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117 records · Page 7

Study of the rotational-level and temperature dependence of the quenching rate of OH fluorescence due to collisions with water molecules

The importance of the OH radical as an intermediate in many combustion reactions and in atmospheric photochemistry has led many researchers to use it as a diagnostic tool in these processes. The amount of data that has been acquired over the years for this radical is quite considerable. However, the quenching rate of OH with water molecules as a function of temperature and the rotational level of the excited state is not very well understood. The motivation of the studies undertaken is to bridge the gap between the low temperature measurements and the high temperature ones reported in the literature. The technique generally employed in these diagnostics is laser-induced fluorescence (LIF), through which rotational state selective excitation of the radical is possible. Furthermore, in a combustion medium, water is produced in abundance so that knowledge of the quenching rate of OH due to water molecules plays a crucial role in interpreting the data. In general, the precursor to an understanding of the collisional quenching rates of OH involves a characterization of the mode in which the radical is produced; the resulting rotational and translational distribution, followed by a measurement of the OH temperature; and ultimately obtaining the rate constants from the pressure dependence of the fluorescence signal. The experimental implementation of these measurements therefore involved, as a first step, the production of the OH radicals in a microwave discharge cell using water vapor as the source, wherein a hydrogen atom is abstracted from H2O. The second step involved the absorption of photons from the frequency-doubled output of a pulsed amplified, single-frequency cw ring dye laser. By tuning the laser to the peak of the transition and observing the fluorescence decay after the laser pulse, the lifetime of the OH in a particular rotational electronic state was determined (tau = 1.4 microseconds for Q(sub 1)(3)). Knowledge of this parameter led to a determination of the quenching rate. By varying the water vapor pressure in the cell and measuring the lifetime as a function of pressure a linear plot of the quenching rate as a function of pressure was obtained. Using this plot, the quenching cross section was deduced. It has therefore been possible to measure the local translational temperature and the quenching cross section with one laser system.

Koker, Edmond B.↗

The Effect of Satellite Observing System Changes on MERRA Water and Energy Fluxes

Because reanalysis data sets offer state variables and fluxes at regular space / time intervals, atmospheric reanalyses have become a mainstay of the climate community for diagnostic purposes and for driving offline ocean and land models. Although one weakness of these data sets is the susceptibility of the flux products to uncertainties because of shortcomings in parameterized model physics, another issue, perhaps less appreciated, is the fact that continual but discreet changes in the evolving observational system, particularly from satellite sensors, may also introduce artifacts in the time series of quantities. In this paper we examine the ability of the NASA MERRA (Modern Era Retrospective Analysis for Research and Applications) and other recent reanalyses to determine variability in the climate system over the satellite record (approximately the last 30 years). In particular we highlight the effect on the reanalysis of discontinuities at the junctures of the onset of passive microwave imaging (Special Sensor Microwave Imager) in late 1987 as well as improved sounding and imaging with the Advanced Microwave Sounding Unit, AMSU-A, in 1998. We first examine MERRA fluxes from the perspective of how physical modes of variability (e.g. ENSO events, Pacific Decadal Variability) are contaminated by artificial step-like trends induced by the onset of new moisture data these two satellite observing systems. Secondly, we show how Redundancy Analysis, a statistical regression methodology, is effective in relating these artifact signals in the moisture and temperature analysis increments to their presence in the physical flux terms (e.g. precipitation, radiation). This procedure is shown to be effective greatly reducing the artificial trends in the flux quantities.

Robertson, Franklin R.↗

The Effect of Satellite Observing System Changes on MERRA Water and Energy Fluxes

Because reanalysis data sets offer state variables and fluxes at regular space / time intervals, atmospheric reanalyses have become a mainstay of the climate community for diagnostic purposes and for driving offline ocean and land models. Although one weakness of these data sets is the susceptibility of the flux products to uncertainties because of shortcomings in parameterized model physics, another issue, perhaps less appreciated, is the fact that continual but discreet changes in the evolving observational system, particularly from satellite sensors, may also introduce artifacts in the time series of quantities. In this paper we examine the ability of the NASA MERRA (Modern Era Retrospective Analysis for Research and Applications) and other recent reanalyses to determine variability in the climate system over the satellite record (approx. the last 30 years). In particular we highlight the effect on the reanalysis of discontinuities at the junctures of the onset of passive microwave imaging (Special Sensor Microwave Imager) in late 1987 and, more prominently, with improved sounding and imaging with the Advanced Microwave Sounding Unit, AMSU-A, in 1998. We first examine MERRA fluxes from the perspective of how physical modes of variability (e.g. ENSO events, Pacific Decadal Variability) are contained by artificial step-like trends induced by the onset of new moisture data these two satellite observing systems. Secondly, we show how Redundancy Analysis, a statistical regression methodology, is effective in relating these artifact signals in the moisture and temperature analysis increments to their presence in the physical flux terms (e.g. precipitation, radiation). This procedure is shown to be effective greatly reducing the artificial trends in the flux quantities.

Robertson, Franklin R.↗

The Radiative Consistency of Atmospheric Infrared Sounder and Moderate Resolution Imaging Spectroradiometer Cloud Retrievals

The consistency of cloud top temperature (Tc) and effective cloud fraction (f) retrieved by the Atmospheric Infrared Sounder (AIRS)/Advanced Microwave Sounding Unit (AMSU) observation suite and the Moderate Resolution Imaging Spectroradiometer (MODIS) on the EOS-Aqua platform are investigated. Collocated AIRS and MODIS TC and f are compared via an 'effective scene brightness temperature' (Tb,e). Tb,e is calculated with partial field of view (FOV) contributions from TC and surface temperature (TS), weighted by f and 1-f, respectively. AIRS reports up to two cloud layers while MODIS reports up to one. However, MODIS reports TC, TS, and f at a higher spatial resolution than AIRS. As a result, pixel-scale comparisons of TC and f are difficult to interpret, demonstrating the need for alternatives such as Tb,e. AIRS-MODIS Tb,e differences ((Delta)Tb,e) for identical observing scenes are useful as a diagnostic for cloud quantity comparisons. The smallest values of DTb,e are for high and opaque clouds, with increasing scatter in (Delta)Tb,e for clouds of smaller opacity and lower altitude. A persistent positive bias in DTb,e is observed in warmer and low-latitude scenes, characterized by a mixture of MODIS CO2 slicing and 11-mm window retrievals. These scenes contain heterogeneous cloud cover, including mixtures of multilayered cloudiness and misplaced MODIS cloud top pressure. The spatial patterns of (Delta)Tb,e are systematic and do not correlate well with collocated AIRS-MODIS radiance differences, which are more random in nature and smaller in magnitude than (Delta)Tb,e. This suggests that the observed inconsistencies in AIRS and MODIS cloud fields are dominated by retrieval algorithm differences, instead of differences in the observed radiances. The results presented here have implications for the validation of cloudy satellite retrieval algorithms, and use of cloud products in quantitative analyses.

clouds↗

Estimating soil wetness using satellite data

Improved estimates of soil wetness were obtained using observations from both the NIMBUS-7 Scanning Multichannel Microwave Radiometer (SMMR) and the NOAA-7 Advanced Very High Resolution Radiometer (AVHRR). SMMR 66 GHz frequency, horizontal polarization, brightness temperature T(BH) was first correlated with soil wetness, as computed using an Antecedent Precipitation Index (API) model, for a number of SMMR ground resolution areas involving a fairly wide range of vegetation densities. The API generally accounted for more than 70 percent of the observed temporal variability in T(BH), with linear correlations being significant at the 1 percent level. The regression slope of T(BH) versus API correlated well, at the 1 percent level, with a vegetation index derived from AVHRR visible and near-infrared observations. The regression intercept was found to correlate less satisfactorily, but was significant at the 5 percent level. These linear regression results were used to develop a diagnostic model for soil wetness using SMMR and AVHRR data only.

Choudhury, Bhaskar J.↗

Definition of International GPM GV Research Program

The Global Precipitation Measurement (GPM) Mission will consist of a constellation of rain-measuring satellites, the main member of which (the core satellite) will serve as the measurement reference to the other members of the constellation. The core satellite is being developed jointly by the National Aeronautics and Space Administration (NASA) and the newly-named Japan Aerospace Exploration Agency (JAXA -- previously NASDA) along with its government partner, the Communications Research Laboratory (CRL). The GPM mission was proposed as a follow-up mission to the Tropical Rainfall Measuring Mission (TRMM) by both NASA and NASDA based on the unparalleled scientific success of TRMM, and has recently been joined by the European Space Agency (ESA) via its formulation of the European GPM mission (i.e., EGPM). GPM is an ambitious mission designed to produce accurate and frequent global observations of precipitation (both rain and snow) made possible by replacing the TRMM satellite with the new core satellite carrying an advanced radar-radiometer system, and serving as the centerpiece for the constellation of some eight (8) additional satellites being provided through international cooperation. The core satellite is to be flown up to high latitudes (inclined some 65-70 degrees), and will carry a Ku/Ka-band, nadir-scanning, dual-frequency precipitation radar (DPR) that is being developed by JAXA and CRL, along with a large aperture, extended frequency-range, conically-scanning passive microwave radiometer being developed by NASA and its industrial partners. Each constellation satellite will also carry some type of multi-channel passive microwave radiometer (as well as a multi-beam Ka-band radar in the case of EGPM) whose rain estimates will be calibrated and referenced to those made by the core satellite, producing for the first time fully-global, continuous, and bias-free precipitation datasets. GPM data will be delivered in near-realtime, taking a major step toward the operational use of precipitation information for model initialization and data assimilation in a number of application areas such as hazardous weather forecasting, flood warning, fresh water resource assessment, and crop growth prediction. In addition, GPM data will complement the now-existing global temperature record, allowing for improved assessments of climate change, particularly those processes in which the global water cycle both forces and responds to climatic drifts in global temperature conditions. A foremost element of this international constellation mission is a parallel international ground validation (GV) network. This GV network is needed to determine uncertainties in the rain retrievals, critical for application of the retrieval information in weather and hydrometeorological modeling and climate diagnostics, as well as assurances that the satellite retrievals of surface rainfall are consistent with those actually measured at the surface. The key aspects of this network is that it must be worldwide and created through the GPM partnership process. Therefore the network will consist of a confederation of government agencies, academic organizations, private institutions, and individual scientists from a collection of nations who have initiated the process by gathering in Abingdon to develop the fundamentals of the international GPM GV research programme. Therefore in keeping with our responsibilities as the front-runners of the programme, the main objectives of this workshop are: (1) to present and share opinions on interests, perspectives, and concerns about GPM GV research; (2) to examine the conceptual and/or planned GPM GV site templates from NASA, NASDA, ESA, and other partners; (3) to define the main scientific objectives of the international GPM GV research programme; (4) to formulate a preliminary set of international GPM GV science and measurement requirements; and (5) to convene a Steering Committee to aid the organization of the GPM GV program, to document its science implementation plans, and to aid planning for follow-up GPM GV meetings.

Smith, Eric A.↗

Ion propulsion

An ion engine is a plasma thruster which produces thrust by extracting ions from the plasma and accelerating them to high velocity with an electrostatic field. The ions are then neutralized and leave the engine as high velocity neutral particles. The advantages of ion engines are high specific impulse and efficiency and their ability to operate over a wide range of input powers. In comparison with other electric thrusters, the ion engine has higher efficiency and specific impulse than thermal electric devices such as the arcjet, microwave, radiofrequency and laser heated thrusters and can operate at much lower current levels than the MPD thruster. However, the thrust level for an ion engine may be lower than a thermal electric thruster of the same operating power, consistent with its higher specific impulse, and therefore ion engines are best suited for missions which can tolerate longer duration propulsive phases. The critical issue for the ion engine is lifetime, since the prospective missions may require operation for several thousands of hours. The critical components of the ion engine, with respect to engine lifetime, are the screen and accelerating grid structures. Typically, these are large metal screens that must support a large voltage difference and maintain a small gap between them. Metallic whisker growth, distortion and vibration can lead to arcing, and over a long period of time ion sputtering will erode the grid structures and change their geometry. In order to study the effects of long time operation of the grid structure, we are developing computer codes based on the Particle-In-Cell (PIC) technique and Laser Induced Fluorescence (LIF) diagnostic techniques to study the physical processes which control the performance and lifetime of the grid structures.

Meserole, J. S.↗

Ion propulsion

An ion engine is a plasma thruster which produces thrust by extracting ions from the plasma and accelerating them to high velocity with an electrostatic field. The ions are then neutralized and leave the engine as high velocity neutral particles. The advantages of ion engines are high specific impulse and efficiency and their ability to operate over a wide range of input powers. In comparison with other electric thrusters, the ion engine has higher efficiency and specific impulse than thermal electric devices such as the arcjet, microwave, radio frequency, and laser heated thrusters and can operate at much lower current levels than the MPD thruster. However, the thrust level for an ion engine may be lower than a thermal electric thruster of the same operating power, consistent with its higher specific impulse, and therefore ion engines are best suited for missions which can tolerate longer duration propulsive phases. The critical issue for the ion engine is lifetime, since the prospective missions may require operation for several thousands of hours. The critical components of the ion engine, with respect to engine lifetime, are the screen and accelerating grid structures. Typically, these are large metal screens that must support a large voltage difference and maintain a small gap between them. Metallic whisker growth, distortion, and vibration can lead to arcing, and over a long period of time ion sputtering will erode the grid structures and change their geometry. In order to study the effects of long time operation of the grid structure, we are developing computer codes based on the particle-in-cell (PIC) technique and laser induced fluorescence (LIF) diagnostic techniques to study the physical processes which control the performance and lifetime of the grid structures.

Meserole, J. S.↗

Evaluation of Enhanced High Resolution MODIS/AMSR-E SSTs and the Impact on Regional Weather Forecast

Over the last few years, the NASA Short-term Prediction Research and Transition (SPoRT) Center has been generating a 1-km sea surface temperature (SST) composite derived from retrievals of the Moderate Resolution Imaging Spectroradiometer (MODIS) for use in operational diagnostics and regional model initialization. With the assumption that the day-to-day variation in the SST is nominal, individual MODIS passes aboard the Earth Observing System (EOS) Aqua and Terra satellites are used to create and update four composite SST products each day at 0400, 0700, 1600, and 1900 UTC, valid over the western Atlantic and Caribbean waters. A six month study from February to August 2007 over the marine areas surrounding southern Florida was conducted to compare the use of the MODIS SST composite versus the Real-Time Global SST analysis to initialize the Weather Research and Forecasting (WRF) model. Substantial changes in the forecast heat fluxes were seen at times in the marine boundary layer, but relatively little overall improvement was measured in the sensible weather elements. The limited improvement in the WRF model forecasts could be attributed to the diurnal changes in SST seen in the MODIS SST composites but not accounted for by the model. Furthermore, cloud contamination caused extended periods when individual passes of MODIS were unable to update the SSTs, leading to substantial SST latency and a cool bias during the early summer months. In order to alleviate the latency problems, the SPoRT Center recently enhanced its MODIS SST composite by incorporating information from the Advanced Microwave Scanning Radiometer-EOS (AMSR-E) instruments as well as the Operational Sea Surface Temperature and Sea Ice Analysis. These enhancements substantially decreased the latency due to cloud cover and improved the bias and correlation of the composites at available marine point observations. While these enhancements improved upon the modeled cold bias using the original MODIS SSTs, the discernable impacts on the WRF model were still somewhat limited. This paper explores several factors that may have contributed to this result. First, the original methodology to initialize the model used the most recent SST composite available in a hypothetical real ]time configuration, often matching the forecast initial time with an SST field that was 5-8 hours offset. To minimize the differences that result from the diurnal variations in SST, the previous day fs SST composite is incorporated at a time closest to the model initialization hour (e.g. 1600 UTC composite at 1500 UTC model initialization). Second, the diurnal change seen in the MODIS SST composites was not represented by the WRF model in previous simulations, since the SSTs were held constant throughout the model integration. To address this issue, we explore the use of a water skin-temperature diurnal cycle prediction capability within v3.1 of the WRF model to better represent fluctuations in marine surface forcing. Finally, the verification of the WRF model is limited to very few over-water sites, many of which are located near the coastlines. In order to measure the open ocean improvements from the AMSR-E, we could use an independent 2-dimensional, satellite-derived data set to validate the forecast model by applying an object-based verification method. Such a validation technique could aid in better understanding the benefits of the mesoscale SST spatial structure to regional models applications.

Schiferl, Luke D.↗