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The design, development, and test of a functional laboratory model ice pack heat sink subsystem are discussed. Operating instructions to include mechanical and electrical schematics, maintenance instructions, and equipment specifications are presented.
The concept of a flight experiment physical phenomena experiment chest, to be used eventually for investigating and demonstrating ice pack heat sink subsystem physical phenomena during a zero gravity flight experiment, is described.
Surface oxidation irreversibly removes both oxygen and hydrogen from the Martian atmosphere at a rate of 10 million-100 billion per square centimeter per second. This rate corresponds to a net loss of 100 to 100,000 grams per square centimeter of H2O, if it is assumed that the loss rate is uniform over geologic time. Heretofore, exospheric escape was considered to be the principal irreversible sink for H2O, but the loss rate was estimated to be only 100 million per square centimeter per second. It is possible that surface oxidation may have had a minor effect on the supply of H2O in the regolith and polar caps.
Observations of the temporal and spatial distribution of N2O in solution are not yet sufficient to permit quantitative assessment of the role of the ocean in the budget of atmospheric N2O. Consideration of the global nitrogen cycle suggests that the land should be the primary source of N2O. The gas is removed in the atmosphere by photolysis and by reaction with O(1D), and there may be additional sinks in the ocean.
A series of investigations was conducted to characterize the physical properties of potassium bifluoride and water solutions for use as the fusible heat sink material in a regenerable portable life support system.
Hypersonic research aircraft design requires careful consideration of thermal stresses. This paper relates some of the problems in a heat sink structural design that can be avoided by appropriate selection of design options including material selection, design concepts, and load paths. Data on several thermal loading conditions are presented on various conventional designs including bulkheads, longerons, fittings, and frames. Results indicate that conventional designs are inadequate and that acceptable designs are possible by incorporating innovative design practices. These include nonintegral pressure compartments, ball-jointed links to distribute applied loads without restraining the thermal expansion, and material selections based on thermal compatibility.
The terrestrial and marine nitrogen cycles are examined in an attempt to clarify how the atmospheric content of N2O is controlled. We review available data on the various reservoirs of fixed nitrogen, the transfer rates between the reservoirs, and estimate how the reservoir contents and transfer rates can change under man's influence. It is seen that sources, sinks and lifetime of atmospheric N2O are not understood well. Based on our limited knowledge of the stability of atmospheric N2O we conclude that future growth in the usage of industrial fixed nitrogen fertilizers could cause a 1% to 2% global ozone reduction in the next 50 years. However, centuries from now the ozone layer could be reduced by as much as 10% if soils are the major source of atmospheric N2O.
Oxidation of CH4 provides the major source for atmospheric H2, which is removed mainly by reaction with OH. Biological activity at earth's surface appears to represent at most a minor sink for H2. Anthropogenic activity is a significant source for both H2 and CO in the present atmosphere and may be expected to exert a growing influence in the future. Models are presented which suggest a rise in the mixing ratio of H2 from its present value of 5.6 ten-millionths to about 1.8 millionths by the year 2100. The mixing ratio of CO should grow from 9.7 hundred-millionths to 2.3 ten-millionths over the same time period, and there should be a rise in CH4 by about a factor of 1.5 associated with anthropogenically induced reductions in tropospheric OH.
The design, fabrication, and testing of a representative shuttle evaporative heat sink (RSEHS) system which vaporizes an expendable fluid to provide cooling for the shuttle heat transport fluid loop is reported. The optimized RSEHS minimum weight design meets or exceeds the shuttle flash evaporator system requirements. A cold trap which cryo-pumps flash evaporator exhaust water from the CSD vacuum chamber test facility to prevent water contamination of the chamber pumping equipment is also described.
Measurements of atmospheric parameters made by the Atmosphere Explorer-C satellite used to identify mechanisms for the production and loss of N(+) ions in the ionosphere are presented. Photo-dissociative ionization of N2 is the main source below 250 km. Above 250 km the reaction O(+)(4S) + N(2D) yields N(+)(3P) + O(3P) is dominant, and a possible minor source of N(+) is the reaction O(+)(2P) + N2 yields N(+) + NO. Photoionization of N(4S) and dissociative charge exchange of He(+) with N2 constitute detectable sources above 350 km. Charge exchange of N(+) with O is a significant sink above 300 km, and the rate coefficients for these reactions are derived.
The reaction probabilities of various atmospheric species incident on a bulk sulfuric acid surface are measured in order to determine the role of sulfuric acid aerosols as pollutant sinks. Reaction products and unreacted starting materials leaving a Knudsen cell flow reactor after collision at 300 K with a H2SO4 surface or a soot surface were detected by mass spectrometry. Significant collision reaction probabilities are observed on a H2SO4 surface for H2O2, HNO3, HO2NO2, ClONO2, N2O5, H2O and NH3, and on soot for NH3. Estimates of the contribution of heterogeneous reactions to pollutant removal under atmospheric conditions indicate that while aerosol removal in the stratosphere is insignificant (loss rate constants approximately 10 to the -10th/sec), heterogeneous reactions may be the dominant loss process for several tropospheric species (loss rate constant approximately 10 to the -5th/sec, comparable to photolysis rate constants).
It is shown that a lifetime of approximately 8 years is most consistent with the observed latitudinal variation of atmospheric methane, requiring the current global emissions of methane to be around 550 teragrams per year. The repeating pattern of a rapid rise of CH4 concentrations in the fall in the Northern Hemisphere indicates a large fall source at latitudes above 30 deg N. The remaining observed seasonal variations are seen as consistent with the seasonal cycle of OH, which removes methane from the atmosphere. An extensive set of self-consistent measurements of methane is reported and analyzed, revealing that methane has increased during the past 3-4 years at rates of 1-1.9 percent per year all over the world at sites ranging from inside the Arctic Circle to the South Pole. The observational results are used in estimating the sources, sinks, and seasonal cycles of CH4 and the effects of human activities on its atmospheric abundance.
It is pointed out that the past few years have seen an unprecedented influx of new experimental information on the dynamics of the neutral upper atmosphere of the earth. Vector wind measurements provide new information for studies of the thermospheric response to magnetospheric forcing. This response occurs through the medium of convecting ionospheric ions set into motion by electric fields of magnetospheric origin. The ultimate sink for much of the energy and momentum coming from the magnetosphere is the neutral thermosphere whose dynamics have, in the past, received far less attention than their ionospheric counterpart because of basic experimental limitations. In this paper, a review is provided of the progress made in the last few years on the basis of the Dynamics Explorer neutral wind observations, taking into account the coupling between the magnetosphere and the thermosphere via the ionosphere.
Heating distributions from analysis of the National Meteorological Center and European Center for Medium Range Weather Forecasts data sets; methods used and problems involved in the inference of diabatic heating; the relationship between differential heating and energy transport; and recommendations on the inference of heat soruces and heat sinks for the planetary show are discussed.
Direct numerical simulations of sink-flow boundary layers, with acceleration parameters K between 1.5 x 10 to the -6th and 3.0 x 10 to the -6th, are presented. The three-dimensional, time-dependent Navier-Stokes equations are solved numerically, using a spectral method, with about one million degrees of freedom. The flow is assumed to be statistically steady, and self-similar. A multiple-scale approximation and periodic conditions are applied to the fluctuations. The turbulence is studied using instantaneous and statistical results. Good agreement with the experiments of Jones and Launder (1972) is observed. The two effects of the favorable pressure gradient are to extend the logarithmic layer, and to alter the energy balance of the turbulence near the edge of the boundary layer. At low Reynolds number the logarithmic layer is shortened and slightly displaced, but wall-layer streaks are present even at the lowest values of R(theta) for which turbulence can be sustained. Large quiescent patches appear in the flow. Relaminarization occurs at K = 3.0 x 10 to the -6th, corresponding to a Reynolds number R(theta) of about 330.
Direct numerical simulations of sink-flow boundary layers, with acceleration parameters K between 1.5 and 3.0 x 10 to the -6 power, are presented. The three-dimensional, time-dependent Navier-Stokes equations are solved numerically using a spectral method, with about 10 to the -6 degrees of freedom. The flow is assumed to be statistically steady, and self-similar. A multiple-scale approximation and periodic conditions are applied to the fluctuations. The turbulence is studied using instantaneous and statistical results. Good agreement with the experiments of Jones and Launder is observed. Two effects of the favorable pressure gradient are to extend the logarithmic layer, and to alter the energy balance of the turbulence near the edge of the boundary layer. At very low Reynolds number the logarithmic layer is shortened and slightly displaced, but wall-layer streaks are present even at the lowest values of the Reynolds number for which turbulence can be sustained. Large quiescent patches appear in the flow. Relaminarization occurs at K = 3.0 x 10 to the -6 power, corresponding to a Reynolds number, based on momentum thickness, of about 330.
Although direct evidence is lacking, indirect evidence suggests that iron-rich clay minerals or poorly-ordered chemical equivalents are widespread on the Martian surface. Such clays can act as sources or sinks for hydrogen ('hydrogen sponges'). Ferrous clays can lose hydrogen and ferric clays gain it by the coupled substitution Fe(3+)O(Fe(2+)OH)-1, equivalent to minus atomic H. This 'oxy-clay' substitution involves only proton and electron migration through the crystal structure, and therefore occurs nondestructively and reversibly, at relatively low temperatures. The reversible, low-temperature nature of this reaction contrasts with the irreversible nature of destructive dehydroxylation (H2O loss) suffered by clays heated to high temperatures. In theory, metastable ferric oxy-clays formed by dehydrogenation of ferrous clays over geologic time could, if exposed to water vapor, extract the hydrogen from it, releasing oxygen.
Potential sources and sinks of formic, acetic, and pyruvic acids over the Amazon forest were investigated using a photochemical model and data collected on gas phase concentrations of these acids in the forest canopy, boundary layer, and free troposphere over the central Amazon Basin during the 1987 wet season. It was found that the atmospheric reactions previously suggested in the literature as sources of carboxylic acids (i.e., the gas phase decomposition of isoprene, the reaction between CH3CO3 and a peroxide, and aqueous phase oxidation of CH2O) appear to be too slow to explain the observed concentrations, suggesting that other atmospheric reactions, so far unidentified, could make a major contribution to the carboxylic acid budgets.