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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Metasurface skin cloak

This disclosure provides systems, methods, and devices related to a metasurface skin cloak. In one aspect, a metasurface skin cloak includes a dielectric layer and a plurality of blocks disposed on the dielectric layer. The dielectric layer is disposed over a surface including a feature on the surface. Each block of the plurality of blocks has a shape that is symmetric about two perpendicular axes. The metasurface skin can render the feature on the surface not optically detectable.

Ni, Xingjie↗

Overview of Quantum Sensing Materials and Techniques for Energy Sector Applications

The energy sector has become increasingly dependent upon highly sensitive sensing devices for a wide range of applications. Variables such as temperature, pH, electromagnetic fields, ions, and pressure must be measured with high precision, often in harsh conditions (e.g. highly corrosive environments due to high temperature, pressure and humidity). These sensors are deployed in infrastructure such as transformers, pipelines, mines, nuclear power plants, and other areas to ensure safe operating conditions and uninterrupted, optimized service. Moreover, new opportunities for sensors have emerged due to the expansion of smart grids/meters, driverless vehicles, and the discovery of new oil, gas, and critical mineral deposits. The continued maturation of quantum sensing technologies offers exciting opportunities for quantum-enhanced measurements within the energy sector that may provide significant improvements in sensitivity beyond the classical limit. Here, an overview of established and emerging quantum materials for sensing applications will be provided, from trapped ions to color centers in diamond and silicon carbide. Associated quantum sensing methods for these materials will be discussed, with an emphasis on platforms that are nearing commercial viability. Specific application opportunities within the energy sector for quantum sensors will then be analyzed, including oil/gas discovery, greenhouse gas emission monitoring, pH and ion sensing, current measurement in electric vehicle batteries, and quantum-enhanced spectroscopy. Remaining barriers, such as quantum sensor platform miniaturization and ruggedization, will also be analyzed. A specific project at the National Energy Technology Laboratory involving the functionalization of qubits using metal-organic frameworks for enhanced quantum sensing will also be highlighted. Here, nitrogen vacancy centers (NV) in nanodiamonds, a commercially available qubit with long coherence times and utilizable quantum properties at room temperature, are encapsulated in a controlled way using the metal-organic framework ZIF-8. The ZIF-8 provides a well-defined, porous scaffold that can be controlled to promote the selective uptake of specific target analytes, such as gas molecules or ions. The quantum sensing performance of this composite material is either preserved or enhanced following ZIF-8 encapsulation; the optically detected magnetic resonance response of the NV nanodiamonds with and without the ZIF-8 coating are identical, while the ZIF-8 coating increases the longitudinal spin relaxation lifetime (T1) of the NV centers, an important parameter for spin relaxometry-based quantum sensing experiments. Taken together, these results demonstrate the importance of qubit functionalization as a crucial step for rationally designing high performance quantum sensors.

Crawford, Scott↗

Combining Spectroscopic and Imaging Galaxy Surveys for Improved Measurements of Large-Scale Structure

Galaxy imaging surveys represent a promising opportunity for testing cosmological models but suffer from significant challenges associated with galaxy redshift uncertainty. I present improved techniques for the use of spectroscopic redshifts for measurements of large-scale structure with galaxy imaging surveys. I additionally present the results of the application of these techniques to data from the Sloan Digital Sky Survey (SDSS) and the Dark Energy Survey (DES). The results of my work are photometric redshift measurements of the approximately 100 million galaxies comprising the the DES Year 3 Weak Lensing Source Galaxy Catalog, constraints on parameters of the Lambda-CDM cosmological model based on the gravitational lensing and clustering of the DES Year 3 source and lens galaxy catalogs, an algorithm for propagating uncertainties measured in simulations to analogous measurements on data, and measurements of the incidence of projection effects in optically detected clusters of galaxies. I argue that continued development of the methods I have worked on is a promising path toward a conclusive test of Lambda-CDM with galaxy surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

High-Sensitivity rf Detection Using an Optically Pumped Comagnetometer Based on Natural-Abundance Rubidium with Active Ambient-Field Cancellation

To detect a specific radio-frequency (rf) magnetic field, rf optically pumped magnetometers (OPMs) require a static magnetic field to set the Larmor frequency of the atoms equal to the frequency of interest. However, unshielded and variable magnetic field environments (e.g., an rf OPM on a moving platform) pose a problem for rf OPM operation. Here, we demonstrate the use of a natural-abundance rubidium vapor to make a comagnetometer to address this challenge. Our implementation builds upon the simultaneous application of several OPM techniques within the same vapor cell. First, we use a modified implementation of an OPM variometer based on 87 Rb to detect and actively cancel unwanted external fields at frequencies ≲60 Hz using active feedback to a set of field control coils. In this experiment, we exploit this stabilized field environment to implement a high-sensitivity rf magnetometer using 85 Rb. Using this approach, we demonstrate the ability to measure rf fields with a sensitivity of approximately 9 fT Hz -1/2 inside a magnetic shield in the presence of an applied field of approximately 20 μT along three mutually orthogonal directions. This demonstration opens up a path toward completely unshielded operation of a high-sensitivity rf OPM.

47 OTHER INSTRUMENTATION↗

Optical monitoring to detect contamination of power grid components

A monitoring system includes an array of optical sensors disposed within a transformer tank. Each optical sensor is configured to have an optical output that changes in response to a temperature within the transformer tank. An analyzer is coupled to the array of optical sensors. The analyzer is configured to determine a sensed temperature distribution based on the sensed temperature. The sensed temperature distribution is compared to an expected distribution. Exterior contamination of the transformer tank is detected based on the comparison.

Mostafavi, Saman↗

Optical monitoring to detect contamination of power grid components

A monitoring system includes an array of optical sensors disposed within a transformer tank. Each optical sensor is configured to have an optical output that changes in response to a temperature within the transformer tank. An analyzer is coupled to the array of optical sensors. The analyzer is configured to determine a sensed temperature distribution based on the sensed temperature. The sensed temperature distribution is compared to an expected distribution. Exterior contamination of the transformer tank is detected based on the comparison.

Mostafavi, Saman↗

Detection of Chymotrypsin by Optical and Acoustic Methods

Chymotrypsin is an important proteolytic enzyme in the human digestive system that cleaves milk proteins through the hydrolysis reaction, making it an interesting subject to study the activity of milk proteases. In this work, we compared detection of chymotrypsin by spectrophotometric dynamic light scattering (DLS) and quartz crystal microbalance (QCM) methods and determined the limit of chymotrypsin detection (LOD), 0.15 ± 0.01 nM for spectrophotometric, 0.67 ± 0.05 nM for DLS and 1.40 ± 0.30 nM for QCM methods, respectively. The sensors are relatively cheap and are able to detect chymotrypsin in 3035 min. While the optical detection methods are simple to implement, the QCM method is more robust for sample preparation, and allows detection of chymotrypsin in non-transparent samples. We give an overview on methods and instruments for detection of chymotrypsin and other milk proteases.

59 BASIC BIOLOGICAL SCIENCES↗

System and method of phase-locked fiber interferometry

A system and method are provided for optical homodyne detection in an optical fiber interferometer. A detection signal is obtained by interfering an optical data signal with a phase-modulated optical reference signal. The modulator for the optical reference signal is phase-locked to an oscillatory modulation waveform. In embodiments, the modulator includes a piezoelectric element. In more specific embodiments, the modulator is a piezoelectric optical fiber-stretcher.

Katzenmeyer, Aaron Michael↗

Selection of optimal wavelengths for optical soiling modelling and detection in photovoltaic modules

Soiling impacts the photovoltaic (PV) module performance by decreasing the amount of light reaching the photovoltaic cells and by changing their external spectral response. Currently, the soiling monitoring market is moving toward optical sensors that measure transmittance or reflectance, rather than directly measuring the impact of soiling on the performance of photovoltaic modules. These sensors, which use a single optical measurement, are not able to correct the soiling losses that depend on the solar irradiance spectra and on the spectral response of the monitored PV material. This work investigates methods that can improve the optical detection of soiling by extracting the full soiling spectrum profiles using only two or three monochromatic measurements. Spectral transmittance data, measured with a spectrophotometer and collected during a 46-week experimental soiling study carried out in Jaén, Spain, was analysed in this work. The use of a spectral profile for the hemispherical transmittance of soiled PV glass is found to significantly improve the soiling detection, returning the lowest errors independently of the PV materials and irradiance conditions. In addition, this work shows that it is also possible to select the measurement wavelengths to minimize the soiling loss detection error depending on the monitored PV semiconductor material (silicon, CdTe, a-Si, CIGS and a representative perovskite). The approaches discussed in this work are also found to be more robust to potential measurement errors compared to single wavelength measurement techniques.

14 SOLAR ENERGY↗

Focusing Optics for Axion Detection: Simulating Sensing Enhancements of Photons in InfraBREAD

The Broadband Reflector Experiment for Axion Detection (BREAD) will search for axions, a promising particle candidate for dark matter, in the high mass range of [$10^{-3}$,1]eV. BREAD acts like a telescope for dark matter, using a parabolic reflector to direct axion-induced photons onto a precise focal spot. InfraBREAD is the experimental version designed to detect photons resulting from axions with infrared frequency using a 1mm × 1mm Superconducting Nanowire Singe Photon Detector (SNSPD). However, at this frequency scale two problems arise: 1) the focal spot becomes smeared across an area larger than the size of the SNSPD detector; 2) any millimeter-scale misalignment shifts in the SNSPD can greatly diminish photon signal. This study performed simulations of novel optical configurations of lenses and reflectors placed around the SNSPD to achieve a greater efficiency than the SNSPD alone through both of these effects. One optical setup was identified called the “Parabolo id to Winston Cone (PTW) Configuration,” which exploits the optics of parabolic reflectors to focus incoming photons from the larger area of the smeared focal spot onto the smaller 1mm 2 area of the detector. The PTW configuration demonstrated overall improvements in efficiency by around 10% through misalignment shifts, with a maximal improvement of 55% in one region.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A Synthetic Pathway for Producing Carbon Dots for Detecting Iron Ions Using a Fiber Optic Spectrometer

Iron detection is of growing importance in the critical minerals sector, where unwanted iron ions are typically removed during the processing of target critical metals. The ideal sensor should utilize inexpensive, scalable materials along with a low-cost, robust, and easy-to-use analysis platform. Here, we demonstrate a simple acid–base synthesis of luminescent iron-responsive carbon dots by reacting ethanolamine, phosphoric acid, and m-phenylenediamine. The carbon dots exhibit selective, iron-specific emission quenching, with the ability to detect part-per-billion levels of iron ions even in 0.1 M HCl. After benchmarking the purified materials using a commercial spectrometer, a “low-cost” process is demonstrated in which carbon dots with minimal purification are coupled with a portable fiber-optic spectrometer for analyzing iron content. Carbon dot-coated paper strips are also evaluated as another convenient platform for iron analysis. Taken together, the sensing material and platforms demonstrated here are well-suited for detecting trace quantities of iron in environmentally relevant conditions, with potential applications in tracking iron removal processes during critical mineral production as one exciting area of interest.

acid mine draining↗

Optical monitoring to detect corrosion of power grid components

A corrosion monitoring system includes one or more objects coupled to respective portions of a transformer tank. The one or more objects are configured to corrode before the respective portions of the transformer tank. At least one optical sensor is coupled to each of the objects. The at least one optical sensor has an optical output that changes in response to strain of the object. An analyzer is coupled to the at least one optical sensor. The analyzer is configured to perform one or more of detecting and predicting corrosion of the transformer tank based on the output of the at least one optical sensor.

Teepe, Mark R.↗

Optical monitoring to detect corrosion of power grid components

A corrosion monitoring system includes one or more objects coupled to respective portions of a transformer tank. The one or more objects are configured to corrode before the respective portions of the transformer tank. At least one optical sensor is coupled to each of the objects. The at least one optical sensor has an optical output that changes in response to strain of the object. An analyzer is coupled to the at least one optical sensor. The analyzer is configured to perform one or more of detecting and predicting corrosion of the transformer tank based on the output of the at least one optical sensor.

Teepe, Mark↗

Prompt Detection of Fast Optical Bursts with the Vera C. Rubin Observatory

Abstract The transient optical sky has remained largely unexplored on very short timescales. While there have been some experiments searching for optical transients from minutes to years, none have had the capability to distinguish millisecond fast optical bursts (FOBs). Such very fast transients could be the optical counterparts of fast radio bursts, the prompt emission from γ -ray bursts, or other previously unknown phenomena. Here, we investigate a novel approach to the serendipitous detection of FOBs, which relies on searching for anomalous spatial images. In particular, due to their short duration, the seeing-distorted images of FOBs should look characteristically different than those of steady sources in a standard optical exposure of finite duration. We apply this idea to simulated observations with the Vera C. Rubin Observatory, produced by tracing individual photons through a turbulent atmosphere, and down through the optics and camera of the Rubin telescope. We compare these simulated images to steady-source star simulations in 15 s integrations, the nominal Rubin exposure time. We report the classification accuracy results of a neural network classifier for distinguishing FOBs from steady sources. From this classifier, we derive constraints in duration–intensity parameter space for unambiguously identifying FOBs in Rubin observations. We conclude with estimates of the total number of detections of FOB counterparts to FRBs expected during the 10 yr Rubin Legacy Survey of Space and Time.

79 ASTRONOMY AND ASTROPHYSICS↗

Inverse model based error detection in beamline optics

Optics tuning in transfer lines and LINACs can be challenging due to the fact that multiple combinations of machine settings can lead to the same diagnostic output. Moreover, the lack of a periodic solution can limit the ability to infer optics in the same way as rings from BPM signals. Model based approaches are often used to assist with the optics tuning in combination with optimization or parameter estimation. Here we have developed a novel approach using machine learning inverse models trained on a known configuration to detect variations in quadrupole settings without explicitly including them in the model. This paper shows a comparison of neural network models and linear models on both a simulation based study and experimental studies conducted at the AGS to RHIC transfer line at Brookhaven National Lab.

43 PARTICLE ACCELERATORS↗

Optical activation and detection of charge transport between individual colour centres in diamond

Understanding the capture of charge carriers by colour centres in semiconductors is important for the development of novel forms of sensing and quantum information processing, but experiments typically involve ensemble measurements, often impacted by defect proximity. In this study, we show that confocal fluorescence microscopy and magnetic resonance can be used to induce and probe charge transport between individual nitrogen-vacancy centres in diamond at room temperature. In our experiments, a ‘source’ nitrogen vacancy undergoes optically driven cycles of ionization and recombination to produce a stream of photogenerated carriers, one of which is subsequently captured by a ‘target’ nitrogen vacancy several micrometres away. We use a spin-to-charge conversion scheme to encode the spin state of the source colour centre into the charge state of the target, which allows us to set an upper bound to carrier injection from other background defects. We attribute our observations to the action of unscreened Coulomb potentials producing giant carrier capture cross-sections, orders of magnitude greater than those measured in ensembles.

36 MATERIALS SCIENCE↗

Facile All-Optical Method for In Situ Detection of Low Amounts of Ammonia

As a key precursor for nitrogenous compounds and fertilizer, ammonia affects our lives in numerous ways. Rapid and sensitive detection of ammonia is essential, both in environmental monitoring and in process control for industrial production. Here we report a novel and nonperturbative method that allows rapid detection of ammonia at low concentrations, based on the all-optical detection of surface-enhanced Raman signals. We show that this simple and affordable approach enables ammonia probing at selected regions of interest with high spatial resolution, making in situ and operando observations possible.

09 BIOMASS FUELS↗