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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Analysis of Broad-Lined Type Ic Supernovae From the (Intermediate) Palomar Transient Factory

We study 34 Type Ic supernovae that have broad spectral features (SNe Ic-BL). This is the only SN type found in association with long duration gamma-ray bursts (GRBs).We obtained our photometric data with the Palomar Transient Factory (PTF) and its continuation, the intermediate PTF (iPTF). This is the first large, homogeneous sample of SNe Ic-BL from an untargeted survey. Furthermore, given the high observational cadence of iPTF, most of these SNe Ic-BL were discovered soon after explosion. We present K-corrected Bgriz light curves of these SNe, obtained through photometry on template-subtracted images. We analyzed the shape of the r-band light curves, finding a correlation between the decline parameter delta m15 and the rise parameter delta m-10. We studied the SN colors and, based on g - r, we estimated the host-galaxy extinction for each event. Peak r-band absolute magnitudes have an average of -18:6 +- 0:5 mag. We fit each r-band light curve with that of SN 1998bw (scaled and stretched) to derive the explosion epochs. We computed the bolometric light curves using bolometric corrections, r-band data, and g - r colors. Expansion velocities from Fe ii were obtained by fitting spectral templates of SNe Ic. Bolometric light curves and velocities at peak were fitted using the semianalytic Arnett model to estimate ejecta mass Mej, explosion energy EK and 56Ni mass M(56Ni) for each SN. We find average values of Mej = 4 +- 3 M sun, EK = (7 +- 6) x 1051 erg, and M(56Ni) = 0:31 +- 0:16 M . The parameter distributions were compared to those presented in the literature and are overall in agreement with them. We also estimated the degree of 56Ni mixing using scaling relations derived from hydrodynamical models and we find that all the SNe are strongly mixed. The derived explosion parameters imply that at least 21% of the progenitors of SNe Ic-BL are compatible with massive (>28 M ), possibly single stars, whereas at least 64% might come from less massive stars in close binary systems.

Supernovae↗
NASA NTRS1983

The Saturn spectrum in the EUV - Electron excited hydrogen

Recent laboratory observations of electron excited H2 in the EUV have brought about the realization that higher Rydberg series band systems make a significant contribution to the emission spectrum. Theoretical cross section estimates for the excitation of the D, D-prime, B-prime, and B-double-prime states agree with these results. Model calculations for particle excitation of the Saturn atmosphere, including the higher states, now show excellent agreement with Voyager auroral and dayside equatorial spectra. The model data also confirm the relative spectral response calibration of the Voyager instruments, providing a basis for accurate analysis of the excitation processes on both Jupiter and Saturn.

Shemansky, D. E.↗
NASA NTRS1983

Diffusion processes in Al2O3 scales - Void growth, grain growth, and scale growth

The internal microstructure and growth kinetics of Al2O3 scales on Ni-15Cr-13Al (wt percent) are investigated by TEM and analyzed in relation to models of diffusivity. Polished arc-melted specimens were oxidized in 1-atm air at 1100 C for 0.1, 1.0, and 20 hours and ion-thinned for TEM at 100 kV. The frequency distribution of void size and grain size is determined for different oxidation times and scale depths. The kinetics of microvoid growth and of grain and scale growth are plotted and related via simplified models to lattice and grain-boundary oxygen diffusivity, respectively. Good agreement is found between model predictions and data obtained by Oishi and Kingery (1960) on oxygen diffusion in bulk Al2O3. The further implications and limitations of these findings are discssed.

Smialek, J. L.↗
NASA NTRS1984

Diurnal transport effects on the F-region plasma at Chatanika under quiet and disturbed conditions

High latitude ionospheric model predictions are compared with the diurnal variations of plasma convection velocities and electron densities observed at Chatanika, Alaska, on geomagnetically quiet and disturbed days near equinox. Since the time-dependent variation of the magnetospheric electric field was not known, plasma drift velocities and ion densities are calculated for two different convection-precipitation models, each of which corresponds to a different level of magnetic activity. Model calculations for the magnetically quiet day produced plasma drift velocities and electron densities that were in good agreement, both qualitatively and quantitatively, with the measurements. The two models have demonstrated the relative sensitivity of the high latitude ionosphere to different combinations of magnetospheric convection and induced vertical drifts associated with thermospheric winds.

Murdin, J.↗
NASA NTRS1989

Advances in understanding the gravity wave spectrum during MAP

Prior to MAP, virtually nothing was known about gravity wave spectra in the atmosphere. The development of observational techniques has played a major role in these studies. Radar and lidar have been particularly important since they can measure atmospheric parameters continuously over large height ranges. Some advances made are: (1) The observed fluctuations and power spectra in the free atmosphere are mostly if not entirely due to a superposition of gravity waves, which can be modeled by the Garrett Munk (GM) model; (2) There is no evidence that 2-D turbulence makes a significant contribution to the observed fluctuations. In any case, the agreement between observations and the GM model shows that the 2DT contribution must be relatively small; (3) Spectra versus vertical wave number are saturated at large wave number, with theory and observations indicating that t approximately equals 3; and (4) Vertical velocity fluctuations and spectra measured near rough terrain are strongly contaminated by mountain waves. But over very flat terrain the spectra are dominated by gravity waves at periods shorter than about 6 hours and apparently by synoptic scale velocities at periods longer than 6 hours. Thus it may be possible to study synoptic scale vertical velocities using radars located in very flat terrain.

Vanzandt, T. E.↗
NASA NTRS2001

Radiation transport modeling and assessment to better predict radiation exposure, dose, and toxicological effects to human organs on long duration space flights

NASA is very interested in improving its ability to monitor and forecast the radiation levels that pose a health risk to space-walking astronauts as they construct the International Space Station and astronauts that will participate in long-term and deep-space missions. Human exploratory missions to the moon and Mars within the next quarter century, will expose crews to transient radiation from solar particle events which include high-energy galactic cosmic rays and high-energy protons. Because the radiation levels in space are high and solar activity is presently unpredictable, adequate shielding is needed to minimize the deleterious health effects of exposure to radiation. Today, numerous models have been developed and used to predict radiation exposure. Such a model is the Space Environment Information Systems (SPENVIS) modeling program, developed by the Belgian Institute for Space Aeronautics. SPENVIS, which has been assessed to be an excellent tool in characterizing the radiation environment for microelectronics and investigating orbital debris, is being evaluated for its usefulness with determining the dose and dose-equivalent for human exposure. Thus far. the calculations for dose-depth relations under varying shielding conditions have been in agreement with calculations done using HZETRN and PDOSE, which are well-known and widely used models for characterizing the environments for human exploratory missions. There is disagreement when assessing the impact of secondary radiation particles since SPENVIS does a crude estimation of the secondary radiation particles when calculating LET versus Flux. SPENVIS was used to model dose-depth relations for the blood-forming organs. Radiation sickness and cancer are life-threatening consequences resulting from radiation exposure. In space. exposure to radiation generally includes all of the critical organs. Biological and toxicological impacts have been included for discussion along with alternative risk mitigation methods--shielding and anti-carcinogens. c 2001. Elsevier Science Ltd. All rights reserved.

STS-91 Shuttle Project↗
DOE OSTI2020

Constructing a spatiotemporally coherent long-term PM2.5 concentration dataset over China during 1980–2019 using a machine learning approach

The lack of long-term observations and satellite retrievals of health-damaging fine particulate matter in China has demanded the estimates of historical PM 2.5 (particulate matter less than 2.5 µm in diameter) concentrations. This study constructs a gridded near-surface PM 2.5 concentration dataset across China covering 1980–2019 using the space-time random forest model with atmospheric visibility observations and other auxiliary data. The modeled daily PM2.5 concentrations are in excellent agreement with ground measurements during 2015–2019, with a coefficient of determination of 0.95 and mean relative error of 12%. Besides the atmospheric visibility which explains 30% of total importance of variables in the model, both emissions and meteorological conditions are also essential factors affecting PM2.5 predictions. From 1980 to 2014, the model-predicted PM2.5 concentrations increased constantly with the maximum growth rate of 5–10 µg/m3/decade over eastern China. Due to the clean air actions, PM 2.5 concentrations have decreased effectively at a rate over 50 µg/m 3 /decade in the North China Plain and 20–50 µg/m 3 /decade over eastern China during 2014–2019. The newly generated dataset of 1-degree gridded PM 2.5 concentrations for the past 40 years across China provides a useful means for investigating interannual and decadal environmental and climate impacts related to aerosols.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1994

Prediction of stress-strain response of SCS-6/Timetal-21S subjected to a hypersonic flight profile

Thermomechanical response of a cross-ply SCS-6/Timetal-21S composite subjected to a generic hypersonic flight profile with the temperature ranging from -130 C to 816 C was evaluated experimentally and analytically. A two dimensional micromechanical anlaysis, VISCOPLY, was used to predict the stress-strain response of the laminate and of the constituents in each ply during thermomechanical loading conditions. In the analysis, the fiber was modeled as elastic with transverse orthotropic and temperature dependent properties and the matrix was modeled using a thermoviscoplastic constitutive relation. The fiber transverse modulus was reduced in the analysis to simulate fiber-matrix interface failure. Reasonable agreement was found between measured and predicted laminate stress-strain response when fiber-matrix debonding was modeled.

Mirdamadi, Massoud↗
DOE OSTI2024

Multiscale assessment of North American terrestrial carbon balance

Abstract. Comparisons of carbon uptake estimates from bottom-up terrestrial biosphere models (TBMs) to top-down atmospheric inversions help assess how well we understand carbon dioxide (CO2) exchange between the atmosphere and terrestrial biosphere. Previous comparisons have shown varying levels of agreement between bottom-up and top-down approaches, but they have almost exclusively focused on large, aggregated scales (e.g., global or continental), providing limited insights into reasons for the mismatches. Here we explore how consistency, defined as the spread in net ecosystem exchange (NEE) estimates within an ensemble of TBMs or inversions, varies with at finer spatial scales ranging from 1∘×1∘ to the continent of North America. We also evaluate how well consistency informs accuracy in overall NEE estimates by filtering models based on their agreement with the variability, magnitude, and seasonality in observed atmospheric CO2 drawdowns or enhancements. We find that TBMs produce more consistent estimates of NEE for most regions and at most scales relative to inversions. Filtering models using atmospheric CO2 metrics causes ensemble spread to decrease substantially for TBMs, but not for inversions. This suggests that ensemble spread is likely not a reliable measure of the uncertainty associated with the North American carbon balance at any spatial scale. Promisingly, applying atmospheric CO2 metrics leads to a set of models with converging flux estimates across TBMs and inversions. Overall, we show that multiscale assessment of the agreement between bottom-up and top-down NEE estimates, aided by regional-scale observational constraints is a promising path towards identifying fine-scale sources of uncertainty and improving both ensemble consistency and accuracy. These findings help refine our understanding of biospheric carbon balance, particularly at scales relevant for informing regional carbon-climate feedbacks.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Enabling energy‐efficient manufacturing of pharmaceutical solid oral dosage forms via integrated techno‐economic analysis and advanced process modeling

Abstract The global pharmaceutical industry is a trillion‐dollar market. However, the pharmaceutical sector often lags in manufacturing innovation and automation which limits its potential to maximize energy efficiency. The integration of techno‐economic analysis (TEA) with advanced process models as part of an overarching smart manufacturing platform, can help industries create business models, which can be adapted for manufacturing to reduce energy consumption and operating costs while ensuring product quality which can further enable a more sustainable process operation. In this study, a rational design of experiment on three unit‐operations (wet granulation, drying, and milling) was performed on a batch (case 1) and continuous (case 2) pharmaceutical process to obtain experimental data. Process models for predicting product quality and energy efficiency of each of the three‐unit operations were developed. The experimental data were used to validate the models and good agreement was observed. The energy consumption of each unit operation was calculated using statistical models relating the power consumption and the process parameters. The developed process models and energy models were further integrated into a TEA framework, which quantified the energy and monetary cost of manufacturing for both batch and continuous manufacturing cases. With this integrated framework, energy costs savings of ~33% was obtained in the continuous manufacturing process (case 2) over the batch process (case 1).

Sampat, Chaitanya↗
DOE OSTI2022

Multiscale modeling of hydrogenolysis of ethane and propane on Ru(0001): Implications for plastics recycling

Plastic waste presents an environmental threat. Chemical recycling via hydrogenolysis can convert plastic waste into waxes, lubricants, and fuels. Among catalysts, Ru stands out for its superior activity and selectivity. The chemistry of light alkane hydrogenolysis can help understanding plastics deconstruction. Here, we perform first-principles calculations, develop descriptor-based relations, and conduct microkinetic modeling and analysis on ethane and propane. Predictions are in excellent agreement with experimental data. We identify a similar cracking pattern for both hydrocarbons entailing a deeply dehydrogenated species with the removal of four hydrogen atoms: CHCH*+* → 2CH* for ethane and CH 3 CCH*+2* → CH 3 C* + CH* for propane. We find that the rate-determining step is the C-C cracking for ethane and the first dehydrogenation from the terminal carbon (CH 3 CH 2 CH 3 *+* → CH 3 CH 2 CH 2 *+H*) for propane. The vinyl species CH 2 CH* produced from propane cracking is responsible for whether a single or multiple cracking events occur and effectively controls the selectivity. Specifically, ethane formation in propane hydrogenolysis is suppressed at elevated temperatures due to over-cracking via multiple (two here) cracking events being preferred over hydrogenation and desorption of ethane from the catalyst. Our workflow and models provide a baseline for future studies on heavier hydrocarbons. Insights into recent experimental studies of polyethylene over Ru-based catalysts are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

The Identity and Chemistry of C 7 H 7 Radicals Observed during Soot Formation

Here we used aerosol mass spectrometry coupled with tunable synchrotron photoionization to measure radical and closed-shell species associated with particle formation in premixed flames and during pyrolysis of butane, ethylene, and methane. We analyzed photoionization (PI) spectra for the C 7 H 7 radical to identify the isomers present during particle formation. For the combustion and pyrolysis of all three fuels, the PI spectra can be fit reasonably well with contributions from four radical isomers: benzyl, tropyl, vinylcyclopentadienyl, and o-tolyl. Although there are significant experimental uncertainties in the isomeric speciation of C7H 7 , the results clearly demonstrate that the isomeric composition of C 7 H 7 strongly depends on the combustion or pyrolysis conditions and the fuel or precursors. Fits to the PI spectra using reference curves for these isomers suggest that all of these isomers may contribute to m/z 91 in butane and methane flames, but only benzyl and vinylcyclopentadienyl contribute to the C 7 H 7 isomer signal in the ethylene flame. Only tropyl and benzyl appear to play a role during pyrolytic particle formation from ethylene, and only tropyl, vinylcyclopentadienyl, and o-tolyl appear to participate during particle formation from butane pyrolysis. There also seems to be a contribution from an isomer with an ionization energy below 7.5 eV for the flames but not for the pyrolysis conditions. Kinetic models with updated and new reactions and rate coefficients for the C 7 H 7 reaction network predict benzyl, tropyl, vinylcyclopentadienyl, and o-tolyl to be the primary C 7 H 7 isomers and predict negligible contributions from other C 7 H 7 isomers. These updated models provide better agreement with the measurements than the original versions of the models but, nonetheless, underpredict the relative concentrations of tropyl, vinylcyclopentadienyl, and o-tolyl in both flames and pyrolysis and overpredict benzyl in pyrolysis. Our results suggest that there are additional important formation pathways for the vinylcyclopentadienyl, tropyl, and o-tolyl radicals and/or loss pathways for the benzyl radical that are currently unaccounted for in the present models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

On visual-vestibular interaction

Experimental evidence is presented regarding visual vestibular interaction, and the results of three studies on the subject are briefly noted. An attempt to put together some of these observations with elementary notions of a visual vestibular interaction program is shown in the form of a flow chart representation of a possible model. This is a nonlinear model in which visual and vestibular influences are linearly weighted when they are in relative agreement but switch to the more believable one when they are in disagreement. A solution to the human space orientation problem is depicted by a schema for optimal subjective orientation based on several sensory modalities.

Young, L. R.↗
NASA NTRS1980

Electroepitaxy of multicomponent systems - Ternary and quarternary compounds

A theoretical model is presented which accounts for the electroepitaxial growth kinetics and composition of multicomponent compounds in terms of mass transport in the liquid and phase diagram relationships. The mass transport in the interface is dominated by electromigration in the absence of convection and by diffusion in the presence of convection. The composition of the solid is controlled by the Peltier effect at the growth interface and by the diffusion and mobility constants of the solute components and the growth velocity (current density). Thus, for a given solution composition, the composition of the solid can be varied by varying the current density. For a given current density the composition remains constant even in the case of relatively thick epitaxial layers. All aspects of the model were found to be in good agreement with the growth and composition characteristics of Ga/x-1/Al/x/As layers.

Bryskiewicz, T.↗
NASA NTRS1990

A simple inertial model for Neptune's zonal circulation

Voyager imaging observations of zonal cloud-tracked winds on Neptune revealed a strongly subrotational equatorial jet with a speed approaching 500 m/s and generally decreasing retrograde motion toward the poles. The wind data are interpreted with a speculative but revealingly simple model based on steady gradient flow balance and an assumed global homogenization of potential vorticity for shallow layer motion. The prescribed model flow profile relates the equatorial velocity to the mid-latitude shear, in reasonable agreement with the available data, and implies a global horizontal deformation scale L(D) of about 3000 km.

Allison, Michael↗
NASA NTRS1998

WFPC2 Observations of Star Clusters in the Magellanic Clouds: The Oldest Star Clusters in the Small Magellanic Cloud - Report 2

We present our analysis of archival Hubble Space Telescope Wide Field Planetary Camera 2 (WFPC2) observations in F45OW ( approximately B) and F555W (approximately V) of the intermediate-age populous star clusters NGC 121, NGC 339, NGC 361, NGC 416, and Kron 3 in the Small Magellanic Cloud. We use published photometry of two other SMC populous star clusters, Lindsay 1 and Lindsay 113, to investigate the age sequence of these seven populous star clusters in order to improve our understanding of the formation chronology of the SMC. We analyzed the V vs B-V and M(sub V) vs (B-V)(sub 0) color-magnitude diagrams of these populous Small Magellanic Cloud star clusters using a variety of techniques and determined their ages, metallicities, and reddenings. These new data enable us to improve the age-metallicity relation of star clusters in the Small Magellanic Cloud. In particular, we find that a closed-box continuous star-formation model does not reproduce the age-metallicity relation adequately. However, a theoretical model punctuated by bursts of star formation is in better agreement with the observational data presented herein.

Mighell, Kenneth J.↗
DOE OSTI2025

Thermal Optimization and Experimental Demonstration of a Silicon Carbide, Half-Bridge Power Module

This paper describes modeling and experimental work to design and demonstrate a silicon carbide (SiC), single-side-cooled power module. Two SiC metal-oxide-semiconductor field-effect transistors (MOSFET) were used for each switch position and packaged on a metalized ceramic substrate. Thermal modeling was first conducted to optimize the module packaging to minimize junction-to-fluid thermal resistance and device temperature variations. This procedure identified the optimal device placement and baseplate thickness to maximize thermal performance. A heat exchanger - incorporating impinging jets of water-ethylene glycol - was designed to cool the module's baseplate to minimize thermal resistance and pumping power. The heat exchanger used relatively low fluid velocities (<1.5 m/s) to minimize erosion-corrosion effects and relatively large fluid channel sizes (>=1 mm) to prevent clogging. The power module concept was fabricated, and experiments were conducted to measure its thermal performance. Direct current was used to power the module devices, and junction temperatures were measured via device temperature-sensitive parameters. The experimental results were found to be in good agreement with model predictions (within 2%) and yielded junction-to-fluid thermal resistance values as low as about 15 mm2 K/W at relatively low pumping power values. The results demonstrate the improved performance associated with jet impingement cooling and represent an improvement over existing channel-flow-type cold plates, which can enable improvements to power density and reliability.

36 MATERIALS SCIENCE↗
NASA NTRS2006

Modeling the Observed QBO and Inter-Annual Variations of the Diurnal Tide in the Mesosphere

In the current version of the Numerical Spectral Model (NSM), the Quasi-biennial Oscillation (QBO) is generated primarily by small-scale gravity waves (GW) from Hines' Doppler Spread Parameterization (DSP). The model does not have topography, and the planetary waves are solely generated by instabilities. We discuss a 3D modeling study that describes the QBO extending from the stratosphere into the upper mesosphere, where the oscillation produces significant inter-annual variations in the diurnal tide. The numerical results are compared with temperature measurements from the SABER (TIMED) and MLS (UARS) instruments obtained by Huang et al. (2006). With a GW source that peaks at the Equator and is taken to be isotropic and independent of season, the NSM generates a QBO with variable periods around 26 months and zonal wind amplitudes of almost 25 m/s at 30 km. As reported earlier, the NSM reproduces the observed equinoctial maxima in the diurnal tide at altitudes around 95 km. The modeled QBO modulates the tide such that the seasonal amplitude maxima can vary from one year to another by as much as 30%. To shed light on the underlying mechanisms, the relative importance of the advection terms are discussed, and they are shown to be important in the stratosphere. At altitudes above 80 km, however, the QBO-related inter-annual variations of the tide are generated primarily by GW momentum deposition. In qualitative agreement with the SABER measurements, the model generates distinct zonal-mean QBO temperature variations in the stratosphere and mesosphere. In the stratosphere, the computed amplitudes are not much smaller than those observed, and the rate of downward propagation at the Equator is reproduced. The modeled temperature amplitudes in the mesosphere, however, are much smaller than those observed. The observed and computed temperature variations of the QBO peak at the Equator but extend with phase reversals to high latitudes, in contrast to the zonal winds that are confined to equatorial latitudes. Hemispherical asymmetries also appear in both the model results and the observations. The temperature amplitudes outside the equatorial region however tend to occur at lower latitudes in the model results. While there is qualitative agreement between the TIMED measurements and the model prediction, there are some areas of significant disagreement that require us to reexamine the present version of the NSM. The numerical results critically depend on the chosen parameters that determine the wave forcing, and there are a number of avenues to improve the performance of the model that had not been tuned to fit the observations. The GW spectrum and its latitude dependence in the troposphere are not well known, and numerical experiments are discussed that describe the related model response. While it appears that eastward propagating Kelvin waves and westward propagating Rossby gravity waves are not the primary source to generate the QBO, the GW forcing can seed the oscillation and act as a catalyst to enhance effectiveness of these planetary waves.

Mayr, Hans G.↗