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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Validation of the Cloud_CCI (Cloud Climate Change Initiative) cloud products in the Arctic

The role of clouds in the Arctic radiation budget is not well understood. Ground-based and airborne measurements provide valuable data to test and improve our understanding. However, the ground-based measurements are intrinsically sparse, and the airborne observations are snapshots in time and space. Passive remote sensing measurements from satellite sensors offer high spatial coverage and an evolving time series, having lengths potentially of decades. However, detecting clouds by passive satellite remote sensing sensors is challenging over the Arctic because of the brightness of snow and ice in the ultraviolet and visible spectral regions and because of the small brightness temperature contrast to the surface. Consequently, the quality of the resulting cloud data products needs to be assessed quantitatively. In this study, we validate the cloud data products retrieved from the Advanced Very High Resolution Radiometer (AVHRR) post meridiem (PM) data from the polar-orbiting NOAA-19 satellite and compare them with those derived from the ground-based instruments during the sunlit months. The AVHRR cloud data products by the European Space Agency (ESA) Cloud Climate Change Initiative (Cloud_CCI) project uses the observations in the visible and IR bands to determine cloud properties. The ground-based measurements from four high-latitude sites have been selected for this investigation: Hyytiälä (61.84°N, 24.29°E), North Slope of Alaska (NSA; 71.32°N, 156.61°W), Ny-Ålesund (Ny-Å; 78.92°N, 11.93°E), and Summit (72.59°N, 38.42°W). The liquid water path (LWP) ground-based data are retrieved from microwave radiometers, while the cloud top height (CTH) has been determined from the integrated lidar–radar measurements. The quality of the satellite products, cloud mask and cloud optical depth (COD), has been assessed using data from NSA, whereas LWP and CTH have been investigated over Hyytiälä, NSA, Ny-Å, and Summit.

54 ENVIRONMENTAL SCIENCES↗

Marine and continental stratocumulus cloud microphysical properties obtained from routine ARM Cimel sunphotometer observations

This study investigates marine and continental stratocumulus (Sc) cloud properties obtained from an automated implementation of a multispectral photometer retrieval. Photometer methods simultaneously retrieve cloud optical depth (τ) and cloud droplet effective radius (r e ), with estimates for liquid water path (LWP) calculated on the availability of those quantities. These applied methods evaluate retrieved cloud properties for Sc identified during a recent 6 year period over the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program sites in Oklahoma, USA (SGP) and in the Azores, Portugal (ENA). Modest agreement in key quantity retrievals is found between the routine photometer products and multisensor collocated profiling references. Cumulative breakdowns contingent on cloud thickness indicate increases in all retrieved quantities in thicker clouds, with larger discrepancies in the relative performance between the retrievals collected in the presence of drizzle. Under continental cloud conditions, the clouds of a similar thickness and r e to those sampled under marine conditions report a factor of 1.5 larger τ and LWP. An r 2 ≅0.65 is found between photometer τ retrievals and shadowband radiometer measurements, with photometer retrievals reporting a high (relative) bias. The τ intercomparisons indicate that variability between retrievals is a factor of three larger than errors reported from individual retrieval input perturbation tests. Photometer r e retrievals suggest a low r 2 (< 0.1) having a standard deviation ≅ 3 µm when compared to ARM baseline multi-sensor radar/radiometer references (accounting for offsets in the cloud droplet number concentration assumptions of the latter). However, photometer LWP calculations remain relatively unbiased in non-drizzling conditions, with errors O (50 g m −2 ) and r 2 ≅0.5 to collocated radiometer and interferometer references. Additional sensitivity tests for island influences on marine Sc properties suggest that while island-influenced winds may promote larger cloud LWP or thickness, the influence could be within retrieval method uncertainty and/or collocated instrument variability.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of cloud height, optical thickness, and phase retrievals from the CHROMA algorithm applied to Sentinel-3 OLCI data

We previously developed the Cloud Height Retrieval from O 2 Molecular Absorption (CHROMA) algorithm for the Ocean Color Instrument (OCI) on the new NASA Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission. Here, we apply CHROMA to observations from the Ocean Land Colour Instrument (OLCI) to guide expectations for PACE, as it will take some time to obtain large-scale validation data for OCI. We use cloud top height (CTH), phase, and (for liquid clouds) cloud optical thickness (COT) data from the ground-based Atmospheric Radiation Measurement (ARM) network to evaluate the OLCI retrievals. We found that OLCI and Moderate Resolution Imaging Spectroradiometer (MODIS) CTH compare similarly well to the ARM reference. OLCI has a tendency to underestimate CTH as CTH increases, and algorithm assumptions about cloud geometric thickness may contribute to this. ARM COT from multifilter shadowband radiometers (MFRSR) and Sun photometers are well-correlated with one another, albeit with a roughly 30 % offset on average; OLCI and MODIS COT agree more closely with the MFRSR data. OLCI retrieval uncertainty estimates show skill at telling low-uncertainty cases from high-uncertainty ones, although CTH uncertainties are underestimated. Additionally, we compare the OLCI data to satellite retrievals based on thermal infrared measurements from MODIS and Sea and Land Surface Temperature Radiometer (SLSTR) data. Differences are broadly consistent with physical expectations based on the A-band vs. thermal techniques, although one key challenge in such aggregated comparisons is different cloud masking sensitivities and algorithm failure rates meaning additional sampling differences are introduced. We conclude by discussing the transition to and possible enhancements for PACE OCI.

Sayer, Andrew M. [Univ. of Maryland Baltimore Coun↗

microbase.c1

MICROBASE is a baseline retrieval of cloud microphysical properties. It uses a combination of observations from the cloud radar, ceilometer, micropulse lidar, microwave radiometer, and balloon-borne radiosonde soundings in order to produce instantaneous vertical profiles of cloud liquid water content (LWC), cloud ice water content (IWC), liquid cloud particle effective radius (LIQRE), and ice cloud particle effective radius (ICERE). Uncertainites are also produced by the VAP. The inputs are by the following VAPs: Active Remote Sensing of Clouds (ARSCL) Merged Sounding (MERGESONDE) Microwave Radiometer Retrievals (MWRRET) The output are daily files.

54 ENVIRONMENTAL SCIENCES↗

Tansey_MICRE_D98_microphysics_V5

This data file contains retrievals of cloud-effective-radius and cloud-droplet-number-concentration for low clouds based on the Dong et al. 1998 retrieval technique for the MICRE campaign. The retrieval is based on observed downwelling broadband SW fluxes and microwave-radiometer-retrieved-liquid-water-path averaged on a 5 minute time scale (mean when low cloud is present). Details on the algorithm and analysis of results are given in Tansey et al. 2024 (submitted DOI: 10.22541/essoar.173482310.03809503/v1). The data is limited to the period 20160410 to 20160612 AND 20170103 to 20170214 during which time good quality microwave-radiometer measurements are available.

54 ENVIRONMENTAL SCIENCES↗

Tansey_MICRE_D98_microphysics_V5

This data file contains retrievals of cloud-effective radius and cloud-droplet-number concentration for low clouds based on the Dong et al. 1998 retrieval technique for the MICRE campaign. The retrieval is based on observed downwelling broadband shortwave (SW) fluxes and microwave-radiometer-retrieved-liquid-water-path averaged on a 5-minute time scale (mean when low cloud is present). Details on the algorithm and analysis of results are given in Tansey et al. 2024 (submitted DOI: 10.22541/essoar.173482310.03809503/v1). The data are limited to the period of 20160410 to 20160612 and 20170103 to 20170214 during which time good quality microwave radiometer measurements are available.

54 ENVIRONMENTAL SCIENCES↗

Physically based correction of systematic errors of Rotating Shadowband Irradiometers

Accurate measurements of direct normal, diffuse horizontal and global horizontal irradiance (DNI, DHI and GHI) are needed for meteorological studies and are essential for the solar resource assessment at potential solar power plant sites. Often, these potential sites are remote and hence require robust sensors that require minimal maintenance that are not affected strongly by soiling. Therefore, Rotating Shadowband Irradiometers (RSI) are widely used for resource assessment. To achieve the required accuracy, corrections for the raw values of RSIs depending on systematic temperature, incidence angle and spectral errors must be used, and a thorough calibration of the sensor head must be applied. The existing correction functions are derived from comparisons of RSIs to thermopile radiometers at selected sites and therefore empirical. Their accuracy is considered to be site dependent. In this work a new correction and calibration method is presented that removes the systematic errors using a physical approach. It is based on information of the sensor properties as well as measurements of its directional response, and incorporates the atmospheric conditions at the measurement site. In this case, no empiric relations obtained from a specific site are required. The method requires estimates of the current DHI and GHI spectra during each measurement of the RSI. Based on these spectra, a spectral correction, which includes a spectrum dependent temperature correction, can be made without employing empirical relationships. The new physical calibration and correction method is tested at three sites and reaches similar results compared to the empirical functions. This is already achieved with rudimentary estimations of the GHI and DHI spectra and we expect that these estimations can be improved in the future. The results indicate that the physical approach reduces the problematic location dependence of the current calibration and correction methods. The physical correction and calibration method show promise for a further improvement of the RSI accuracy.

47 OTHER INSTRUMENTATION↗

Aerosol Optical Depth Best Estimate Value-Added Product Report

Four aerosol optical depth (AOD) products are offered by four collocated ground-based instruments deployed at the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Southern Great Plains (SGP) observatory (SGP Central Facility 1 [C1] and Extended Facility 13 [E13]) for more than two decades. Two of these instruments, the multifilter rotating shadowband radiometers (MFRSRs C1 and E13), are sensors with horizontal hemispherical receivers shaded by rotating shadowbands.

47 OTHER INSTRUMENTATION↗

MiniCarb: a passive, occultation-viewing, 6U CubeSat for observations of CO 2 , CH 4 , and H 2 O

In this report we present the final design, environmental testing, and launch history of MiniCarb, a 6U CubeSat developed through a partnership between NASA Goddard Space Flight Center and Lawrence Livermore National Laboratory. MiniCarb’s science payload, developed at Goddard, was an occultation-viewing, passive laser heterodyne radiometer for observing methane, carbon dioxide, and water vapor in Earth’s atmosphere at ~1.6 µm s -1 . MiniCarb’s satellite, developed at Livermore, implemented their CubeSat Next Generation Bus plug-and-play architecture to produce a modular platform that could be tailored to a range of science payloads. Following the launch on 5 December 2019, MiniCarb traveled to the International Space Station and was set into orbit on 1 February 2020 via Northrop Grumman’s Cygnus capsule which deployed MiniCarb with tipoff rotation of about 20° s (significantly higher than the typical rate of 3° s -1 from prior CubeSats), from which the attitude control system was unable to recover resulting in a loss of power. In spite of this early failure, MiniCarb had many successes including rigorous environmental testing, successful deployment of its solar panels, and a successful test of the radio and communication through the Iridium network. This prior work and enticing cost (approximately $\$2$ M for the satellite and $\$$250 K for the payload) makes MiniCarb an ideal candidate for a low-cost and rapid rebuild as a single orbiter or constellation to globally observe key greenhouse gases.

47 OTHER INSTRUMENTATION↗

Progress in ITER ECE diagnostic design and integration

The ITER electron cyclotron emission (ECE) diagnostic system has primary roles in providing measurements of the core electron temperature profile and the electron temperature fluctuation associated with the neoclassical tearing modes. The ITER ECE system includes a radial and oblique line-of-sight. Four 43-meter long low-loss transmission lines (TLs) are designed to transmit millimeter wave power in the frequency range of 70–1000 GHz in both X- and O-mode polarization from the port plug to the ECE instrumentation room in the diagnostic building. The measurement instrumentation includes two Fourier transform spectrometer (FTS) systems and two radiometer systems. The Indian Domestic Agency (IN-DA) and United States Domestic Agency share the responsibility. The IN-DA scope excluding instrumentation and control has passed its preliminary design review and is progressing towards the final design review (FDR). In parallel, the diagnostic integration in different areas is ongoing. Furthermore, several captive components for the TLs have passed FDR and will be manufactured for installation in the tokamak building soon. A peer review meeting has been held on the prototype hot calibration source, and its integration and new thermal analysis in the diagnostic shield module are continuing. A prototype TL is being tested. A prototype polarizing Martin-Puplett type FTS, operating in the frequency range 70–1000 GHz, features an in-vacuo fast scanning mechanism and a cryo-cooled dual-channel THz detector system. Its performance has been assessed in detail against ITER requirements.

47 OTHER INSTRUMENTATION↗

Interpolated Sounding and Gridded Sounding Value-Added Products

Standard Atmospheric Radiation Measurement (ARM) Climate Research Facility sounding files provide atmospheric state data in one dimension of increasing time and height per sonde launch. Many applications require a quick estimate of the atmospheric state at higher time resolution. The INTERPOLATEDSONDE (i.e., Interpolated Sounding) Value-Added Product (VAP) transforms sounding data into continuous daily files on a fixed time-height grid, at 1-minute time resolution, on 332 levels, from the surface up to a limit of approximately 40 km. The grid extends that high so the full height of soundings can be captured; however, most soundings terminate at an altitude between 25 and 30 km, above which no data is provided. Between soundings, the VAP linearly interpolates atmospheric state variables in time for each height level. In addition, INTERPOLATEDSONDE provides relative humidity scaled to microwave radiometer (MWR) observations.The INTERPOLATEDSONDE VAP, a continuous time-height grid of relative humidity-corrected sounding data, is intended to provide input to higher-order products, such as the Merged Soundings (MERGESONDE; Troyan 2012) VAP, which extends INTERPOLATEDSONDE by incorporating model data. The INTERPOLATEDSONDE VAP also is used to correct gaseous attenuation of radar reflectivity in products such as the KAZRCOR VAP.

54 ENVIRONMENTAL SCIENCES↗

NREL Comparison of Absolute Cavity Pyrgeometers, InfraRed Integrating Sphere, and Pyrgeometers Traceable to World Infrared Standard Group: September 25-October 6, 2023

The comparison of the absolute cavity pyrgeometers (ACPs) with the InfraRed Integrating Sphere (IRIS), Eppley Precision Infrared Radiometer (PIR) pyrgeometers, and Kipp & Zonen (KZ) pyrgeometers traceable to the World Infrared Standard Group (WISG) was held during NREL ACP and IRIS Comparisons (NAIC) from September 25 to October 6, 2023. Data from all instruments was collected during nighttime clear sky conditions only. The irradiance measured by the ACPs is collected in 30 seconds intervals during the measurement period of two hours, and 10 seconds intervals during the calibration period of 6 minutes. During the comparison, the average (av) irradiance difference measured by ACPs and IRIS9 varied from -0.75 W/m 2 to 0.76 W/m 2 , standard deviation (sd) from 0.78 W/m 2 to 1.04 W/m 2 , and uncertainty U95 from 1.96 W/m 2 to 2.07 W/m 2 . The average irradiance difference measured by ACP95F3 minus the irradiance measured by all pyrgeometers varied from 1.64 to 3.96 W/m 2 , sd from 1.70 W/m 2 to 1.86 W/m 2 , and uncertainty U 95 from 3.78 W/m 2 to 5.42W/m 2 . Note that from September 25th at 18:31 to September 29 th at 5:30 ACP96F3 irradiance is calculated using Bruce, et al 2023 method.

47 OTHER INSTRUMENTATION↗

Latest Development to Establish the World Reference with Traceability to SI Units for Measuring the Atmospheric Shortwave and Longwave Irradiance

To date, Interim world reference traceable to blackbody (not sky/atmosphere) is used as a reference noted as a World Infrared Standard Group (WISG). Plan forward: to develop a reference standards traceable to SI InfraRed Integrating Sphere (IRIS) Developed by the World Radiation Center (PMOD) is traceable to blackbody irradiance. Absolute Cavity Pyrgeometer (ACP) developed by NLR is a self-calibrating radiometer using heat substitution to measure the atmospheric longwave irradiance. ACP is a contribution to develop the world reference with traceability to SI, using the outdoor irradiance as the source, instead of blackbody.

14 SOLAR ENERGY↗

An Algorithm to Retrieve Total Precipitable Water Vapor in the Atmosphere from FengYun 3D Medium Resolution Spectral Imager 2 (FY-3D MERSI-2) Data

The atmosphere has substantial effects on optical remote sensing imagery of the Earth&rsquo;s surface from space. These effects come through the functioning of atmospheric particles on the radiometric transfer from the Earth&rsquo;s surface through the atmosphere to the sensor in space. Precipitable water vapor (PWV), CO 2 , ozone, and aerosol in the atmosphere are very important among the particles through their functioning. This study presented an algorithm to retrieve total PWV from the Chinese second-generation polar-orbiting meteorological satellite FengYun 3D Medium Resolution Spectral Imager 2 (FY-3D MERSI-2) data, which have three near-infrared (NIR) water vapor absorbing channels, i.e., channel 16, 17, and 18. The algorithm was improved from the radiance ratio technique initially developed for Moderate-Resolution Imaging Spectroradiometer (MODIS) data. MODTRAN 5 was used to simulate the process of radiant transfer from the ground surfaces to the sensor at various atmospheric conditions for estimation of the coefficients of ratio technique, which was achieved through statistical regression analysis between the simulated radiance and transmittance values for FY-3D MERSI-2 NIR channels. The algorithm was then constructed as a linear combination of the three-water vapor absorbing channels of FY-3D MERSI-2. Measurements from two ground-based reference datasets were used to validate the algorithm: the sun photometer measurements of Aerosol Robotic Network (AERONET) and the microwave radiometer measurements of Energy&rsquo;s Atmospheric Radiation Measurement Program (ARMP). The validation results showed that the algorithm performs very well when compared with the ground-based reference datasets. The estimated PWV values come with root mean square error (RMSE) of 0.28 g/cm 2 for the ARMP and 0.26 g/cm 2 for the AERONET datasets, with bias of 0.072 g/cm 2 and 0.096 g/cm 2 for the two reference datasets, respectively. The accuracy of the proposed algorithm revealed a better consistency with ground-based reference datasets. Thus, the proposed algorithm could be used as an alternative to retrieve PWV from FY-3D MERSI-2 data for various remote sensing applications such as agricultural monitoring, climate change, hydrologic cycle, and so on at various regional and global scales.

54 ENVIRONMENTAL SCIENCES↗

Thorium chelators for targeted alpha therapy: Rapid chelation of thorium-226

We report one of the main challenges in targeted alpha therapy is assuring delivery of the α-particle dose to the targeted cells. Thus, it is critical to identify ligands for α-emitting radiometals that will form complexes that are very stable, both in vitro and in vivo. In this investigation, thorium-227 (t 1/2 = 18.70 days) chelation of ligands containing hydroxypyridinonate (HOPO) or picolinic acid (pa) moieties and the stability of the resultant complexes were studied. Chelation reactions were followed by reversed-phased HPLC and gamma spectroscopy. Studies revealed that high 227 Th chelation yields could be obtained within 2.5 h or less with ligands containing four Me-3,2-HOPO moieties, 1 (83%) and 2 (65%), and also with ligands containing pa moieties, H 4 octapa 3 (65%) and H 4 py4pa 6 (87%). No reaction occurred with H 4 neunpa-p-Bn-NO 2 4, and the chelation reaction with another pa ligand H 4 pypa 5 gave inconsistent yields with a very broad radio-HPLC peak. The ligands spermine-(Me-3,2-HOPO) 4 1, H 4 octapa 3, and H 4 py4pa 6 had high stability (i.e., 87% of 227 Th still bound to the ligand) in phosphate-buffered saline at room temperature over a 6-day period. Preliminary studies with ligand 6 demonstrated efficient chelation of thorium-226 (t 1/2 = 30.57 min) when heated to 80°C for 5 min.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Monitoring water quality in the lower Kansas River using remote sensing

Abstract We demonstrate how to combine remote sensing data from satellite imagery (Sentinel‐2) with in situ water quality gauging (USGS Super Gages and the Gybe hyperspectral radiometer) to create spatially dense maps of water quality parameters (chlorophyll‐a concentration, turbidity, and nitrate plus nitrite concentration) along the lower Kansas River. The water quality maps are created using locally tuned models of the target water quality parameters, and this study describes the steps used to design, calibrate, and validate the empirical correlations. Water quality parameters such as chlorophyll‐a concentration are correlated with well‐studied absorption and scattering features in the visible spectrum (roughly 400–700 nm). Nutrients (such as nitrate plus nitrite concentration) lack strong absorption features in the visible spectrum, and in those cases we describe a novel surrogate data modeling approach that identifies overlapping water parcels between the in situ gauging and the remote sensing imagery. Measurements from the overlapping water parcels yield excellent correlations () for the target water quality parameters for limited windows of time (or limited sections of river reaches). Examples are provided illustrating how the water quality maps can be used to track river inputs from ungauged sources (such as creeks), or reveal the mixing patterns at the confluences.

Tufillaro, Nicholas↗

Coastal-Fog Microphysics Using In-Situ Observations and GOES-R Retrievals

Here, the objective of this work is to evaluate GOES-R based fog conditions occurred during the C-FOG (Toward Improving Coastal Fog Prediction) field campaign. C-FOG is designed to advance understanding of fog formation, development, and dissipation over coastal environments to improve its predictability. The project took place along coastlines and open water environments of Eastern Canada (Nova Scotia, NS and the Island of Newfoundland, NL) during August-October of 2018 where environmental conditions play an important role for late season’s fog formation. During the C-FOG field campaign, instruments were located at the Ferryland Supersite, NL, with 2 main sites, and five satellite sites, as well as on the Research Vessel (R/V) Hugh R. Sharp. Key measurement instruments included a Gondola carrying a CDP (cloud droplet probe) and a BCP (backscatter cloud probe) was used for measuring droplet spectra from 1-75 µm on the R/V. A LPM (laser precipitation monitor) with 100 µm-1 cm size range and an OPC (optical particle counter) with 0.3-17 µm at 16 spectral channels provided information for fog and drizzle discrimination. Remote sensing platforms (e.g. profiling microwave radiometer, PMWR), Ceilometer, Lidar), meteorological towers, tethered balloons, and GOES-R products (e.g. fog coverage and droplet size and liquid water path) were used to evaluate fog over horizontal and vertical dimensions. Results suggest that effective radius, phase, liquid water path, and liquid water content values obtained from GOES-R and PMWR were comparable to ground based in-situ observations. It is concluded that integration of observations and nowcasting products may help improve short term local fog predictions.

54 ENVIRONMENTAL SCIENCES↗

Characteristic of cryogenic hydrogen flames from high-aspect ratio nozzles

Unintentional leaks at hydrogen fueling stations have the potential to form hydrogen jet flames, which pose a risk to people and infrastructure. The heat flux from these jet flames are often used to develop separation distances between hydrogen components and buildings, lot-lines, etc. The heat flux and visible flame length is well understood for releases from round nozzles, but real unintended leaks would be expected to be from higher aspect-ratio cracks. Here, we measured the visible flame length and heat-flux characteristics of cryogenic hydrogen flames from high-aspect ratio nozzles. Heat flux measurements from 5 radiometers were used to assess the single-point vs the multi-point methods for interpretation of heat flux sensor data, finding the axial distance of the sensor for a single-point heat flux measurement to be important. We compare the flame length and heat flux data to flames of both cryogenic and compressed hydrogen from round nozzles. The aspect ratio of the release does not affect the flame length or heat flux significantly, for a given mass flow under the range of conditions studied. The engineering correlations presented in this work enable the prediction of flame length and heat flux which can be used to assess risk at hydrogen fueling stations with liquid hydrogen and develop science-based separation distances for these stations.

08 HYDROGEN↗