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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Properties of simulated comet mantle

The properties of freeze-dried dilute dispersions of dust in water ice are of considerable interest in studies of comet nucleus mantles. The formation of a rind residue produced by the sublimation of water ice containing various amounts of fine clay particles may be an important process. A simulation of the development of the dry dust rind on the surface of comets is presented. This rind is the result of preferential ice sublimation. The development and disruption of this rind and its subsequent levitation by water vapor flow is studied. The most interesting rind simulant is produced by dispersing 0.1 micron particles of montmorillonite in water in concentrations of 10%, 1%, and 0.1%. These dispersions are then sprayed into liquid nitrogen in the form of 100 micron droplets. The frozen droplets are then freeze-dried in a vacuum which prevents the ice temperature from rising above -30 C. Sublimation of the nitrogen and the water produced dry rinds. The most striking result was the development of large cohesive matrices of individual clay particles, and in some cases a continuous cohesive crust. Scanning electron microscope (SEM) observations reveal that the material formed by freeze-drying the 0.1% dispersion does not retain the original spherical shape of the sprayed 100 micron droplets; instead it consists of a continuous filamentary network, as shown in the SEM stereo micrographs.

Fanale, F. P.↗
NASA NTRS1985

Experimental characterization of fatigue crack tip processes

Many analytical models have been proposed to describe the physical processes attendant to a fatigue crack tip, as well as the rate at which fatigue cracks grow. By applying advanced experimental methods (such as electron channeling, stereoimaging, and in-situ cyclic loading in an SEM) to a broad range of structural materials, it has been shown that it is possible to critically assess the physical assumptions incorporated into the models. Refinements in existing models and the development of new ones have resulted. New insights into materials' behavior are providing guidelines for improving the fatigue resistance of structural alloys. In the near future, even more advanced experimental methods, such as high temperature SEM stages and small angle neutron scattering, will be available to study creep/fatigue interactions in metals and ceramics.

Lankford, J.↗
NASA NTRS1983

Fungi and bacteria involved in desert varnish formation

Desert varnish is a coating of ferromanganese oxides and clays that develops on rock surfaces in arid to semi-arid regions. Active respiration but not photosynthesis was detected on varnished rock surfaces from the Sonoran Desert. Light microscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations, and cultivation experiments indicate that both fungi, primarily dematiaceous hyphomycetes, and bacteria are found on and within desert varnish coatings from the arid regions studied. Some fungi grow as microcolonial fungi (MCF) on rocks, and microscopic observations suggest MCF become incorporated in the varnish coating. SEM-EDAX (energy dispersive X-ray systems) analyses indicate the MCF contain 3 of the characteristic elements of varnish: iron, aluminum, and silicon. In some locations, MCF are also enriched in manganese relative to the rock substratum. Furthermore, some of the dematiaceous hyphomycetes that have been cultivated are able to oxidize manganese under laboratory conditions. It is possible that manganese-oxidizing bacteria, which are found in varnish, also play an important role in varnish formation.

Taylor-George, S.↗
NASA NTRS1984

The application of thermodynamic and spectroscopic techniques to adhesion in the polyimide/Ti 6-4 and polyphenylquinoxaline/Ti 6-4 systems

The results of calorimetric measurements of Ti adherend surfaces are presented. The measurements were carried out after several chemical pretreatments and after fracture of several lap shear samples aged at high temperature. The exact composition of the Ti samples was Ti(6 percent Al-4 percent V). The adhesives used were polyimides and polyphenylquinoxalines (PPQ). Each chemical pretreatment was accompanied by a unique spectroscopic feature which was characterized by XPS, SEM, and specular reflectance infrared spectroscopy. The energetics of the interaction between primer solutions and the Ti adherend were evaluated by microcalorimetry. Changes in the structure of the surface oxide layer upon heating of the adherend were deduced from immersion temperatures of the PI and PPQ solutions. The XPS and SEM data are given is a table.

Dias, S.↗
NASA NTRS1987

Charge-coupled-device response to electron beam energies of less than 1 keV up to 20 keV

Recent developments of backside treatment for the backside-illuminated scientifc CCD imagers have shown near-theoretical efficiency even at the short wavelength region of the spectrum. By using SEM performance comparisons of backside-treated and untreated CCDs to an electron flux varying from 1 to 100 pA and beam energy ranging from less than 1 keV up to 20 keV are obtained. The theoretical analysis, the SEM testing procedure, and the quantum efficiency measurement results are presented. It is shown, for example, that the average quantum efficiency increases from less than 1 percent for an untreated CCD to nearly 40 percent for a backside-treated CCD at a beam energy of 1 kev.

Daud, Taher↗
NASA NTRS1988

Atmospheric Electrical Modeling in Support of the NASA F-106 Storm Hazards Project

A recently developed storm electrification model (SEM) is used to investigate the operating environment of the F-106 airplane during the NASA Storm Hazards Project. The model is 2-D, time dependent and uses a bulkwater microphysical parameterization scheme. Electric charges and fields are included, and the model is fully coupled dynamically, microphysically and electrically. One flight showed that a high electric field was developed at the aircraft's operating altitude (28 kft) and that a strong electric field would also be found below 20 kft; however, this low-altitude, high-field region was associated with the presence of small hail, posing a hazard to the aircraft. An operational procedure to increase the frequency of low-altitude lightning strikes was suggested. To further the understanding of lightning within the cloud environment, a parameterization of the lightning process was included in the SEM. It accounted for the initiation, propagation, termination, and charge redistribution associated with an intracloud discharge. Finally, a randomized lightning propagation scheme was developed, and the effects of cloud particles on the initiation of lightning investigated.

Helsdon, John H., Jr.↗
NASA NTRS1988

In situ fatigue loading stage inside scanning electron microscope

A fatigue loading stage inside a scanning electron microscopy (SEM) was developed. The stage allows dynamic and static high-magnification and high-resolution viewing of the fatigue crack initiation and crack propagation processes. The loading stage is controlled by a closed-loop servohydraulic system. Maximum load is 1000 lb (4450 N) with test frequencies ranging up to 30 Hz. The stage accommodates specimens up to 2 inches (50 mm) in length and tolerates substantial specimen translation to view the propagating crack. At room temperature, acceptable working resolution is obtainable for magnifications ranging up to 10,000X. The system is equipped with a high-temperature setup designed for temperatures up to 2000 F (1100 C). The signal can be videotaped for further analysis of the pertinent fatigue damage mechanisms. The design allows for quick and easy interchange and conversion of the SEM from a loading stage configuration to its normal operational configuration and vice versa. Tests are performed entirely in the in-situ mode. In contrast to other designs, the NASA design has greatly extended the life of the loading stage by not exposing the bellows to cyclic loading. The loading stage was used to investigate the fatigue crack growth mechanisms in the (100)-oriented PWA 1480 single-crystal, nickel-based supperalloy. The high-magnification observations revealed the details of the crack growth processes.

Telesman, Jack↗
NASA NTRS1990

Fatigue crack propagation behavior of a single crystalline superalloy

Crack propagation mechanisms occurring at various temperatures in a single crystalline Ni-base alloy, Rene N4, were investigated. The rates of crack growth at 21, 704, 927, 1038, and 1093 C were measured in specimens with 001-line and 110-line directions parallel to the load axis and the machined notch, respectively, using a pulsed dc potential drop apparatus, and the fracture surfaces at each temperature were examined using SEM. Crack growth rates (CGRs) for specimens tested at or below 927 C were similar, while at two higher temperatures, the CGRs were about an order of magnitude higher than at the lower temperatures. Results of SEM observations showed that surface morphologies depended on temperature.

Lerch, B. A.↗
NASA NTRS1990

Characterization of the corrosion resistance of several alloys to dilute biologically active solutions

Sulfate reducing bacteria and acid producing bacteria/fungi detected in hygiene waters increased the corrosion rate in aluminum alloy. Biologically active media enhanced the formation of pits on metal coupons. Direct observation of gas evolved at the corrosion sample, coupled with scanning electron microscopy (SEM) and energy dispersive x-ray analysis of the corrosion products indicates that the corrosion rate is increased because the presence of bacteria favor the reduction of hydrogen as the cathodic reaction through the reaction of oxygen and water. SEM verifies the presence of microbes in a biofilm on the surface of corroding samples. The bacterial consortia are associated with anodic sites on the metal surface, aggressive pitting occurs adjacent to biofilms. Many pits are associated with triple points and inclusions in the aluminum alloy microstructure. Similar bacterial colonization was found on the stainless steel samples. Fourier transform Infrared Spectroscopy confirmed the presence of carbonyl groups in pitted areas of samples exposed to biologically active waters.

Walsh, Daniel W.↗
NASA NTRS1991

The development and evaluation of an alternative powder prepregging technique for use with LaRC-TPI/graphite composites

An alternative powder prepregging method for use with LaRC-TPI (a thermoplastic polyimide)/graphite composites is investigated. The alternative method incorporates the idea of moistening the fiber prior to powder coating. Details of the processing parameters are given and discussed. The material was subsequently laminated into small coupons which were evaluated for processing defects using electron microscopy. After the initial evaluation of the material, no major processing defects were encountered but there appeared to be an interfacial adhesion problem. As a result, prepregging efforts were extended to include an additional fiber system, XAS, and a semicrystalline form of the matrix. The semicrystalline form of the matrix was the result of a complex heat treating cycle. Using scanning electron microscopy (SEM), the fiber/matrix adhesion was evaluated in these systems relative to the amorphous/XAS coupons. Based on these results, amorphous and semicrystalline/AS-4 and XAS materials were prepregged and laminated for transverse tensile testing. The results of these tests are presented, and in an effort to obtain more information on the effect of the matrix, remaining semicrystalline transverse tensile coupons were transformed back to the amorphous state and tested. The mechanical properties of the transformed coupons returned to the values observed for the original amorphous coupons, and the interfacial adhesion, as observed by SEM, was better than in any previous sample.

Ogden, Andrea L.↗
NASA NTRS1991

Properties of large area ErBa2Cu3O(7-x) thin films deposited by ionized cluster beams

ErBa2Cu3O(7-x) films have been produced by simultaneous deposition of Er, Ba, and Cu from three ionized cluster beam (ICB) sources at acceleration voltages of 0.3 to 0.5 kV. Combining ozone oxidation with ICB deposition at 650 C eliminated any need of post annealing processing. The substrates were rotated at 10 rotations per minute during the deposition which took place at a rate of about 3 to 4 nm. Films with areas up to 70 mm in diameter have been made by ICB deposition. These films, 100 nm thick, were deposited on SrTiO3 (100) substrates at 650 C in a mixture of six percent O3 in O2 at a total pressure of 4 x 10(exp -4) Torr. They had T(sub c) ranging from 84.3 K to 86.8 K over a 70 mm diameter and J(sub c) above 10(exp 6) A/sq cm at 77 K. X ray diffraction measurements of the three samples showed preferential c-axis orientation normal to the substrate surface. Scanning electron micrographs (SEM) of the three samples also show some texture dependence on sample position. For the three samples, there is a correlation between SEM texture, full width at half-maximum of rocking curves and J(sub c) versus temperature curves.

Levenson, L. L.↗
NASA NTRS1992

Interplanetary meteoroid debris in LDEF metal craters

The extraterrestrial meteoroid residue found lining craters in the Long Duration Exposure Facility (LDEF) aluminum and gold targets is highly variable in both quantity and type. In typical craters only a minor amount of residue is found and for these craters it is evident that most of the impacting projectile was ejected during crater formation. Less than 10 percent of the craters greater than 100 microns contain abundant residue consistent with survival of a major fraction of the projectile. In these cases the residue can be seen optically as a dark liner and it can easily be analyzed by SEM-EDX techniques. Because they are rare, the craters with abundant residue must be a biased sampling of the meteoroids reaching the earth. Factors that favor residue retention are low impact velocity and material properties such as high melting point. In general, the SEM-EDX observations of crater residues are consistent with the properties of chondritic meteorites and interplanetary dust particles collected in the stratosphere. Except for impacts by particles dominated by single minerals such as FeS and olivine, most of the residue compositions are in broad agreement with the major element compositions of chondrites. In most cases the residue is a thin liner on the crater floor and these craters are difficult to quantitatively analyze by EDX techniques because the electron beam excites both residue and underlying metal substrate. In favorable cases, the liner is thick and composed of vesicular glass with imbedded FeNi, sulfide and silicate grains. In the best cases of meteoroid preservation, the crater is lined with large numbers of unmelted mineral grains. The projectiles fragmented into micron sized pieces but the fragments survived without melting. In one case, the grains contain linear defects that appear to be solar flare tracks. Solar flare tracks are common properties of small interplanetary particles and their preservation during impact implies that the fragments were not heated above 600 C. We are investigating the meteoroid fragments in LDEF metal craters to determine the properties of interplanetary dust and to determine if there are meteoroid types that are overlooked or otherwise undetected in cosmic dust collections obtained from the stratosphere and polar ice.

Brownlee, D. E.↗
NASA NTRS1992

Laboratory investigations of the aerosols in the stratosphere of Titan

Results of experiments in which particles were produced from UV photolysis of C2H2, C2H4, or HCN, separately or in mixtures, modeling Titan's upper atmosphere, are presented. The particles were collected on disks and examined by Scanning Electron Microscopy (SEM). Measurements of particle sizes and shapes and of aggregation were determined from the SEM photographs.

Scattergood, Thomas W.↗
NASA NTRS1992

Secondary electron yields of solar system ices

The secondary electron yields of H2O, CO2, NH3, and CH3OH ices have been measured as a function of electron beam energy in the 2- to 30-keV energy range. The ices were produced on a liquid-nitrogen-cooled cold finger and transferred under vacuum to a SEM where the yield measurements were made. The imaging capabilities of the SEM provide a means of correlating the yield measurements with the morphology of the ices and are also used to monitor charging effects. The yields were determined by measuring the amplified current from a secondary electron detector and calibrating this current signal with the amplified current signal from samples of metals with known secondary electron yields. Each of the measured yields is found to decrease with an increase in energy in the 2- to 30-keV range. Estimates are given for the maximum secondary electron yield Y(max) of each ice and the energy at which this maximum yield occurs. Implications for the charging of solar system ice grains are discussed.

Suszcynsky, David M.↗
NASA NTRS1992

Recession of FEP specimens from trays D11 and B7

We report work done at Boeing Defense and Space Group on analysis of silvered teflon specimens taken from selected locations of the Long Duration Exposure Facility under support from a contract provided by NASA LaRC. The samples discussed in this presentation were taken from the unexposed side of D11 and extended through the folded area of this blanket into the exposed area. Two similar areas were cut from blanket B7, one from the edge of the blanket near row six and one from the edge of the blanket near row eight and within a few centimeters of the copper grounding strap for B7. The specimens were each divided into three sections by cutting with a scapel. Two of the sections were mounted in a potting compound, which was cut and polished such that the cross-sectional thickness of each was exposed. One piece was mounted straight and the other was mounted in an attempt to configure the specimens such that it was bent with a radius of curvature similar to the on-orbit configuration. The third portion of each specimen was used for SEM images to help define the angle of exposure with respect to the ram at each location on the specimen. Photomicrographs were taken in cross section from the edge of the blanket through the curved transition region into the exposed area of the blanket. The thickness of the Fluorinated Ethylene Propylene (FEP) layer was determined at known distances from the edge of the blanket. SEM images were obtained at known distances to help define the angle with respect to ram and therefore establish the atomic oxygen fluence on each location and correlate this exposure with thickness. Thickness measurements made with a two to three centimeter distance minimized the uncertainty arising from variations in the as-manufactured thickness of each blanket. The nominal angle from ram of the exposed portion of each blanket, and the fact that the unexposed edge portions are approximately at right angles to the exposed portion were also used to help define the angles. Thickness measurements were taken at specified locations. An average thickness for the unexposed portion of the blanket was determined. Changes in thickness were then determined by difference.

Pippin, H. Gary↗
NASA NTRS1993

A study of the UV and VUV degradation of FEP

UV and VUV degradation of fluorinated ethylene propylene (FEP) copolymer was studied using electron spin resonance (ESR) spectroscopy, x-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The ESR study revealed the formation of a terminal polymer radical. The stability of this radical was investigated under different environments. An XPS study of FEP film exposed to VUV and atomic oxygen showed that oxidation takes place on the polymer surface. The study revealed also that the percentage of CF2 in the polymer surface decreased with exposure time and the percentage of CF, CF3, and carbon attached to oxygen increased. SEM micrographs of FEP film exposed to VUV and atomic oxygen identified a rough surface with undulations similar to sand dunes.

George, Graeme A.↗
NASA NTRS1993

Hypervelocity impact survivability experiments for carbonaceous impactors

We performed a series of hypervelocity impact experiments using carbon-bearing impactors (diamond, graphite, fullerenes, phthalic acid crystals, and Murchison meteorite) into Al plate at velocities between 4.2 and 6.1 km/s. These tests were made to do the following: (1) determine the survivability of carbon forms and organize molecules in low hypervelocity impact; (2) characterize carbonaceous impactor residues; and (3) determine whether or not fullerenes could form from carbonaceous impactors, under our experimental conditions, or survive as impactors. An analytical protocol of field emission SEM imagery, SEM-EDX, laser Raman spectroscopy, single and 2-stage laser mass spectrometry, and laser induced fluorescence (LIF) found the following: (1) diamonds did not survive impact at 4.8 km/s, but were transformed into various forms of disordered graphite; (2) intact, well-ordered graphite impactors did survive impact at 5.9 km/sec, but were only found in the crater bottom centers; the degree of impact-induced disorder in the graphite increases outward (walls, rims, ejecta); (3) phthalic acid crystals were destroyed on impact (at 4.2 km/s, although a large proportion of phthalic acid molecules did survive impact); (4) fullerenes did not form as products of carbonaceous impactors (5.9 - 6.1 km/s, fullerene impactor molecules mostly survived impact at 5.9 km/s; and (5) two Murchison meteorite samples (launched at 4.8 and 5.9 km/s) show preservation of some higher mass polycyclic aromatic hydrocarbons (PAHs) compared with the non-impacted sample. Each impactor type shows unique impactor residue morphologies produced at a given impact velocity. An expanded methodology is presented to announce relatively new analytical techniques together with innovative modifications to other methods that can be used to characterize small impact residues in LDEF craters, in addition to other acquired extraterrestrial samples.

Bunch, T. E.↗
NASA NTRS1993

Projectile compositions and modal frequencies on the chemistry of micrometeoroids LDEF experiment

The Chemistry of Micrometeoroids Experiment (LDEF instrument A0187-1) exposed witness plates of high-purity gold (greater than 99.99 percent Au) and commercial aluminum (greater than 99 percent Al) with the objective of analyzing the residues of cosmic-dust and orbital-debris particles associated with hypervelocity impact craters. The gold substrates were located approximately 8 deg off LDEF's trailing edge (Bay A03), while the aluminum surfaces resided in Bay A11, approximately 52 deg from LDEF's leading edge. SEM-EDX techniques were employed to analyze the residues associated with 199 impacts on the gold and 415 impacts on the aluminum surfaces. The residues that could be analyzed represent natural or man-made materials. The natural particles dominate at all particle sizes less than 5 micron. It is possible to subdivide both particle populations into subclasses. Chondritic compositions dominate the natural impactors (71 percent), followed by monomineralic, mafic-silicate compositions (26 percent), and by Fe-Ni rich sulfides (approximately 3 percent). Approximately 30 percent of all craters on the gold collectors were caused by man-made debris such as aluminum, paint flakes, and other disintegrated, structural and electronic components. Equations-of-state and associated calculations of shock stresses for typical LDEF impacts into the gold and aluminum substrates suggest that substantial vaporization may have occurred during many of the impacts and is the reason why approximately 50 percent of all craters did not contain sufficient residue to permit analysis by the SEM-EDX technique. After converting the crater diameters into projectile sizes using encounter speeds typical for the trailing-edge and forward-facing (Row 11) directions, and accounting for normalized exposure conditions of the CME collectors, we derived the absolute and relative fluxes of specific projectile classes. The natural impactors encounter all LDEF pointing directions with comparable, modal frequencies suggesting compositional (and dynamic) homogeneity of the interplanetary-dust environment in near-Earth orbit.

Bernhard, Ronald P.↗