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At least 127 records · Page 7

Collisional quenching of cometary emission in the 18 centimeter OH transitions

A model of collisional quenching of the OH 2Pi(3/2) J = 3/2 Lambda doublet in cometary comae is presented. It is found that collisions with ions and electrons in the outer coma have a strong quenching effect on the Swings-effect inversion of the Lambda doublet that is responsible for the OH radio emission at 18 cm wavelength. For the conditions of Halley's comet, collisional quenching should lead radio observers to systematically underestimate the OH parent production rate by a factor of approximately 3 relative to its actual value, and in general, radio-derived production rates should always be less than or equal to UV-derived production rates, which are relatively unaffected by this process. The observation that UV production rates exceed those derived by radio techniques is well known; the direct measurement of this ratio, using a consistent coma model, should provide information about the ion and electron content of the cometary coma.

Schloerb, F. Peter↗

An analysis of the coma of comet Bennett 1970 II

Brightness profiles for emission features of H2O(+) in comet Bennett 1970 II are analyzed, taking into account the role of chemical reactions in the coma. By comparing the rates of transport processes derived from the brightness profile with known chemical rate constants, upper limits on the abundances and production rates of H2O, CH4, NH3, and other possible coma constituents are found. The derived upper limit on the H2O production rate inside 10 to the 4th power km is less than the observed OH production rate averaged over the coma of this comet. It is concluded that the brightness profiles of H2O(+) and OH in comet Bennett 1970 II which are presently available are inconsistent with production of OH primarily by photodissociation of H2O molecules sublimating from the nucleus. The existence of an extended source of H2O is not ruled out.

Oppenheimer, M.↗

Effect of solar proton events in 1978 and 1979 on the odd nitrogen abundance in the middle atmosphere

Daily average solar proton flux data for 1978 and 1979 are used in a proton energy degradation scheme to derive ion pair production rates and atomic nitrogen production rates. The latter are computed in a form suitable for inclusion in an atmopheric, two-dimensional, time-dependent photochemical model. Odd nitrogen distributions are computed from the model, including atomic nitrogen production from solar protons, and are compared with baseline distributions. The comparisons show that the average effect of the solar protons in 1978 and 1979 was to cause changes in odd nitrogen only above 10 mbar and at latitudes only above about 50 deg in both hemispheres. The influence of the solar proton-produced odd nitrogen on the local abundance of odd nitrogen depends primarily on the background odd nitrogen abundance as well as the altitude and season.

Jackman, Charles H.↗

Novel duplex vapor: Electrochemical method for silicon solar cells

The scaled up chemical reactor for a SiF4-Na reaction system is examined for increased reaction rate and production rate. The reaction system which now produces 5 kg batches of mixed Si and NaF is evaluated. The reactor design is described along with an analysis of the increased capacity of the Na chip feeder. The reactor procedure is discussed and Si coalescence in the reaction products is diagnosed.

Nanis, L.↗

Hypervolatiles in a Jupiter-Family Comet: Observations of 45P/Honda-Mrkos-Pajdusakova Using iSHELL at the NASA-IRTF

We used the new high spectral resolution cross-dispersed facility spectrograph, iSHELL, at the NASA Infrared Telescope Facility on Maunakea, HI, to observe Jupiter-family comet (JFC) 45P/Honda-Mrkos-Pajdusakova. We report water production rates, as well as production rates and abundance ratios relative to H2O, for eight trace parent molecules (native ices), CO, CH4, H2CO, CH3OH, HCN, NH3, C2H2, and C2H6, on 2 days spanning UT 2017 January 6/7 and 7/8, shortly following perihelion. Trace species were measured simultaneously with H2O and/or OH prompt emission, a proxy for H2O production, thereby providing a robust and consistent means of establishing the native ice composition of 45P. Its favorable geocentric radial velocity (approximately minus 35 kilometers per second) permitted sensitive measures of the "hypervolatiles" CO and CH4, which are substantially undercharacterized in JFCs. Our results represent the most precise ground-based measures of CO and CH4 to date in a JFC, providing a foundation for building meaningful statistics regarding their abundances. The abundance ratio for CH4 in 45P (0.79 percent plus or minus 0.06 percent relative to H2O) was consistent with its median value as measured among Oort Cloud comets, whereas CO (0.60 percent plus or minus 0.04 percent) was strongly depleted. Compared with all measured comets, HCN (0.049 percent plus or minus 0.012 percent) was strongly depleted, CH3OH (3.6 percent plus or minus 0.3 percent) was enriched, and the remaining species were consistent with their respective median abundances. The volatile composition measured for 45P could indicate processing of ices prior to their incorporation into its nucleus. Spatial analysis of emissions suggests enhanced release of more volatile species into the sunward-facing hemisphere of the coma.

DiSanti, Michael A.↗

Formation of organic molecules on Titan

A mechanism is proposed for the formation of complex organic nitrogen compounds in the dense lower atmosphere of Titan. The mechanism is based on three-body association reactions with HCNH(+) ions formed by the reaction of N(+) with CH4, which lead to the production of ethyl cyanide, vinyl cyanide and cyanoacetylene. Calculations for a model atmosphere consistent with the preliminary interpretation of Voyager 1 data for the region of maximum cosmic ray activated chemistry, corresponding to a temperature between 150 and 160 K and a pressure of 20 mbar, are presented which show substantial organic nitrile and hydrogen cyanide production rates. Based on these production rates, it is expected that significant equilibrium concentrations of these compounds will be found on Titan.

Capone, L. A.↗

On the interaction of auroral protons with the earth's atmosphere

The interaction of energetic auroral protons with the atmosphere is investigated. The results of a random number algorithm that describes the proton-hydrogen interconversion reactions as the beam loses energy are adopted to construct an energy deposition curve applicable over a wide range of initial proton energies. Ionization rates and production rates of ejected electrons are computed and emission rates of hydrogen Balmer alpha and beta lines are evaluated using recently available low energy cross-sections.

Rees, M. H.↗

Propagation of cosmic-ray nuclei in a diffusing galaxy with convective halo and thin matter disk

A diffusion model for cosmic-ray propagation in the galaxy that includes the effects of convection in the halo is presented. Calculations are made for 13 primary and secondary nuclei with rigidities between 1 and 1000 GV using interaction loss rates, secondary production rates, and radioactive decay on the basis of recent new cross-section measurements. It is found that, in order to fit the rather weak radial dependence of cosmic-ray protons derived from gamma-ray data, the radial profile of the cosmic-ray sources must also have a weak radial dependence. It is suggested that convection perpendicular to the disk of the Milky Way Galaxy may not be important even at rigidities less than a few GV. The obtained limits on halo thicknesses are consistent with what can be determined for the distribution of cosmic-ray electrons in the halo based on the distribution of radio synchrotron emission in this and other galaxies.

Webber, W. R.↗

Major outburst of periodic Comet Halley at a heliocentric distance of 14 AU

The properties and evolution of the major outburst experienced by Comet Halley at 14 AU during February-March 1991 are studied. It is found that the observed halo is a segment of a conical surface populated by solid particles ejected from a localized, temporarily activated region on the sunlit hemisphere of the spinning nucleus. The total mass of the ejecta was at least 10 exp 12 g and CO was probably the prime driver, accelerating the smallest grains to a terminal velocity of about 45 m/s. The mass loading of the gas flow by particulate matter is enormous, with the mass production rate exceeding the expected production rate of CO by a factor of several tens.

Sekanina, Z.↗

Mars brine formation experiment

The presence of water-soluble cations and anions in the Martian regolith has been the subject of speculation for some time. Viking lander data provided evidence for salt-cemented crusts on the Martian surface. If the crusts observed at the two Viking landing sites are, in fact, cemented by salts, and these crusts are globally widespread, as IRTM-derived thermal inertia studies of the Martian surface seem to suggest, then evaporite deposits, probably at least in part derived from brines, are a major component of the Martian regolith. The composition of liquid brines in the subsurface, which not only may be major agents of physical weathering but may also presently constitute a major deep subsurface liquid reservoir, is currently unconstrained by experimental work. A knowledge of the chemical identity and rate of production of Martian brines is a critical first-order step toward understanding the nature of both these fluids and their precipitated evaporites. Laboratory experiments are being conducted to determine the identity and production rate of water-soluble ions that form in initially pure liquid water in contact with Mars-mixture gases and unaltered Mars-analog minerals.

Moore, Jeffrey M.↗

Evaluation of a Stirling Solar Dynamic System for Lunar Oxygen Production

An evaluation of a solar concentrator-based system for producing oxygen from the lunar regolith was performed. The system utilizes a solar concentrator mirror to provide thermal energy for the oxygen production process as well as thermal energy to power a Stirling heat engine for the production of electricity. The electricity produced is utilized to operate the equipment needed in the oxygen production process. The oxygen production method utilized in the analysis was the hydrogen reduction of ilmenite. Utilizing this method of oxygen production a baseline system design was produced. This baseline system had an oxygen production rate of 0.6 kg/hr with a concentrator mirror size of 5 m. Variations were performed on the baseline design to show how changes in the system size and process rate effected the oxygen production rate.

Colozza, Anthony J.↗

Solar Energy Systems for Lunar Oxygen Generation

An evaluation of several solar concentrator-based systems for producing oxygen from lunar regolith was performed. The systems utilize a solar concentrator mirror to provide thermal energy for the oxygen production process. Thermal energy to power a Stirling heat engine and photovoltaics are compared for the production of electricity. The electricity produced is utilized to operate the equipment needed in the oxygen production process. The initial oxygen production method utilized in the analysis is hydrogen reduction of ilmenite. Utilizing this method of oxygen production a baseline system design was produced. This baseline system had an oxygen production rate of 0.6 kg/hr with a concentrator mirror size of 5 m. Variations were performed on the baseline design to show how changes in the system size and process (rate) affected the oxygen production rate. An evaluation of the power requirements for a carbothermal lunar regolith reduction reactor has also been conducted. The reactor had a total power requirement between 8,320 to 9,961 W when producing 1000 kg/year of oxygen. The solar concentrator used to provide the thermal power (over 82 percent of the total energy requirement) would have a diameter of less than 4 m.

Colozza, Anthony J.↗

Volatile Composition and Outgassing in C/2018 Y1 (IWAMOTO): Extending Detection Limits for High-Resolution IR Cometary Spectroscopy at the NASA-IRTF

We used iSHELL, the powerful high-resolution ( λ/Δλ~ 40,000) cross-dispersed IR spectrograph at the NASA-IRTF to measure the native ice composition and outgassing of moderately bright, long-period comet C/2018 Y1 (Iwamoto) (hereafter Y1) within weeks of its discovery. We measured production rates for H2O, and production rates and abundance ratios relative to H2O for eight trace molecules, including the most complete measure of cometary CH4 achieved to date. Compared with mean abundances measured among comets, our study revealed enriched CH3OH and C2H6 yet depleted CO and C2H2, perhaps indicating highly efficient H- atom addition on interstellar grains prior to their incorporation into the nucleus. The combined high spectral resolving power and broad spectral coverage of iSHELL allowed characterizing cometary composition using only three instrument settings, and its long-slit coverage allowed comparing the spatial distributions of molecular emissions and dust continuum.

DiSanti, M. A.↗

Ecosystem and physiological controls over methane production in northern wetlands

Peat chemistry appears to exert primary control over methane production rates in the Canadian Northern Wetlands Study (NOWES) area. We determined laboratory methane production rate potentials in anaerobic slurries of samples collected from a transect of sites through the NOWES study area. We related methane production rates to indicators of resistance to microbial decay (peat C: N and lignin: N ratios) and experimentally manipulated substrate availability for methanogenesis using ethanol (EtOH) and plant litter. We also determined responses of methane production to pH and temperature. Methane production potentials declined along the gradient of sites from high rates in the coastal fens to low rates in the interior bogs and were generally highest in surface layers. Strong relationships between CH4 production potentials and peat chemistry suggested that methanogenesis was limited by fermentation rates. Methane production at ambient pH responded strongly to substrate additions in the circumneutral fens with narrow lignin: N and C: N ratios (delta CH4/delta EtOH = 0.9-2.3 mg/g) and weakly in the acidic bogs with wide C: N and lignin: N ratios (delta CH4/delta EtOH = -0.04-0.02 mg/g). Observed Q(sub 10) values ranged from 1.7 to 4.7 and generally increased with increasing substrate availability, suggesting that fermentation rates were limiting. Titration experiments generally demonstrated inhibition of methanogenesis by low pH. Our results suggest that the low rates of methane emission observed in interior bogs during NOWES likely resulted from pH and substrate quality limitation of the fermentation step in methane production and thus reflect intrinsically low methane production potentials. Low methane emission rates observed during NOWES will likely be observed in other northern wetland regions with similar vegetation chemistry.

Valentine, David W.↗

Lightcurve of comet Austin(1989c1) and its dust mantle development

Brightness variations of comet Austin(1989c1) were investigated in terms of the variations of water production rate. We translated the visual brightness data into water production rates using Newburn's semi-empirical law. The curve of the water production rates as a function of heliocentric distance was compared with the model calculations that assumed energy balance between the solar incident and vaporization of water. Thermal flow in a dust mantle at a surface of the nucleus is also included in the model. The model calculations including the dust mantle are more favorable for the observed rate than non-dust mantle cases. The extinction after the perihelion passage suggests that the dust mantle developed gradually.

Hasegawa, Hitoshi↗

Highly Depleted Ethane and Mildly Depleted Methanol in Comet 21P/Giacobini-Zinner: Application of a New Empirical nu(sub 2) Band Model for CH30H Near 50 K

Infrared spectra of Comet 2lP/Giacobini-Zinner (hereafter 2IP/GZ) were obtained using NIRSPEC at Keck II on UT 2005 June 03, approximately one month before perihelion, that simultaneously measured H2O, C2H6, and CH3OH. For H2O, the production rate of 3.8 x 10(exp 28) molecules / S was consistent with that measured during other apparitions of 21P/GZ retrieved from optical, infrared, and mm-wavelength observations. The water analysis also provided values for rotational temperature (T(sub rot) = 55(epx +3) /-.2 K) and the abundance ratio of ortho- and para-water (3.00 +/-0.15, implying a spin temperature exceeding 50 K). Six Q-branches in the V7 band of C2H6 provided a production rate (5.27 +/- 0.90 x 10(exp 25)/S) that corresponded to an abundance ratio of 0.139 +/- 0.024 % relative to H2O, confirming the previously reported strong depletion of C2H6 from IR observations during the 1998 apparition, and in qualitative agreement with the depletion in C2 known from optical studies. For CH30H, we applied our recently published ab initia model for the v3 band to obtain a rotational temperature (48(exp + 10) / -7 K) consistent with that obtained for H2O. In addition we applied a newly developed empirical model for the CH30H v2 band, and obtained a production rate consistent with that obtained from the v3 band. Combining results from both v2 and v3 bands provided a production rate (47.5 +/- 4.4 x 10(exp 25) / S) that corresponded to an abundance ratio of 1.25 +/- 0.12 % relative to H2O in 21P/GZ. Our study provides the first measure of primary volatile production rates for any Jupiter family comet over multiple apparitions using high resolution IR spectroscopy.

DiSanti, M. A.↗

Studies of the role of metastables and doubly ionized species in the chemical and thermal structure of the Venusian and Martian ionospheres

Models of the upper atmospheres of Mars and Venus were constructed using Viking and Pioneer Venus data. The neutral densities, with the exception of NO, N(4S), N(2D) and N(2P) were taken from the measured values, along with the neutral, ion, and electron temperatures. Using solar fluxes and relevant cross sections, the production rates of ions and neutral fragments by photo and electron impact processes were computed. These production rates were combined with chemical production rates and loss along with one dimensional transport eddy diffusion, molecular and ambi polar diffusion, and thermal diffusion, to determine the densities of ions and odd nitrogen species. Preliminary calculations show that the chemistry of metastables and doubly ionized species is important in the ionospheres of Mars and Venus. Production of N(+) in metastable reactions is particularly important, and it explains the discrepancy between the measurements of earlier models. Production of CO(+) is also affected. Reactions of O(++) and O(+)(2D) with N2 have important consequences for the escape rate of atomic nitrogen from the Martian atmosphere.

Fox, J. L.↗

Energy yields for hydrogen cyanide and formaldehyde syntheses - The HCN and amino acid concentrations in the primitive ocean

Simulated prebiotic atmospheres containing either CH4, CO, or CO2, in addition to N2, H2O, and variable amounts of H2, were subjected to the spark from a high-frequency Tesla coil, and the energy yields for the syntheses of HCN and H2CO were estimated from periodic (every two days) measurements of the compound concentrations. The mixtures with CH4 were found to yield the highest amounts of HCN, whereas the CO mixtures produced the highest yields of H2CO. These results model atmospheric corona discharges. From the yearly energy yields calculated and the corona discharge available on the earth, the yearly production rate of HCN was estimated; using data on the HCN production rates and the experimental rates of decomposition of amino acids through the submarine vents, the steady state amino acid production rate in the primitive ocean was calculated to be about 10 nmoles/sq cm per year.

Stribling, Roscoe↗