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At least 127 records · Page 7

Quantitative and sensitive analysis of CN molecules using laser induced low pressure He plasma

We report the results of experimental study on CN 388.3 nm and C I 247.8 nm emission characteristics using 40 mJ laser irradiation with He and N{sub 2} ambient gases. The results obtained with N{sub 2} ambient gas show undesirable interference effect between the native CN emission and the emission of CN molecules arising from the recombination of native C ablated from the sample with the N dissociated from the ambient gas. This problem is overcome by the use of He ambient gas at low pressure of 2 kPa, which also offers the additional advantages of cleaner and stronger emission lines. The result of applying this favorable experimental condition to emission spectrochemical measurement of milk sample having various protein concentrations is shown to yield a close to linear calibration curve with near zero extrapolated intercept. Additionally, a low detection limit of 5 μg/g is found in this experiment, making it potentially applicable for quantitative and sensitive CN analysis. The visibility of laser induced breakdown spectroscopy with low pressure He gas is also demonstrated by the result of its application to spectrochemical analysis of fossil samples. Furthermore, with the use of CO{sub 2} ambient gas at 600 Pa mimicking the Mars atmosphere, this technique also shows promising applications to exploration in Mars.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Reproducibility of Radiokrypton in Deep Desert Aquifers: Insights from a Decade of Research

Great technical advances have been achieved since the first atom-trap trace analysis (ATTA) -based radiokrypton application in Egypt, where 1 Myr old groundwater was discovered. Beyond advances in ATTA measurement capabilities, including reduction in sample size, analysis duration, and analytical uncertainty, major progress has been achieved over the past two decades in the sample collection and preparation techniques. These advances paved the expansion of ATTA-based noble gas applications to many other aquifers worldwide, illuminating the nature and flow pattern of deep groundwater systems. While the potential of this new analytical technique for old groundwater dating is well recognized, another important aspect yet to be examined is the reproducibility of radiokrypton in aquifers over time, i.e., how representative is a discrete groundwater sample, collected at a specific time and location, for the natural groundwater system? The likelihood of a negative answer is increased by flow-field disturbance in aquifers following massive groundwater abstraction. Here, in this work, we present repeated 81 Kr sampling and measurements in twenty-one sites over Israel, mostly of deep (up to 1 km) wells tapping confined aquifers in the arid to hyperarid Negev desert. The results demonstrate that radiokrypton measurements are indeed reproducible, even in cases where samples were collected as long as nine years apart and from highly productive (∼1 Mm 3 /yr order) pumping wells. Furthermore, many of the repeated measurements in this study (17 out of the 21 sites) were conducted with different ATTA Instruments in two different laboratories using slightly different sampling, preparation, and analysis techniques, yet with an overall good agreement. The consistency in the ATTA-based 81 Kr-dating results over time highlights the robustness of this state-of-the-art technique as a tool to unravel groundwater flow patterns and encourages further applications to many other yet-to-be-explored deep aquifers.

atom-trap trace analysis↗

Improved cache performance in Monte Carlo transport calculations using energy banding

We present an energy banding algorithm for Monte Carlo (MC) neutral particle transport simulations which depend on large cross section lookup tables. In MC codes, read-only cross section data tables are accessed frequently, exhibit poor locality, and are typically too much large to fit in fast memory. Thus, performance is often limited by long latencies to RAM, or by off-node communication latencies when the data footprint is very large and must be decomposed on a distributed memory machine. The proposed energy banding algorithm allows maximal temporal reuse of data in band sizes that can flexibly accommodate different architectural features. The energy banding algorithm is general and has a number of benefits compared to the traditional approach. In the present analysis we explore its potential to achieve improvements in time-to-solution on modern cache-based architectures.

97 MATHEMATICS AND COMPUTING↗

A Comprehensive Analysis of Real-World Accelerometer Data Quality in a Global Smartphone-based Seismic Network

The proliferation of low-cost sensors in smartphones has facilitated numerous applications; however, large-scale deployments often encounter performance issues. Sensing heterogeneity, which refers to varying data quality due to factors such as device differences and user behaviors, presents a significant challenge. In this research, we perform an extensive analysis of 3-axis accelerometer data from the MyShake system, a global seismic network utilizing smartphones. We systematically evaluate the quality of approximately 22 million 3-axis acceleration waveforms from over 81 thousand smartphone devices worldwide, using metrics that represent sampling rate and noise level. We explore a broad range of factors influencing accelerometer data quality, including smartphone and accelerometer manufacturers, phone specifications (release year, RAM, battery), geolocation, and time. Our findings indicate that multiple factors affect data quality, with accelerometer model and smartphone specifications being the most critical. In addition, we examine the influence of data quality on earthquake parameter estimation and show that removing low-quality accelerometer data enhances the accuracy of earthquake magnitude estimation.

58 GEOSCIENCES↗

Time Dependence of the IBEX Ribbon and the Globally Distributed Energetic Neutral Atom Flux Using the First 9 Years of Observations

Observations from the Interstellar Boundary Explorer (IBEX) of energetic neutral atoms (ENAs) reveal two populations, those emitted from a narrow (~20°–40°) ribbon that is centered on the local interstellar magnetic field, and a globally distributed flux (GDF) that is controlled by processes in the heliosheath. This is a third study utilizing a previously developed technique to separate ENA emissions in the ribbon from the GDF. In the first ribbon separation study, we analyzed the first year of IBEX data at the energies of 0.7 keV and above; the second study analyzed data down to 0.2 keV using the first five years of IBEX data. Here, we utilize the separation analysis from 0.7 keV and above to study time evolution in 3 year intervals over the first nine years of IBEX data. This study is the first to reveal the global time evolution of the GDF distinct from that of the IBEX ribbon. We show that the time evolution of the GDF within 40° of the upwind pressure maximum is driven by changes in the solar wind ram pressure through compression and rarefaction in the heliosheath. In contrast, the GDF is relatively stable in the region centered on the heliotail downwind with respect to the interstellar flow. The evolution of the IBEX ribbon is observed to have a time lag with respect to the upwind GDF evolution, likely due to the secondary (neutral) solar wind source. The time lag observed in the ribbon evolution is consistent with the generation of ions retained for several years beyond the heliopause. These observations lend further support to secondary solar wind models of the IBEX ribbon, but also require that there is a significant several year time lag for reneutralization of ions that form the IBEX ribbon. We use this study of the 9 year separation of the IBEX ribbon from the globally distributed flux to prepare for a formal IBEX data release of ribbon and globally distributed flux maps to the heliophysics community.

79 ASTRONOMY AND ASTROPHYSICS↗

Model-based approaches to calibration and certification of nondestructive assay systems - 15615

Increasingly, model-based methods founded in physics are employed to calibrate, or extend the calibration of, nondestructive assay (NDA) systems used to characterize materials contaminated with plutonium, uranium, and other radioactive isotopes. In addition, modeling and mathematical methods are used to establish system parameters, correction factors, and measurement uncertainty components in NDA measurements. The methods combine the characteristics of the measurement configuration (detector structure, object shape and dimensions, source-detector distance and orientation, and collimation), generator knowledge of the waste composition, and known physical properties of the system in order to establish these parameters, factors, and components. These methods offer several important benefits over traditional methods used to test, calibrate, operate, and certify radiation measurement systems. First, instruments can be set up and put into service more quickly and correctly using a model-based approach. Second, calibrations can be performed, tested, and modified with reduced use of plutonium and uranium standards when modeling and mathematical methods are employed. Also, modeled approaches avoid calibration error resulting from heterogeneous source distribution. Moreover, the parameters can be installed quickly and simply in an office setting without the need for the safety, security, and safeguards considerations that are present when standards are used. Calibrations can also be tailored to fit unique or nonstandard container configurations (for example, over-packed drums), new container types, or specialized matrices. Finally, when modeling methods are applied, correction factors and measurement uncertainty elements can be developed, tested, and validated relatively quickly and without the need for surrogate matrix materials and a large number of test measurements. A combined gamma and neutron NDA system has recently been moved from Idaho National Laboratory to the TA 55 facility at Los Alamos National Laboratory (LANL). The system will be used to assay transuranic waste packaged in drums. After the move, the system was modified to replace degraded components and improve system performance. Afterwards, it was set up to assay different container types and to extend the calibration range. Model-based approaches were used to adapt the system to its new purpose at LANL. This report will describe the setup, calibration, and certification of the combined system at LANL Included in this discussion will be the measurement applications and details of the measurement methods. The steps in these processes that involved the use of modeling and mathematical calculations to replace or supplement more traditional methods will be identified and discussed. Finally, an overarching discussion of the methods and advantages of model-based methods to establish the properties of NDA systems will be presented. We conclude that validated mathematical methods offer a robust, flexible, and mature approach which is technically defensible from first principle physics. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Synchronization properties of coupled chaotic neurons: The role of random shared input

Spike-time correlations of neighbouring neurons depend on their intrinsic firing properties as well as on the inputs they share. Studies have shown that periodically firing neurons, when subjected to random shared input, exhibit asynchronicity. Here, we study the effect of random shared input on the synchronization of weakly coupled chaotic neurons. The cases of so-called electrical and chemical coupling are both considered, and we observe a wide range of synchronization behaviour. When subjected to identical shared random input, there is a decrease in the threshold coupling strength needed for chaotic neurons to synchronize in-phase. The system also supports lag–synchronous states, and for these, we find that shared input can cause desynchronization. We carry out a master stability function analysis for a network of such neurons and show agreement with the numerical simulations. The contrasting role of shared random input for complete and lag synchronized neurons is useful in understanding spike-time correlations observed in many areas of the brain.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Characterizing the effect of hypersonic boundary layer turbulence on antenna performance: A computational approach

The degradation of antenna performance during hypersonic re-entry is a well known phenomenon that can lead to complete radio blackout. Recent additions to the Empire code establish it as a tool for the study and analysis of the problem. Coupling to the Sandia Parallel Aerodynamics and Reentry Code (SPARC) enables the electromagnetic analysis of realistic re-entry plasma profiles. The geometric flexibility afforded by both Empire and SPARC allow the consideration of arbitrary vehicle and antenna configurations. We have used this tool to study antenna performance during re-entry when the boundary layer becomes turbulent. A concise description of line-of-sight transmissions, which employs advanced statistical methods, was developed. New insights into the low altitude reflectometer readings of RAM-C2 are offered. Techniques for the reconstruction of the re-entry plasma profile from reflectometer data were explored.

42 ENGINEERING↗

Aroclor 1254, a developmental neurotoxicant, alters energy metabolism- and intracellular signaling-associated protein networks in rat cerebellum and hippocampus

The vast literature on the mode of action of polychlorinated biphenyls (PCBs) indicates that PCBs are a unique model for understanding the mechanisms of toxicity of environmental mixtures of persistent chemicals. PCBs have been shown to adversely affect psychomotor function and learning and memory in humans. Although the molecular mechanisms for PCB effects are unclear, several studies indicate that the disruption of Ca{sup 2+}-mediated signal transduction plays significant roles in PCB-induced developmental neurotoxicity. Culminating events in signal transduction pathways include the regulation of gene and protein expression, which affects the growth and function of the nervous system. Our previous studies showed changes in gene expression related to signal transduction and neuronal growth. In this study, protein expression following developmental exposure to PCB is examined. Pregnant rats (Long Evans) were dosed with 0.0 or 6.0 mg/kg/day of Aroclor-1254 from gestation day 6 through postnatal day (PND) 21, and the cerebellum and hippocampus from PND14 animals were analyzed to determine Aroclor 1254-induced differential protein expression. Two proteins were found to be differentially expressed in the cerebellum following PCB exposure while 18 proteins were differentially expressed in the hippocampus. These proteins are related to energy metabolism in mitochondria (ATP synthase, sub unit {beta} (ATP5B), creatine kinase, and malate dehydrogenase), calcium signaling (voltage-dependent anion-selective channel protein 1 (VDAC1) and ryanodine receptor type II (RyR2)), and growth of the nervous system (dihydropyrimidinase-related protein 4 (DPYSL4), valosin-containing protein (VCP)). Results suggest that Aroclor 1254-like persistent chemicals may alter energy metabolism and intracellular signaling, which might result in developmental neurotoxicity. -- Highlights: Black-Right-Pointing-Pointer We performed brain proteomic analysis of rats exposed to the neurotoxicant, Aroclor 1254. Black-Right-Pointing-Pointer Cerebellum and hippocampus were analyzed by 2D DIGE and Mass spectrometry. Black-Right-Pointing-Pointer Proteins affected participate in Energy metabolism, calcium signaling and nervous system growth.

60 APPLIED LIFE SCIENCES↗

NO FLARES FROM GAMMA-RAY BURST AFTERGLOW BLAST WAVES ENCOUNTERING SUDDEN CIRCUMBURST DENSITY CHANGE

Afterglows of gamma-ray bursts are observed to produce light curves with the flux following power-law evolution in time. However, recent observations reveal bright flares at times on the order of minutes to days. One proposed explanation for these flares is the interaction of a relativistic blast wave with a circumburst density transition. In this paper, we model this type of interaction computationally in one and two dimensions, using a relativistic hydrodynamics code with adaptive mesh refinement called RAM, and analytically in one dimension. We simulate a blast wave traveling in a stellar wind environment that encounters a sudden change in density, followed by a homogeneous medium, and compute the observed radiation using a synchrotron model. We show that flares are not observable for an encounter with a sudden density increase, such as a wind termination shock, nor for an encounter with a sudden density decrease. Furthermore, by extending our analysis to two dimensions, we are able to resolve the spreading, collimation, and edge effects of the blast wave as it encounters the change in circumburst medium. In all cases considered in this paper, we find that a flare will not be observed for any of the density changes studied.

79 ASTRONOMY AND ASTROPHYSICS↗

A Detailed Vehicle Simulation Process to Support CAFE Standards for the MY 2024–2026 Analysis

In 1975, Congress passed the Energy Policy and Conservation Act (EPCA), requiring standards for corporate average fuel economy (CAFE), and charging the U.S. Department of Transportation (DOT) with the establishment and enforcement of these standards. The Secretary of Transportation has delegated these responsibilities to the National Highway Traffic Safety Administration (NHTSA).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Dynamic modelling of a double-pendulum gantry crane system incorporating payload

The natural sway of crane payloads is detrimental to safe and efficient operation. Under certain conditions, the problem is complicated when the payloads create a double pendulum effect. This paper presents dynamic modelling of a double-pendulum gantry crane system based on closed-form equations of motion. The Lagrangian method is used to derive the dynamic model of the system. A dynamic model of the system incorporating payload is developed and the effects of payload on the response of the system are discussed. Extensive results that validate the theoretical derivation are presented in the time and frequency domains.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

FY2018 Analysis Annual Progress Report

During fiscal year 2018 (FY 2018), the U.S. Department of Energy Vehicle Technologies Office (VTO) funded analysis projects supportive of VTO’s goals to pursue early stage research in vehicle and mobility system technologies to improve energy efficiency, increase energy reliability and security, improve transportation affordability, and promote economic growth. VTO analysis projects result in a foundation of data, analytical models, and applied analyses that provide insights into critical transportation energy problems and assist in research investment prioritization and portfolio planning.

33 ADVANCED PROPULSION SYSTEMS↗

Process Intensification for Nanostructure Aluminum Extrusions

A new technology called Shear Assisted Processing and Extrusion (ShAPE™), pioneered at the Pacific Northwest National Laboratory (PNNL), has the potential to revolutionize the US extrusion industry. Maturation of the ShAPE™ process would create a new cross cutting US manufacturing technology that advances three key the objectives within AMO; namely, nanomaterials processing, process intensification, and materials for extreme and harsh environments. PNNL and SCM Metals Products, Inc. (SCM), a division of Kymera International, will collaborate to mature the ShAPE™ extrusion process beyond TRL 3 to increase the likelihood of its adoption by industry. PNNL’s custom (one-of-a-kind in the world) ShAPE™ machine will be used to extrude round rods of high strength aluminum alloy feedstock powder provided by SCM. As proof-of-concept, PNNL has previously extruded 5 mm diameter rods with SCM aluminum alloy powder AL-12.4TM. This project aims to scale up the process to a diameter of 25 mm while retaining the excellent mechanical properties achieved for the 5 mm diameter rods. The degree of process intensification with ShAPE™ will also be estimated. The primary objectives of this project are as follows. 1) Fabricate 25 mm diameter nanostructured extrusions in bulk, directly from AL-12.4TM aluminum alloy powder without the need for canning, degassing, compaction, and other intermediate steps typical of powder metallurgy extrusion. 2) Achieve a microstructure with an ultrafine grained (UFG <1 µm) aluminum matrix having refined and homogenously distributed nanoscale second phases. 3) Show that the ram force can be significantly reduced compared to conventional powder metallurgy extrusion of the same material and estimate the extent of process intensification that may be possible with ShAPE™. 4) Demonstrate improved high-temperature mechanical properties compared to conventional extrusion of the same material. The following tasks will be undertaken to achieve these objectives. PNNL will develop the die set and process parameters necessary to fabricate Al-12.4TM extrusions with a 25 mm diameter. Microstructural analysis will be performed by PNNL while mechanical testing will be conducted by SCM. With information learned from the process development and characterization, PNNL will perform an estimate of the degree of process intensification that may be possible with ShAPE™.

42 ENGINEERING↗

ON DARK PEAKS AND MISSING MASS: A WEAK-LENSING MASS RECONSTRUCTION OF THE MERGING CLUSTER SYSTEM A520 ,

Merging clusters of galaxies are unique in their power to directly probe and place limits on the self-interaction cross-section of dark matter. Detailed observations of several merging clusters have shown the intracluster gas to be displaced from the centroids of dark matter and galaxy density by ram pressure, while the latter components are spatially coincident, consistent with collisionless dark matter. This has been used to place upper limits on the dark matter particle self-interaction cross-section of order 1 cm{sup 2} g{sup -1}. The cluster A520 has been seen as a possible exception. We revisit A520 presenting new Hubble Space Telescope Advanced Camera for Surveys mosaic images and a Magellan image set. We perform a detailed weak-lensing analysis and show that the weak-lensing mass measurements and morphologies of the core galaxy-filled structures are mostly in good agreement with previous works. There is, however, one significant difference: We do not detect the previously claimed 'dark core' that contains excess mass with no significant galaxy overdensity at the location of the X-ray plasma. This peak has been suggested to be indicative of a large self-interaction cross-section for dark matter (at least {approx}5{sigma} larger than the upper limit of 0.7 cm{sup 2} g{sup -1} determined by observations of the Bullet Cluster). We find no such indication and instead find that the mass distribution of A520, after subtraction of the X-ray plasma mass, is in good agreement with the luminosity distribution of the cluster galaxies. We conclude that A520 shows no evidence to contradict the collisionless dark matter scenario.

79 ASTRONOMY AND ASTROPHYSICS↗

Diffraction of radio-frequency waves by plasma turbulence in the edge of a tokamak

The Mie-Lorenz-Debye theory of scattering of radio frequency waves (RF) by filamentary structures in the edge of a tokamak plasma has been established in prior publications. These results have been verified. Theory and computations show that RF can be reflected, refracted, and diffracted by turbulence. Furthermore, the filamentary structures lead to side scattering of waves and excitation of wave modes different from the launched RF. It is important to quantify the overall effect of turbulence on the propagation of RF since efficiency of heating and current drive by RF waves depends upon the wave characteristics. The commonly used RF ranges vary from the low frequency ion-cyclotron (IC) waves, to medium frequency lower-hybrid (LH) waves, to high-frequency electron cyclotron (EC) waves with wavelengths respectively, large, comparable, or smaller than the radial dimensions of the filaments. Currently, we discuss the scattering as well as the forces exerted by different RF in the edge plasma. Also, we present a code for 3D full wave scattering analysis of arbitrary tensor permittivity and plasma density profiles. The study is applicable to ITER-like plasmas, as well as to plasmas in medium sized tokamaks such as TCV, ASDEX-U and DIII-D and high field concepts like SPARC.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗