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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Parametric analysis of anodic degradation mechanisms for fast charging lithium batteries with graphite anode

In this work, we report the impact of the temperature-driven synergistically-coupled anodic degradation mechanisms on the electrochemical performance of lithium batteries with graphite anode over multiple cycles. Temperature dependence of electrochemical reactions and damage mechanisms, such as solid electrolyte interface (SEI) growth, lithium plating/stripping, dead lithium storage/dissolution, and film cracking are incorporated into the degradation model. Results of a parametric analysis are presented, evaluating the effects of charging rates (1–6 C), operating temperatures (-15 – 45°C) and electrode design parameters, on the relative performance fade in the lithium-ion battery. Thermo-electrochemical process maps are developed to provide insights into the relationship between electrode performance and failure mechanisms. The simulation results predict a severe capacity loss due to lithium plating at low temperatures, which is further aggravated at high charging rates. A common strategy for mitigating lithium plating, through charging at high temperatures, also results in rapid capacity loss due to accelerated SEI formation. Simulation results are used to identify the combination of operating conditions and electrode design parameters that improve the electrochemical performance of the battery. These results demonstrate an opportunity to design safe and high-performance lithium-ion batteries, guided by anodic degradation models.

Battery design↗

Characteristic constitution model and microstructure of an Al-3.5Cu-1.5Li alloy subjected to thermal deformation

The constitution model and microstructure of 2A97 Al-Li alloy during thermal deformation were investigated. The thermal deformation behavior was dominated by the interaction between work hardening and dynamic softening. The constitution model was constructed to predict the rheology behavior, in which Zener-Holloman equation with a fifth-order polynomial was set to describe the effect of various strains on the material parameters. Processing maps displayed to exist two unstable domains in microstructure (one domain with the temperature range from 300 °C to 370 °C and the strain rate range from 10{sup 0.5} s{sup −1} to 10s{sup −1}, and the other with the temperature range from 380 °C to 500 °C and the strain rate range from 0 s{sup −1} to 10 s{sup −1}). Microstructural characteristics of dynamic recovery (DRV) and dynamic recrystallization (DRX) in the stable domain and local rheology in the unstable domain were observed, respectively. The dynamic precipitation (DPN) of T{sub 1} phases and the interaction between dislocations and Al{sub 20}Cu{sub 2}Mn{sub 3} and Al{sub 3}Zr phases were concluded by high resolution transmission electron microscopy (HRTEM), which was the first experimental evidence for the DPN in 2A97 Al-Li alloy. All these confirmed the occurrence of the continuous dynamic recrystallization during thermal deformation.

36 MATERIALS SCIENCE↗

High-Fidelity Single-Shot Readout for a Spin Qubit via an Enhanced Latching Mechanism

The readout of semiconductor spin qubits based on spin blockade is fast but suffers from a small charge signal. Previous work suggested large benefits from additional charge mapping processes; however, uncertainties remain about the underlying mechanisms and achievable fidelity. In this work, we study the single-shot fidelity and limiting mechanisms for two variations of an enhanced latching readout. We achieve average single-shot readout fidelities greater than 99.3% and 99.86% for the conventional and enhanced readout, respectively, the latter being the highest to date for spin blockade. The signal amplitude is enhanced to a full one-electron signal while preserving the readout speed. Furthermore, layout constraints are relaxed because the charge sensor signal is no longer dependent on being aligned with the conventional (2,0)–(1,1) charge dipole. Silicon donor-quantum-dot qubits are used for this study, for which the dipole insensitivity substantially relaxes donor placement requirements. One of the readout variations also benefits from a parametric lifetime enhancement by replacing the spin-relaxation process with a charge-metastable one. This provides opportunities to further increase the fidelity. The relaxation mechanisms in the different regimes are investigated. This work demonstrates a readout that is fast, has a one-electron signal, and results in higher fidelity. As a result, it further predicts that going beyond 99.9% fidelity in a few microseconds of measurement time is within reach.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

QTG-Finder2: A Generalized Machine-Learning Algorithm for Prioritizing QTL Causal Genes in Plants

Linkage mapping has been widely used to identify quantitative trait loci (QTL) in many plants and usually requires a time-consuming and labor-intensive fine mapping process to find the causal gene underlying the QTL. Previously, we described QTG-Finder, a machine-learning algorithm to rationally prioritize candidate causal genes in QTLs. Although it showed good performance, QTG-Finder could only be used in Arabidopsis and rice because of the limited number of known causal genes in other species. Here we tested the feasibility of enabling QTG-Finder to work on species that have few or no known causal genes by using orthologs of known causal genes as training set. The model trained with orthologs could recall about 64% of Arabidopsis and 83% of rice causal genes when the top 20% ranked genes were considered, which is similar to the performance of models trained with known causal genes. The average precision was 0.027 for Arabidopsis and 0.029 for rice. We further extended the algorithm to include polymorphisms in conserved non-coding sequences and gene presence/absence variation as additional features. Using this algorithm, QTG-Finder2, we trained and cross-validated Sorghum bicolor and Setaria viridis models. The S. bicolor model was validated by causal genes curated from the literature and could recall 70% of causal genes when the top 20% ranked genes were considered. Furthermore, we applied the S. viridis model and public transcriptome data to prioritize a plant height QTL and identified 13 candidate genes. QTL-Finder2 can accelerate the discovery of causal genes in any plant species and facilitate agricultural trait improvement.

59 BASIC BIOLOGICAL SCIENCES↗

Gleeble Compression Tests on As-Cast Alloy 709 Samples

Compression tests were performed on as-cast Alloy 709 (heat 58776-3) using Gleeble ® 3500-GTC system at Oak Ridge National Laboratory (ORNL). The testing temperature range was 900 °C to 1200 °C and the nominal true strain rate range was 0.001/s to 40/s. The tested specimens were delivered to Argonne National Laboratory (ANL) for confirmatory microstructure analysis. The test data were provided to ANL for the construction of the processing map for Alloy 709.

36 MATERIALS SCIENCE↗

OSO-7 observations of high galactic latitude X-ray sources

Six hundred days of observations by the X-ray detectors aboard OSO-7 have been analyzed. All-sky maps of X-ray intensity have been constructed from these data. A sample map is displayed. Seven sources with galactic latitude greater than 10 deg, discovered during the mapping process, are reported, and upper limits are set on other high-latitude sources. The OSO-7 results are compared with those of Uhuru, and an implication of this comparison, that many of the high-latitude sources may be variable, is discussed.

Markert, T. H.↗

X-ray observations of the North Polar Spur

The X-ray enhancement associated with the North Polar Spur (Radio Loop I) was observed by a soft X-ray instrument on OSO 8 during August 1975. This paper presents image-processed maps of the region scanned, a detailed analysis of the X-ray data, and interpretations of the data in terms of supernova remnant models. If the neutral hydrogen ridge, radio continuum ridge, and X-ray emission ridge are all associated, then they cannot all be fitted by a single supernova remnant model because they require different energies of explosion. A reheated supernova remnant model does appear compatible with all the available observations.

Iwan, D.↗

Geology

Three objectives were outlined: (1) global distribution, geometry and composition of continental rock units; (2) morphology and structure of the continental crust; and (3) monitoring selected surface processes. Mapping soil, sediment and rock characteristics for land surfaces requires the use of visible, reflected, thermal and radio parts of the spectrum. Digital topographic data (elevation, slope angle, slope magnitude) are needed to correct reflectance, emission, and radar data. In addition, images of the topographic data provide fundamental information on the morphology and structure of the land.

Arvidson, R.↗

Age discrimination among basalt flows using digitally enhanced LANDSAT imagery

Digitally enhanced LANDSAT MSS data were used to discriminate among basalt flows of historical to Tertiary age, at a test site in Northwestern Saudi Arabia. Spectral signatures compared favorably with a field-defined classification that permits discrimination among five groups of basalt flows on the basis of geomorphic criteria. Characteristics that contributed to age definition include: surface texture, weathering, color, drainage evolution, and khabrah development. The inherent gradation in the evolution of geomorphic parameters, however, makes visual extrapolation between areas subjective. Therefore, incorporation of spectrally-derived volcanic units into the mapping process should produce more quantitatively consistent age groupings.

Blodget, H. W.↗

Agricultural land cover mapping with the aid of digital soil survey data

A study is recounted which assessed the effect of stratifying multidate Landsat MSS data on land cover classification accuracy. The study area covered 49,184 ha (121,534 acres) in Gentry County in northwestern Missouri. A pixel-by-pixel comparison of the two land cover classifications with field-verified land cover indicated improvements in identification of all cover types when land areas were stratified by soils. The introduction of soil map information to the land cover mapping process can improve discrimination of land cover types and reduce confusion among crop types that may be caused by soil-specific management practices, soil-induced crop development differences, and background reflectance characteristics.

Stoner, E. R.↗

Development of the instruments for the Gamma Ray Observatory

The Gamma Ray Observatory (GRO) is to be launched in 1988 by the STS. The GRO will feature four very large instruments: the Oriented Scintillation Spectrometer Experiment (OSSE), the Imaging Compton Telescope (COMPTEL), the Energetic Gamma Ray Experiment Telescope (EGRET) and the Burst and Transient Source Experiment (BATSE). The instruments weigh from 900-1200 kg each, and required the development of specialized lifting and dolly devices to permit their assembly, manipulation and testing. The GRO is intended a{s a tool for studying discrete celestial objects such as black holes, neutron stars and other gamma-ray emitting objects, scanning for nucleosynthesis processes, mapping the Galaxy and other, high energy galaxies in terms of gamma rays, searching for cosmological effects and observing gamma ray bursts. The instruments will be sensitive from the upper end mof X-rya wavelengths to the highest energies possible. Details of the hardware and performance specifications of each of the instruments are discussed.

Madden, J. J.↗

Planning collision free paths for two cooperating robots using a divide-and-conquer C-space traversal heuristic

A method was developed to plan feasible and obstacle-avoiding paths for two spatial robots working cooperatively in a known static environment. Cooperating spatial robots as referred to herein are robots which work in 6D task space while simultaneously grasping and manipulating a common, rigid payload. The approach is configuration space (c-space) based and performs selective rather than exhaustive c-space mapping. No expensive precomputations are required. A novel, divide-and-conquer type of heuristic is used to guide the selective mapping process. The heuristic does not involve any robot, environment, or task specific assumptions. A technique was also developed which enables solution of the cooperating redundant robot path planning problem without requiring the use of inverse kinematics for a redundant robot. The path planning strategy involves first attempting to traverse along the configuration space vector from the start point towards the goal point. If an unsafe region is encountered, an intermediate via point is identified by conducting a systematic search in the hyperplane orthogonal to and bisecting the unsafe region of the vector. This process is repeatedly applied until a solution to the global path planning problem is obtained. The basic concept behind this strategy is that better local decisions at the beginning of the trouble region may be made if a possible way around the 'center' of the trouble region is known. Thus, rather than attempting paths which look promising locally (at the beginning of a trouble region) but which may not yield overall results, the heuristic attempts local strategies that appear promising for circumventing the unsafe region.

Weaver, Johnathan M.↗

Theoretical damping in roll and rolling moment due to differential wing incidence for slender cruciform wings and wing-body combinations

A method of analysis based on slender-wing theory is developed to investigate the characteristics in roll of slender cruciform wings and wing-body combinations. The method makes use of the conformal mapping processes of classical hydrodynamics which transform the region outside a circle and the region outside an arbitrary arrangement of line segments intersecting at the origin. The method of analysis may be utilized to solve other slender cruciform wing-body problems involving arbitrarily assigned boundary conditions. (author)

Adams, Gaynor J↗

New Strategy for Exploration Technology Development: The Human Exploration and Development of Space (HEDS) Exploration/Commercialization Technology Initiative

In FY 2001, NASA will undertake a new research and technology program supporting the goals of human exploration: the Human Exploration and Development of Space (HEDS) Exploration/Commercialization Technology Initiative (HTCI). The HTCI represents a new strategic approach to exploration technology, in which an emphasis will be placed on identifying and developing technologies for systems and infrastructures that may be common among exploration and commercial development of space objectives. A family of preliminary strategic research and technology (R&T) road maps have been formulated that address "technology for human exploration and development of space (THREADS). These road maps frame and bound the likely content of the HTCL Notional technology themes for the initiative include: (1) space resources development, (2) space utilities and power, (3) habitation and bioastronautics, (4) space assembly, inspection and maintenance, (5) exploration and expeditions, and (6) space transportation. This paper will summarize the results of the THREADS road mapping process and describe the current status and content of the HTCI within that framework. The paper will highlight the space resources development theme within the Initiative and will summarize plans for the coming year.

Mankins, John C.↗

Self-Reacting Friction Stir Welding for Aluminum Alloy Circumferential Weld Applications

Friction stir welding is an innovative weld process that continues to grow in use, in the commercial, defense, and space sectors. It produces high quality and high strength welds in aluminum alloys. The process consists of a rotating weld pin tool that plasticizes material through friction. The plasticized material is welded by applying a high weld forge force through the weld pin tool against the material during pin tool rotation. The high weld forge force is reacted against an anvil and a stout tool structure. A variation of friction stir welding currently being evaluated is self-reacting friction stir welding. Self-reacting friction stir welding incorporates two opposing shoulders on the crown and root sides of the weld joint. In self-reacting friction stir welding, the weld forge force is reacted against the crown shoulder portion of the weld pin tool by the root shoulder. This eliminates the need for a stout tooling structure to react the high weld forge force required in the typical friction stir weld process. Therefore, the self-reacting feature reduces tooling requirements and, therefore, process implementation costs. This makes the process attractive for aluminum alloy circumferential weld applications. To evaluate the application of self-reacting friction stir welding for aluminum alloy circumferential welding, a feasibility study was performed. The study consisted of performing a fourteen-foot diameter aluminum alloy circumferential demonstration weld using typical fusion weld tooling. To accomplish the demonstration weld, weld and tack weld development were performed and fourteen-foot diameter rings were fabricated. Weld development consisted of weld pin tool selection and the generation of a process map and envelope. Tack weld development evaluated gas tungsten arc welding and friction stir welding for tack welding rings together for circumferential welding. As a result of the study, a successful circumferential demonstration weld was produced leading the way for future circumferential weld implementation.

Bjorkman, Gerry↗

The Hydrosphere State (Hydros) Satellite Mission: An Earth System Pathfinder for Global Mapping of Soil Moisture and Land Freeze/Thaw

The Hydrosphere State Mission (Hydros) is a pathfinder mission in the National Aeronautics and Space Administration (NASA) Earth System Science Pathfinder Program (ESSP). The objective of the mission is to provide exploratory global measurements of the earth's soil moisture at 10-km resolution with two- to three-days revisit and land-surface freeze/thaw conditions at 3-km resolution with one- to two-days revisit. The mission builds on the heritage of ground-based and airborne passive and active low-frequency microwave measurements that have demonstrated and validated the effectiveness of the measurements and associated algorithms for estimating the amount and phase (frozen or thawed) of surface soil moisture. The mission data will enable advances in weather and climate prediction and in mapping processes that link the water, energy, and carbon cycles. The Hydros instrument is a combined radar and radiometer system operating at 1.26 GHz (with VV, HH, and HV polarizations) and 1.41 GHz (with H, V, and U polarizations), respectively. The radar and the radiometer share the aperture of a 6-m antenna with a look-angle of 39 with respect to nadir. The lightweight deployable mesh antenna is rotated at 14.6 rpm to provide a constant look-angle scan across a swath width of 1000 km. The wide swath provides global coverage that meet the revisit requirements. The radiometer measurements allow retrieval of soil moisture in diverse (nonforested) landscapes with a resolution of 40 km. The radar measurements allow the retrieval of soil moisture at relatively high resolution (3 km). The mission includes combined radar/radiometer data products that will use the synergy of the two sensors to deliver enhanced-quality 10-km resolution soil moisture estimates. In this paper, the science requirements and their traceability to the instrument design are outlined. A review of the underlying measurement physics and key instrument performance parameters are also presented.

Entekhabi, D.↗

HYTHIRM Radiance Modeling and Image Analyses in Support of STS-119, STS-125 and STS-128 Space Shuttle Hypersonic Re-entries

We provide the first geometrically accurate (i.e., 3-D) temperature maps of the entire windward surface of the Space Shuttle during hypersonic reentry. To accomplish this task we began with estimated surface temperatures derived from CFD models at integral high Mach numbers and used them, the Shuttle's surface properties and reasonable estimates of the sensor-to-target geometry to predict the emitted spectral radiance from the surface (in units of W sr-1 m-2 nm-1). These data were converted to sensor counts using properties of the sensor (e.g. aperture, spectral band, and various efficiencies), the expected background, and the atmosphere transmission to inform the optimal settings for the near-infrared and midwave IR cameras on the Cast Glance aircraft. Once these data were collected, calibrated, edited, registered and co-added we formed both 2-D maps of the scene in the above units and 3-D maps of the bottom surface in temperature that could be compared with not only the initial inputs but also thermocouple data from the Shuttle itself. The 3-D temperature mapping process was based on the initial radiance modeling process. Here temperatures were guessed for each node in a well-resolved 3-D framework, a radiance model was produced and compared to the processed imagery, and corrections to the temperature were estimated until the iterative process converged. This process did very well in characterizing the temperature structure of the large asymmetric boundary layer transition the covered much of the starboard bottom surface of STS-119 Discovery. Both internally estimated accuracies and differences with CFD models and thermocouple measurements are at most a few percent. The technique did less well characterizing the temperature structure of the turbulent wedge behind the trip due to limitations in understanding the true sensor resolution. (Note: Those less inclined to read the entire paper are encouraged to read an Executive Summary provided at the end.)

Gibson, David M.↗

Towards an Improved High Resolution Global Long-Term Solar Resource Database

This paper presents an overview of an ongoing project to develop and deliver a solar mapping processing system to the National Renewable Energy Laboratory (NREL) using the data sets that are planned for production at the National Climatic Data Center (NCDC). NCDC will be producing a long-term radiance and cloud property data set covering the globe every three hours at an approximate resolution of 10 x 10 km. NASA, the originators of the Surface meteorology and Solar Energy web portal are collaborating with SUNY-Albany to develop the production system and solar algorithms. The initial result will be a global long-term solar resource data set spanning over 25 years. The ultimate goal of the project is to also deliver this data set and production system to NREL for continual production. The project will also assess the impact of providing these new data to several NREL solar decision support tools.

Stackhouse, Paul W.↗