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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Probing the electrolyte/electrode interface with vibrational sum frequency generation spectroscopy: A review

Over the past decades, Lithium-ion batteries have seen extensive improvements, and as a result are now the primary choice in many applications for their power, energy, and durability. In recent years, battery cost has reduced by orders of magnitude through adoption of new materials and processes. Despite these advances, interfaces in these battery systems are yet to be fully understood. This is seen as a major limitation to further increase cycle life, calendar life, abuse tolerance, and performances. A major obstacle is a lack of comprehensive understanding of the complex dynamic chemical processes occurring at the electrolyte/electrode interface. In this context, vibrational sum frequency generation (vSFG) spectroscopy possesses the unique capability of probing a molecularly thin interfacial layer to obtain molecular-level information through nonlinear optical interaction. Probing the molecular level processes at the interfaces using such a versatile technique would be a game changer in the advancement of current battery research knowledge. This review article summarizes recent vSFG studies on the electrolyte/electrode interface of various electrode materials and nonaqueous electrolytes for LIBs and discusses future research perspectives. Finally, overall, this focused review highlights the advantages and versatility of vSFG that can be used to further advance present-day battery research.

25 ENERGY STORAGE↗
NASA NTRS2023

Implementing the GEOSS Water Strategy: From Observations to Decisions

In 2014, The GEOSS Water Strategy – From Observations to Decisions was published and steps were taken to implement the Strategy’s recommendations. The Strategy highlighted priority areas where the application of Earth observations to water research and water management decisions would have significant scientific and societal benefits. This article reviews the implementation of the Strategy’s recommendations over the past eight years. After a review of the Strategy’s assessment of the needs for water observations and their applications, it then reviews actions taken in response to the Strategy’s recommendations in its four major themes: improved data acquisition for Essential Water Variables, research and product development, interoperability, and capacity development. It highlights significant achievements in the implementation of the Strategy including some motivated by factors beyond this Strategy, reviews actions taken by participating agencies and programs for each of the main themes and summarizes the remaining challenges in achieving the Strategy’s full implementation. The article not only is an update for the Water Community regarding the GEOSS Water Strategy, but it is also an example of how other communities could develop and promulgate a set of strategic recommendations, monitor progress, and carry out assessments of their effectiveness.

Earth observations↗
DOE OSTI2019

Glass Transition Phenomenon for Conjugated Polymers

Conjugated polymers are emerging as promising building blocks for a broad range of modern applications including skin-like electronics, wearable optoelectronics, and sensory technologies. In the past three decades, the optical and electronic properties of conjugated polymers have been extensively studied, while their thermomechanical properties, especially the glass transition phenomenon which fundamentally represents the polymer chain dynamics, have received much less attention. Currently, there is a lack of design rules that underpin the glass transition temperature of these semirigid conjugated polymers, putting a constraint on the rational polymer design for flexible stretchable devices and stable polymer glass that is needed for the devices' long-term morphology stability. In this review article, the glass transition phenomenon for polymers, glass transition theories, and characterization techniques are first discussed. Furthermore, previous studies on the glass transition phenomenon of conjugated polymers are reviewed and a few empirical design rules are proposed to fine-tune the glass transition temperature for conjugated polymers. The review paper is finished with perspectives on future directions on studying the glass transition phenomena of conjugated polymers. The goal of this perspective is to draw attention to challenges and opportunities of controlling, predicting, and designing polymeric semiconductors, specifically to accommodate their end use.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Management of Low-Flow Vascular Malformations: Clinical Presentation, Classification, Patient Selection, Imaging and Treatment

This review article aims to give an overview of the current state of imaging, patient selection, agents and techniques used in the management of low-flow vascular malformations. The review includes the current classifications for low-flow vascular malformations including the 2014 updates. Clinical presentation and assessment is covered with a detailed section on the common sclerosant agents used to treat low-flow vascular malformations, including dosing and common complications. Imaging is described with a guide to a simple stratification of the use of imaging for diagnosis and interventional techniques.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2017

A review of slip transfer: applications of mesoscale techniques

In this review article, we present and discuss recent mesoscale modeling studies of slip transmission of dislocations through biphase interfaces. Specific focus is given to fcc/fcc material systems. We first briefly review experimental, atomistic, and continuum-scale work that has helped to shape our understanding of these systems. Then several mesoscale methods are discussed, including Peierls–Nabarro models, discrete dislocation dynamics models, and phase field-based techniques. Recent extensions to the mesoscale mechanics technique called phase field dislocation dynamics are reviewed in detail. Results are compiled and discussed in terms of the proposed guidelines that relate composite properties to the critical stress required for a slip transmission event.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Functional stimuli-responsive polymers on micro- and nano-patterned interfaces

Micro- and nano-patterned surfaces offer precise control over morphology and chemical composition, enhancing the stability, durability, and functionality of coating materials. When combined with stimuli-responsive polymers, these surfaces gain dynamic adaptability, enabling reversible binding, reusable sensing, and selective molecular capture. Furthermore, while recent review articles have explored various aspects of stimuli-responsive materials, from hydrogel patterns for bioanalytical applications to shape-morphing hydrogels for soft robotics and sensors, a comprehensive review focused on the integration of smart polymers with micro- or nano-patterned interfaces remains absent. This review addresses key surface patterning techniques, including soft lithography, colloidal lithography, and polymer brush photolithography, as well as advances in surface-initiated polymerization methods, such as surface-initiated controlled radical polymerization (SI-CRP). In addition, we discuss recent progress in integrating stimuli-responsive polymers with patterned surfaces to create advanced, functional materials.

Colloidal lithography↗
DOE OSTI2019

Thermal Conductivity Reduction in a Nanophononic Metamaterial versus a Nanophononic Crystal: A Review and Comparative Analysis

Abstract The notion of a locally resonant metamaterial—widely applied to light and sound—has recently been introduced to heat, whereby the thermal conductivity is reduced primarily by intrinsic localized atomic vibrations rather than scattering mechanisms. This article reviews and analyzes this new emerging concept, termed nanophononic metamaterial (NPM), and contrasts it with the competing concept of a nanophononic crystal (NPC) in which thermal conductivity reduction is realized primarily via nanoscale Bragg scattering. Both the NPM and NPC core mechanisms require the presence of a sufficient level of wave behavior, which is possible when there is a relatively wide distribution of the phonon mean free path (MFP). Silicon serves as a perfect material to form NPMs and NPCs given its relatively large average phonon MFP. This offers a unique opportunity considering silicon's abundance and mature fabrication technology. It is shown in this comparative study that while both the NPM and NPC nanosystems may be rendered to serve as extreme insulators of heat, an NPM may do so without excessive reduction in the minimum feature size–which is key to keeping the electrical properties intact. This trait makes a silicon‐based NPM poised to serve as a low‐cost thermoelectric material with exceptional performance.

Hussein, Mahmoud I.↗
DOE OSTI2024

Silica–Derived Nanostructured Electrode Materials for ORR, OER, HER, CO 2 RR Electrocatalysis, and Energy Storage Applications: A Review**

Silica-derived nanostructured catalysts (SDNCs) are a class of materials synthesized using nanocasting and templating techniques, which involve the sacrificial removal of a silica template to generate highly porous nanostructured materials. The surface of these nanostructures is functionalized with a variety of electrocatalytically active metal and non-metal atoms. SDNCs have attracted considerable attention due to their unique physicochemical properties, tunable electronic configuration, and microstructure. These properties make them highly efficient catalysts and promising electrode materials for next generation electrocatalysis, energy conversion, and energy storage technologies. The continued development of SDNCs is likely to lead to new and improved electrocatalysts and electrode materials. This review article provides a comprehensive overview of the recent advances in the development of SDNCs for electrocatalysis and energy storage applications. It analyzes 337,061 research articles published in the Web of Science (WoS) database up to December 2022 using the keywords “silica”, “electrocatalysts”, “ORR”, “OER”, “HER”, “HOR”, “CO 2 RR”, “batteries”, and “supercapacitors”. The review discusses the application of SDNCs for oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), carbon dioxide reduction reaction (CO 2 RR), supercapacitors, lithium-ion batteries, and thermal energy storage applications. It concludes by discussing the advantages and limitations of SDNCs for energy applications.

25 ENERGY STORAGE↗
DOE OSTI2021

On the additive manufacturing (3D printing) of viscoelastic materials and flow behavior: From composites to food manufacturing

Additive manufacturing (AM) or more commonly known as 3D-printing has gained much ground in industrial manufacturing because of its breakthrough in rapid prototyping and processes. To date, the 3D-printing market has grown significantly and is poised for growth in line with digitization of manufacturing. Furthermore, the main objective of this review article focuses on the viscoelastic behavior (viscous solution) of 3D printing materials at ambient conditions, which are not essentially under melt-flow or higher temperatures. The initial section reviews the basic concepts on viscosity and viscoelastic phenomenon, with emphasis on the preferred conditions a viscous material should have prior to 3D-printing. Several examples of structures formed from viscoelastic materials through 3D-printing are also detailed, as well as the various curing techniques for different printed objects or models. While there is much interest on industrial applications, the last part surveys various food formulations used for 3D-printing.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Nonlinear magneto-plasmonics

Nonlinear magneto-plasmonics (NMP) describes systems where nonlinear optics, magnetics and plasmonics are all involved. In such systems, nonlinear magneto-optical Kerr effect (nonlinear MOKE) plays an important role as a characterization method, and Surface Plasmons (SPs) work as catalyst to induce many new effects. Magnetization-induced second-harmonic generation (MSHG) is the major nonlinear magneto-optical process involved. The new effects include enhanced MSHG, controlled and enhanced magnetic contrast, etc. Nanostructures such as thin films, nanoparticles, nanogratings, and nanoarrays are critical for the excitation of SPs, which makes NMP an interdisciplinary research field in nanoscience and nanotechnology. In this review article, we organize recent work in this field into two categories: surface plasmon polaritons (SPPs) representing propagating surface plasmons, and localized surface plasmons (LSPs), also called particle plasmons. We review the structures, experiments, findings, and the applications of NMP from various groups.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Progress in Theoretical Study of Metal Halide Perovskite Solar Cell Materials

Lead halide perovskites have recently emerged as promising absorbers for fabricating low-cost and high-efficiency thin-film solar cells. The record power conversion efficiency of lead halide perovskite-based solar cells has rapidly increased from 3.8% in 2009 to 22.1% in early 2016. Such rapid improvement is attributed to the superior and unique photovoltaic properties of lead halide perovskites, such as the extremely high optical absorption coefficients and super-long photogenerated carrier lifetimes and diffusion lengths that are not seen in any other polycrystalline thin-film solar cell materials. In the past a few years, theoretical approaches have been extensively applied to understand the fundamental mechanisms responsible for the superior photovoltaic properties of lead halide perovskites and have gained significant insights. Here, this review article highlights the important theoretical results reported in literature for the understanding of the unique structural, electronic, optical, and defect properties of lead halide perovskite materials. For comparison, we also review the theoretical results reported in literature for some lead-free perovskites, double perovskites, and nonperovskites.

14 SOLAR ENERGY↗
DOE OSTI2022

Materials for electrification of everything: Moving toward sustainability

We report society is at a unique tipping point in a move from conventional fossil fuel based technologies to renewable sourced electrified technologies which can enable creating a carbon neutral or carbon negative energy economy. Many of the key approaches to achieving this transition in the critical areas of transportation, buildings and manufacturing depend on new materials and new approaches to rapidly increase electrification. This article reviews the overall energy landscape and highlights specific areas where new materials are critical to enabling transitions in energy storage, hydrogen utilization, transportation, buildings and the chemical industry and the articles on these topics that follow. How these transitions can be best integrated and the global societal impact of these transitions is also discussed. The development of new materials is instrumental in accelerating the move to a cleaner electrified society. The "electrification of everything" is increasingly important if we are to mitigate the adverse effects of climate change and materials will play a critical role realizing this goal.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Structure-based mechanism and inhibition of cholesteryl ester transfer protein

Purpose of Review: Cholesteryl ester transfer proteins (CETP) regulate plasma cholesterol levels by transferring cholesteryl esters (CEs) among lipoproteins. Lipoprotein cholesterol levels correlate with the risk factors for atherosclerotic cardiovascular disease (ASCVD). This article reviews recent research on CETP structure, lipid transfer mechanism, and its inhibition. Recent Findings: Genetic deficiency in CETP is associated with a low plasma level of low-density lipoprotein cholesterol (LDL-C) and a profoundly elevated plasma level of high-density lipoprotein cholesterol (HDL-C), which correlates with a lower risk of atherosclerotic cardiovascular disease (ASCVD). However, a very high concentration of HDL-C also correlates with increased ASCVD mortality. Considering that the elevated CETP activity is a major determinant of the atherogenic dyslipidemia, i.e., pro-atherogenic reductions in HDL and LDL particle size, inhibition of CETP emerged as a promising pharmacological target during the past two decades. CETP inhibitors, including torcetrapib, dalcetrapib, evacetrapib, anacetrapib and obicetrapib, were designed and evaluated in phase III clinical trials for the treatment of ASCVD or dyslipidemia. Although these inhibitors increase in plasma HDL-C levels and/or reduce LDL-C levels, the poor efficacy against ASCVD ended interest in CETP as an anti-ASCVD target. Nevertheless, interest in CETP and the molecular mechanism by which it inhibits CE transfer among lipoproteins persisted. Insights into the structural-based CETP-lipoprotein interactions can unravel CETP inhibition machinery, which can hopefully guide the design of more effective CETP inhibitors that combat ASCVD. Summary: Individual-molecule 3D structures of CETP bound to lipoproteins provide a model for understanding the mechanism by which CETP mediates lipid transfer and which in turn, guide the rational design of new anti-ASCVD therapeutics.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Novel scalings of neutron star properties from analyzing dimensionless Tolman–Oppenheimer–Volkoff equations

The Tolman–Oppenheimer–Volkoff (TOV) equations govern the radial evolution of pressure and energy density in static neutron stars (NSs) in hydrodynamical equilibrium. Using the reduced pressure and energy density with respect to the NS central energy density, the original TOV equations can be recast into dimensionless forms. While the traditionally used integral approach for solving the original TOV equations require an input nuclear Equation of State (EOS), the dimensionless TOV equations can be anatomized by using the reduced pressure and energy density as polynomials of the reduced radial coordinate without using any input nuclear EOS. It has been shown in several of our recent works that interesting and novel perspectives about NS core EOS can be extracted directly from NS observables by using the latter approach. Our approach is based on intrinsic and perturbative analyses of the dimensionless (IPAD) TOV equations (IPAD-TOV). In this review article, we first discuss the length and energy density scales of NSs as well as the dimensionless TOV equations for scaled variables and their perturbative solutions near NS cores. We then review several new insights into NS physics gained from solving perturbatively the scaled TOV equations. Whenever appropriate, comparisons with the traditional approach from solving the original TOV equations will be made. In particular, we first show that the nonlinearity of the TOV equations basically excludes a linear EOS for dense matter in NS cores. We then show that perturbative analyses of the scaled TOV equations enable us to reveal novel scalings of the NS mass, radius and the compactness with certain combinations of the NS central pressure and energy density. Thus, observational data on either mass, radius or compactness can be used to constrain directly the core EOS of NS matter independent of the still very uncertain nuclear EOS models. As examples, the EOS of the densest visible matter in our Universe before the most massive neutron stars collapse into black holes (BHs) as well as the central EOS of a canonical or a 2.1 solar mass NS are extracted without using any nuclear EOS model. In addition, we show that causality in NSs sets an upper bound of about 0.374 for the ratio of pressure over energy density and correspondingly a lower limit for trace anomaly in supra-dense matter. We also demonstrate that the strong-field gravity plays a fundamental role in extruding a peak in the density/radius profile of the speed of sound squared (SSS) in massive NS cores independent of the nuclear EOS. Finally, some future perspectives of NS research using the new approach reviewed here by solving perturbatively the dimensionless TOV equations are outlined.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Review of the Clinical and Biologic Aspects of Human Papillomavirus-Positive Squamous Cell Carcinomas of the Head and Neck

Human papillomavirus (HPV), a known etiology of a subset of head-and-neck squamous cell carcinomas (HNCs), causes numerous alterations in normal cellular functions. This article reviews the biology, detection, and treatment of HPV-positive HNC. The role of HPV oncoproteins in tumor development, the natural history of HPV infection, and risk factors for and prevention of transmission of oral HPV are considered. Commonly used methods for detecting HPV infection, including limitations of these methods, are discussed to aid the practicing clinician in using these tests in their clinical practice. Clinical characteristics of HPV-positive HNC, including potential explanations for the improved outcomes seen in patients with HPV-positive HNC, are assessed. Ongoing clinical trials specific for patients with HPV-positive HNC are described, and areas in need of additional research are summarized. Until the results of ongoing trials are known, treatment of HPV-positive HNC should not differ in clinical practice from treatment of similar non-HPV related cancers.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2022

Searching for Pairs of Higgs Bosons in the LHC Run 2 Dataset

The discovery of the Higgs boson confirms the existence of a scalar sector of the standard model, responsible for electroweak symmetry breaking, but the nature and properties of the potential at the origin of this mechanism are still unknown. By studying the production of pairs of Higgs bosons (HH), physicists can directly measure the coupling of the Higgs boson to itself and thus determine the shape of this potential, which has far-reaching implications on the origin and evolution of our Universe. Because of this deep connection to the foundations of electroweak symmetry breaking, HH production is also an ideal place to search for manifestations of yet-unknown physics, such as modifications of the strength of the self-coupling and of the interaction between pairs of vector bosons and Higgs bosons. In this review article, we summarize the current searches for HH production at ATLAS and CMS, using the LHC Run 2 dataset, discuss the implications of our current constraints on physics beyond the standard model, and briefly review prospect for future HH searches.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Recent Advances in the Chemistry of Hydrometallurgical Methods

Producing pure substances has been the obsession of scientists for centuries and has defined chemistry as we know it. Nowadays, most of our economy still relies on the chemist ability to extract and purify metallic elements from raw or recycled materials, which, in most cases, is done partly or entirely via hydrometallurgical methods. In this work, the authors present the critical aspects of this relatively overlooked, yet critical, chemistry discipline. This review article highlights the importance of hydrometallurgical processes for strategic industrial sectors, put in perspective traditional separation methods with emerging ones (new metal-binding chelators, ionic liquids, deep eutectic solvents, microfluidic devices, biomaterials, etc.), critically reviews progress made on separation methods over the past two decades, and highlights the challenges lying ahead for the hydrometallurgists in academia and the industry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Optical nanostructures design, fabrication, and applications for solar/thermal energy conversion

Optical nanostructures can control the optical absorption and emission properties of surfaces and are therefore being investigated for solar thermophotovoltaics, thermophotovoltaics, solar thermal, infrared sensing, infrared sources, incandescent light sources, and thermal imaging applications, among many others. This review article describes various modeling methods available for design of optical nanostructures to control light absorption and emission properties of surfaces, as well as various methods available for the fabrication of large area nanostructured surfaces. Throughout the review, we provide examples of state of the art energy generation devices using such optical nanostructures. A discussion of outstanding obstacles for the achievement of high efficiency solar thermophotovoltaics systems is provided along with examples of systems showing exceptional promise.

Gupta, Mool C.↗