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At least 127 records · Page 7

Simple analytic potentials for linear ion traps

A simple analytical model was developed for the electric and ponderomotive (trapping) potentials in linear ion traps. This model was used to calculate the required voltage drive to a mercury trap, and the result compares well with experiments. The model gives a detailed picture of the geometric shape of the trapping potential and allows an accurate calculation of the well depth. The simplicity of the model allowed an investigation of related, more exotic trap designs which may have advantages in light-collection efficiency.

Janik, G. R.↗

The tectonic and volcanic history of Mercury as inferred from studies of scarps, ridges, troughs, and other lineaments

Tectonic and volcanic modification of the Mercurian surface is discussed, and nine landform classes are defined. An evolutionary chronology, based on reported interpretations of scarp, ridge, trough, and other lineament features, is presented, and the roles (in chronological order) of accretion and differentiation, tidal spindown, plains volcanism, heavy bombardment, cooling/contraction, Caloris impact, intense surface modification, basin subsidence, local plains volcanism, isostatic basin uplift, and light cratering are considered. The observational data were obtained by Mariner 10.

Dzurisin, D.↗

Instrument Design and In Orbit Performance of Planetary L1dars at NASA GSFC

Space lidars provides a unique and powerful tool in earth environment monitoring and planetary exploration. Lidars operate at a much shorter wavelength than radars and can have a much narrower beam and much smaller transmitter and receiver. Lidars carry their own light sources and can continue measurement day and night, and over polar regions, where the passive instruments cannot observe. NASA Goddard Space Flight Center (GSFC) has developed several space lidars, three of them on planetary missions. These were the Mars Orbiter Laser Altimeter (MOLA) on the Mars Observer and Mars Global Surveyor missions, the Mercury Laser Altimeter (MLA) on the MErcury Surface Space ENvironment, GEochemistry and Ranging (MESSENGER) mission and the Lunar Orbital Laser Altimeter (LOLA) on the Lunar Reconnaissance (LRO) mission. These lidars all use similar technologies but with major improvement from one instrument In the next in size, power, measurement capability and operating environment.

Sun, Xiaoli↗

Analysis of Solids Obtained from 201O, 201P, 202A, and 202B Contactors in the Salt Waste Processing Facility

In December 2022, Savannah River Mission Completion personnel recovered solids samples from four contractors (EXT-001, EXT-007, EXT-031, and EXT-040) employed at the Salt Waste Processing Facility (SWPF). These solids were submitted to Savannah River National Laboratory for analysis and characterization. This Technical Report outlines the analytical findings and observations associated with these samples and explores the potential source of solid generation within the SWPF. The following conclusions are offered as a result of this work: the light color solids recovered from EXT-007 are consistent with crystallized, soluble salt components (such as sodium nitrate, sodium hydroxide, and sodium carbonate), all of which can be easily re-dissolved in process water and do not represent a threat to SWPF CSSX processing. While the light solids from the top of EXT-040 were not analyzed, it is believed that they share similar characteristics to those recovered from EXT-007; The dark color solids recovered from EXT-001, EXT-031, and the inside of EXT-040 appear to be complex, consisting of several different types of solids: High concentrations of mercury (Hg, 40-75% by mass) partially present as elemental Hg are consistent with the precipitation of Hg 0 /Hg 2+ from disproportionation of Hg + species in pH swing conditions; Moderate concentrations of titanium (Ti) (2-7%, by mass) are also present, often co-located with Hg. This is consistent with co-precipitation, entrainment, and/or amalgamation of Ti and Hg; Moderate concentrations of iron (Fe) (1-3%, by mass) are observed in SWPF solids and are likely attributable to erosion of stainless-steel components within the CSSX process; Small concentrations of tungsten (W) and cobalt (Co) (<1%, by mass) are observed in SWPF solids. The presence of these solids is consistent with the erosion of components coated with W and Co (e.g., Stellite); Small concentrations of aluminum (Al) (<1%, by mass) are observed in the form of gibbsite and potentially sodium aluminosilicate. The presence of these compounds is likely attributable to the pH swing observed between the scrub and extraction cycles within the CSSX process. The following recommendations are made as a result of this work: Testing should be performed to determine the chemical drivers, process, and mechanism of Hg precipitation in CSSX processing. Special care should be taken to include titanium in tests to evaluate the potential for co-precipitation, entrainment, and amalgamation; Hg-mitigation options that would minimize or eliminate risks of Hg precipitation and solids accumulation (e.g., Hg-absorption techniques, ion exchange/adsorbents, flowsheet changes, etc.) should be assessed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A hidden demethylation pathway removes mercury from rice plants and mitigates mercury flux to food chains

Dietary exposure to methylmercury (MeHg) causes irreversible damage to human cognition and is mitigated by photolysis and microbial demethylation of MeHg. Rice (Oryza sativa L.) has been identified as a major dietary source of MeHg. However, it remains unknown what drives the process within plants for MeHg to make its way from soils to rice and the subsequent human dietary exposure to Hg. Here we report a hidden pathway of MeHg demethylation independent of light and microorganisms in rice plants. This natural pathway is driven by reactive oxygen species generated in vivo, rapidly transforming MeHg to inorganic Hg and then eliminating Hg from plants as gaseous Hg°. MeHg concentrations in rice grains would increase by 2.4- to 4.7-fold without this pathway, which equates to intelligence quotient losses of 0.01–0.51 points per newborn in major rice-consuming countries, corresponding to annual economic losses of US$30.7–84.2 billion globally. Importantly, this discovered pathway effectively removes Hg from human food webs, playing an important role in exposure mitigation and global Hg cycling.

59 BASIC BIOLOGICAL SCIENCES↗

Atmospheres of the Moon and Mercury

Mercury and the Moon have long been considered to be similar objects, but this view was based on limited information at visible wavelengths. It is now known that real differences exist in the atmospheres and in the rock types as deduced from mid-infrared observations. Lunar Ar and perhaps Ne were observed from Apollo landed experiments in spite of a large local background. An ultraviolet spectrometer (UVS) in orbit placed upper limits on a number of gases including H and O. At Mercury, the UVS on Mariner 10 measured H, He, and perhaps O and again a number of upper limits for other gases. Less than a decade ago, emissions of Na and K were observed from the ground, with abundances 2 orders of magnitude smaller on the Moon than on Mercury. It is likely that impacting meteoroids bring a significant amount of water to Mercury, whose atmosphere should therefore contain water vapor. This notion is supported by the recent discovery of radar-bright polar deposits almost certainly composed of ice. A variety of origins is likely for the different components. Impact of meteoroids could supply water, Na, and K, and could also vaporize surface material; Na, K, and Ar could be degassed from the crust. H is probably from the solar wind, and He could reasonably come from degassing or the solar wind. A substantial loss process for all components is photoionization (or dissociation); ions on one side are swept away into the solar wind and on the other are swept back to the surface. This process is complicated at Mercury by its permanent magnetic field, but there is little doubt that both loss and recycling still occur. Some of the recycling probably occurs by way of the magnetotail through night side auroral precipitation; atoms implanted in the surface will diffuse back into the atmosphere shortly after dawn, an effect that seems to be present for K. Finally the light atoms H and He have high enough velocities to escape directly, an effect that may be enhanced by the suprathermal velocity distributions that are likely to be present.

Hunten, D. M.↗

Very high resolution radiometer

A primary sensor used in environmental and earth-resource observation, the Very High Resolution Radiometer (VHRR) was designed for use on the ITOS D series spacecraft. The VHRR provides a 0.47 mile resolution made possible with a mercury-cadmium-telluride detector cooled to approximately 105 K by a passive radiator cooler. The components of this system are described. The optical subsystem of the VHRR consists of a scanning mirror, a Dall-Kirkham telescope, a dichroic beam splitter, relay lenses, spectral filters, and an IR detector. Signal electronics amplify and condition the signals from the infrared and visible light detector. Sync generator electronics provides the necessary time signals. Scan-drive electronics is used for commutation of the motor winding, velocity, and phase control. A table lists the performance parameters of the VHRR.

Aronson, A. I.↗

Martian Crater Size Distributions and Terrain Age

The crater size/frequency distributions of large ( 8 km) craters on the Moon and terrestrial planets display two very different curves representing two crater populations. The heavily cratered regions of the Moon, Mercury, and Mars show the same highly structured curve which cannot be represented by a single slope distribution function. In contrast, the lunar post mare crater population has a size/frequency distribution which differs significantly from that in the highlands over the same diameter range, and can be represented by a single-slope distribution function of -2.8 differential. On areas of martian lightly cratered northern plains, the crater population is essentially identical to that of the post mare population. This indicates that the same two families of impacting objects were responsible for the cratering records on both Moon and Mars. The thickness of mantling material varies among the various plains units, and can be calculated from the depth/diameter scaling relations for martian craters.

Nadine G Barlow↗

Magellan

Of all the planets in the solar system, Venus is the most like our own Earth in size, mass, and distance from the Sun. The motions of our planetary "twin" were known to the ancients, and its apparent changes in shape, similar to the phases of the Moon, were first studied by Galileo more than four centuries ago. In the modern era, it is by far the most visited world in the solar system - more than 20 spacecraft from the Soviet Union and the United States have been sent there since the early 1960's. The clouds of Venus have been probed, the structure and composition of its atmosphere measured, its landscape photographed, and its rocks chemically analyzed by automated landers. Yet, for all our fascination with Venus, we have only a sketchy, general knowledge of the planet's surface. While the other three "terrestrial" worlds - Earth, Mercury, and Mars have long since been mapped, details of the face of Venus are still largely unknown, due to the planet's dense, constant cloud cover. The clouds prevent us from ever photographing the solid surface, even from space, with conventional cameras. Beginning in the early 1960s, scientists on Earth began to counter this problem by using radar waves, which, unlike visible light, are able to penetrate the Venusian clouds and reflect off the solid planet back to Earth. With the help of computer processing, these radar reflections can be turned into pictures of the Venus surface. Earth-based radar imaging is thus extremely valuable. but it also is limited-Venus always shows the same hemisphere to us when it is near enough in its orbit for high-resolution study, so only a fraction of the planet can be explored from Earth.

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Arc discharge convection studies: A Space Shuttle experiment

Three mercury vapor arc lamps were tested in the microgravity environment of one of NASA's small, self-contained payloads during STS-41B. A description of the payload structural design, photographic and optical systems, and electrical system is provided. Thermal control within the payload is discussed. Examination of digital film data indicates that the 175 watt arc lamp has a significant increase in light output when convection is removed in the gravity-free environment of space.

Bellows, A. H.↗

Unsaturated Sulfur Crown Ethers Can Extract Mercury(II) and Show Promise for Future Copernicium(II) Studies: A Combined Experimental and Computational Study

The unsaturated hexathia-18-crown-6 (UHT18C6) molecule was investigated for the extraction of Hg(II) in HCl and HNO3 media. This extractant can be directly compared to the recently studied saturated hexathia-18-crown-6 (HT18C6). The default conformation of the S lone pairs in UHT18C6 is endodentate, where the pocket of the charge density, according to the crystal structures, is oriented toward the center of the ring, which should allow better extraction for Hg(II) compared to the exodentate HT18C6. Batch study experiments showed that Hg(II) had better extraction at low acid molarity (ca. 99% in HCl and ca. 95% in HNO 3 ), while almost no extraction was observed above 0.4 M HCl and 4 M HNO 3 (<5%). Speciation studies were conducted with the goal of delineating a plausible extraction mechanism. Density functional theory calculations including relativistic effects were carried out on both Hg(II)-encapsulated HT18C6 and UHT18C6 complexes to shed light on the binding strength and the nature of bonding. Our calculations offer insights into the extraction mechanism. In addition to Hg(II), calculations were performed on the hypothetical divalent Cn(II) ion, and showed that HT18C6 and UHT18C6 could extract Cn(II). Finally, the extraction kinetics were explored to assess whether this crown can extract the short-lived Cn(II) species in a future online experiment.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Microbial Communities Associated with Methylmercury Degradation in Paddy Soils

Bioaccumulation of the neurotoxin methylmercury (MeHg) in rice has raised worldwide concerns because of its risks to human health. Certain microorganisms are able to degrade MeHg in pure cultures, but the roles and diversities of the microbial communities in MeHg degradation in rice paddy soils are unknown. Using a series of microcosms, we investigated MeHg degradation in paddy soils from Hunan, Guizhou, and Hubei provinces, representing three major rice production regions in China, and further characterized one of the soils from the Hunan Province for microbial communities associated with MeHg degradation. Microbial demethylation was observed in all three soils, demonstrated by significantly more MeHg degraded in the unsterilized soils than in the sterilized controls. More demethylation occurred in water-saturated soils than in unsaturated soils, but the addition of molybdate and bromoethanesulfonic acid as the respective inhibitors of sulfate reducing bacteria and methanogens showed insignificant effects on MeHg degradation. However, the addition of Cu enhanced MeHg degradation and the enrichment of Xanthomonadaceae in the unsaturated soil. 16S rRNA Illumina sequencing and metatranscriptomic analyses of the Hunan soil consistently revealed that Catenulisporaceae, Frankiaceae, Mycobacteriaceae, and Thermomonosporaceae were among the most likely microbial taxa in influencing MeHg degradation in the paddy soil, and they were confirmed by combined analyses of the co-occurrence network, random forest modeling, and linear discriminant analysis of the effect size. Furthermore, our results shed additional light onto the roles of microbial communities in MeHg degradation in paddy soils and its subsequent bioaccumulation in rice grains.

59 BASIC BIOLOGICAL SCIENCES↗

NASA Tech Briefs, July 2009

Topics covered include: Dual Cryogenic Capacitive Density Sensor; Hail Monitor Sensor; Miniature Six-Axis Load Sensor for Robotic Fingertip; Improved Blackbody Temperature Sensors for a Vacuum Furnace; Wrap-Around Out-the-Window Sensor Fusion System; Wide-Range Temperature Sensors with High-Level Pulse Train Output; Terminal Descent Sensor Simulation; A Robust Mechanical Sensing System for Unmanned Sea Surface Vehicles; Additive for Low-Temperature Operation of Li-(CF)n Cells; Li/CFx Cells Optimized for Low-Temperature Operation; Number Codes Readable by Magnetic-Field-Response Recorders; Determining Locations by Use of Networks of Passive Beacons; Superconducting Hot-Electron Submillimeter-Wave Detector; Large-Aperture Membrane Active Phased-Array Antennas; Optical Injection Locking of a VCSEL in an OEO; Measuring Multiple Resistances Using Single-Point Excitation; Improved-Bandwidth Transimpedance Amplifier; Inter-Symbol Guard Time for Synchronizing Optical PPM; Novel Materials Containing Single-Wall Carbon Nanotubes Wrapped in Polymer Molecules; Light-Curing Adhesive Repair Tapes; Thin-Film Solid Oxide Fuel Cells; Zinc Alloys for the Fabrication of Semiconductor Devices; Small, Lightweight, Collapsible Glove Box; Radial Halbach Magnetic Bearings; Aerial Deployment and Inflation System for Mars Helium Balloons; Steel Primer Chamber Assemblies for Dual Initiated Pyrovalves; Voice Coil Percussive Mechanism Concept for Hammer Drill; Inherently Ducted Propfans and Bi-Props; Silicon Nanowire Growth at Chosen Positions and Orientations; Detecting Airborne Mercury by Use of Gold Nanowires; Detecting Airborne Mercury by Use of Palladium Chloride; Micro Electron MicroProbe and Sample Analyzer; Nanowire Electron Scattering Spectroscopy; Electron-Spin Filters Would Offer Spin Polarization Greater than 1; Subcritical-Water Extraction of Organics from Solid Matrices; A Model for Predicting Thermoelectric Properties of Bi2Te3; Integrated Miniature Arrays of Optical Biomolecule Detectors; A Software Rejuvenation Framework for Distributed Computing; Kurtosis Approach to Solution of a Nonlinear ICA Problem; Robust Software Architecture for Robots; R4SA for Controlling Robots; Bio-Inspired Neural Model for Learning Dynamic Models; Evolutionary Computing Methods for Spectral Retrieval; Monitoring Disasters by Use of Instrumented Robotic Aircraft; Complexity for Survival of Living Systems; Using Drained Spacecraft Propellant Tanks for Habitation; Connecting Node; and Electrolytes for Low-Temperature Operation of Li-CFx Cells.

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Metal/silicate fractionation in the solar system.

Fractionation between the metal and silicate components of objects in the inner solar system has long been recognized as a necessity in order to explain the observed density variations of the terrestrial planets and the H-group, L-group dichotomy of the ordinary chondrites. This paper discusses the densities of the terrestrial planets in light of current physical and chemical models of processes in the solar nebula. It is shown that the observed density trends in the inner solar system need not be the result of special fractionation processes, and that the densities of the planets may be direct results of simultaneous application of both physical and chemical restraints on the structure of the nebula, most notably the variation of temperature with heliocentric distance. The density of Mercury is easily attributed to accretion at temperatures so high that MgSiO3 is only partially retained but Fe metal is condensed. The densities of the other terrestrial planet are shown to be due to different degrees of retention of S, O and H as FeS, FeO and hydrous silicates produced in chemical equilibrium between condensates and solar-composition gases.

Lewis, J. S.↗

Meteoroid Engineering Model – Final Report

We developed a parametric model of the spatial distribution of sporadic meteoroids by taking their primary source to be short-period comets with aphelia less than 7 AU which showed to be the major source of dust released through the sublimation of cometary ices. We constrained the model to fit the observed distribution of particles deduced from the zodiacal light measurements of Helios I and II as well as Earth-based radio-meteor observations. We also considered the contribution to the sporadic meteor complex from long-period comets. An origin for the North and South Toroidal source of sporadic meteors is proposed and the results of calculations for the likely characteristics of asteroidal meteors are also presented. Predicted fluxes and radiant distributions of sporadic meteors in the region between Mercury and Mars are shown as well. We have also included the effects of the gravitational shielding and focusing of the planets and shown that flux enhancements of up to 70% are possible at some locations.

Jones, J.↗

Coating Processes Boost Performance of Solar Cells

NASA currently has spacecraft orbiting Mercury (MESSENGER), imaging the asteroid Vesta (Dawn), roaming the red plains of Mars (the Opportunity rover), and providing a laboratory for humans to advance scientific research in space (the International Space Station, or ISS). The heart of the technology that powers those missions and many others can be held in the palm of your hand - the solar cell. Solar, or photovoltaic (PV), cells are what make up the panels and arrays that draw on the Sun s light to generate electricity for everything from the Hubble Space Telescope s imaging equipment to the life support systems for the ISS. To enable NASA spacecraft to utilize the Sun s energy for exploring destinations as distant as Jupiter, the Agency has invested significant research into improving solar cell design and efficiency. Glenn Research Center has been a national leader in advancing PV technology. The Center s Photovoltaic and Power Technologies Branch has conducted numerous experiments aimed at developing lighter, more efficient solar cells that are less expensive to manufacture. Initiatives like the Forward Technology Solar Cell Experiments I and II in which PV cells developed by NASA and private industry were mounted outside the ISS have tested how various solar technologies perform in the harsh conditions of space. While NASA seeks to improve solar cells for space applications, the results are returning to Earth to benefit the solar energy industry.

Source record↗

Dependence of Mercurian Atmospheric Column Abundance Estimations on Surface-Reflectance Modeling

Column abundance estimates of sodium, and analogously, potassium, in Mercury's exosphere are strongly correlated to the surface reflection model used to calibrate the spectral data and the surface reflection model incorporated into the atmospheric radiative transfer solution. Depending on the surface reflection model parameters used, there can be differences in calibration factors of up to +/- 30% and differences in estimated column abundance of up to +/- 35%. Although the surface reflectance may not be used in the calibration of spacecraft measurements, the interaction between the reflected surface light and the atmospheric brightness remains important.

Domingue, Deborah L.↗

Seismic effects from major basin formation on the Moon and Mercury

Grooved and hilly terrains are reported which occur at the antipode of major basins on the Moon (Imbrium, Orientale) and Mercury (Caloris). Order-of-magnitude calculations, for an Imbrium-size impact on the Moon, indicate P-wave-induced surface displacements of 10 m at the basin antipode that would arrive prior to secondary ejecta. Comparable surface waves are reported which would arrive subsequent to secondary ejecta impacts and would increase in magnitude as they converge at the antipode. Other seismically induced surface features include: subdued, furrowed crater walls produced by landslides and concomitant secondary impacts; emplacement and leveling of light plains units owing to seismically induced "fluidization" of slide material; knobby, pitted terrain around old basins from enhancement of seismic waves in ancient ejecta blankets; and the production and enhancement of deep-seated fractures that led to the concentration of farside lunar maria in the Apollo-Ingenii region.

Schultz, P. H.↗