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At least 127 records · Page 7

Oak Ridge National Laboratory Analysis of Waste Isolation Pilot Plant Samples: Integrated Summary Report

Nondestructive and destructive analytical methods were used to analyze samples of debris collected from the top of R15 C5, the lip of R16 C4, the parent drum, and the continuous air monitor (CAM) and fixed air sampler (FAS) filters in addition to MgO samples collected from the tops of R14 C2, R14 C4, R14 C6 and R16 C4. The analytical evidence supports the conclusion that an exothermic oxidation reaction of Swheat Scoop® by metal nitrate salts produced sufficient quantities of gas to breach drum 68660. The metals and the acidic environment found in drum 68660 are known to accelerate these oxidation reactions. Moreover, the ratio of metal nitrate salts in drum 68660 was in a range in which a low melting eutectic mixture could form, which would also accelerate the oxidation reactions. Nitrated organics were not detected and they are not necessary to produce the exothermic reaction leading to the breach of drum 68660. All the contents of the drum were not consumed and the material ejected from drum 68660 either did not experience temperatures over 200 °C, or their exposure to elevated temperatures was very limited in duration (<seconds).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Simultaneous Thermal Analysis of WIPP and LANL Waste Drum Samples: A Preliminary Report

On Friday, February 14, 2014, an incident in P7R7 of the WIPP underground repository released radioactive material into the environment. The direct cause of the event was a breached transuranic (TRU) waste container, subsequently identified as Drum 68660. Photographic and other evidence indicates that the breach of 68660 was caused by an exothermic event. Subsequent investigations (Britt, 2015; Clark and Funk, 2015; Wilson et al., 2015; Clark, 2015) indicate that the combination of nitrate salts, pH neutralizing chemicals, and organic-based adsorbent represented a potentially energetic mixture. The materials inside the breached steel drum consisted of remediated, 30- to 40-year old, Pu processing wastes from LANL. The contents were processed and repackaged in 2014. Processing activities at LANL included: 1) neutralization of acidic liquid contents, 2) sorption of the neutralized liquid, and 3) mixing of acidic nitrate salts with an absorber to meet waste acceptance criteria. The contents of 68660 and its sibling, 68685, were derived from the same parent drum, S855793. Drum S855793 originally contained ten plastic bags of acidic nitrate salts, and four bags of mixed nitrate and oxalate salts generated in 1985 by Pu recovery operations. These salts were predominantly oxalic acid, hydrated nitrate salts of Mg, Ca, and Fe, anhydrous Na(NO 3 ), and minor amounts of anhydrous and hydrous nitrate salts of Pb, Al, K, Cr, and Ni. Other major components include sorbed water, nitric acid, dissolved nitrates, an absorbent (Swheat Scoop®) and a neutralizer (KolorSafe®). The contents of 68660 are described in greater detail in Appendix E of Wilson et al. (2015)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Deformed Materials: Towards a Theory of Materials Morphology Dynamics

This grant supported work on the response of crystals to external stress. Our primary work described how disordered structural materials break in two (statistical models of fracture in disordered materials), studied models of deformation bursts (avalanches) that mediate deformation on the microscale, and developed continuum dislocation dynamics models for plastic deformation (as when scooping ice cream bends a spoon, Fig. 9). Glass is brittle -- it breaks with almost atomically smooth fracture surfaces. Many metals are ductile -- when they break, the fracture surface is locally sheared and stretched, and it is this damage that makes them hard to break. Bone and seashells are made of brittle material, but they are strong because they are disordered -- lots of little cracks form as they are sheared and near the fracture surface, diluting the external force. We have studied materials like bone and seashells using simulations, mathematical tools, and statistical mechanics models from physics. In particular, we studied the extreme values of fracture strengths (how likely will a beam in a bridge break far below its design strength), and found that the traditional engineering tools could be improved greatly. We also studied fascinating crackling-noise precursors -- systems which formed microcracks of a broad range of sizes before they broke. Ductile metals under stress undergo irreversible plastic deformation -- the planes of atoms must slide across one another (through the motion of dislocations) to change the overall shape in response to the external force. Microscopically, the dislocations in crystals move in bursts of a broad range of sizes (termed 'avalanches' in the statistical mechanics community, whose motion is deemed 'crackling noise'). In this grant period, we resolved a longstanding mystery about the average shape of avalanches of fixed duration (using tools related to an emergent scale invariance), we developed the fundamental theory describing the shapes of avalanches and how they are affected by the edges of the microscope viewing window, we found that slow creep of dislocations can trigger an oscillating response explaining recent experiments, we explained avalanches under external voltage, and we have studied how avalanches in experiments on the microscale relate to deformation of large samples. Inside the crystals forming the metal, the dislocations arrange into mysterious cellular structures, usually ignored in theories of plasticity. Writing a natural continuum theory for dislocation dynamics, we found that it spontaneously formed walls -- much like models of traffic jams and sonic booms. These walls formed rather realistic cellular structures, which we examined in great detail -- our walls formed fractal structures with fascinating scaling properties, related to those found in turbulent fluids. We found, however, that the numerical and mathematical tools available to solve our equations were not flexible enough to incorporate materials-specific information, and our models did not show the dislocation avalanches seen experimentally. In the last year of this grant, we wrote an invited review article, explaining how plastic flow in metals shares features with other stressed materials, and how tools of statistical physics used in these other systems might be crucial for understanding plasticity.

36 MATERIALS SCIENCE↗

Waste Control Specialists Technical Review Team Report

1. Modeling of Drum 68660 and the WCS Drums: A calibrated model of Los Alamos National Laboratory (LANL) Drum 68660 indicates that pressurization of the drum by restriction of drum venting could have led to the thermal runaway reaction at the Waste Isolation Pilot Plant (WIPP) in 2014, supporting the hypothesis that the contents of the drum were not fundamentally different from the overall remediated nitrate salt (RNS) waste stream. 2. Nitric Acid Reactions and Aging of the Waste: The stability of the WCS RNS waste with respect to autocatalytic thermal runaway due to nitric acid chemistry should increase over time as the nitric acid is depleted from chemical reactions in the drum. However, this cannot be confirmed because of the lack of long-term experimental data on the impact of aging on the reactivity of RNS waste. The calibrated model indicates that the waste drums retain most of their reactive components, metal nitrate salts and sWheat Scoop ® , even after eight years. 3. Pressure Effects and Runaway Reactions: The calibrated model indicates that if the drums and standard waste boxes (SWBs) are not allowed to pressurize during transport or storage and they are stored at historical WIPP repository temperatures, then an autocatalytic thermal runaway event is not expected to occur. Since the cause of Drum 68660 pressurization is not known, decision makers are not able to tailor mitigating strategies to the initiating event. Consequently, mitigating strategies must consider all feasible internal and external events that could lead to the pressurization of the drums. 4. Temperature Effects and Runaway Reactions: Temperature also has a strong influence on the stability of the waste. The calibrated model indicates that cooling the drums or SWBs can reduce the possibility of autocatalytic thermal runaway reactions. Simulations suggest that for a drum with a plugged vent, the probability of thermal runaway may be reduced or eliminated if wastes are maintained at or below 43 °F through active cooling measures from the initiation of transport until emplacement at WIPP.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

WCM water content for ACE-ENA

The WCM-2000, manufactured by Science Engineering Associates (SEA), is a multi-element water content measuring system that measures both liquid water content (LWC) and total water content (TWC), allowing the inference of ice water content (IWC). The TWC is measured by a scoop-shaped sensor that collects both liquid and ice phase hydrometeors. The WCM-2000 also has two heated wire elements that are exposed directly to the airstream and a reference or compensation element that is exposed to the airflow but not the condensed water. The two heated wires measure the LWC for different size droplets and are sized to match the Johnson-Williams (JW) (021 Wire) LWC probe (0.5 mm; Neel 1955) and the King (083 Wire) probe (2 mm; King et al. 1978). The WCM-2000 is calibrated according to the manufacturer instructions, which involve a dedicated test flight in cloud-free air. Each flight is also corrected for zero-offset bias using clear-air measurements

54 ENVIRONMENTAL SCIENCES↗

Development of an Advanced Annular Combustor

The objective of the effort described in this report was to determine the structural durability of a full-scale advanced annular turbojet combustor using ASTM A-1 type fuel and operating at conditions typical of advanced supersonic aircraft. A full-scale annular combustor of the ram-induction type was fabricated and subjected to a 325-hour cyclic endurance test at conditions representative of operation in a Mach 3.0 aircraft. The combustor exhibited extensive cracking and scoop burning at the end of the test program. But these defects had no appreciable effect on combustor performance, as performance remained at a high level throughout the endurance program. Most performance goals were achieved with pressure loss values near 6% and 8%, and temperature rise variation ratio (deltaTVR) values near 1.25 and l.22 at takeoff and cruise conditions, respectively. Combustion efficiencies approached l004 and the exit radial temperature profiles were approximately as desired.

Rusnak, J. P.↗

Gas turbine combustor insensitive to compressor outlet distortion

Short-length annular combustor for turbojet engines eliminates change of exit temperature profile. Individual scoops of full annular height control air distribution so that shifts in the radial velocity profile of air entering the combustor will not affect combustion process or alter exit temperature profile.

Humenik, F.↗

Automatic air flow control in air conditioning ducts

Device is designed which automatically selects air flow coming from either of two directions and which can be adjusted to desired air volume on either side. Device uses one movable and two fixed scoops which control air flow and air volume.

Obler, H. D.↗

Solar and galactic cosmic ray exposure of Surveyor 3 as determined from cosmogenic radionuclide measurements

The proton-produced Na-22 content of samples of Surveyor 3 TV camera, surface sampler scoop, and other components was determined by nondestructive gamma ray spectrometry. The contributions of the nine most prominent solar flares to Na-22 production were calculated to be 18 dpm/kg. The observed activity in the Surveyor 3 samples was 62 + or - dpm/kg. This indicates a galactic proton contribution of about 44 dpm/kg, which adjusted for spallation of Al gives a value of 42 dpm/kg. This is compared to measurements of 88 dpm/kg in the Lost City meteorite which had an orbit extending to 2.35 AU, with a 4 pi bombardment as compared to the 2 pi bombardment of the samples on the lunar surface. The agreement between Na-22 production in Surveyor 3 and the Lost City meteorite offers evidence that the galactic cosmic ray flux is almost the same at 1 Au and at 2.35 AU.

Rancitelli, L. A.↗

Spacecraft orientation and exposure to environment, Appendix A

Material removed from the spacecraft and returned to earth remained on the lunar surface for 31.9 lunations. None of the returned parts received the maximum 10,686 hours of exposure because of shadowing by the planar array antenna, solar panel, thermal control compartments, or other parts of the spacecraft. To determine the actual exposure of specific parts to sunlight, six series of photographs were taken. A one-fifth-scale model spacecraft was oriented to a collimated light source simulating the orientation of Surveyor with the sun. Three cameras were set up to view different parts of the spacecraft. The data obtained from these photographs permitted an evaluation of the effects of exposure to solar radiation on the camera and its parts, the surface sampling scoop, and the strut from the radar altimeter and Doppler velocity sensor.

Nickle, N. L.↗

Bearing strength of lunar soil.

Bearing load vs penetration curves have been measured on a 1.3 g sample of lunar soil from the scoop of the Surveyor 3 soil mechanics surface sampler, using a circular indentor 2 mm in diameter. Measurements were made in an Earth laboratory, in air. This sample provided a unique opportunity to evaluate earlier, remotely controlled, in-situ measurements of lunar surface bearing properties. Bearing capacity, measured at a penetration equal to the indentor diameter, varied from 0.02-0.04 N/sq cm at bulk densities of 1.15 g/cu cm to 30-100 N/sq cm at 1.9 g/cu cm. Deformation was by compression directly below the indentor at bulk densities below 1.61 g/cu cm, by outward displacement at bulk densities over 1.62 g/cu cm. Preliminary comparison of in-situ remote measurements with those on returned material indicates good agreement if the lunar regolith at Surveyor 3 has a bulk density of 1.6 g/cu cm at 2.5 cm depth.

Jaffe, L. D.↗

Evaluation of an experimental short-length annular combustor: One-side-entry dilution airflow concept

A test program was conducted to evaluate an experimental short-length annular combustor that uses a one-side-entry dilution airflow concept. The combustor design features scoops on the outer liner for controlling the primary- and secondary-zone airflow distribution. Combustor inlet total pressures were limited to 62 N/sq cm (90 psia) with inlet-air temperatures from 590 K (600 F) to 890 K (1150 F). At a diffuser inlet Mach number of 0.25, the exit temperature pattern factor was 0.44 with an average exit temperature of 1436 K (2124 F) and a total pressure loss of 4.3 percent. At a diffuser inlet Mach number of 0.31, the exit temperature pattern factor was reduced to 0.29 with an average exit temperature of 1450 K (2151 F) and a total pressure loss of 6.1 percent. Nominal combustion efficiencies of 100 percent were obtained with the ASTM A-1 fuel. Exhaust gas emissions, smoke, and altitude relight data are included with exit-temperature profiles and distribution patterns.

Humenik, F. M.↗

Aircraft water vapor measurements utilizing an aluminum oxide hygrometer

A hygrometer for water vapor measurements from an aircraft has been developed. An aluminum oxide hygrometer mounted in an aircraft Rosemount air temperature scoop was flown on NASA and USAF aircraft. Water vapor measurements were conducted up to 40,000 feet with penetration into the stratosphere. Good agreement was obtained with simultaneously flown remote sounders of water vapor. During transcontinental flights the hygrometer demonstrated adequate response to measure the natural variability of water vapor near the tropopause. Rapid response was demonstrated in pursuit of the jet wake of an F-104 at 35,000 feet.

Hilsenrath, E.↗

High altitude aircraft water vapor measurements.

A hygrometer for water vapor measurements from an aircraft was developed. An aluminum oxide hygrometer mounted in an aircraft Rosemount air temperature scoop was flown on the NASA Convair 990 and on a USAF B-57 aircraft. Water vapor measurements from the Convair 990 were conducted up to 40,000 ft with penetration into the stratosphere. Good agreement was obtained with simultaneously flown remote sounders of water vapor. During transcontinental flights the hygrometer demonstrated adequate response to measure the natural variability of water vapor near the tropopause. Rapid response was demonstrated in pursuit of the jet wake of an F-104 at 35,000 ft.

Hilsenrath, E.↗

Shear strength of lunar soil from Oceanus Procellarum.

Soil from the scoop of Surveyor 3, returned to earth by Apollo 12 astronauts, has been tested in a miniature shear box at five bulk densities, from 0.99 to 1.87 g/cu cm. Cohesion increased with bulk density from .03 to .3 N/sq cm; internal friction angle increased from 13 to 56 deg. Shear stress vs normal stress data fit a logarithmic relationship better than a linear one, at normal stresses of .003 to 3 N/sq cm. Results of these tests, in air, show no systematic differences from those for tests made elsewhere in vacuum and nitrogen. Results agree with those obtained in remotely controlled lunar surface operations with Surveyor 3 and other spacecraft provided that the bulk density was slightly underestimated for the on-surface measurements.

Jaffe, L. D.↗