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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

A photochemical model of ozone interference effects in laser detection of tropospheric OH

Laser-generated interference in the laser-induced fluorescence detection of tropospheric hydroxyl is addressed by a detailed photochemical model. This phenomenon arises through photolysis of ozone by the detection laser and subsequent reaction of O(1D) with H2O to form OH. The approach is direct time integration of the coupled differential equations describing the pertinent chemical reactions, collisional energy transfer, and photolytic and spectroscopic processes, including an assessment of limitations due to uncertainties in the input parameters. The goal is to use the model to quantitatively design OH detection methods so that the experimental results need not rely on such a model for interpretation. Previously reported measurements of tropospheric OH appear to have been contaminated by ozone interference effects and by optical saturation of the monitoring transition. However, suggested improvements can reduce the problem to interference levels below 200,000 OH molecules/cu cm, permitting measurements useful for testing theories of fast tropospheric photochemistry.

Smith, Gregory P.↗
NASA NTRS1990

OH vertical column abundance - Tropical measurements

Measurements of the vertical column abundance of atmospheric hydroxyl (OH) have been made during the period 1987-1989 at the National Weather Service (NWS) station at Moen, Truk, Federated States of Micronesia (7 deg N, 152 deg E). A total of 384 independent data sets was obtained. Tropical OH abundance levels average about 22 percent above corresponding mid-latitude values, with OH levels during late winter and early spring up to 50 percent above those observed at 40 deg N. Stratospheric wind and temperature data obtained from the daily NWS radiosonde data are examined for correlations with the OH results.

Burnett, Clyde R.↗
NASA NTRS1990

Simultaneous, in situ measurements of OH and HO2 in the stratosphere

Stratospheric OH and HO2 radical densities have been measured between 36 and 23 km using a balloon-borne, in situ instrument launched from Palestine, Texas on August 25, 1989. OH is detected using the laser-induced fluorescence technique (LIF) employing a Cu-vapor-laser pumped dye laser coupled with an enclosed-flow detection chamber. HO2 is detected nearly simultaneously by adding NO to the sample flow to convert ambient HO2 to OH. Observed OH and HO2 densities ranged from 8.0 + or - 2.8 x 10 to the 6th and 1.4 + or - 0.5 x 10 to the 7th molec/cu cm, respectively, at 36 km, to 1.4 + or - 0.5 x 10 to the 6th and 3.0 + or - 1.0 x 10 to the 6th at 23 km, where the uncertainty is + or - sigma. The HO2 density exhibits a maximum in the 34-30 km region of 1.7 + or - 0.6 x 10 to the 7th. The data were obtained over a solar zenith angle variation of 51 deg at 36 km to 61 deg at 23 km. O3 and H2O densitites also were measured simultaneously with separate instruments.

Stimpfle, R. M.↗
NASA NTRS1990

Tropospheric OH in a three-dimensional chemical tracer model - An assessment based on observations of CH3CCl3

The paper introduces the representation of tropospheric chemistry allowing for calculation of chemical reaction rates within a chemical tracer model (CTM) simulation with the accuracy comparable to that of a detailed chemical model. The global distribution of tropospheric OH is calculated as a function of time, atmospheric composition, temperature, and solar irradiance. The globally integrated OH concentration weighted by frequency of reaction with CH3CCl3 is evaluated, along with the feasibility of using the observed latitudinal distribution of CH3CCl3 as a test for computed concentrations of OH. Seasonal variations of CH3CCl3 are also considered as a potential test for computed concentrations of OH. It is demonstrated that annual cycles of CH3CCl3 are controlled, or strongly influenced, by dynamical processes at latitudes northward of 25 deg South.

Spivakovsky, C. M.↗
NASA NTRS1991

OH prompt emission in Comet IRAS-Araki-Alcock (1983 VII)

Following Bertaux's (1986) suggestion that photodissociative OH fluorescence can furnish a direct measure of water-density distribution within about 100 km of the cometary nucleus, if sufficiently high spatial resolution is available, attention is presently given to IUE-obtained UV spectra of two comets which differ only as to effective spatial resolution, in order to search for OH prompt emission. IRAS-Araki-Alcock (1983 VII) and Tuttle (1980 XIII) spectra are compared at comparable heliocentric, but differing geocentric, distances; evidence is thereby obtained for OH prompt emission in Comet IRAS-Araki-Alcock, whose implied water-production rate reflects an instantaneous value which may be compared with that derived from OH solar resonance fluorescence.

Budzien, S. A.↗
NASA NTRS1991

Gravity wave-driven fluctuations in OH nightglow from an extended, dissipative emission region

The paper theoretically examines the modification of the characteristics of OH nightglow from an extended emission region by eddy momentum and eddy thermal diffusivities. The reactions that account for OH decay are presented with the additional modifications demonstrating the importance of the upper limit of vertical integration of the extended source. When the vertical wavelengths are smaller than the thickness of the main OH emission region, oscillations cause the effects, particularly at long wavelengths. Eddy diffusion increases the vertical wavelength, and therefore the interference effects related to a finite range of vertical integration can be reduced by accounting for eddy diffusion. It is determined that the effects of eddy momentum and thermal diffusivities are important elements of gravity wave dynamics and should be considered when calculating OH emission perturbations and related variables.

Schubert, G.↗
NASA NTRS1992

KrF laser-induced OH fluorescence imaging in a supersonic combustion tunnel

Planar fluorescence images of OH in a continuous-flow, electrical-resistively heated, high enthalpy, hydrogen-air combustion tunnel, induced by a tunable KrF laser, were recorded. These images were compared to previously recorded fluorescence images induced by a doubled-dye laser under similar conditions. Images induced by the doubled-dye laser system demonstrated a severe distortion caused by absorption and fluorescence trapping. By contrast, images of the fluorescence induced by the tunable KrF laser retained the symmetry properties of the flow. Based on signal-to-noise ratio measurements the yield of the fluorescence induced by the doubled-dye laser is larger than the fluorescence yield induced by the KrF laser. The measurements in the present facility of OH fluorescence induced by the KrF laser were limited by the photon-statistical noise. Based 2 on this result, doubled-dye laser systems are recommended for OH imaging in small and OH lean (less than 10 exp 15/cu cm) facilities. KrF lasers should be selected otherwise.

Quagliaroli, T. M.↗
NASA NTRS1992

Observations of OH in comet Levy with the Nancay radio telescope

Due to extremely favorable excitation conditions, comet Levy (1990c) exhibited in August-September 1990 the strongest OH 18-cm signal ever recorded in a comet at the Nancay radio telescope. This unique opportunity was used to measure the OH satellite lines at 1612 and 1721 MHz, to perform extensive mapping of the OH radio emission and to make a sensitive evaluation of the cometary magnetic field, of the H2O outflow velocity and of the OH production rate.

Bockelee-Morvan, Dominique↗
NASA NTRS1991

8-OH-DPAT does not interfere with habituation to motion-induced emesis in cats

Experiments were performed to determine if suppression of motion-induced emesis (motion sickness) by 8-OH-DPAT altered the development or retention of habituation to the motion stimulus. Cats received 8-OH-DPAT followed by provocative motion on three consecutive treatment days. A drug-free test on the fourth day resulted in an incidence of emesis that was not different from that obtained on the fourth consecutive day of drug-free motion testing. Three consecutive days of treatment with 8-OH-DPAT without motion had no effect on the incidence of motion sickness on the fourth day. It was concluded that suppression of motion sickness by 8-OH-DPAT does not alter the acquisition or retention of habituation.

Lucot, James B.↗
NASA NTRS1994

Ion-assisted tropospheric OH measurement technique

The present technique measures atmospheric OH concentrations by first titrating OH into isotopically labeled H2(exp 34)SO4 by a series of gas phase reactions in an effectively wall-less flow tube reactor on a time-scale which is short in comparison to the OH lifetime. The gas phase H2SO4 concentration is then determined by reacting it with NO3(-)(center dot)HNO3 ions in a flow tube, and subsequently measuring the resulting (HSO4(-))/(NO3(-)) ion ratio. Since the determination of H2SO4 concentration does not depend on the measurement of an absolute photon flux or chemical concentration but rather only on the relative concentration measurement of two fairly similar mass ions in conjunction with a fixed reaction time and reaction rate coefficient, no in-field calibration technique should be required. The ion-assisted OH measurement technique provides a concentration measurement about once each 10 to 20 seconds and had a detection sensitivity less than or equal to 1 x 10(exp 5) molecules/cu cm (2 standard deviations) with an integration time of 5 minutes during the past field study. Typically, the total background signal level is in the low 10(exp 6) molecule/cu cm range with the scatter in this background (or background noise in 5 minutes) in the mid 10(exp 4) molecules/cu cm range.

Eisele, Fred L.↗
NASA NTRS1993

Theoretical reaction pathways for the formation of (Si(OH)5)(1-) and the deprotonation of orthosilicic acid in basic solution

The stability of (Si(OH)5)(1-) is predicted by means of molecular orbital calculations. Si is predicted to be as stable in basic aqueous solutions as hydrated (/OH/3SiO)(1-) and more stable than Si(OH)4 + (OH)(1-). Vibrational analysis of (Si(OH)5)(1-) predicts Raman and IR spectra that are not compatible with the presence of Si in some silicate glasses under ambient temperature compression.

Kubicki, J. D.↗
NASA NTRS1994

Laboratory kinetic studies of OH and CO2 relevant to upper atmospheric radiation balance

During the first year of this program, we have made considerable progress toward the measurement of the dipole moments of vibrationally excited OH radicals. Our primary accomplishments have been 1) the modification of the original slit jet spectrometer for the study of radical species and 2) the observation of infrared chemiluminescence from the vibrationally excited OH radicals formed in the H + ozone reaction in the supersonic jet. We are optimistic that we will soon observe OH* laser induced fluorescence in the jet. Modulation of this fluorescence with microwave radiation in an applied electric field will be the final step required for the precise determination of the vibrational dependence of the OH dipole moment.

Nelson, David D.↗
NASA NTRS2001

Sources, Sinks, and the Distribution of OH in the Lower Stratosphere

Extensive measurement campaigns by the NASA ER-2 research aircraft have obtained a nearly pole-to-pole database of the species that control HOx (OH + HO2) chemistry. The wide dynamic range of these in situ measurements provides an opportunity to demonstrate empirically the mechanisms that control the HOx system. Measurements in the lower stratosphere show a remarkably tight correlation of OH concentration with the solar zenith angle (SZA). This correlation is nearly invariant over latitudes ranging from 70 S to 90 N and all seasons. An analysis of the production and loss of HOx in terms of the rate determining steps of reaction sequences developed by Johnston and Podolske and Johnston and Kinnison is used to clarify the behavior of the system and to directly test our understanding of the system with observations. Calculations using in situ measurements show that the production rate of HOx is proportional to O3 and ultraviolet radiation flux. The loss rate is proportional to the concentration and the partitioning of NOy (reactive nitrogen) and the concentration of HO2. In the absence of heterogeneous reactions, the partitioning of NOy is controlled by O3 and NOx and the concentration of HO2 is controlled by NOy and O3, so that the removal rate of OH is buffered against changes in the correlation of O3 and NOy. The heterogeneous conversion of NO2 to HNO3 is not an important net source of HO, because production and removal sequences are nearly balanced. Changes in NOy partitioning resulting from heterogeneous chemistry have a large effect on the loss rates of HOx, but little or no impact on the measured abundance of OH. The enhanced loss rates at high NO2/HNO3 are offset in the data set examined here by enhanced production rates resulting from increased photolysis rates resulting from the decreased O3 column above the ER-2.

Hanisco, T. F.↗
NASA NTRS2004

TRACE-P OH and HO2 Measurements with the Airborne Tropospheric Hydrogen Oxides Sensor (ATHOS) on the DC-8

The Airborne Tropospheric Hydrogen Oxides Sensor (ATHOS) measures OH and HO2 from the NASA DC-8. This instrument detects OH by laser induced fluorescence (LIF) in detection chambers at low pressure and detects HO2 by chemical conversion with NO followed by LIF detection. The demonstrated detection limit (S/N=2, 5 min.) for OH is about 0.005 pptv (1x10(exp 6)/cu cm at 2 km altitude) and for HO2 is 0.05 pptv (1x10(exp 6)/cu cm at 2 km altitude). We will use ATHOS to measure OH, HO2, and HO2/OH during TRACE- P, analyze these results by comparing them against fundamental relationships and computer models, and publish the analyses. TRACE-P HO(x), measurements will help develop a clearer picture of the atmospheric oxidation and 0 3 production that occur as Asian pollution spreads across the Pacific Ocean.

Brune, William H.↗
NASA NTRS2004

The Companion to the Central Mira Star of the Protoplanetary Nebula OH 231.8+4.2

We present deep optical long-slit spectra of the peculiar protoplanetary nebula (PPN) OH 231.8+4.2 obtained with the 6.5 m Baade Telescope at Las Campanas Observatory (Chile). In addition to the molecular absorption bands characteristic of the M9-10 III star inside OH 231.8+4.2 (QX Pup), we identify lines of the Balmer series in absorption, which do not form in the cool atmospheres of late M-type stars. We also confirm the presence of a blue continuum excess with an intensity that is a factor 30 larger than that expected for an M9-10 III star. Our results indicate the presence of a source hotter than QX Pup illuminating OH 231.8+4.2 that is likely a main-sequence star with spectral type A. We discuss how the formation and nebular evolution of OH 231.8+4.2 could have been affected by the presence of a binary system in its core.

binaries↗
NASA NTRS2016

OH PLIF Visualization of a Premixed Ethylene-fueled Dual-Mode Scramjet Combustor

Hydroxyl radical (OH) planar induced laser fluorescence (PLIF) measurements have been performed in a small-scale scramjet combustor at the University of Virginia Aerospace Research Laboratory at nominal simulated Mach 5 enthalpy. OH lines were carefully chosen to have fluorescent signal that is independent of pressure and temperature but linear with mole fraction. The OH PLIF signal was imaged in planes orthogonal to and parallel to the freestream flow at different equivalence ratios. Flameout limits were tested and identified. Instantaneous planar images were recorded and analyzed to compare the results with width increased dual-pump enhanced coherent anti-Stokes Raman spectroscopy (WIDECARS) measurements in the same facility and large eddy simulation/Reynolds average Navier-Stokes (LES/RANS) numerical simulation. The flame angle was found to be approximately 10 degrees for several different conditions, which is in agreement with numerical predictions and measurements using WIDECARS. Finally, a comparison between NO PLIF non-combustion cases and OH PLIF combustion cases is provided: the comparison reveals that the dominant effect of flame propagation is freestream turbulence rather than heat release and concentration gradients.

Cantu, Luca M. L.↗
NASA NTRS2024

Variations in Apatite F, Cl, and OH Abundances in Primitive Achondrites: Evidence of Fractional Melting?

The apatite group minerals [Ca 5 (PO 4 ) 3 (F,Cl,OH)] are some of the primary mineralogical reservoirs for phosphorus on Earth and a common phosphate mineral within a broad range of extraterrestrial samples. Naturally occurring apatite hosts F, Cl, and OH as essential structural constituents, and all three make up the apatite endmembers fluorapatite, chlorapatite, and hydroxylapatite, respectively. Although apatite is one of the most common phosphate minerals in meteorites and rocks from Earth, it typically occurs at minor to trace abundances. Apatite has been widely used as a mineralogical tool to probe the interiors of both differentiated and undifferentiated parent bodies for information about volatiles; however, little work has been done on apatite F, Cl, and OH abundances of apatite from primitive achondrite meteorites. There are broad differences between apatite X -site chemistry in chondrite parent bodies (typically F-poor) compared to apatite from basaltic rocks from many achondrite parent bodies (Cl-poor, apart from Mars). These differences could indicate that planetary differentiation processes, namely melting, play an important role in the evolution of apatite X -site chemistry. In fact, some ordinary chondrite meteorites that exhibit evidence of minor impact melting have apatite with X -site compositions that are much more F-rich than typical chondrite apatite. McCubbin et al., hypothesized that the F-rich compositions of the apatite in ordinary chondrites affected by impact melting could be the result of apatite partially melting, driving the residual apatite to more F-rich compositions; however, they also indicated that degassing of the more volatile Cl and H may also contribute to the F-enrichment. To further test the partial melting hypothesis, we investigate the F, Cl, and OH (by difference) abundances of apatite from primitive achondrite parent bodies given that they are thought to come from partially differentiated parent bodies that represent residues after partial melting. Consequently, their apatites could provide valuable insights into the effects of melting on apatite X -site chemistry. In this study, we report F and Cl abundances of apatite from a broad array of primitive achondrite meteorites, and we develop a model for apatite fractional melting using known apatite-melt partitioning relationships. Together, we use these results to further elucidate the role of melting on apatite X -site compositions.

F M McCubbin↗
NASA NTRS1973

Kinetics of the reaction OH (v equals 0) plus O3 yields HO2 plus O2

The rate constant (kl) of the reaction OH(v=o) + O3 yields HO2 + O2 measured over the temperature range 220 to 450 K at total pressures between 2 and 5 torr using ultraviolet fluorescent scattering for the detection of OH radicals. An Arrhenius expression was obtained, and the rate constant for the reaction HO2 + O3 yields OH + 2O2 was inferred to be less than 0.1 kl over the entire temperature interval.

Anderson, J. G.↗