects walk on the treadmill: 1) full body 3-dimensional kinematics using a motion capture system (Motion Analysis Corp., Santa Rosa, CA); 2) the shock-wave transmitted from heel-strike to the head using triaxial accelerometers placed on the tibia and head (Entran, Fairfield, NJ); 3) vertical forces using an instrumented treadmill (Kistler Instrument Corp., Amherst, NY); 4) Dynamic visual acuity using Landolt Cs presented on a laptop computer located 4m from the eyes and 5) Gait cycle timing using foot-switches (Motion Lab Systems, Inc., Baton Rouge, LA) attached to the plantar surface of each shoe at the heel and toe. The FMT evaluates a subject's ability to perform challenging locomotor maneuvers similar to those encountered during an egress from a space vehicle. Subjects step over and duck under obstacles along with negotiating a series of pylons set up on a base of 10 cm thick medium density foam. The dependent measures for the FMT are time to complete the course and the number of obstacles touched. To date, we have collected pre and postflight locomotion data from Expeditions 5-9 who will serve as part of the control group for this study. Preliminary results comparing the recovery rates in gait control sub-systems obtained from the ITLT and FMT performance showed two recovery patterns: 1) a concordant recovery trend between gait control parameters and FMT performance indicating a restitution pattern of recovery and 2) gait controecovery that lagged recovery in FMT performance suggesting that improvement in locomotor function was attained through a pattern of substitution. These data suggest that recovery of postflight locomotor function may occur through adaptive mechanisms that lead to either restitution or substitution of function. Understanding the modes of postflight readaptation has implications for countermeasure development and testing and in astronaut postflight rehabilitation.

Bloomberg, J. J.↗