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At least 127 records · Page 7

Containerless polymeric microsphere production for biomedical applications

A containerless method that produces highly uniform microspheres (greater than 50 microns in diameter) from many materials has been developed for biomedical applications. A piezoelectrically vibrated drop generator forms uniform (monodisperse) monomer droplets that are either electrostatistically levitated and polymerized using UV irradiation, or free-radical polymerized. Spheres of 2-hydroxyethyl methacrylate polymer have been produced with diameters of 155 microns + or - 1.57 percent.

Rhim, W. K.↗

A reference standard for bidirectional reflection distribution function and bidirectional transmission distribution function measurement

A Lambertian reference standard for uniformly scattering a beam of light is constructed of a plate having a planar surface with a layer of glue disposed on the surface. An evenly packed layer of monodisperse spheres is set in the layer, and when the standard is used for bi-directional (BRDF) measurements, the spheres are coated with a layer of highly relective substance, such as gold or silver. When the standard is used for bi-directional transmittance distribution function (BTDF) measurements, the spheres are of a transparent material and are provided with a roughened surface, as by acid etching. In this case, the layer of glue is an optical cement, and the plate is of glass, with the spheres, the layer, and the plate all possessing a similar refractive index.

Witherow, William K.↗

Protein crystal nucleation kinetics using relative light-scattering techniques: Center director's discretionary fund

Light-scattering intensity measurements are a sensitive method for following changes in the hydrodynamic radius of particles in solution. The approach used in this report utilizes the light-scattering intensity ratios of a polydisperse to a monodisperse system. By numerically modeling the process, and fitting the model curves to the data, estimates have been obtained for the dimerization equilibrium constant, the dimer + dimer yields tetramer equilibrium constant, and the association rate constant for the dimerization process.

Pusey, Marc Lee↗

Simulation of water vapor condensation on LOX droplet surface using liquid nitrogen

The formation of ice or water layers on liquid oxygen (LOX) droplets in the Space Shuttle Main Engine (SSME) environment was investigated. Formulation of such ice/water layers is indicated by phase-equilibrium considerations under conditions of high partial pressure of water vapor (steam) and low LOX droplet temperature prevailing in the SSME preburner or main chamber. An experimental investigation was begun using liquid nitrogen as a LOX simulant. A monodisperse liquid nitrogen droplet generator was developed which uses an acoustic driver to force the stream of liquid emerging from a capillary tube to break up into a stream of regularly space uniformly sized spherical droplets. The atmospheric pressure liquid nitrogen in the droplet generator reservoir was cooled below its boiling point to prevent two phase flow from occurring in the capillary tube. An existing steam chamber was modified for injection of liquid nitrogen droplets into atmospheric pressure superheated steam. The droplets were imaged using a stroboscopic video system and a laser shadowgraphy system. Several tests were conducted in which liquid nitrogen droplets were injected into the steam chamber. Under conditions of periodic droplet formation, images of 600 micron diameter liquid nitrogen droplets were obtained with the stroboscopic video systems.

Powell, Eugene A.↗

High-temperature LDV seed particle development

The feasibility of developing a method for making monodisperse, unagglomerated spherical particles greater than 50 nm in diameter was demonstrated. Carbonaceous particles were made by pyrolyzing ethylene with a pulsed CO2 laser, thereby creating a non-equilibrium mixture of carbon, hydrogen, hydrocarbon vapors, and unpyrolyzed ethylene. Via a complex series of reactions, the carbon and hydrocarbon vapors quickly condensed into the spherical particles. By cooling and dispersing them in a supersonic expansion immediately after their creation, the hot newly-formed spheres were prevented from colliding and coalescing, thus preventing the problem of agglomeration which as plagued other investigators studying laser-simulated particle formation. The cold particles could be left suspended in the residual gases indefinitely without agglomerating. Their uniform sizes and unagglomerated nature were visualized by collecting the particles on filters that were subsequently examined using electron microscopy. It was found the mean particle size can be coarsely controlled by varying the initial ethylene pressure, and can be finely controlled by varying the fluence (energy/unit area) with which the laser irradiates the gas. The motivating application for this research was to manufacture particles that could be used as laser Doppler velocimetry (LDV) seeds in high-temperature high-speed flows. Though the particles made in this program will not evaporate until heated to about 3000 K, and thus could serve as LDV seeds in some applications, they are not ideal when the hot atmosphere is also oxidizing. In that situation, ceramic materials would be preferable. Research performed elsewhere has demonstrated that selected ceramic materials can be manufactured by laser pyrolysis of appropriate supply gases. It is anticipated that, when the same gases are used in conjunction with the rapid cooling technique, unagglomerated spherical ceramic particles can be made with little difficulty. Such particles would also be valuable to manufacturers of ceramic or abrasive products, and this technique may find its greatest commercial potential in those areas.

Frish, Michael B.↗

Rotating reactor studies

Undesired gravitational effects such as convection or sedimentation in a fluid can sometimes be avoided or decreased by the use of a closed chamber uniformly rotated about a horizontal axis. In a previous study, the spiral orbits of a heavy or buoyant particle in a uniformly rotating fluid were determined. The particles move in circles, and spiral in or out under the combined effects of the centrifugal force and centrifugal buoyancy. A optimization problem for the rotation rate of a cylindrical reactor rotated about its axis and containing distributed particles was formulated and solved. Related studies in several areas are addressed. A computer program based on the analysis was upgraded by correcting some minor errors, adding a sophisticated screen-and-printer graphics capability and other output options, and by improving the automation. The design, performance, and analysis of a series of experiments with monodisperse polystyrene latex microspheres in water were supported to test the theory and its limitations. The theory was amply confirmed at high rotation rates. However, at low rotation rates (1 rpm or less) the assumption of uniform solid-body rotation of the fluid became invalid, and there were increasingly strong secondary motions driven by variations in the mean fluid density due to variations in the particle concentration. In these tests the increase in the mean fluid density due to the particles was of order 0.015 percent. To a first approximation, these flows are driven by the buoyancy in a thin crescent-shaped depleted layer on the descending side of the rotating reactor. This buoyancy distribution is balanced by viscosity near the walls, and by the Coriolis force in the interior. A full analysis is beyond the scope of this study. Secondary flows are likely to be stronger for buoyant particles, which spiral in towards the neutral point near the rotation axis under the influence of their centrifugal buoyancy. This is because the depleted layer is thicker and extends all the way around the reactor.

Roberts, Glyn O.↗

Group evaporation

Liquid fuel combustion process is greatly affected by the rate of droplet evaporation. The heat and mass exchanges between gas and liquid couple the dynamics of both phases in all aspects: mass, momentum, and energy. Correct prediction of the evaporation rate is therefore a key issue in engineering design of liquid combustion devices. Current analytical tools for characterizing the behavior of these devices are based on results from a single isolated droplet. Numerous experimental studies have challenged the applicability of these results in a dense spray. To account for the droplets' interaction in a dense spray, a number of theories have been developed in the past decade. Herein, two tasks are examined. One was to study how to implement the existing theoretical results, and the other was to explore the possibility of experimental verifications. The current theoretical results of group evaporation are given for a monodispersed cluster subject to adiabatic conditions. The time evolution of the fluid mechanic and thermodynamic behavior in this cluster is derived. The results given are not in the form of a subscale model for CFD codes.

Shen, Hayley H.↗

The electrospray: Fundamentals and combustion applications

Liquid fuel dispersion in practical systems is typically achieved by spraying the fuel into a polydisperse distribution of droplets evaporating and burning in a turbulent gaseous environment. In view of the nearly unsurmountable difficulties of this two-phase flow, it would be useful to use an experimental arrangement that allow a systematic study of spray evolution and burning in configurations of gradually increasing levels of complexity, starting from laminar sprays to fully turbulent ones. An Electrostatic Spray (ES) of charged droplets lends itself to this type of combustion experiments under well-defined conditions and can be used to synthesize gradually more complex spray environments. In its simplest configuration, a liquid is fed into a small metal tube maintained at several kilovolts relative to a ground electrode few centimeters away. Under the action of the electric field, the liquid meniscus at the outlet of the capillary takes a conical shape, with a thin jet emerging from the cone tip. This jet breaks up farther downstream into a fine spray of charged droplets. Several advantages distinguish the electrospray from alternative atomization techniques: the self-dispersion property of the spray due to coulombic repulsion; the absence of droplet coalescence; the potential control of the trajectories of charged droplets by suitable disposition of electrostatic fields; and the decoupling of atomization, which is strictly electrostatic, from gas flow processes. Furthermore, as recently shown in our laboratory, the electrospray can produce quasi-monodisperse droplets over a very broad size range (1-100 microns). The ultimate objective of this research project is to study the formation and burning of electrosprays of liquid fuels first in laminar regimes and then in turbulent ones. Combustion will eventually be investigated in conditions of three-dimensional droplet-droplet interaction, for which experimental studies have been limited to either qualitative observations in sprays or more quantitative observations on simplified systems consisting of a small number of droplets or droplet arrays. The compactness and potential controllability of this spray generaiton system makes it appealing for studies to be undertaken in the next two years on electrospray combustion in reduced-gravity environments such as those achievable at NASA microgravity test facilities.

Gomez, Alessandro↗

Structure of confined laminar spray diffusion flames: Numerical investigation

The structure of confined laminar spray diffusion flames is investigated numerically by solving the gas-phase conservation equations for mass species, continuity, momentum, and energy and the liquid-phase equations for droplet position, velocity, size, and temperature. A one-step global reaction scheme along with six equilibrium reactions are employed to model the flame chemistry. Monodisperse as well as polydisperse sprays are considered. The numerical results demonstrate that liquid spray flames substantially differ from gaseous flames in their structure, i.e., temperature, concentration, and velocity fields, shape, and dimensions under the same conditions. Spray flames are predicted to be taller and narrower than their counterpart gaseous ones and their shapes are almost cylindrical. This is in agreement with experimental observations. The numerical computations also show that the use of the equilibrium reactions with the one-step reaction scheme decreases the flame temperature compared to the one-step reaction scheme without the equilibrium reactions and more importantly increases the surface area of the flame zone due to a phenomenon termed 'equilibrium broadening.' The spray flames also possess a finite thickness with minimal overlap of the fuel and oxygen species. A case for which a fuel-mixture consisting of 20 to 80 percent gas-liquid by mass is introduced into the combustor is also investigated and compared with predictions using only gaseous or liquid fuel.

Mawid, M. A.↗

Optimization of the parameters for a rotating, mixed-phase reactor

The motion of small, monodisperse particles in fluid was studied in a horizontal, cylindrical container rotating about its axis. One instigation for the study was the common requirement for mixed-phase, chemical or biological reactors to maintain particles in suspension for extended periods. A cylindrical, rotating reactor can allow long-term particle suspension without particle collisions and resulting agglomeration. The purpose of this study was to verify parametric effects and optimize the time of particle suspension. The theoretical and experimental results were obtained for inert, constant-diameter particles of nearly neutral buoyancy. The centrifugal buoyancy and gravitation terms were both included in the equations of motion. Laser illumination, photography and computer imaging were used to measure experimental particle concentration.

Cleland, J. G.↗

Light scattering by size-shape distributions of randomly oriented axially symmetric particles of a size comparable to a wavelength

Rigorously light scattering by size-shape distributions of randomly oriented axially symmetric particles are calculated by the T-matrix method, as extended to randomly oriented scatterers. The computational scheme is described along with a newly developed convergence procedure that makes it possible to substantially reduce computer time and storage requirements. The elements of the Stokes scattering matrix for a power-law size distribution of randomly oriented moderately aspherical spheroids are shown to be much smoother than and differ substantially from those of equivalent monodisperse spheroids; averaging over orientations does not eliminate the necessity of averaging over particle sizes. The angular-scattering behavior of the ensembles of nonspherical particles is found to be significantly different from that of the equivalent polydisperse spheres.

Mishchenko, Michael I.↗

Performance of a focused cavity aerosol spectrometer for measurements in the stratosphere of particle size in the 0.06-2.0-micrometer-diameter range

A focused cavity aerosol spectrometer aboard a NASA ER-2 high-altitude aircraft provided high-resolution measurements of the size of the stratospheric particles in the 0.06-2.0-micrometer-diameter range in flights following the eruption of Mount Pinatubo in 1991. Effects of anisokinetic sampling and evaporation in the sampling system were accounted for by means adapted and specifically developed for this instrument. Calibrations with monodisperse aerosol particles provided the instrument's response matrix, which upon inversion during data reduction yielded the particle size distributions. The resultant dataset is internally consistent and generally shows agreement to within a factor of 2 with comparable measurements simultaneously obtained by a condensation nuclei counter, a forward-scattering spectrometer probe, and aerosol particle impactors, as well as with nearby extinction profiles obtained by satellite measurements and with lidar measurements of backscatter.

Jonsson, H. H.↗

Charge-induced secondary atomization in diffusion flames of electrostatic sprays

The combustion of electrostatic sprays of heptane in laminar counterflow diffusion flames was experimentally studied by measuring droplet size and velocity distributions, as well as the gas-phase temperature. A detailed examination of the evolution of droplet size distribution as droplets approach the flame shows that, if substantial evaporation occurs before droplets interact with the flame, an initially monodisperse size distribution becomes bimodal. A secondary sharp peak in the size histogram develops in correspondence of diameters about one order of magnitude smaller than the mean. No evaporation mechanism can account for the development of such bimodality, that can be explained only in terms of a disintegration of droplets into finer fragments of size much smaller than that of the parent. Other evidence in support of this interpretation is offered by the measurements of droplet size-velocity correlation and velocity component distributions, showing that, as a consequence of the ejection process, the droplets responsible for the secondary peak have velocities uncorrelated with the mean flow. The fission is induced by the electric charge. When a droplet evaporates, in fact, the electric charge density on the droplet surface increases while the droplet shrinks, until the so-called Rayleigh limit is reached at which point the repulsion of electric charges overcomes the surface tension cohesive force, ultimately leading to a disintegraton into finer fragments. We report on the first observation of such fissions in combustion environments. If, on the other hand, insufficient evaporation has occurred before droplets enter the high temperature region, there appears to be no significant evidence of bimodality in their size distribution. In this case, in fact, the concentration of flame chemi-ions or, in the case of positively charged droplets, electrons may be sufficient for them to neutralize the charge on the droplets and to prevent disruption.

Gomez, Alessandro↗

The reaction probability of N2O5 with sulfuric acid aerosols at stratospheric temperatures and compositions

We have measured the rate of reaction of N2O5 with H2O on monodisperse, submicrometer H2SO4 particles in a low-temperature flow reactor. Measurements were carried out at temperatures between 225 K and 293 K on aerosol particles with sizes and compositions comparable to those found in the stratosphere. At 273 K, the reaction probability was found to be 0.103 +/- 0.0006, independent of H2SO4 composition from 64 to 81 wt%. At 230 K, the reaction probability increased from 0.077 for compositions near 60% H2SO4 to 0.146 for compositions near 70% H2SO4. Intermediate conditions gave intermediate results except for low reaction probabilities of about 0.045 at 260 K on aerosols with about 78% H2SO4. The reaction probability did not depend on particle size. These results imply that the reaction occurs essentially at the surface of the particle. A simple model for this type of reaction that reproduces the general trends observed is presented. the presence of formaldehyde did not affect the reaction rate.

Fried, Alan↗

Spray combustion at normal and reduced gravity in counterflow and co-flow configurations

Liquid fuel dispersion in practical systems is typically achieved by spraying the fuel into a polydisperse distribution of droplets evaporating and burning in a turbulent gaseous environment In view of the nearly insurmountable difficulties of this two-phase flow, a systematic study of spray evaporation and burning in configurations of gradually increasing levels of complexity, starting from laminar sprays to fully turbulent ones, would be useful. A few years ago we proposed to use an electrostatic spray of charged droplets for this type of combustion experiments under well-defined conditions. In the simplest configuration, a liquid is fed into a small metal tube maintained at several kilovolts relative to a ground electrode few centimeters away. Under the action of the electric field, the liquid meniscus at the outlet of the capillary takes a conical shape, with a thin jet emerging from the cone tip (cone-jet mode). This jet breaks up farther downstream into a spray of charged droplets - the so-called ElectroSpray (ES). Several advantages distinguish the electrospray from alternative atomization techniques: (1) it can produce quasi-monodisperse droplets over a phenomenal size range; (2) the atomization, that is strictly electrostatic, is decoupled from gas flow processes, which provides some flexibility in the selection and control of the experimental conditions; (3) the Coulombic repulsion of homopolarly charged droplets induces spray self-dispersion and prevents droplet coalescence; (4) the ES provides the opportunity of studying regimes of slip between droplets and host gas without compromising the control of the spray properties; and (5) the compactness and potential controllability of this spray generation system makes it appealing for studies in reduced-gravity environments aimed at isolating the spray behavior from natural convection complications. With these premises, in March 1991 we initiated a series of experiments under NASA sponsorship (NAG3-1259 and 1688) in which the ES was used as a research tool to examine spray combustion in counter-flow and co-flow spray diffusion flames, as summarized below. The ultimate objective of this investigation is to examine the formation and burning of sprays of liquid fuels, at both normal and reduced gravity, first in laminar regimes and then in turbulent ones.

Gomez, Alessandro↗

Internal and surface phenomena in metal combustion

Combustion of metals has been widely studied in the past, primarily because of their high oxidation enthalpies. A general understanding of metal combustion has been developed based on the recognition of the existence of both vapor-phase and surface reactions and involvement of the reaction products in the ensuing heterogeneous combustion. However, distinct features often observed in metal particle combustion, such as brightness oscillations and jumps (spearpoints), disruptive burning, and non-symmetric flames are not currently understood. Recent metal combustion experiments using uniform high-temperature metal droplets produced by a novel micro-arc technique have indicated that oxygen dissolves in the interior of burning particles of certain metals and that the subsequent transformations of the metal-oxygen solutions into stoichiometric oxides are accompanied with sufficient heat release to cause observed brightness and temperature jumps. Similar oxygen dissolution has been observed in recent experiments on bulk iron combustion but has not been associated with such dramatic effects. This research addresses heterogeneous metal droplet combustion, specifically focusing on oxygen penetration into the burning metal droplets, and its influence on the metal combustion rate, temperature history, and disruptive burning. A unique feature of the experimental approach is the combination of the microgravity environment with a novel micro-arc Generator of Monodispersed Metal Droplets (GEMMED), ensuring repeatable formation and ignition of uniform metal droplets with controllable initial temperature and velocity. The droplet initial temperatures can be adjusted within a wide range from just above the metal melting point, which provides means to ignite droplets instantly upon entering an oxygen containing environment. Initial droplet velocity will be set equal to zero allowing one to organize metal combustion microgravity experiments in a fashion similar to usual microgravity liquid fuel droplet combustion studies. In addition, the internal compositions of rapidly quenched metal particles will be analyzed using SEM technique. Such compositions are similar to those existing during the combustion and provide new insight on metal combustion processes. The results of this experimental work will be used to model the fundamental mechanisms of metal combustion. Preliminary experimental results on Al and Zr particle combustion at normal gravity are discussed here.

Dreizin, Edward L.↗

Internal and Surface Phenomena in Heterogenous Metal Combustion

The phenomenon of gas dissolution in burning metals was observed in recent metal combustion studies, but it could not be adequately explained by the traditional metal combustion models. The research reported here addresses heterogeneous metal combustion with emphasis on the processes of oxygen penetration inside burning metal and its influence on the metal combustion rate, temperature history, and disruptive burning. The unique feature of this work is the combination of the microgravity environment with a novel micro-arc generator of monodispersed metal droplets, ensuring repeatable formation and ignition of uniform metal droplets with a controllable initial temperature and velocity. Burning droplet temperature is measured in real time with a three wavelength pyrometer. In addition, particles are rapidly quenched at different combustion times, cross-sectioned, and examined using SEM-based techniques to retrieve the internal composition history of burning metal particles. When the initial velocity of a spherical particle is nearly zero, the microgravity environment makes it possible to study the flame structure, the development of flame nonsymmetry, and correlation of the flame shape with the heterogeneous combustion processes.

Dreizin, Edward L.↗

Forced Convection and Sedimentation Past a Flat Plate

The steady laminar flow of a well-mixed suspension of monodisperse solid spheres, convected steadily past a horizontal flat plate and sedimenting under the action of gravity, is examined. It is shown that, in the limit as Re approaches infinity and epsilon approaches 0, where Re is the bulk Reynolds number and epsilon is the ratio of the particle radius a to the characteristic length scale L, the analysis for determining the particle concentration profile has several aspects in common with that of obtaining the temperature profile in forced-convection heat transfer from a wall to a fluid stream moving at high Reynolds and Prandtl numbers. Specifically, it is found that the particle concentration remains uniform throughout the O(Re(exp -1/2)) thick Blasius boundary layer except for two O(epsilon(exp 2/3)) thin regions on either side of the plate, where the concentration profile becomes non-uniform owing to the presence of shear-induced particle diffusion which balances the particle flux due to convection and sedimentation. The system of equations within this concentration boundary layer admits a similarity solution near the leading edge of the plate, according to which the particle concentration along the top surface of the plate increases from its value in the free stream by an amount proportional to X(exp 5/6), with X measuring the distance along the plate, and decreases in a similar fashion along the underside. But, unlike the case of gravity settling on an inclined plate in the absence of a bulk flow at infinity considered earlier, here the concentration profile remains continuous everywhere. For values of X beyond the region near the leading edge, the particle concentration profile is obtained through the numerical solution of the relevant equations. It is found that, as predicted from the similarity solution, there exists a value of X at which the particle concentration along the top side of the plate attains its maximum value phi(sub m) and that, beyond this point, a stagnant sediment layer will form that grows steadily in time. This critical value of X is computed as a function of phi(sub s), the particle volume fraction in the free stream. In contrast, but again in conformity with the similarity solution, for values of X sufficiently far removed from the leading edge along the underside of the plate, a particle-free region is predicted to form adjacent to the plate. This model, with minor modifications, can be used to describe particle migration in other shear flows, as, for example, in the case of crossflow microfiltration.

Pelekasis, Nikolaos A.↗