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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

A Study of the Combustion of Aluminum Borohydride in a Small Supersonic Wind Tunnel

The combustion of aluminum borohydride in the Mach 2 airstream of a 3.84- by 10-inch wind tunnel was studied by analyzing gas samples taken from the airstream. Gas mixture composition was determined with the aid of a vacuum apparatus and gas chromatograph. The overall combustion efficiency of the fuel was assumed to be good because the combustion efficiency of its hydrogen component was found to be high. The increase of the lateral surface area of the combustion region was dependent upon the degree of mixing of fuel and its combustion products with air. In the flame zone where there was insufficient oxygen for complete combustion, the metal components of the fuel appeared to burn preferentially to the hydrogen component.

Allen, Harrison, Jr.↗

Review of jet engine emissions.

The various constituents in jet engine exhaust during typical takeoff or cruise conditions are presented in a table. The categories considered include inerts and unreacted oxygen from air, products of complete combustion of fuel, products of incomplete combustion, oxides of nitrogen formed during the heating of air, and elements or compounds derived from sulfur and trace metals present in kerosene fuel. Typical jet engine emission characteristics are discussed together with the effect of operating variables on emissions, and combustor design techniques to reduce emissions. Particular attention is given to emissions in the upper atmosphere, and to methods to reduce nitric oxide emissions.

Grobman, J. S.↗

Advanced launch vehicle upper stages using liquid propulsion and metallized propellants

Metallized propellants are liquid propellants with a metal additive suspended in a gelled fuel or oxidizer. Typically, aluminum particles are the metal additives. These propellants provide increase in the density and/or the specific impulse of the propulsion system. Using metallized propellants for volume- and mass-constrained upper stages can deliver modest increases in performance for Low Earth Orbit to Geosynchronous Earth Orbit and other Earth orbital transfer missions. Metallized propellants, however, can enable very fast planetary missions with a single-stage upper stage system. Trade studies comparing metallized propellant stage performance with non-metallized upper stages and the Inertial Upper Stage are presented. These upper stages are both one- and two-stage vehicles that provide the added energy to send payloads to altitudes and onto trajectories that are unattainable with only the launch vehicle. The stage designs are controlled by the volume and the mass constraints of the Space Transportation System and Space Transportation System-Cargo launch vehicles. The influences of the density and specific impulse increases enabled by metallized propellants are examined for a variety of different stage and propellant combinations.

Palaszewski, B. A.↗

Combustion Synthesis of Sm0.5Sr0.5CoO3-x and La0.6Sr0.4CoO3-x Nanopowders for Solid Oxide Fuel Cell Cathodes

Nanopowders of Sm0.5Sr0.5CoO(3-x) (SSC) and La0.6Sr0.4CoO(3-x) (LSC) compositions, which are being investigated as cathode materials for intermediate temperature solid oxide fuel cells, were synthesized by a solution-combustion method using metal nitrates and glycine as fuel. Development of crystalline phases in the as-synthesized powders after heat treatments at various temperatures was monitored by x-ray diffraction. Perovskite phase in LSC formed more readily than in SSC. Single phase perovskites were obtained after heat treatment of the combustion synthesized LSC and SSC powders at 1000 and 1200 C, respectively. The as-synthesized powders had an average particle size of ~12 nm as determined from x-ray line broadening analysis using the Scherrer equation. Average grain size of the powders increased with increase in calcination temperature. Morphological analysis of the powders calcined at various temperatures was done by scanning electron microscopy.

Bansal, Narottam P.↗

Dual membrane hollow fiber fuel cell and method of operating same

A gaseous fuel cell is described which includes a pair of electrodes formed by open-ended, ion-exchange hollow fibers, each having a layer of metal catalyst deposited on the inner surface and large surface area current collectors such as braided metal mesh in contact with the metal catalyst layer. A fuel cell results when the electrodes are immersed in electrolytes and electrically connected. As hydrogen and oxygen flow through the bore of the fibers, oxidation and reduction reactions develop an electrical potential. Since the hollow fiber configuration provides large electrode area per unit volume and intimate contact between fuel and oxidizer at the interface, and due to the low internal resistance of the electrolyte, high power densities can be obtained.

Ingham, J. D.↗

Determination of Combustion Product Radicals in a Hydrocarbon Fueled Rocket Exhaust Plume

The identification of metallic effluent materials in a rocket engine exhaust plume indicates the health of the engine. Since 1989, emission spectroscopy of the plume of the Space Shuttle Main Engine (SSME) has been used for ground testing at NASA's Stennis Space Center (SSC). This technique allows the identification and quantification of alloys from the metallic elements observed in the plume. With the prospect of hydrocarbon-fueled rocket engines, such as Rocket Propellant 1 (RP-1) or methane (CH4) fueled engines being considered for use in future space flight systems, the contributions of intermediate or final combustion products resulting from the hydrocarbon fuels are of great interest. The effect of several diatomic molecular radicals, such as Carbon Dioxide , Carbon Monoxide, Molecular Carbon, Methylene Radical, Cyanide or Cyano Radical, and Nitric Oxide, needs to be identified and the effects of their band systems on the spectral region from 300 nm to 850 nm determined. Hydrocarbon-fueled rocket engines will play a prominent role in future space exploration programs. Although hydrogen fuel provides for higher engine performance, hydrocarbon fuels are denser, safer to handle, and less costly. For hydrocarbon-fueled engines using RP-1 or CH4 , the plume is different from a hydrogen fueled engine due to the presence of several other species, such as CO2, C2, CO, CH, CN, and NO, in the exhaust plume, in addition to the standard H2O and OH. These species occur as intermediate or final combustion products or as a result of mixing of the hot plume with the atmosphere. Exhaust plume emission spectroscopy has emerged as a comprehensive non-intrusive sensing technology which can be applied to a wide variety of engine performance conditions with a high degree of sensitivity and specificity. Stennis Space Center researchers have been in the forefront of advancing experimental techniques and developing theoretical approaches in order to bring this technology to a more mature stage.

Langford, Lester A.↗

Advanced Launch Vehicle Upper Stages Using Liquid Propulsion and Metallized Propellants

Metallized propellants are liquid propellants with a metal additive suspended in a gelled fuel or oxidizer. Typically, aluminum (Al) particles are the metal additive. These propellants provide increase in the density and/or the specific impulse of the propulsion system. Using metallized propellant for volume-and mass-constrained upper stages can deliver modest increases in performance for low earth orbit to geosynchronous earth orbit (LEO-GEO) and other earth orbital transfer missions. Metallized propellants, however, can enable very fast planetary missions with a single-stage upper stage system. Trade studies comparing metallized propellant stage performance with non-metallized upper stages and the Inertial Upper Stage (IUS) are presented. These upper stages are both one- and two-stage vehicles that provide the added energy to send payloads to altitudes and onto trajectories that are unattainable with only the launch vehicle. The stage designs are controlled by the volume and the mass constraints of the Space Transportation System (STS) and Space Transportation System-Cargo (STS-C) launch vehicles. The influences of the density and specific impulse increases enabled by metallized propellants are examined for a variety of different stage and propellant combinations.

Palaszewski, Bryan A.↗

High energy-density liquid rocket fuel performance

A fuel performance database of liquid hydrocarbons and aluminum-hydrocarbon fuels was compiled using engine parametrics from the Space Transportation Engine Program as a baseline. Propellant performance parameters are introduced. General hydrocarbon fuel performance trends are discussed with respect to hydrogen-to-carbon ratio and heat of formation. Aluminum-hydrocarbon fuel performance is discussed with respect to aluminum metal loading. Hydrocarbon and aluminum-hydrocarbon fuel performance is presented with respect to fuel density, specific impulse, and propellant density specific impulse.

Rapp, Douglas C.↗

High energy-density liquid rocket fuel performance

A fuel performance database of liquid hydrocarbons and aluminum-hydrocarbon fuels was compiled using engine parametrics from the Space Transportation Engine Program as a baseline. Propellant performance parameters are introduced. General hydrocarbon fuel performance trends are discussed with respect to hydrogen-to-carbon ratio and heat of formation. Aluminum-hydrocarbon fuel performance is discussed with respect to aluminum metal loading. Hydrocarbon and aluminum-hydrocarbon fuel performance is presented with respect to fuel density, specific impulse and propellant density specific impulse.

Rapp, Douglas C.↗

Method and Apparatus for Thermal Spraying of Metal Coatings Using Pulsejet Resonant Pulsed Combustion

An apparatus and method [or thermal spraying a metal coating on a substrate is accomplished with a modified pulsejet and optionally an ejector to assist in preventing oxidation. Metal such a Aluminum or Magnesium may be used. A pulsejet is first initiated by applying fuel, air. and a spark. Metal is inserted continuously in a high volume of meta1 into a combustion chamber of the pulsejet. The combustion is thereafter. controlled resonantly at high frequency and the metal is heated to a molten state. The metal is then transported from the combustion chamber into a tail pipe of said pulsejet and is expelled therefrom at high velocity and deposited on a target substrate.

Paxson, Daniel E.↗

Method and Apparatus for Thermal Spraying of Metal Coatings Using Pulsejet Resonant Pulsed Combustion

An apparatus and method for thermal spraying a metal coating on a substrate is accomplished with a modified pulsejet and optionally an ejector to assist in preventing oxidation. Metal such as Aluminum or Magnesium may be used. A pulsejet is first initiated by applying fuel, air, and a spark. Metal is inserted continuously in a high volume of metal into a combustion chamber of the pulsejet. The combustion is thereafter controlled resonantly at high frequency and the metal is heated to a molten state. The metal is then transported from the combustion chamber into a tailpipe of said pulsejet and is expelled therefrom at high velocity and deposited on a target substrate.

Paxson, Daniel E.↗

Centrifugal Nuclear Thermal Rocket Challenges and Potential

The Centrifugal Nuclear Thermal Rocket (CNTR) is a liquid fueled fission propulsion concept designed to heat propellant to 5000 K prior to expansion through a nozzle. A specific impulse up to 1800 s may be achieved using hydrogen propellant, and a specific impulse up to 1000 s may be achieved using more storable propellants such as methane, ammonia, or propane. The high uranium density of the liquid metallic uranium or liquid uranium carbide fuel will help enable compact engines suitable for missions such as fast (<15 month) round trip human Mars missions or high delta-V missions in cislunar space. Long term applications of the CNTR could include the advanced exploration and utilization of the solar system through direct use of in-situ volatiles as propellant. Challenges associated with the CNTR are numerous. Centrifugal force is used to retain the liquid fuel in rotating fuel cylinders, and rotational velocities up to 5000 rpm may be required. Propellant flow must be directed such that all structures and moderators in the core are adequately cooled prior to the propellant entering the liquid fuel and being heated to 5000 K. The rotating fuel cylinder wall (RFCW) must have an inner surface designed to be compatible with liquid uranium metal or uranium carbide fuel up to at least 1500 K, and that inner surface may also need to be textured to help maintain acceptable wall temperatures. Propellant must flow radially inward through the RFCW while fuel is simultaneously contained. The RFCW should ideal-ly be made from a material with low neutron absorption to help minimize engine mass and facilitate the use of High Assay Low Enriched Uranium (HALEU) fuel in the system. The drive system for the rotating fuel cylinders must support all phases of operation. This paper will discuss computational and experimental research being conducted to address some of the challenges associated with the CNTR, and will also note potential mission benefits from the CNTR.

Michael G. Houts↗

Experimental Investigation of Vibratory Stresses in a Concentric-Ring Direct-Air-Cycle Nuclear Fuel Element

Preliminary tests made by the General Electric Company indicated that aerodynamic loads might cause large enough distortions in the thin sheet-metal rings of a nuclear fuel element to result in structural failure. The magnitude of the distortions in a test fuel element was determined from strains measured with airflow conditions simulating those expected during engine operation. The measured vibratory strains were low enough to indicate the improbability of failure by fatigue. A conservative estimate of the radial deflection that accompanied peak strains in the outer ring was +0.0006 inch.

Chiarito, Patrick T.↗

Effect of fuel density and heating value on ram-jet airplane range

An analytical investigation of the effects of fuel density and heating value on the cruising range of a ram-jet airplane was made. Results indicate that with present-day knowledge of chemical fuels, neither very high nor very low fuel densities have any advantages for long-range flight. Of the fuels investigated, the borohydrides and metallic boron have the greatest range potential. Aluminum and aluminum hydrocarbon slurries were inferior to pure hydrocarbon fuel and boron-hydrocarbon slurries were superior on a range basis. It was concluded that the practical difficulties associated with the use of liquid hydrogen fuel cannot be justified on a range basis.

MISSILES↗

Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane

A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion.TM.. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon.TM.-binder structure is immersed within a Nafion.TM./methanol bath to impregnate the electrode with Nafion.TM.. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

Surampudi, Subbarao↗

Organic fuel cell methods and apparatus

A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion.TM.. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon.TM.-binder structure is immersed within a Nafion.TM./methanol bath to impregnate the electrode with Nafion.TM.. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

Surampudi, Subbarao↗

Organic fuel cell methods and apparatus

A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion.TM.. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon.TM.-binder structure is immersed within a Nafion.TM./methanol bath to impregnate the electrode with Nafion.TM.. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

Surampudi, Subbarao↗