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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Novel High Efficient Organic Photovoltaic Materials

In man's mission to the outer space or a remote site, the most abundant, renewable, nonpolluting, and unlimited external energy source is light. Photovoltaic (PV) materials can convert light into electrical power. In order to generate appreciable electrical power in space or on the Earth, it is necessary to collect sunlight from large areas due to the low density of sunlight, and this would be very costly using current commercially available inorganic solar cells. Future organic or polymer based solar cells seemed very attractive due to several reasons. These include lightweight, flexible shape, ultra-fast optoelectronic response time (this also makes organic PV materials attractive for developing ultra-fast photo detectors), tunability of energy band-gaps via molecular design, versatile materials synthesis and device fabrication schemes, and much lower cost on large-scale industrial production. It has been predicted that nano-phase separated block copolymer systems containing electron rich donor blocks and electron deficient acceptor blocks will facilitate the charge separation and migration due to improved electronic ultrastructure and morphology in comparison to current polymer composite photovoltaic system. This presentation will describe our recent progress in the design, synthesis and characterization of a novel donor-bridge-acceptor block copolymer system for potential high-efficient organic optoelectronic applications. Specifically, the donor block contains an electron donating alkyloxy derivatized polyphenylenevinylene, the acceptor block contains an electron withdrawing alkyl-sulfone derivatized polyphenylenevinylene, and the bridge block contains an electronically neutral non-conjugated aliphatic hydrocarbon chain. The key synthetic strategy includes the synthesis of each individual block first, then couple the blocks together. While the donor block stabilizes the holes, the acceptor block stabilizes the electrons. The bridge block is designed to hinder the electron-hole recombination. Thus, improved charge separation is expected. In addition, charge migration will also be facilitated due to the expected nano-phase separated and highly ordered block copolymer ultrastructural. The combination of all these factors will result in significant overall enhancement of photovoltaic power conversion efficiency.

Sun, Sam↗

Advanced TUFROC Thermal Protection System Evolution Under Re-entry like Conditions

Toughened Unipiece Fibrous Reinforced Oxidation-resistant Composite (TUFROC) and its successor, Advanced TUFROC, are state-of-the-art thermal protection systems (TPS) for high temperature reusable applications. Originally designed for use on the wing-leading edge of X-37B, TUFROC is an insulative tiled system consisting of a low-conductivity ceramic base, a carbonaceous cap, and multiple coatings for thermal performance. The improved Advanced TUFROC has demonstrated reusability up to 2900 °F and single use capabilities exceeding 3200 °F. This effort explores the evolution of Advanced TUFROC when exposed to re-entry like conditions via arc jet testing. Chemical reactions and constituent migration resulting from the aerothermal heating are known to occur and are studied in detail. Further, the interaction between the multiple constituents and layers will be discussed as this is believed to have a significant impact on the overall performance. Characterization includes structural analysis via optical microscopy, scanning electron microscopy and energy-dispersive x-ray spectroscopy.

Thermal protection system↗

Lunar Dust Simulant Particle Adhesion on Copolyimide Alkyl Ethers

Mitigation of lunar dust contamination is one of the greatest challenges to be overcome to realize a sustained lunar presence. Likely solutions will integrate active mitigation strategies, requiring the input of external energy, and passive materials, exhibiting an intrinsic resistance to lunar dust adhesion. In this work, a series of copolyimide alkyl ethers containing per fluorinated side-chains were generated to evaluate the influence surface modification agents have on surface chemical, topographical, and mechanical properties. An expanded testing protocol to characterize the adhesion interaction between lunar dust simulant and the copolyimide substrate was carried out. The interfacial adhesion strength was in-situ measured by a custom-built particulate adhesion instrument, utilizing a sonic wand. Surface mechanical properties were characterized by nanoindentation, utilizing the continuous stiffness measurement approach. A nominal presence of surface modifying agents, 1 wt%, resulted in a six-fold reduction in adhesion strength of the interface. A strong inverse correlation between the adhesion strength and Young’s modulus of the substrate was identified. The reduction was attributed to a synergistic interaction between the surface energy, surface roughness, and modulus of the copolyimide alkyl ethers film.

Lunar Dust, Particulate Adhesion, Surface Migratio↗

NSI customer service representatives and user support office: NASA Science Internet

The NASA Science Internet, (NSI) was established in 1987 to provide NASA's Offices of Space Science and Applications (OSSA) missions with transparent wide-area data connectivity to NASA's researchers, computational resources, and databases. The NSI Office at NASA/Ames Research Center has the lead responsibility for implementing a total, open networking program to serve the OSSA community. NSI is a full-service communications provider whose services include science network planning, network engineering, applications development, network operations, and network information center/user support services. NSI's mission is to provide reliable high-speed communications to the NASA science community. To this end, the NSI Office manages and operates the NASA Science Internet, a multiprotocol network currently supporting both DECnet and TCP/IP protocols. NSI utilizes state-of-the-art network technology to meet its customers' requirements. THe NASA Science Internet interconnects with other national networks including the National Science Foundation's NSFNET, the Department of Energy's ESnet, and the Department of Defense's MILNET. NSI also has international connections to Japan, Australia, New Zealand, Chile, and several European countries. NSI cooperates with other government agencies as well as academic and commercial organizations to implement networking technologies which foster interoperability, improve reliability and performance, increase security and control, and expedite migration to the OSI protocols.

Source record↗

Distributed processing on the Space Shuttle - A case study

A Power Extension Package (PEP) has been designed to provide additional electrical power and energy during Shuttle sortie missions. The considered investigation was conducted to determine the most suitable allocation of PEP monitoring and control functions between the Orbiter's existing (centralized) Systems Management General Purpose Computer and an embedded PEP processor. PEP monitoring and control functions are examined, and a configuration definition is considered, taking into account the 'functional migration' process, function allocation criteria, and candidate functional configurations. A trade study is conducted, giving attention to an assessment of four candidate configurations. Assessment factors are related to cost, development risk, aspects of reliability and safety, PEP design complexity, PEP/STS integration complexity, flight operations, and launch/landing site operations. A thorough (subjective) assessment of the PEP system life cycle indicates substantial benefits from a distributed processing approach.

Schoonmaker, P. B.↗

Novel High Efficient Organic Photovoltaic Materials

Solar energy is a renewable, nonpolluting, and most abundant energy source for human exploration of a remote site or outer space. In order to generate appreciable electrical power in space or on the earth, it is necessary to collect sunlight from large areas and with high efficiency due to the low density of sunlight. Future organic or polymer (plastic) solar cells appear very attractive due to their unique features such as light weight, flexible shape, tunability of energy band-gaps via versatile molecular or supramolecular design, synthesis, processing and device fabrication schemes, and much lower cost on large scale industrial production. It has been predicted that supramolecular and nano-phase separated block copolymer systems containing electron rich donor blocks and electron deficient acceptor blocks may facilitate the charge carrier separation and migration due to improved electronic ultrastructure and morphology in comparison to polymer composite system. This presentation will describe our recent progress in the design, synthesis and characterization of a novel block copolymer system containing donor and acceptor blocks covalently attached. Specifically, the donor block contains an electron donating alkyloxy derivatized polyphenylenevinylene (RO-PPV), the acceptor block contains an electron withdrawing alkyl-sulfone derivatized polyphenylenevinylene (SF-PPV). The key synthetic strategy includes the synthesis of each individual block first, then couple the blocks together. While the donor block has a strong PL emission at around 560 nm, and acceptor block has a strong PL emission at around 520 nm, the PL emissions of final block copolymers are severely quenched. This verifies the expected electron transfer and charge separation due to interfaces of donor and acceptor nano phase separated blocks. The system therefore has potential for variety light harvesting applications, including high efficient photovoltaic applications.

Sun, Sam↗

Aeolus -A Mission to Study the Thermal and Wind Environment of Mars

Aeolus is a small satellite mission to observe surface and atmospheric forcing and general circulation of Mars, by measuring surface energy balance, atmospheric temperatures, aerosols and clouds, and winds. Critically, Aeolus will make these measurements at all local times of day, providing information on both seasonal and diurnal variability. To date, direct measurements of Martian wind speeds have only been possible at the surface, only during daylight hours, and over small areas limited by rover traverse capabilities. From orbit, thermal measurements (e.g., estimates from assumed geostrophic balance) as well as images of dust storms and dune migration have provided inputs to derive current data sets on Martian winds. However, Mars General Circulation models demonstrate that wind speeds derived from these indirect measurements may be in error by 50 to 100%. For this reason, direct wind velocity measurements have been deemed "High Priority" by MEPAG (Mars Exploration Program Analysis Group); measuring wind speeds and corresponding thermal data is vital to understanding the climate of Mars. Aeolus will carry four Spatial Heterodyne Spectrometers (SHS), coupled to two orthogonal viewing telescopes. These high-resolution near-infrared spectrometers will measure CO2 (daytime absorption) and O2 (day and night emission) lines in the Martian atmosphere. Doppler shifts in these lines can be measured during Martian day and night, resolving wind speeds down to ~5 m/s. Orthogonal views allow the spectrometers to capture wind vectors over all observation locations. Aeolus will also carry the atmospheric limb-viewing Thermal Limb Sounder (TLS) to measure atmospheric temperatures, water ice clouds, and dust abundances across all altitudes where winds are measured. Finally, the Surface Radiometric Sensor Package (SuRSeP), a nadir viewing radiometer, will measure the total reflected solar and emitted thermal radiance, surface temperature, and water cloud and dust total column abundances. The combined spectral and thermal measurements will provide a new understanding of the global energy balance, dust transport processes, and climate cycles in the Martian atmosphere. Aeolus will consist of a single satellite in a near-polar orbit, allowing it to pass over all local times, with the baseline mission observing all seasons of an entire Martian year (two Earth years). Aeolus was one of two Martian smallsat concepts selected for study through the Planetary Science Deep Space SmallSat Studies program. This talk will provide an overview of the mission, including science rationale, instruments, spacecraft, and mission operations concept.

and winds↗

Effects of fog droplets on wake vortex decay rate

A simple model for the motion of particles in a laminar line vortex is discussed. The energy required to accelerate a set of these particles was determined and shown to be only a small fraction of the energy content of the vortex flow. It is shown that this energy transfer is unlikely to be sufficient to significantly modify the vortex decay rate. It is further argued that the effect of the particle on the viscous properties of the resulting two phase fluid leads to a slower decay rate than in single phase air flow. However, this conclusion may not necessarily follow for turbulence flows. Results show that the migration of particles to the outer flow results in a redistribution of the velocity profile in the vortex and in a non-uniform two phase viscosity across the core. It is suggested that these effects may accelerate vortex bursting.

Moulden, T. H.↗

Ultralow Frequency Waves as an Intermediary for Solar Wind Energy Input Into the Radiation Belts

Enhancements of electron fluxes in the outer radiation belt have been closely linked to increases in solar wind speed and density as well as to prolonged intervals of southward interplanetary magnetic field. Periodic oscillations in the Earth's magnetic field with frequencies in the range of a few millihertz (ultralow frequency or ultralow frequency waves) may be an intermediary through which these solar wind drivers influence radiation belt dynamics due to their potential for resonant interactions with energetic electrons causing the radial migration of resonant electrons. Using data from more than 180 ground magnetometers contributing to the worldwide SuperMAG collaboration, we explore possible relationships between relativistic electron flux variations and the spatial and temporal profiles of ultralow frequency wave power contained in the Pc5 frequency band (2–7 mHz). During 19 geomagnetic storms marked by relativistic (1.5 MeV < E < 6 MeV) electron flux enhancements and 19 storms that led to prolonged electron flux depletions, Pc5 wave power is found penetrating to L shells as low as 2–3. The enhancement of Pc5 wave power starts almost simultaneously with the storm onset. The depth of wave activity penetration was found associated with the strength of geomagnetic activity (Spearman's ρ = 0.54), which is also related to the location of electron flux maximum observed in the recovery phase. Pc5 wave activity persists longer (for up to ≈62 hr) for those storms that produced relativistic electrons. We also investigate the combination of interplanetary conditions necessary to differentiate the response of relativistic electron fluxes to geomagnetic storms. A coupling function that captures the increased reconnection rate at the dayside magnetopause affecting magnetospheric processes which may produce Pc5 wave power offers an additional key to further understanding the outer belt dynamics.

Georgiou, M.↗

An Efficient Monte Carlo Method for Modeling Radiative Transfer in Protoplanetary Disks

Monte Carlo methods have been shown to be effective and versatile in modeling radiative transfer processes to calculate model temperature profiles for protoplanetary disks. Temperatures profiles are important for connecting physical structure to observation and for understanding the conditions for planet formation and migration. However, certain areas of the disk such as the optically thick disk interior are under-sampled, or are of particular interest such as the snow line (where water vapor condenses into ice) and the area surrounding a protoplanet. To improve the sampling, photon packets can be preferentially scattered and reemitted toward the preferred locations at the cost of weighting packet energies to conserve the average energy flux. Here I report on the weighting schemes developed, how they can be applied to various models, and how they affect simulation mechanics and results. We find that improvements in sampling do not always imply similar improvements in temperature accuracies and calculation speeds.

radiative transfer↗

Influence of a Simple Heat Loss Profile on a Pure Diffusion Flame

The presence of soot on the fuel side of a diffusion flame results in significant radiative heat losses. The influence of a fuel side heat loss zone on a pure diffusion flame established between a fuel and an oxidizer wall is investigated by assuming a hypothetical sech(sup 2) heat loss profile. The intensity and width of the loss zone are parametrically varied. The loss zone is placed at different distances from the Burke-Schumann flame location. The migration of the temperature and reactivity peaks are examined for a variety of situations. For certain cases the reaction zone breaks through the loss zone and relocates itself on the fuel side of the loss zone. In all cases the temperature and reactivity peaks move toward the fuel side with increased heat losses. The flame structure reveals that the primary balance for the energy equation is between the reaction term and the diffusion term. Extinction plots are generated for a variety of situations. The heat transfer from the flame to the walls and the radiative fraction is also investigated, and an analytical correlation formula, derived in a previous study, is shown to produce excellent predictions of our numerical results when an O(l) numerical multiplicative constant is employed.

Ray, Anjan↗

Excited state dynamics of thulium ions in yttrium aluminum garnets

The processes that take place in the excited states of a trivalent Thulium (Tm) ion in an Yttrium Aluminum Garnet (YAG) crystal, being relevant to the use of this system for laser applications, have been the object of several studies. We have reexamined this system focusing our attention on the dynamics of Tm following its excitation in the H-3(sub 4) level. Under these conditions the system relaxes through a cross-relaxation process. H-3(sub 4) yields F-3(sub 4), H-3(sub 6) yields F-3(sub 4), whose rate depends upon both the concentration of the Tm ion and the temperature of the crystal. The excitation spectrum obtained by monitoring the 1.8 micron emission of Tm (due to the F-3(sub 4) yields H-3(sub 6) transition) indicates an increase in the contribution to this emission from the H-3(sub 4) level relative to the H-3(sub 5) level as the Tm concentration increases; this shows the increased role played by the H-3(sub 4) level in pumping the infrared emission. Correspondingly, the duration of the luminescence originating in the H-3(sub 4) level is shortened as the concentration of Tm increases. The concentration quenching of this lifetime can be fit to a model which assumes that the cross-relaxation is due to a dipole-dipole interaction; from this fit, the intrinsic Tm lifetime in the absence of cross relaxation can be derived. We have used this lifetime to calculate the rate of the cross-relaxation process. We have evaluated this rate as a function of the temperature and found it to be fastest at 77 K. We have also calculated the microscopic interaction parameters for the cross-relaxation process by using two independent experimental features: (1) the time evolution of the emission from the H-3(sub 4) level; and (2) the spectral overlap between the H-3(sub 4) yields F-3(sub 4) emission and the H-3(sub 6) yields F-3(sub 4) absorption. We have also considered the migration of excitation among the Tm ions in the F-3(sub 4) level and calculated the relevant microparameter by the use of the relevant spectral overlap. The data are consistent with the model in which the Tm ions, once excited into the H-3(sub 4) level decay by cross-relaxation to the F-3(sub 4), and then transfer rapidly their energy to other Tm ions.

Armagan, G.↗

Dynamic processes in Be star atmospheres. 3: Rapid multiwavelength variability in gamma Cassiopeiae

A review of the characteristics of X-ray emission from gamma Cas suggests various weaknesses with conventional scenarios that invoke Be wind interactions with a putative binary companion. To explore whether this emission might arise instead from sporadic high-energy events on the Be star itself, we have examined the temporal behavior of Voyager 1 FUV spectra and He I lambda 6678 line profiles. The FUV continuum light curves show a continuous rapid variability with a range of greater than or = 0.2 mag over a timescale of approximately 1 hr. All indications are that this variability is real. The difference spectrum of the inferred fluctuating component is identical to the photospheric spectrum, ruling out an origin much hotter than the star's effective temperature. A histogram of flux differences formed from consecutive observations shows a flat-topped distribution out to 0.2 mag. This result bears a striking resemblance to histograms constructed from EXOSAT and Ginga data, suggesting that the X-ray and FUV variabilities could have a common origin. Evidence is also presented of rapid variability in optical spectral lines associated with the stars photosphere. Time series of difference profiles of the lambda 6678 line confirm the existence of migrating subfeatures reported by earlier studies. The comoving average of these profiles shows that these features have a shape resembling a symmetrical 'wave-packet'. Wave packets appear to be preceeded and rejuvenated by a sharp central absorption feature. We also report a transient emission feature in lambda 6678 that is similar to brief emissions once reported by Slettebak & Snow in UV resonance line profiles of Si IV and Mg II. We argue that the FUV and optical variability may find an explanation in terms of magnetic flares. Solar white-light flares offer a possible paradigm. However, problems remain with such explanations, in particular their high mean energy, frequency, and temperature.

Smith, Myron A.↗

Steady and Unsteady Flow Field Measurements Within a NASA 22-Inch Fan Model

Results are presented of an experiment conducted to investigate possible sources of fan noise in the flow developed by a 22-in. (55.9 cm) diameter turbofan model. Flow diagnostic data were acquired to identify possible sources of both tone and broadband noise. Laser Doppler velocimetry was used to characterize the tip flows that develop within the rotor blade passages, the wake flow downstream of the rotor, and the shock waves that develop on the blades when operated at transonic relative tip speeds. Single-point hot-wire measurements were made in the rotor wake to determine the frequency content and the length scales of the flow unsteadiness. The results document the changes in the rotor wake flow with both rotor speed and axial distance downstream of the rotor. The data also show the tip flow development within the blade passage, its migration downstream, and (at high rotor speeds) its merging with the blade wake of the following blade. Data also depict the variation of the tip flow with tip clearance. LDV data obtained within the blade passages at high rotor speeds illustrate the passage-to-passage variation of the mean shock position. Spectra computed from the single-point hot-wire measurements illustrate how the energy in the flow oscillations is split between periodic and random components, and how this split varies with both radial and axial position in the rotor wake.

Podboy, Gary G.↗

An Approach to Reasoning Service Migration in Data and Reasoning Fabric (DRF) Implementation

In this paper we consider service placement problem for Data and Reasoning Fabric (DRF) enabled airspace operations assuming a fixed cloud/edge infrastructure with allocated computing, storage and power resources, where cloud/edge servers, and communication stations are in a wired connected network, while vehicles use a wireless network for communication. The objective is to automatically select the best location for the requested service execution, which achieves minimum cost while satisfying the user quality of service (QoS) and available resources constraints. To this end, we estimate for each potential location the response time, consumed energy and total cost; formulate an optimization problem for cost minimization given the users QoS constraints and network infrastructure limitations; and solve it using nonlinear programming tools. The approach is applied to trajectory re-planning use case to handle a no-fly zone contingency in real time.

Vahram Stepanyan↗

Monte Carlo studies of liquid semiconductor surfaces - Si and Ge

The liquid-vapor interface of Si and Ge, and of Si doped with impurities is studied using the empirical Stillinger-Weber two- and three-body potentials. The surface tension of the pure elements is calculated by use of a direct evaluation of the free energy required to create the surface. For Si, both the surface tension and its temperature derivative are in good agreement with experiment. To within numerical accuracy, the free surfaces of both Si and Ge have a monotonically decreasing density, with a 10-90 percent surface width of about 2.2 A in both cases. When large and small model impurities are introduced into pure liquid Si, they are found in the simulations to migrate, respectively, towards the surface and away from the surface. This behavior is consistent with the interpretation that impurities with atoms larger than Si tend to lower the surface tension.

Wang, Z. Q.↗

Vortices in turbulence

Theoretical and experimental results of studies to determine the flow parameters and structures of plane mixing layers are reported. Smoke visualization, combined with hot-wire anemometry, sheets of laser light, and photography were used to gather data from the wall flow. The behavior of vortex rods was examined, noting that the rods persisted only if new vortex energy was supplied from the sublayer. A power spectral density was defined for the velocity fluctuations, as was a hierarchy of velocity scales for geometrically similar vortices. The length scale grows linearly with downstream distance, where the flow structures are fed by longitudinal vortices. A model is developed for vortex pairing in sequential order from the bottom of the mixing layer outward in a repetitive process involving vortex stretching. The model is actually a migration strategy that satisfies the flow self-preservation constraints.

Perry, A. E.↗

Some Improvements in Utilization of Flash Memory Devices

Two developments improve the utilization of flash memory devices in the face of the following limitations: (1) a flash write element (page) differs in size from a flash erase element (block), (2) a block must be erased before its is rewritten, (3) lifetime of a flash memory is typically limited to about 1,000,000 erases, (4) as many as 2 percent of the blocks of a given device may fail before the expected end of its life, and (5) to ensure reliability of reading and writing, power must not be interrupted during minimum specified reading and writing times. The first development comprises interrelated software components that regulate reading, writing, and erasure operations to minimize migration of data and unevenness in wear; perform erasures during idle times; quickly make erased blocks available for writing; detect and report failed blocks; maintain the overall state of a flash memory to satisfy real-time performance requirements; and detect and initialize a new flash memory device. The second development is a combination of hardware and software that senses the failure of a main power supply and draws power from a capacitive storage circuit designed to hold enough energy to sustain operation until reading or writing is completed.

Gender, Thomas K.↗