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At least 127 records · Page 7

Description of the NRL isothermal haze chamber

In the IHC the critical supersaturation is inferred from the measurement of the size of particles which have grown to their equilibrium size at exactly 100 percent RH. The largest size channel corresponds to a critical supersaturation of 0.014 percent. The growth time required for particles of this size to reach their equilibrium size exceeds the 110 second residence time in the IHC. Since the supersaturation spectrum is always very steep in this region, the contribution of these larger particles which have not yet attained their equilibrium size to smaller size channels is negligible. However, failure of these particles to reach their equilibrium size could result in a significant lowering of the count in the size channel corresponding to the smaller critical supersaturation.

Hoppel, W. A.↗

Dynamics of Droplet Extinction in Slow Convective Flows

The classical model for droplet combustion predicts that the square of the droplet diameter decreases linearly with time. It also predicts that a droplet of any size will burn to completion over a period of time. However, it has been known for some time that under certain conditions flames surrounding a droplet, in a quiescent environment, could extinguish because of insufficient residence time for the chemistry to proceed to completion. This type of extinction that occurs for smaller droplets has been studied extensively in the past. Large droplets, on the other hand, exhibit a different type of extinction where excessive radiative heat loss from the flame zone leads to extinction. This mode of "radiative extinction" was theoretically predicted for droplet burning by Chao et al. and was observed in recent space experiments in a quiescent environment. Thus far, the fundamental flammability limit prescribed by radiative extinction of liquid droplets has been measured only under quiescent environmental conditions. In many space platforms, however, ventilation systems produce small convective flows and understanding of the influences of this convection on the extinction process will help better define the radiative extinction flammability boundaries. Boundaries defined by experiments and captured using theoretical models could provide enhanced fire safety margin in space explor1999063d investigation of convective effects will help in interpretations of burning-rate data obtained during free-floated droplet combustion experiments with small residual velocities.

Nayagam, V.↗

Contamination Analysis Tools

This talk presents 3 different tools developed recently for contamination analysis:HTML QCM analyzer: runs in a web browser, and allows for data analysis of QCM log filesJava RGA extractor: can load in multiple SRS.ana files and extract pressure vs. time dataC++ Contamination Simulation code: 3D particle tracing code for modeling transport of dust particulates and molecules. Uses residence time to determine if molecules stick. Particulates can be sampled from IEST-STD-1246 and be accelerated by aerodynamic forces.

Numerical Simulation of Rotation-Driven Plasma Transport In the Jovian Magnetosphere

A Jupiter version of the Rice Convection Model (RCM-J) was developed with support of an earlier NASA SR&T grant. The conversion from Earth to Jupiter included adding currents driven by centrifugal force, reversing the planetary magnetic field, and rescaling various parameters. A series of informative runs was carried out, all of them solving initial value problems. The simulations followed an initial plasma torus configuration as it fell apart by interchange instability. Some conclusions from the simulations were the following: 1. We confirmed that, for conventional values of the torus density and ionospheric conductance, the torus disintegrates by interchange instability on a time scale of approx. one day, which is 1-2 orders of magnitude shorter than the best estimates of the average residence time of plasma in the torus. 2. In the model, the instability could be slowed to an arbitrary degree by the addition of sufficient impounding energetic particles, as suggested earlier by Siscoe et al (1981). However, the observed energetic particles do not seem sufficient to guarantee impoundment (e.g., Mauk et al., 1996). 3. Whether inhibited by impoundment or not, the interchange was found to proceed by the formation of long fingers, which get thinner as they get longer. This picture differed dramatically from the conventional radial-diffusion picture (e.g., Siscoe and Summers (1981)), more superficially with the outward-moving-blob picture (Pontius and Hill, 1989). The obvious limitation of the original RCM-J was that it could not represent a plasma source. We could represent the decay of a pre-existing torus, but we could not represent the way ionization of material from Io continually replenishes the plasma. We consequently were precluded from studying a whole set of fundamental issues of torus theory, including whether the system can come to a steady state.

Wolf, Richard A.↗

The Life and Times of Supervolcanoes: Inferences from Long Valley Caldera

Cataclysmic eruptions of silicic magma from "supervolcanoes" are among the most awe-inspiring natural phenomena found in the geologic record, in terms of size, power, and potential hazard. Based on the repose intervals between eruptions of this magnitude, the magmas responsible for them could accumulate gradually in the shallow crust over time scales that may be in excess of a million years (Smith, 1979; Spera and Crisp, 1981; Shaw, 1985). Pre-eruption magma residence time scales can also be inferred from the age difference between eruption (i.e., using 40Ar/39Ar dating to determine the time when hot erupted material cools to below its Ar closure temperature, 200 to 600 degC) and early pre-eruption crystallization (i.e., zircon saturation temperatures; Reid et al., 1997). I will discuss observations from Long Valley a Quaternary volcanic center in California. Long Valley is a voluminous, dominantly silicic caldera system. Based on extensive dating of accessory minerals (e.g., U-Th-Pb dating of zircon and allanite) along with geochemical and isotopic data we find that silicic magmas begin to crystallize 10's to 100's of thousands of years prior to their eruption and that rhyolites record episodes of punctuated and independent evolution rather than the periodic tapping of a long-lived magma. The more punctuated versus more gradual magma accumulation rates required by the absolute and model ages, respectively, imply important differences in the mass and heat fluxes associated with the generation, differentiation, and storage of voluminous rhyolites and emphasize the need to reconcile the magmatic age differences.

Simon, Justin↗

Flame Synthesis of Single- and Multi-Walled Carbon Nanotubes and Nanofibers

Metal-catalyzed carbon nanotubes are highly sought for a diverse range of applications that include nanoelectronics, battery electrode material, catalysis, hydrogen storage media and reinforcing agents in polymer composites. These latter applications will require vast quantities of nanotubes at competitive prices to be economically feasible. Moreover, reinforcing applications may not require ultrahigh purity nanotubes. Indeed, functionalization of nanotubes to facilitate interfacial bonding within composites will naturally introduce defects into the tube walls, lessening their tensile strength. Current methods of aerosol synthesis of carbon nanotubes include laser ablation of composite targets of carbon and catalyst metal within high temperature furnaces and decomposition of a organometallics in hydrocarbons mixtures within a tube furnace. Common to each approach is the generation of particles in the presence of the reactive hydrocarbon species at elevated temperatures. In the laser-ablation approach, the situation is even more dynamic in that particles and nanotubes are borne during the transient cooling phase of the laser-induced plasma for which the temperature far exceeds that of the surrounding hot gases within the furnace process tube. A shared limitation is that more efficient methods of nanoparticle synthesis are not readily incorporated into these approaches. In contrast, combustion can quite naturally create nanomaterials such as carbon black. Flame synthesis is well known for its commercial scalability and energy efficiency. However, flames do present a complex chemical environment with steep gradients in temperature and species concentrations. Moreover, reaction times are limited within buoyant driven flows to tens of milliseconds. Therein microgravity can greatly lessen temperature and spatial gradients while allowing independent control of flame residence times. In preparation for defining the microgravity experiments, the work presented here focuses on the effect of catalyst particle size and reactant gas in 1g.

VanderWal, R. L.↗

Transient catalytic combustor model

A quasi-steady gas phase and thermally thin substrate model is used to analyze the transient behavior of catalytic monolith combustors in fuel lean operation. The combustor response delay is due to the substrate thermal inertia. Fast response is favored by thin substrate, short catalytic bed length, high combustor inlet and final temperatures, and small gas channel diameters. The calculated gas and substrate temperature time history at different axial positions provides an understanding of how the catalytic combustor responds to an upstream condition change. The computed results also suggest that the gas residence times in the catalytic bed in the after bed space are correlatable with the nondimensional combustor response time. The model also performs steady state combustion calculations; and the computed steady state emission characteristics show agreement with available experimental data in the range of parameters covered. A catalytic combustor design for automotive gas turbine engine which has reasonably fast response ( 1 second) and can satisfy the emission goals in an acceptable total combustor length is possible.

Tien, J. S.↗

Cumulus cloud model estimates of trace gas transports

Draft structures in convective clouds are examined with reference to the results of the NASA Amazon Boundary Layer Experiments (ABLE IIa and IIb) and calculations based on a multidimensional time dependent dynamic and microphysical numerical cloud model. It is shown that some aspects of the draft structures can be calculated from measurements of the cloud environment. Estimated residence times in the lower regions of the cloud based on surface observations (divergence and vertical velocities) are within the same order of magnitude (about 20 min) as model trajectory estimates.

Garstang, Michael↗

NH3 column abundances over Lauder, New Zealand

Gaseous NH3 has been observed in the atmosphere over central New Zealand with infrared absorption spectra. The amount of NH3 shows marked variability, which is strongly correlated with time of day and season. The pattern is similar to data obtained in Denver, Colorado, but is much more variable than data from Hampton, Virginia. The rapid variability indicates a residence time of 8 hours in some cases.

Murcray, Frank J.↗

A preliminary assessment of olivine phenocrysts from the monogenetic basalt of the McCartys Flow, Zuni-Bandera Volcanic Field, New Mexico

Monogenetic small-volume basaltic volcanoes are the most abundant subaerial volcanic landforms on Earth but are some of the most poorly understood systems. Their short durations, small volumes, and lack of recurrence make monitoring and hazard assessment difficult. The Zuni-Bandera volcanic field in western New Mexico contains small-volume basaltic centers erupting tholeiitic to alkalic basalts. Evidence shows no correlation of magma composition with eruption age, location, or volumetric output, prompting questions about the influence of magma ascent rates, magma storage conditions, and mantle source characteristics on lava compositions. Here, we present olivine major and minor element mineral chemistry from the 3200-year-old McCartys Flow, the youngest tholeiite basalt in the volcanic field. Olivine displays four phenocryst types with unique textures and major and minor element compositions. Multiple olivine types co-exist at the thin section scale. Major and minor element diffusion at frozen melt–phenocryst interfaces was modeled, revealing magma residence times ranging from 3–9 months. Type 3 olivine phenocrysts require step function initial conditions and record diffusion re-equilibration followed by magma mixing. These profiles indicate the magma resided in the reservoir for 10–15 years and accumulated from multiple batches of mixed magmas less than 10 days before the eruption. Our results show that primitive magmas in small-volume monogenetic volcanoes have complex lithospheric magmatic histories and stored in magma bodies influenced by an open system to develop different local chemical environments.

Gary S. Michelfelder↗

A numerical procedure for analysis of finite rate reacting flows

Combustion processes in rocket propulsion systems are characterized by the existence of multiple, vastly differing time and length scales, as well as flow-speeds at wide variation of Mach numbers. The chemical kinetics processes in the highly active reaction zone are characterized by much smaller scales compared to fluid convective and diffusive time scales. An operator splitting procedure for transient finite rate chemistry problems has been developed using a pressure based method, which can be applied to all speed flows without difficulties. The splitting of chemical kinetics terms formed the fluid-mechanical terms of the species equation ameliorated the difficulties associated with the disparate time scales and stiffness in the set of equations which describes highly exothermic combustion. A combined efficient ordinary differential equations (ODE) solver was used to integrate the effective chemical source terms over the residence time at each grid cell. One and two dimensional reacting flow situations were carried out to demonstrate and verify the current procedure. Different chemical kinetics with different degrees of nonlinearity have also been incorporated to test the robustness and generality of the proposed method.

Shang, H. M.↗

Effects of C/O Ratio and Temperature on Sooting Limits of Spherical Diffusion Flames

Limiting conditions for soot particle inception in spherical diffusion flames were investigated numerically. The flames were modeled using a one-dimensional, time accurate diffusion flame code with detailed chemistry and transport and an optically thick radiation model. Seventeen normal and inverse flames were considered, covering a wide range of stoichiometric mixture fraction, adiabatic flame temperature, residence time and scalar dissipation rate. These flames were previously observed to reach their sooting limits after 2 s of microgravity. Sooting-limit diffusion flames with scalar dissipation rate lower than 2/s were found to have temperatures near 1400 K where C/O = 0.51, whereas flames with greater scalar dissipation rate required increased temperatures. This finding was valid across a broad range of fuel and oxidizer compositions and convection directions.

Lecoustre, V. R.↗

Development of processes for the production of solar grade silicon from halides and alkali metals, phase 1 and phase 2

High temperature reactions of silicon halides with alkali metals for the production of solar grade silicon are described. Product separation and collection processes were evaluated, measure heat release parameters for scaling purposes and effects of reactants and/or products on materials of reactor construction were determined, and preliminary engineering and economic analysis of a scaled up process were made. The feasibility of the basic process to make and collect silicon was demonstrated. The jet impaction/separation process was demonstrated to be a purification process. The rate at which gas phase species from silicon particle precursors, the time required for silane decomposition to produce particles, and the competing rate of growth of silicon seed particles injected into a decomposing silane environment were determined. The extent of silane decomposition as a function of residence time, temperature, and pressure was measured by infrared absorption spectroscopy. A simplistic model is presented to explain the growth of silicon in a decomposing silane enviroment.

Dickson, C. R.↗

Carbon Emissions from Deforestation in the Brazilian Amazon Region

A simulation model based on satellite observations of monthly vegetation greenness from the Moderate Resolution Imaging Spectroradiometer (MODIS) was used to estimate monthly carbon fluxes in terrestrial ecosystems of Brazilian Amazon and Cerrado regions over the period 2000-2002. The NASA-CASA (Carnegie Ames Stanford Approach) model estimates of annual forest production were used for the first time as the basis to generate a prediction for the standing pool of carbon in above-ground biomass (AGB; gC/sq m) for forested areas of the Brazilian Amazon region. Plot-level measurements of the residence time of carbon in wood in Amazon forest from Malhi et al. (2006) were interpolated by inverse distance weighting algorithms and used with CASA to generate a new regional map of AGB. Data from the Brazilian PRODES (Estimativa do Desflorestamento da Amazonia) project were used to map deforested areas. Results show that net primary production (NPP) sinks for carbon varied between 4.25 Pg C/yr (1 Pg=10(exp 15)g) and 4.34 Pg C for the region and were highest across the eastern and northern Amazon areas, whereas deforestation sources of CO2 flux from decomposition of residual woody debris were higher and less seasonal in the central Amazon than in the eastern and southern areas. Increased woody debris from past deforestation events was predicted to alter the net ecosystem carbon balance of the Amazon region to generate annual CO2 source fluxes at least two times higher than previously predicted by CASA modeling studies. Variations in climate, land cover, and forest burning were predicted to release carbon at rates of 0.5 to 1 Pg C/yr from the Brazilian Amazon. When direct deforestation emissions of CO2 from forest burning of between 0.2 and 0.6 Pg C/yr in the Legal Amazon are overlooked in regional budgets, the year-to-year variations in this net biome flux may appear to be large, whereas our model results implies net biome fluxes had actually been relatively consistent from year to year during the period 2000-2002. This is the first study to use MODIS data to model all carbon pools (wood, leaf, root) dynamically in simulations of Amazon forest deforestation from clearing and burning of all kinds.

Potter, C.↗

Chlorofluoromethanes in the stratosphere and some possible consequences for ozone

Inert chlorofluoromethanes are used by man as refrigerants and aerosol propellants. These substances eventually escape and diffuse upward into the stratosphere. At great enough heights, UV sunlight can photodissociate these chlorofluorocarbons into chlorine atoms which will catalytically destroy ozone molecules. Chlorofluoromethane production has been increasing steadily in recent years to its present level of about a megaton per year, and chlorofluorocarbon usage will probably continue to grow in the future. Calculations with a one-dimensional time-dependent atmospheric model suggests that, if projected increases in chlorofluoromethane use materialize and there is no tropospheric destruction mechanism for these gases, the total global abundance of ozone may be reduced by more than 20 per cent over the next 50 years. If the residence times for these fluorocarbons in the troposphere are in the range of 10-30 years, however, predicted ozone depletions would be significantly smaller.

Turco, R. P.↗

An Assessment of the Surface Longwave Direct Radiative Effect of Airborne Dust in Zhangye China During the Asian Monsoon Year Field Experiment (2008)

Tiny suspensions of solid particles or liquid droplets, called aerosols, hover in earth's atmosphere and can be found over just about anywhere including oceans, deserts, vegetated areas, and other global regions. Aerosols come in a variety of sizes, shapes, and compositions which depend on such factors as their origin and how long they have been in the atmosphere (i.e., their residence time). Some of the more common types of aerosols include mineral dust and sea salt which get lifted from the desert and ocean surfaces, respectively by mechanical forces such as strong winds. Depending on their size, aerosols will either fall out gravitationally, as in the case of larger particles, or will remain resident in the atmosphere where they can undergo further change through interactions with other aerosols and cloud particles. Not only do aerosols affect air quality where they pose a health risk, they can also perturb the distribution of radiation in the earth-atmosphere system which can inevitably lead to changes in our climate. One aerosol that has been in the forefront of many recent studies, particularly those examining its radiative effects, is mineral dust. The large spatial coverage of desert source regions and the fact that dust can radiatively interact with such a large part of the electromagnetic spectrum due to its range in particle size, makes it an important aerosol to study. Dust can directly scatter and absorb solar and infrared radiation which can subsequently alter the amount of radiation that would otherwise be present in the absence of dust at any level of the atmosphere like the surface. This is known as radiative forcing. At the surface dust can block incoming solar energy, however at infrared wavelengths, dust acts to partially compensate the solar losses. Evaluating the solar radiative effect of dust aerosols is relatively straightforward due in part to the relatively large signal-to-noise ratio in the measurements. At infrared wavelengths, on the other hand, the effect is rather difficult to ascertain since the measured dust signal level is on the same order as the instrumental uncertainties. Although the radiative impact of dust is much smaller in the infrared, it can still have a noticeable influence on the distribution of energy in the Earth-atmosphere system. This is mainly attributed to the strong light-absorptive properties commonly found in many earth minerals.

Hansell, Richard A.↗

Development and Implementation of Non-Newtonian Rheology Into the Generalized Fluid System Simulation Program (GFSSP)

One of the goals of this program was to develop the experimental and analytical/computational tools required to predict the flow of non-Newtonian fluids through the various system components of a propulsion system: pipes, valves, pumps etc. To achieve this goal we selected to augment the capabilities of NASA's Generalized Fluid System Simulation Program (GFSSP) software. GFSSP is a general-purpose computer program designed to calculate steady state and transient pressure and flow distributions in a complex fluid network. While the current version of the GFSSP code is able to handle various systems components the implicit assumption in the code is that the fluids in the system are Newtonian. To extend the capability of the code to non-Newtonian fluids, such as silica gelled fuels and oxidizers, modifications to the momentum equations of the code have been performed. We have successfully implemented in GFSSP flow equations for fluids with power law behavior. The implementation of the power law fluid behavior into the GFSSP code depends on knowledge of the two fluid coefficients, n and K. The determination of these parameters for the silica gels used in this program was performed experimentally. The n and K parameters for silica water gels were determined experimentally at CFDRC's Special Projects Laboratory, with a constant shear rate capillary viscometer. Batches of 8:1 (by weight) water-silica gel were mixed using CFDRC s 10-gallon gelled propellant mixer. Prior to testing the gel was allowed to rest in the rheometer tank for at least twelve hours to ensure that the delicate structure of the gel had sufficient time to reform. During the tests silica gel was pressure fed and discharged through stainless steel pipes ranging from 1", to 36", in length and three diameters; 0.0237", 0.032", and 0.047". The data collected in these tests included pressure at tube entrance and volumetric flowrate. From these data the uncorrected shear rate, shear stress, residence time, and viscosity were evaluated using formulae for non-Newtonian, power law fluids. The maximum shear rates (corrected for entrance effects) obtained in the rheometer with the current setup were in the 150,000 to 170,000sec- range. GFSSP simulations were performed with a flow circuit simulating the capillary rheometer and using Power Law gel viscosity coefficients from the experimental data. The agreement between the experimental data and the simulated flow curves was within +/-4% given quality entrance effect data.

DiSalvo, Roberto↗

Preliminary studies of autoignition and flashback in a premixing-prevaporizing flame tube using Jet-A fuel at lean equivalence ratios

Lean equivalence ratios from 0.3 to 0.7 were observed. Combustor inlet air pressures were varied from 0.54 to 2.5 MPa, combustor inlet air temperatures from 550 to 700 K, and reference velocities from 8 to 35 meters per second. Autoignition delay times ranged from 15 to 100 milliseconds and varied inversely with pressure. The Arrhenius activation energy was 41,840 joules per mole. Temperature rise data were obtained in a long premixing-prevaporizing tube at a pressure of 0.56 MPa. Preflame temperature rise data were a function of equivalence ratio, inlet air temperature, and tube residence time. Significant temperature rise occurred above temperatures of 760 K, with autoignition occurring at 775 K for equivalence ratios greater than 0.47. The reactions were similar to cool-flame phenomena. Flashback velocities were measured at temperatures of 610 and 700 K, pressure of 0.56 MPa, and equivalence ratios from 0.6 to 1. Flashback velocities varied from 30 to 65 meters per second.

Marek, C. J.↗