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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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122 records · Page 7

Future North Atlantic tropical cyclone intensities in thermodynamically modified historical environments

Tropical cyclones (TCs) rank as the deadliest and most financially crippling natural disasters in the United States for the last half-century. It is imperative to assess potential shifts in TC intensity within the paradigm of an evolving climate. In this study, we have modeled the intensities of 620 historical TC events in the North Atlantic Basin using the Risk Analysis Framework for Tropical Cyclones (RAFT)'s deep learning intensity model. By applying a thermodynamic warming signal extrapolated from Global Climate Models, we rerun historical events under eight different future climate scenarios, providing a spectrum of potential TC intensity outcomes. One of the future simulations indicates a staggering 43% increase in the number of major hurricanes, underscoring the critical impact of climate change on TC intensity. Additionally, an interactive dashboard has been created to enable users to explore individual storm simulations and understand the influence of future climate signals on environmental conditions of TC development and resulting TC intensities. This dataset and the user-friendly tool offer invaluable resources for systematic exploration of the discrete effects that changes in the air-sea thermodynamic state have on the intensities of TCs.

Climate Change↗

Future North Atlantic tropical cyclone intensities in thermodynamically modified historical environments

Tropical cyclones (TCs) have ranked as the deadliest and most financially crippling natural disasters in the United States. It is imperative to assess potential shifts in TC intensity within the paradigm of an evolving climate. In this study we apply a fixed-constraint storyline approach that holds storm tracks and initial conditions constant to probe future TC intensity in the North Atlantic Basin. First, we simulate 618 historical TC events using the Risk Analysis Framework for Tropical Cyclones (RAFT)'s deep-learning intensity model. Next, we apply warming signals derived from eight CMIP6 climate scenarios and rerun each event to explore how intensities respond across scenarios. Finally, we develop an interactive dashboard that allows users to explore individual storm simulations and the scenario-modified environmental drivers. Together, this dataset and tool provide a clear, illustrative way to investigate how TC intensity responds to changes in air-sea state.

Climate Change↗

LSST Commissioning Camera

The LSST Commissioning Camera (LSSTComCam) was mounted on the Simonyi Survey Telescope in August 2022 and observed for seven weeks in late 2024 until it was removed from the telescope in December 2024. It is a smaller, fully functional version of LSSTCam, with only the central raft of 9 4k x 4k CCDs (all ITL sensors) and comprising 144 megapixels. Every CCD has 16 amplifiers, each reading 1 million pixels. LSSTComCam was designed to enable end-to-end testing of the observatory’s systems, including data acquisition, image processing, and observatory operations.

79 ASTRONOMY AND ASTROPHYSICS↗

Resilient Autonomous Wind Farms: Preprint

With the advent of an increasing number of control strategies that seek to optimize wind turbine performance on a farm-level, taking account of individual wind turbine information to achieve wind farm-level objectives has become an increasingly important goal. Methods for controlling wind turbines on an individual and farm level have seen significant development, and an abundance of new implementations for gathering and using data from turbines have created potential for novel control mechanisms which can further optimize the performance and delivery characteristics of a wind farm. A key element of making these wind farms more efficient is to develop reliable algorithms that use local sensor information that is already being collected, such as supervisory control and data acquisition (SCADA) data, local meteorological stations, and nearby radars/sodars/lidars. Making use of information from all wind turbines in a wind farm can enable such approaches as determining the atmospheric conditions across the farm, improving fault-finding, and enabling more efficient overall control of farm-wide optimizations through mechanisms such as wake-steering. However, these approaches typically involve a centralized communications and control center. In order to ensure the resilient operation of the farm, it is necessary to develop an approach which distributes the calculation and communication amongst multiple nodes throughout the farm. In this fashion, a redundant, robust, and secure network can be created, which can tolerate faults in calculation, communication, and even external attacks which seek to disrupt the operation of the wind farm. This paper introduces the use of the Raft Byzantine Fault Tolerance algorithm in the implementation of autonomous control of a wind farm. This implementation will allow for fault tolerance for malfunctioning nodes, sensors, transmitters, and connectors. This approach is equally extensible to account for malicious actors. It will be shown to achieve overall consensus, provided the number of faults/malicious nodes is less than 3$n$+1, where $n$ is the number of turbine cluster faults which may occur, and to be robust in the face of multiple arbitrary faults.

autonomous↗

Amphiphilic Block Copolymers for Flocculation and Hydrophobization of Legacy Waste Suspensions in Flotation Driven Dewatering Operations - 20162

Flotation has been effectively demonstrated as a low footprint, high efficiency separation process when utilising simple anionic surface modifying agents such as sodium dodecyl sulphate (SDS). These agents increase hydrophobicity to remove suspended cationic surface charged particulates such as Mg(OH){sub 2} from waste suspensions similar to those at British nuclear fuel management sites- where corrosion processes have degraded fuel cladding. The technology is advantageous as it could effectively be retrofitted into existing waste management facilities at nuclear waste management sites such Sellafield and Hanford as the simplicity (no moving parts) and size of this technology coupled with low cost of construction could be rapidly deployed to aid in risk and hazard reduction decommissioning operations with minimum impact to secondary waste generation. Previously, sodium dodecyl sulphate has been deployed as a collector agent to increase the hydrophobicity of Mg(OH){sub 2} suspended particles, achieving a maximum particulate extraction percentage of 93%. To achieve further particulate extraction, flotation performance has been determined to be a function of the hydrodynamic limitations extracting fine material (>20 μm). Fine particulates have been shown in the minerals industry to have an inability to overcome slipstreams created from rising bubbles in flotation cells, likely due to the low mass and thus momentum of the colloidal material, preventing interaction between the hydrophobized particles and air-water interfaces (bubbles). To combat this mass transfer resistance poly(acrylic acid)-block-poly(n-butyl acrylate) amphiphilic diblock copolymers were synthesised via reversible addition-fragmentation chain-transfer (RAFT) polymerisation. The anticipated mode of action of these polymers involves the hydrophilic poly(acrylic acid) block polymer acting as a flocculation agent to increase the mass of the aggregates, and the hydrophobic poly(n-butyl acrylate) modifies the hydrophobicity of the resulting flocs. The concentration of this polymer (termed a macro-collector) was varied and the change in particle size distribution of the particulate suspension was analysed using static light scattering. The flotation performance was then characterised by several methods including percentage particulate recovery, volume reduction factor and residual bulk particulate concentration. This was then benchmarked against the traditional surfactant collector agent SDS. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Customized Nanostructured Ceramics via Microphase Separation 3D Printing

To date, the restricted capability to fabricate ceramics with independently tailored nano- and macroscopic features has hindered their implementation in a wide range of crucial technological areas, including aeronautics, defense, and microelectronics. In this study, a novel approach that combines self- and digital assembly to create polymer-derived ceramics with highly controlled structures spanning from the nano- to macroscale is introduced. Polymerization-induced microphase separation of a resin during digital light processing generates materials with nanoscale morphologies, with the distinct phases consisting of either a preceramic precursor or a sacrificial polymer. By precisely controlling the molecular weight of the sacrificial polymer, the domain size of the resulting material phases can be finely tuned. Pyrolysis of the printed objects yields ceramics with complex macroscale geometries and nanoscale porosity, which display excellent thermal and oxidation resistance, and morphology-dependent thermal conduction properties. This method offers a valuable technological platform for the simplified fabrication of nanostructured ceramics with complex shapes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Induced seismicity red-light thresholds for enhanced geothermal prospects in the Netherlands

Prospects for geothermal energy in the Netherlands have renewed concerns around induced earthquakes. Risks from induced earthquakes are managed by traffic light protocols (TLPs), where the red-light is chosen as the stop-point before exceeding a tolerance to risk. Here, we simulate post-shut-in earthquake scenarios based on realistic information for the Netherlands. We focus on three risk metrics: aggregates like nuisance and damage impacts and also local personal risk (LPR) – a likelihood of building collapse fatality for an individual. Our results show that the severity of these risks varies spatially by orders of magnitude. Prior induced seismicity (e.g., the 2012 Huizinge event) provides a reference baseline to calibrate the Dutch earthquake risk tolerances. We find that these calibrated risk tolerances are similar to those observed in North America, suggesting an underlying sociological ‘license to operate.’ Furthermore, the use of calibrated risk tolerances results in nuisance concerns completely eclipsing the other two metrics. We compare our results to a hypothetical Groningen geothermal operation and find that our approach sets red-light thresholds approximately one magnitude unit below the ML 3.6 Huizinge event. Overall, our results provide a first-order recommendation for red-light thresholds and proactive management of Dutch enhanced geothermal induced seismicity.

15 GEOTHERMAL ENERGY↗

Slender-body approach for computing second-order wave loads in the frequency domain

This work presents a slender-body approach to evaluate the second-order wave loads acting on a floating structure in the frequency domain. The approach is in the same spirit as the common use of Morison’s equation to approximate the wave loads without solving the radiation/diffraction problem. To do so, we employ Rainey’s equation, which can be seen as an extension of the inertial part of Morison’s equation to include nonlinear effects. We introduce modifications to Rainey’s formulation in order to evaluate wave kinematics at the mean body position instead of the original approach of considering instantaneous displacements. We also propose a simple approximation to partially account for wave scattering effects on the second-order loads based on the analytical solution of a surface-piercing bottom-mounted vertical circular cylinder. Though limited to structures composed of cylinders, this slender-body approach is orders of magnitude faster than computing second-order wave coefficients with a radiation/diffraction code. We implemented this approach for difference-frequency (slow drift) loads in an open-source frequency-domain floating wind turbine model. We present comparisons against results obtained with radiation/diffraction theory for three reference floating wind turbine designs: the OC3-Hywind spar, the OC4-DeepCwind semisubmersible, and the VolturnUS-S semisubmersible. In general, the results show that the proposed slender-body approach with the correction to approximate wave scattering effects provides useful estimations of the difference-frequency wave loads and the resulting motions of the floater.

17 WIND ENERGY↗

Miktoarm Star Polymers: Synthesis and Applications

Polymers with precisely controlled structure and function are in high demand across a diverse array of applications spanning the life sciences and nanotechnology. One prototypical example is a class of branched block copolymers known as miktoarm stars (μ-stars), which contain two or more arm compositions connected at a common junction. Miktoarm stars have attracted considerable attention since their physical properties can be different from conventional linear block copolymers. This perspective highlights the latest developments and historical context in the field of miktoarm star polymers, including design strategies, synthetic techniques, and advanced characterization tools used to avoid common preparation pitfalls and tailor properties for emerging applications. Furthermore, our contemporary perspective on μ-star polymers is a resource for inspiring future research into this exciting class of materials at the intersection of chemistry, physics, and advanced technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigating the Role of Polymer Architecture in Poly(methyl methacrylate) Depolymerization

Advanced architectures in polymers have garnered traction within the last two decades due to their distinct and tunable properties compared to linear analogs. However, the effects of architecture on nascent polymethacrylate depolymerization strategies remain underexplored. Herein, we investigate the depolymerization behavior of poly(methacrylate)-based star copolymers synthesized via a core-first approach. By incorporating either labile chain-end or pendent-group triggers, we demonstrate the first direct comparison of bulk depolymerization behaviors in star versus linear methacrylate copolymers under matched conditions. While pendent-triggered systems required higher loadings of N-(methacryloxy)phthalimide methacrylate (PhthMA) to achieve similar mass loss compared to linear copolymers, chain-end-initiated depolymerization showed enhanced efficiency of monomer liberation in the star topology. Furthermore, these findings highlight the importance of considering macromolecular architecture in designing sustainable polymers and provide actionable guidelines for installing depolymerization triggers based on polymer topology.

Copolymers↗

Anisotropic Dynamics and Mechanics of Macromolecular Crystals Containing Lattice-Patterned Polymer Networks

The mechanical and functional properties of many crystalline materials depend on cooperative changes in lattice arrangements in response to external perturbations. However, the flexibility and adaptiveness of crystalline materials are limited. Additionally, the bottom-up, molecular-level design of crystals with desired dynamic and mechanical properties at the macroscopic level remains a considerable challenge. To address these challenges, we had previously integrated mesoporous, cubic ferritin crystals with hydrogel networks, resulting in hybrid materials (polymer integrated crystals or PIX) which could undergo dramatic structural changes while maintaining crystalline periodicity and display efficient self-healing. Here, the dynamics and mechanics of these ferritin-PIX were devoid of directionality, which is an important attribute of many molecular and macroscopic materials/devices. In this study, we report that such directionality can be achieved through the use of ferritin crystals with anisotropic symmetries (rhombohedral or trigonal), which enable the templated formation of patterned hydrogel networks in crystallo. The resulting PIX expand and contract anisotropically without losing crystallinity, undergo prompt bending motions in response to stimuli, and self-heal efficiently, capturing some of the essential features of sophisticated biological devices like skeletal muscles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Projecting U.S. coastal storm surge risks and impacts with deep learning

Storm surge is one of the deadliest hazards posed by tropical cyclones (TCs), yet assessing its current and future risk is difficult due to the phenomenon’s rarity and physical complexity. Recent advances in artificial intelligence applications to natural hazard modeling suggest a new avenue for addressing this problem. We develop a deep learning storm surge model to efficiently estimate coastal surge risk in the United States from 900 000 synthetic TC events, accounting for projected changes in TC behavior and sea levels. The derived historical 100 year surge (the event with a 1% yearly exceedance probability) agrees well with historical observations and other modeling techniques. When coupled with an inundation model, we find that heightened TC intensities and sea levels by the end of the century result in a 50% increase in population at risk. Key findings include markedly heightened risk in Florida, and critical thresholds identified in Georgia and South Carolina.

RAFT↗

The Impacts of Geothermal Operations on Groundwater

In 2018, the Bureau of Land Management's (BLM's) National Renewable Energy Coordination Office, through its Geothermal Program, funded the National Renewable Energy Laboratory (NREL) to review existing literature for potential cases in which geothermal wells contributed to groundwater contamination. NREL conducted an extensive literature review but was unable to find any cases of groundwater contamination resulting from geothermal operations. This paper includes cases in which wellbore failures did not affect groundwater and areas where geothermal operations may have affected other resources, such as hot springs and geysers.

BLM↗