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At least 127 records · Page 7

Investigation of soil properties using different techniques of mid‐infrared spectroscopy

Summary Diffuse reflectance spectroscopy (DRF), attenuated total reflectance spectroscopy (ATR) and Fourier transform infrared photoacoustic spectroscopy (PAS) are useful techniques that are commonly used to characterize soil properties. Here, these techniques were used to evaluate individual properties of 1456 paddy soil samples from Nanjing, China, to explore their features in the mid‐infrared range. The diffuse reflectance spectroscopy showed broad and shouldered peaks that ranged from 4000 to 500 cm −1 . Attenuated total reflectance spectroscopy produced main peaks around 1000 cm −1 . Fourier transform infrared photoacoustic spectroscopy spectra showed several moderate intensity peaks in the regions of 4000–2600 and 2500–500 cm −1 . The effective variables (wavenumbers) were selected using an uninformative variable elimination (UVE) algorithm to predict soil pH, and soil organic matter (SOM), total nitrogen (TN) and available phosphorus (AP) contents; it used a self‐adaptive partial least squares model (SAM–PLS). The results showed that selected wavenumbers improved the accuracy of prediction for pH, and SOM, TN and AP contents. For the prediction of pH, ATR spectra showed marginally better performance than the other spectra. The DRF spectroscopy was the optimal method for SOM and TN prediction. Available phosphorus contents were predicted poorly by all three spectra. Furthermore, mid‐infrared incident light paths, absorption modes, sensing styles, as well as peak interference and the prediction model, were the main factors that affected the assessment of soil properties in the three types of spectroscopy. Highlights Soil spectra data were measured with DRF, ATR and PAS spectrometers over the range 4000–500 cm −1 . A UVE algorithm was used to select effective wavenumbers from the full spectrum. The pH, SOM, TN and AP were estimated using three techniques based on a SAM–PLS model. Mid‐infrared incident light paths and absorption modes affected prediction performance of the three techniques.

Ma, F.↗

SU-C-BRB-05: Determining the Adequacy of Auto-Contouring Via Probabilistic Assessment of Ensuing Treatment Plan Metrics in Comparison with Manual Contours

Purpose: To determine if auto-contour and manual-contour—based plans differ when evaluated with respect to probabilistic coverage metrics and biological model endpoints for prostate IMRT. Methods: Manual and auto-contours were created for 149 CT image sets acquired from 16 unique prostate patients. A single physician manually contoured all images. Auto-contouring was completed utilizing Pinnacle’s Smart Probabilistic Image Contouring Engine (SPICE). For each CT, three different 78 Gy/39 fraction 7-beam IMRT plans are created; PD with drawn ROIs, PAS with auto-contoured ROIs, and PM with auto-contoured OARs with the manually drawn target. For each plan, 1000 virtual treatment simulations with different sampled systematic errors for each simulation and a different sampled random error for each fraction were performed using our in-house GPU-accelerated robustness analyzer tool which reports the statistical probability of achieving dose-volume metrics, NTCP, TCP, and the probability of achieving the optimization criteria for both auto-contoured (AS) and manually drawn (D) ROIs. Metrics are reported for all possible cross-evaluation pairs of ROI types (AS,D) and planning scenarios (PD,PAS,PM). Bhattacharyya coefficient (BC) is calculated to measure the PDF similarities for the dose-volume metric, NTCP, TCP, and objectives with respect to the manually drawn contour evaluated on base plan (D-PD). Results: We observe high BC values (BC≥0.94) for all OAR objectives. BC values of max dose objective on CTV also signify high resemblance (BC≥0.93) between the distributions. On the other hand, BC values for CTV’s D95 and Dmin objectives are small for AS-PM, AS-PD. NTCP distributions are similar across all evaluation pairs, while TCP distributions of AS-PM, AS-PD sustain variations up to %6 compared to other evaluated pairs. Conclusion: No significant probabilistic differences are observed in the metrics when auto-contoured OARs are used. The prostate auto-contour needs improvement to achieve clinically equivalent plans.

60 APPLIED LIFE SCIENCES↗

Dual activity of anthocyanidin reductase supports the dominant plant proanthocyanidin extension unit pathway

Proanthocyanidins (PAs) are plant natural products important for agriculture and human health. They are polymers of flavan-3-ol subunits, commonly (-)-epicatechin and/or (+)-catechin, but the source of the in planta extension unit that comprises the bulk of the polymer remains unclear, as does how PA composition is determined in different plant species. Anthocyanidin reductase (ANR) can generate 2,3-cis-epicatechin as a PA starter unit from cyanidin, which itself arises from 2,3-trans-leucocyanidin, but ANR proteins from different species produce mixtures of flavan-3-ols with different stereochemistries in vitro. Genetic and biochemical analyses here show that ANR has dual activity and is involved not only in the production of (-)-epicatechin starter units but also in the formation of 2,3-cis-leucocyanidin to serve as (-)-epicatechin extension units. Differences in the product specificities of ANRs account for the presence/absence of PA polymerization and the compositions of PAs across plant species.

59 BASIC BIOLOGICAL SCIENCES↗

Design, Manufacture, and Experimental Serviceability Validation of ITER Blanket Components

In 2014, the Russian Federation and the ITER International Organization signed two Procurement Arrangements (PAs) for ITER blanket components: 1.6.P1ARF.01 “Blanket First Wall” of February 14, 2014, and 1.6.P3.RF.01 “Blanket Module Connections” of December 19, 2014. The first PA stipulates development, manufacture, testing, and delivery to the ITER site of 179 Enhanced Heat Flux (EHF) First Wall (FW) Panels intended for withstanding the heat flux from the plasma up to 4.7MW/m{sup 2}. Two Russian institutions, NIIEFA (Efremov Institute) and NIKIET, are responsible for the implementation of this PA. NIIEFA manufactures plasma-facing components (PFCs) of the EHF FW panels and performs the final assembly and testing of the panels, and NIKIET manufactures FW beam structures, load-bearing structures of PFCs, and all elements of the panel attachment system. As for the second PA, NIKIET is the sole official supplier of flexible blanket supports, electrical insulation key pads (EIKPs), and blanket module/vacuum vessel electrical connectors. Joint activities of NIKIET and NIIEFA for implementing PA 1.6.P1ARF.01 are briefly described, and information on implementation of PA 1.6.P3.RF.01 is given. Results of the engineering design and research efforts in the scope of the above PAs in 2015–2016 are reported, and results of developing the technology for manufacturing ITER blanket components are presented.

42 ENGINEERING↗

Materials Data on AsP by Materials Project

PAs crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two PAs ribbons oriented in the (0, 1, 0) direction. As3+ is bonded in an L-shaped geometry to two equivalent P3- atoms. Both As–P bond lengths are 2.38 Å. P3- is bonded in a trigonal non-coplanar geometry to two equivalent As3+ and one P3- atom. The P–P bond length is 2.22 Å.

36 MATERIALS SCIENCE↗

Materials Data on AsP by Materials Project

PAs is Halite, Rock Salt structured and crystallizes in the trigonal R3m space group. The structure is two-dimensional and consists of three PAs sheets oriented in the (0, 0, 1) direction. As3+ is bonded in a 6-coordinate geometry to three equivalent P3- atoms. All As–P bond lengths are 2.45 Å. P3- is bonded in a 6-coordinate geometry to three equivalent As3+ atoms.

36 MATERIALS SCIENCE↗

Analysis Results for Sub-Samples of SRS Tanks 30, 32, and 39 to Support Evaluations of the I-129 Inventory

In order to appropriately model and predict the chemical integrity and performance of cementitious materials used for waste immobilization at the Savannah River Site (SRS), it is critical to understand the I-129 solubility and distribution within the tank farm. Iodine in radioactive waste and in environmental media is typically highly mobile and long lived. Iodine is ubiquitous in SRS tank waste and waste forms. The iodine is assumed to be soluble and present at low levels in Performance Assessments (PAs) for SRS Tank Farms, and is one of the dose drivers in the PAs for both the SRS Salt Disposal Facility (SDF) and the H-Area Tank Farm (HTF). Analysis of tank waste samples is critical to understanding the Tank Farm iodine inventory and reducing disposal uncertainty. Higher than expected iodine levels have recently been observed in residual solids isolated from some SRS tanks prior to closure, indicating uncertainty regarding the chemical species involved. If the iodine inventory uncertainty is larger than anticipated, future work may be necessary to reduce the uncertainty. This memorandum satisfies a portion of the work scope identified in Task Plan SRNL-RP-2016-00651. A separate memorandum issued previously, reported historical unpublished I-129 data, a significant portion of which was below detectable analytical limits. This memorandum includes iodine and general chemical analysis results for six archived SRNL samples which were previously reported to have I-129 concentrations below detectable limits. Lower sample dilution factors were used for the current analyses in order to obtain concentrations above detection. The samples analyzed included surface and depth samples from SRS tanks 30, 32, and 39.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Fiscal Year 2018 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site, Nye County, Nevada

The U.S. Department of Energy Standard Disposal Authorization Statement and Tank Closure Documentation (DOE-STD-5002-2017) requires preparation of an Annual Summary Report comparing low-level radioactive waste disposal facilities operations with the Disposal Authorization Statement (DAS) and its supporting technical documents including the performance assessment (PA) and the composite analysis (CA). The fiscal year (FY) 2018 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) was prepared by reviewing planned and discovered changes, waste receipts, monitoring results, research and development (R&D) results, and the status of DAS conditions and issues to assess the validity of the DASs, PAs, and CAs. The Area 3 RWMS was placed in stand-by in 2006 and remained inactive in FY 2018. Resumption of waste disposal operations is planned for FY 2019. No proposed actions, new information, or discoveries affecting the Area 3 RWMS were identified in FY 2018. No significant changes have occurred since preparation of the most recent special analysis, which indicates a continuing reasonable expectation of meeting the PA performance objectives and measures, and the CA dose constraint in DOE O 435.1, “Radioactive Waste Management.” No changes were made to documents supporting the Radioactive Waste Management Basis (RWMB) including the PA, CA, DAS, waste acceptance criteria (WAC), closure plan, monitoring plan, or maintenance plan. Monitoring results for the most recent year with available data, calendar year (CY) 2017, indicate no changes to long-term trends and no results inconsistent with expected performance. R&D results for the Area 3 RWMS Drainage Lysimeter Facility continue to be consistent with the conceptual site model (CSM). All Area 3 RWMS DAS conditions and secondary issues were closed in 2002. The Area 5 RWMS continued disposal operations within the Northern Expansion Area in FY 2018. Eighty-six changes involving proposed actions, new information, or discoveries affecting the Area 5 RWMS PA and CA were screened during FY 2018 in the Unreviewed disposal question (UDQ) process. Twenty-two changes required UDQ evaluations and two changes resulted in unreviewed composite analysis question evaluations. None of the proposed actions, new information, or discoveries had significant impacts on the PAs or CAs. All of the planned changes were implemented. No special analyses were performed, and no changes were made to documents supporting the RWMB including the PA, CA, DAS, WAC, closure plan, monitoring plan, or maintenance plan. Planning continued and construction commenced on development of the Western Expansion Area within the Radioactive Waste Management Complex. All Area 5 RWMS DAS conditions and secondary issues were closed in 2002. The cumulative effects of changes occurring since preparation of the Area 5 RWMS PA and CA were assessed with the current baseline PA/CA model. Model results indicate that there is a reasonable expectation that the PA performance objectives and measures, and the CA dose constraint in DOE O 435.1, “Radioactive Waste Management,” can be met. No PA or CA mean result exceeds 50% of its performance objective. Monitoring results and R&D results continue to be consistent with the CSM. Monitoring results for CY 2017 indicate no changes to long-term trends and no results inconsistent with expected performance. R&D results for the Area 5 RWMS Weighing Lysimeter Facility continue to be consistent with the CSM. The FY 2018 review of Area 3 RWMS and Area 5 RWMS disposal operations supports the following conclusions: The Area 3 and Area 5 RWMS PA and associated CA assumptions and conclusions remain valid based on consideration of all changes identified or planned; The reasonable expectation that the Area 3 and Area 5 RWMSs will meet the performance objectives identified in DOE O 435.1, “Radioactive Waste Management”, remains valid; and The DAS, based on interpretation of the data collected, monitoring results, and other information, continues to be adequate.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Maintenance Plan for the Performance Assessments and Composite Analyses for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site (Rev.3)

U.S. Department of Energy (DOE) Order 435.1, Radioactive Waste Management, requires that performance assessments (PAs) and composite analyses (CAs) for low-level radioactive waste (LLW) disposal facilities be maintained by the responsible field office. This plan describes the activities performed to maintain the PA and the CA for the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) at the Nevada National Security Site (NNSS). The plan is based on DOE Order 435.1 Radioactive Waste Management (DOE 2007), DOE Manual 435.1-1, Radioactive Waste Management Manual (DOE 2011), and DOE Standard DOE-STD-5002-2017, Disposal Authorization Statement and Tank Closure Documentation (DOE 2017). The facility’s Disposal Authorization Statement (DAS) specifies conditions for the continuing operation of a LLW facility. The DAS is issued based on a review of the facility's PA, CA, the maintenance plan, preliminary closure plan, and preliminary monitoring plan. The DAS specifies the limits and conditions on construction, design, operations, and closure of the low-level waste facility based on these reviews. The Maintenance Plan uses an Unreviewed Disposal Question (UDQ)/Unreviewed Composite Analysis Question (UCAQ) change control process to identify, evaluate, and control planned or discovered changes affecting the PA, CA, DAS, or other documents composing the Radioactive Waste Management Basis (RWMB). The UDQ/UCAQ process uses the PA and CA GoldSim models to calculate updated results, assess the significance of changes, and to assess the need to revise the PA, CA, or DAS. In addition to the change control process, the Maintenance Plan requires an annual review of all changes and an annual assessment of the need to revise RWMB documents, plans, and programs. The cumulative effect of all changes is assessed annually by preparing a revised PA and CA baseline model that is used to update PA and CA results. The updated results are used to assess compliance with the PA performance objectives and the CA dose constraint, and to assess the need to revise the PAs, CAs, and other documents, plans, and programs supporting the RWMB. An Annual Summary Report documenting the results and conclusions of the annual review is prepared and submitted to DOE.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Safety Functions and Features, Events and Processes for the E-Area Performance Assessment

The DOE Technical Standard, “Disposal Authorization Statement and Tank Closure Documentation,” (DOE 2017) recommends the use of safety functions and features, events and processes (FEPs) to support development of conceptual models and identification of scenarios to be considered in a performance assessment (PA). The FEP process provides a means to describe how a PA considers and addresses the factors that could influence the performance of key barriers. Understanding the roles of barriers in terms of limiting migration helps to focus on how changes in the system could lead to a situation where those roles cannot be fulfilled and there is the potential for compromised performance. The FEPs screening and review process was used to identify FEPs that are relevant for the EArea Low-Level Waste Facility (LLWF) and specifically those FEPs that could have a detrimental impact on the effectiveness of a given safety function. For this PA, a default list of FEPs developed at the International Atomic Energy Agency (IAEA 2004) and an approach implemented for PAs at the Hanford and Idaho sites (Mehta et al. 2016, DOE-ID 2019) are used to identify processes and events that could influence the effectiveness of a given safety function for the E-Area LLWF (e.g., subsidence can impact the safety function of the cover system and lead to increased infiltration). The Hanford and Idaho PAs represent two of the most recent applications of this approach. The PA evaluates the potential impacts of changes in performance of different features of the system and demonstrates that the safety functions represent multiple and redundant barriers. Barrier analyses, assuming a safety function is not present, also test the robustness of the system in the event of the loss of one or more safety functions. Such evaluations also support a qualitative illustration of the concept of defense in depth. The safety concept for closure of the E-Area LLWF (generically referred to as “E-Area”) encompasses a variety of different features (i.e., administrative controls, natural site features, and engineered barriers) that reduce the potential impacts on human health and the environment from the residual waste that will remain after closure. These features can be represented as a collection of safety functions acting independently and as a system to provide for overall safety. In some applications, there have been attempts to assign numerical expectations to specific safety functions, but that is not the intent in this case. The concept of safety functions is used more qualitatively in two ways for this PA: 1. To illustrate the robustness of the E-Area design, operational practices and closure approach by documenting features that are and are not credited in different modeling cases. 2. To identify the roles of the different features and potential processes and events that could compromise the performance of safety features and need to be considered when developing the modeling approach. This report addresses both safety functions and FEPs for the E-Area PA.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hanford Site Composite Analysis Data Package: Exposure Scenarios and Radionuclide Specific Dose Conversion Factors

This data package summarizes the exposure assumptions, equations, and methods used to calculate radionuclide-specific unit dose factors and the radiological doses for both groundwater and atmospheric pathways as a part of the updated Hanford Site Composite Analysis (CA). An All Pathways Representative Person exposure scenario is considered to evaluate exposure via both groundwater and atmospheric transport pathways. The radiological dose assessments for both groundwater and atmospheric pathways are included in the performance assessments (PAs) for various Waste Management Areas at the Hanford Site. This data package calculates exposure route-specific and total unit dose factors for CA-specific radionuclides of concern based on the exposure assumptions used in the CA and PAs. This data package also presents the results and comparison of the radionuclide-specific unit dose factors based on the exposure assumptions used in the revised Hanford Site Composite Analysis and Hanford Site performance assessments for low-level waste disposal facilities.

61 RADIATION PROTECTION AND DOSIMETRY↗

OmegaWINGS: The First Complete Census of Post-starburst Galaxies in Clusters in the Local Universe

Galaxies that abruptly interrupt their star formation in <1.5 Gyr present recognizable features in their spectra (no emission and Hδ in absorption) and are called post-starburst (PSB) galaxies. By studying their stellar population properties and their location within the clusters, we obtain valuable insights on the physical processes responsible for star formation quenching. We present the first complete characterization of PSB galaxies in clusters at 0.04<z<0.07, based on WINGS and OmegaWINGS data, and contrast their properties to those of passive (PAS) and emission-line (EML) galaxies. For V<20, PSBs represent 7.2 ± 0.2% of cluster galaxies within 1.2 virial radii. Their incidence slightly increases from the outskirts toward the cluster center and from the least toward the most luminous and massive clusters, defined in terms of X-ray luminosity and velocity dispersion. The phase-space analysis and velocity-dispersion profile suggest that PSBs represent a combination of galaxies with different accretion histories. Moreover, PSBs with the strongest Hδ are consistent with being recently accreted. PSBs have stellar masses, magnitudes, colors, and morphologies intermediate between PAS and EML galaxies, typical of a population in transition from being star-forming to passive. Comparing the fraction of PSBs to the fraction of galaxies in transition on longer timescales, we estimate that the short-timescale star formation quenching channel contributes two times more than the long timescale one to the growth of the passive population. Processes like ram-pressure stripping and galaxy–galaxy interactions are more efficient than strangulation in affecting star formation.

79 ASTRONOMY AND ASTROPHYSICS↗

Dynamics at the serine loop underlie differential affinity of cryptochromes for CLOCK:BMAL1 to control circadian timing

Mammalian circadian rhythms are generated by a transcription-based feedback loop in which CLOCK:BMAL1 drives transcription of its repressors (PER1/2, CRY1/2), which ultimately interact with CLOCK:BMAL1 to close the feedback loop with ~24 hr periodicity. Here we pinpoint a key difference between CRY1 and CRY2 that underlies their differential strengths as transcriptional repressors. Both cryptochromes bind the BMAL1 transactivation domain similarly to sequester it from coactivators and repress CLOCK:BMAL1 activity. However, we find that CRY1 is recruited with much higher affinity to the PAS domain core of CLOCK:BMAL1, allowing it to serve as a stronger repressor that lengthens circadian period. We discovered a dynamic serine-rich loop adjacent to the secondary pocket in the photolyase homology region (PHR) domain that regulates differential binding of cryptochromes to the PAS domain core of CLOCK:BMAL1. Notably, binding of the co-repressor PER2 remodels the serine loop of CRY2, making it more CRY1-like and enhancing its affinity for CLOCK:BMAL1.

59 BASIC BIOLOGICAL SCIENCES↗

NASA study of an automated Pilot Advisory System

A Pilot Advisory System (PAS) concept for high-density uncontrolled airports is discussed where the general aviation pilots will be provided with automatic audio voice airport and air traffic advisories within two minute intervals and with mid-air collision warnings whenever such situations arise. Free of manual inputs, the PAS includes the options of fixed-base operator runway select, automatic restart and self-test, and remote inquiry of system status and messages.

Parker, L. C.↗

PMR polyimides from solutions containing mixed endcaps

Previous studies have shown that partial substitution of p-aminostyrene (PAS) for the monomethylester of endo-5-norbornene-2, 3-dicarboxylic acid (NE) lowered the cure temperature of PMR polyimides from 316 to 260 C, but the modified PMR polyimides required higher compression-molding pressures than state-of-the-art PMR-15. In this study PMR polyimides are prepared employing three encaps: NE, PAS, and endo-N-phenyl-5-norbornene-2,3-dicarboximide (PN). The effect of PN addition on the processing characteristics and glass transition temperatures of graphite fiber-reinforced PMR composites is studied. The room temperature and short-time 316 C mechanical properties of the composites are determined. The weight loss and mechanical property retention characteristics of the composites after exposure in air at 316 C are also determined.

Delvigs, P.↗

Kidney cell electrophoresis in space flight: Rationale, methods, results and flow cytometry applications

Cultures of human embryonic kidney cells consistently contain an electrophoretically separable subpopulation of cells that produce high levels of urokinase and have an electrophoretic mobility about 85 percent as high as that of the most mobile human embryonic kidney cells. This subpopulation is rich in large epithelioid cells that have relatively little internal structure. When resolution and throughput are adequate, free fluid electrophoresis can be used to isolate a broad band of low mobility cells which also produces high levels of plasminogen activators (PAs). In the course of performing this, it was discovered that all electrophoretic subpopulations of cultured human embryonic kidney cells produce some PAs and that separate subpopulations produce high quantities of different types of PA's. This information and the development of sensitive assays for this project have provided new insights into cell secretion mechanisms related to fibrinolysis. These advances would probably not have been made without the NASA program to explore fundamental questions of free fluid electrophoresis in space.

Todd, P.↗

Autoclavable addition polyimides for 371 C composite applications

Studies were conducted to improve the thermo-oxidative stability (TOS) of PMR type polyimides by the substitution of para-aminostyrene (PAS) for the nadic ester endcap in second generation PMR polyimides (PMR-2). The nadic endcap which provides the PMR polyimides with their relative ease of fabrication, both by limiting the molecular weight of the prepolymer and by undergoing the final addition cure without volatiles, is also the weak link with regard to TOS. A polyimide formulated with PAS endcaps, called V-CAP, utilizes a two step reaction sequence similar to that of the PMR polyimides and can be easily autoclave molded into low void composite materials. Resin studies included two formulations of both PMR-2 and V-CAP, corresponding to n=9 and n=14 prepolymer stoichiometry. Unidirectional reinforced T40R graphite fiber laminates were fabricated from each of the resins was post-cured in either air at 385 C or nitrogen at 400 C. Composite specimens were aged in air at 371 C and mechanical properties were measured at 371 C before and after exposure.

Vannucci, R. D.↗

A review and update of the NASA aircraft noise prediction program propeller analysis system

The National Aeronautics and Space Administration (NASA) Aircraft Noise Prediction Program (ANOPP) Propeller Analysis System (PAS) is a set of computational modules for predicting the aerodynamics, performance, and noise of propellers. The ANOPP PAS has the capability to predict noise levels for propeller aircraft certification and produce parametric scaling laws for the adjustment of measured data to reference conditions. A technical overview of the prediction techniques incorporated into the system is presented. The prediction system has been applied to predict the noise signature of a variety of propeller configurations including the effects of propeller angle of attack. A summary of these validation studies is discussed with emphasis being placed on the wind tunnel and flight test programs sponsored by the Federal Aviation Administration (FAA) for the Piper Cherokee Lance aircraft. A number of modifications and improvements have been made to the system and both DEC VAX and IBM-PC versions of the system have been added to the original CDC NOS version.

Golub, Robert A.↗