Search NASA⌕ Search

SEARCH · Search NASA

Results for “SODIUM VAPOR”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

ETF Grout Expansion: Effects of Different Slags and Struvite Precipitation Protocols (Stirring Time)

The ETF ammonia tolerant grout waste form was developed by the Vitreous State Laboratory (VSL) to stabilize ammonium and thereby prevent emission of ammonia vapor during solidification of an ammonium-rich, concentrated sodium sulfate aqueous waste stream generated at the Hanford Effluent Treatment Facility (ETF). VSL personnel did not observe expansion in samples prepared during the waste form development work. However, Savannah River National Laboratory (SRNL) personnel detected expansion, in a few ETF grout samples, up to ~ 20 percent vertical expansion, while preforming work scope to evaluate the effect of ETF brine compositional ranges on the precipitation and solidification processes. The initial work requests can be found in Washington River Protection Services (WRPS) Statement of Work (SOW, Requisitions #: 339922 Revisions 0 and 1, March 11, 2021, and November 2021, respectively. As a result of the waste form expansion observed by SRNL, additional evaluation was requested by WRPS SOW Requisitions #: 356730 Revision 0 and Revision 1, February 1, 2022, and July 11, 2022, respectively. The goal of these requests was to determine whether differences in the slags and / or in sample preparation protocols used by VSL and SRNL were the cause of the expansion observed in the SRNL samples. G. Chen, WRPS, arranged a materials exchange between VSL and SRNL and coordinated the VSL protocol(s) for grouting and curing 1L batches of Base Case ETF base case simulant. Materials were exchanged between VSL and SRNL. Both laboratories performed the VSL struvite precipitation-solidification protocol and cured samples for at least 28 days. Differences in VSL and SRNL slag compositions, mineralogy and particle size results in themselves or combined were determined to not be the cause of the expansion because all samples expanded regardless of whether the VSL or SRNL slags were used. The fundamental cause of the observed expansion could not be attributed to minor variations in the following: 1) chemistry of the slag and other reagents, 2) container wall thickness, 3) ambient bench top curing conditions at VSL and SRNL, 4) pH adjustments to 7 ± a few tenths of unit, nor 5) stirring time between the precipitation and solidification process steps. Additional observations include: grout samples prepared with VSL slag expanded less than those prepared with the SRNL slag and, based on a very limited sample set, some samples stirred for longer times expanded less than those stirred for 20 minutes.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2014

The Lunar Atmosphere and Dust Environment Explorer (LADEE): Initial Science Results

On September 6, 2013, a near-perfect launch of the first Minotaur V rocket successfully carried NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE) into a high-eccentricity geocentric orbit. LADEE arrived at the Moon on October 6, 2013, dur-ing the government shutdown. The spacecraft impact-ed the lunar surface on April 18, 2014, following a completely successful mission. LADEE's science objectives were twofold: (1) De-termine the composition and variability of the lunar atmosphere; (2) Characterize the lunar exospheric dust environment, and its variability. The LADEE science payload consisted of the Lunar Dust Experiment (LDEX), which sensed dust impacts in situ, for parti-cles between 100 nm and 5 micrometers; a neutral mass spectrometer (NMS), which sampled lunar exo-spheric gases in situ, over the 2-150 Dalton mass range; an ultraviolet/visible spectrometer (UVS) ac-quired spectra of atmospheric emissions and scattered light from tenuous dust, spanning a 250-800 nm wave-length range. UVS also performed dust extinction measurements via a separate solar viewer optic. The following are preliminary results for the lunar exosphere: (1) The helium exosphere of the Moon, first observed during Apollo, is clearly dominated by the delivery of solar wind He++. (2) Neon 20 is clearly seen as an important constituent of the exosphere. (3) Argon 40, also observed during Apollo and arising from interior outgassing, exhibits variations related to surface temperature-driven condensation and release, and is also enhanced over specific selenographic longi-tudes. (4) The sodium abundance varies with both lu-nar phase and with meteoroid influx, implicating both solar wind sputtering and impact vaporization process-es. (5) Potassium was also routinely monitored and exhibits some of the same properties as sodium. (6) Other candidate species were seen by both NMS and UVS, and await confirmation. Dust measurements have revealed a persistent "shroud" of small dust particles between 0.7 and sev-eral micrometers in size, present over the pre-dawn and morning sector of the Moon. This tenuous dust exosphere, with densities of approximately 10(exp -5) m(exp -3), appears to be sustained by the ejecta of micrometeoroid impacts.

lunar atmosphere↗
NASA NTRS2003

Mixed Conducting Electrodes for Better AMTEC Cells

Electrode materials that exhibit mixed conductivity (that is, both electronic and ionic conductivity) have been investigated in a continuing effort to improve the performance of the alkali metal thermal-to-electric converter (AMTEC). These electrode materials are intended primarily for use on the cathode side of the sodium-ion-conducting solid electrolyte of a sodium-based AMTEC cell. They may also prove useful in sodium-sulfur batteries, which are under study for use in electric vehicles. An understanding of the roles played by the two types of conduction in the cathode of a sodium-based AMTEC cell is prerequisite to understanding the advantages afforded by these materials. In a sodium-based AMTEC cell, the anode face of an anode/solid-electrolyte/cathode sandwich is exposed to Na vapor at a suitable pressure. Upon making contact with the solid electrolyte on the anode side, Na atoms oxidize to form Na+ ions and electrons. Na+ ions then travel through the electrolyte to the cathode. Na+ ions leave the electrolyte at the cathode/electrolyte interface and are reduced by electrons that have been conducted through an external electrical load from the anode to the cathode. Once the Na+ ions have been reduced to Na atoms, they travel through the cathode to vaporize into a volume where the Na vapor pressure is much lower than it is on the anode side. Thus, the cathode design is subject to competing requirements to be thin enough to allow transport of sodium to the low-pressure side, yet thick enough to afford adequate electronic conductivity. The concept underlying the development of the present mixed conducting electrode materials is the following: The constraint on the thickness of the cathode can be eased by incorporating Na+ -ionconducting material to facilitate transport of sodium through the cathode in ionic form. At the same time, by virtue of the electronically conducting material mixed with the ionically conducting material, reduction of Na+ ions to Na atoms can take place throughout the thickness of the cathode. The net effect is to reduce the diffusion and flow resistance to sodium through the electrode while reducing the electronic resistance by providing shorter conduction paths for electrons. Reduced resistance to both sodium transport and electronic conductivity results in an increase in electric power output.

Ryan, Margaret↗
NASA NTRS1978

High temperature heat pipe research at NASA Lewis Research Center

In the course of studies of thermionic power plants for space applications, high-temperature refractory metal heat pipes have been designed and built for alkali metal working fluids. Fabrication of tungsten wire-reinforced tantalum pipes by chemical vapor deposition is discussed; the development of reinforced pipes with integral arteries produced by chemical vapor deposition is also mentioned. The feasibility of using lithium, sodium, potassium, cesium or mercury as the working fluid in the heat pipes is also reviewed. Operation of a lithium-filled heat pipe of about 3-kW capacity for several thousand hours is reported.

Tower, L. K.↗
DOE OSTI2022

Analysis on the Preliminary Gap Conductance Test with Single Primary Heat Extraction and Removal Emulator

Microreactor is a type of nuclear reactor that is intended to produce thermal energy from the micro and integrated design. Among various microreactor roadmaps, microreactor with heat pipes is one of the promising designs that under active development. At Idaho National Laboratory (INL) and supported by the Department of Energy (DOE) Microreactor Program (MRP), a Single Primary Heat Extraction and Removal Emulator (SPHERE) was developed. The main purpose of SPHRE is to understand thermal performance of heat pipe in the conjunction of heat source without using nuclear material. The heat pipe used in the SPHERE has sodium as a working fluid, with Argon gas in the vapor region, thus this heat pipe is variable conductance heat pipe (VCHP). The volume of non-condensable gas changes with power and elapsed time, so the area covered by non-condensable gas changes. This gives an effect that passively controls the cooling capability of condenser section. This preliminary experiment was intended to perform a gap conductance experiment that reveals heat transfer characteristics of gas at the gap around the heat pipe. However, there are not many experimental data that deals with heat transfer of the gas at the gap around heat pipe. In this research, the preliminary experimental result regarding to the heat pipe performance with different composition of gas at the gap, level of power is presented. The experimental data will be used for the validation study of SOCKEYE as a future plan.

42 ENGINEERING↗
NASA NTRS1992

Error Analysis of Wind Measurements for the University of Illinois Sodium Doppler Temperature System

Four-frequency lidar measurements of temperature and wind velocity require accurate frequency tuning to an absolute reference and long term frequency stability. We quantify frequency tuning errors for the Illinois sodium system, to measure absolute frequencies and a reference interferometer to measure relative frequencies. To determine laser tuning errors, we monitor the vapor cell and interferometer during lidar data acquisition and analyze the two signals for variations as functions of time. Both sodium cell and interferometer are the same as those used to frequency tune the laser. By quantifying the frequency variations of the laser during data acquisition, an error analysis of temperature and wind measurements can be calculated. These error bounds determine the confidence in the calculated temperatures and wind velocities.

Pfenninger, W. Matthew↗
NASA NTRS2008

NaK Variable Conductance Heat Pipe for Radioisotope Stirling Systems

In a Stirling radioisotope power system, heat must continually be removed from the General Purpose Heat Source (GPHS) modules to maintain the modules and surrounding insulation at acceptable temperatures. The Stirling convertor normally provides most of this cooling. If the Stirling convertor stops in the current system, the insulation is designed to spoil, preventing damage to the GPHS, but also ending use of that convertor for the mission. An alkali-metal Variable Conductance Heat Pipe (VCHP) was designed to allow multiple stops and restarts of the Stirling convertor. In the design of the VCHP for the Advanced Stirling Radioisotope Generator, the VCHP reservoir temperature can vary between 40 and 120 C. While sodium, potassium, or cesium could be used as the working fluid, their melting temperatures are above the minimum reservoir temperature, allowing working fluid to freeze in the reservoir. In contrast, the melting point of NaK is -12 C, so NaK can't freeze in the reservoir. One potential problem with NaK as a working fluid is that previous tests with NaK heat pipes have shown that NaK heat pipes can develop temperature non-uniformities in the evaporator due to NaK's binary composition. A NaK heat pipe was fabricated to measure the temperature non-uniformities in a scale model of the VCHP for the Stirling Radioisotope system. The temperature profiles in the evaporator and condenser were measured as a function of operating temperature and power. The largest delta T across the condenser was 2S C. However, the condenser delta T decreased to 16 C for the 775 C vapor temperature at the highest heat flux applied, 7.21 W/ square cm. This decrease with increasing heat flux was caused by the increased mixing of the sodium and potassium in the vapor. This temperature differential is similar to the temperature variation in this ASRG heat transfer interface without a heat pipe, so NaK can be used as the VCHP working fluid.

Tarau, Calin↗
NASA NTRS2012

A Small, Remotely Operated, Coronagraph located at Small Observatory to obtain Frequent Low-cost Remote Observations of the Lunar Exosphere

The sodium in the lunar exosphere is a marker for the study of the lunar exosphere because the sodium possesses two strong resonance transitions from the ground state whose wavelengths fall in the visible spectrum near 590 nm. Emissions at these wavelengths are thus, observable from Earth. Observations have shown that the exosphere responds in a complex way to the external processes (impact vaporization, sputtering, and photon stimulated desorption) that weather the lunar regolith to produce the sodium (Sarantos et aI., Icarus, 205, 2010). Unraveling the sodium production allows us to study the processes that weather the regolith. Obtaining the extensive time sequence of observations required to unravel the sources of sodium using conventional observatories is impractical, and too expensive. Effectively imaging the lunar sodium exosphere close to the Moon requires an off-axis rejection of scattered light that can only be obtained with a coronagraph sited at an observatory dedicated to remote robotic observing (the Winer Observatory in Sonoita Arizona) that can obtain the quality and quantity of lunar sodium observations needed to answer these questions, and at modest cost. The design uses Commercial Off the Shelf Technology (COTS). We are working to begin routine the observations before the launch of the Lunar Atmosphere and Dust Environment Explorer (LADEE) mission.

Morgan, Thomas↗
NASA NTRS1993

The effect of Na vapor on the Na content of chondrules

Chondrules contain higher concentrations of volatiles (Na) than expected for melt droplets in the solar nebula. Recent studies have proposed that chondrules may have formed under non-canonical nebular conditions such as in particle/gas-rich clumps. Such chondrule formation areas may have contained significant Na vapor. To test the hypothesis of whether a Na-rich vapor would minimize Na volatilization reaction rates in a chondrule analog and maintain the Na value of the melt, experiments were designed where a Na-rich vapor could be maintained around the sample. A starting material with a melting point lower that typical chondrules was required to keep the logistics of working with Na volatilization from NaCl within the realm of feasibility. The Knippa basalt, a MgO-rich alkali olivine basalt with a melting temperature of 1325 +/- 5 C and a Na2O content of 3.05 wt%, was used as the chondrule analog. Experiments were conducted in a 1 atm, gas-mixing furnace with the fO2 controlled by a CO/CO2 gas mixture and fixed at the I-W buffer curve. To determine the extent of Na loss from the sample, initial experiments were conducted at high temperatures (1300 C - 1350 C) for duration of up to 72 h without a Na-rich vapor present. Almost all (up to 98%) Na was volatilized in runs of 72 h. Subsequent trials were conducted at 1330 C for 16 h in the presence of a Na-rich vapor, supplied by a NaCl-filled crucible placed in the bottom of the furnace. Succeeding Knudsen cell weight-loss mass-spectrometry analysis of NaCl determined the P(sub Na) for these experimental conditions to be in the 10(exp -6) atm range. This value is considered high for nebula conditions but is still plausible for non-canonical environments. In these trials the Na2O content of the glass was maintained or in some cases increased; Na2O values ranged from 2.62% wt to 4.37% wt. The Na content of chondrules may be controlled by the Na vapor pressure in the chondrule formation region. Most heating events capable of producing chondrules are sufficient to volatile Na. Sodium volatilization reaction rates will be reduced to varying degrees from melt droplets, depending on the magnitude of the P(sub Na) generated. A combination of Na vapor during, and Na diffusion back into chondrules after, formation could maintain and/or enrich Na concentrations in chondrules.

Lewis, R. Dean↗
NASA NTRS2011

A Concept for Small, Remotely Operated, Coronagraph located at Small Observatory to Obtain Frequent Low-cost Remote Observations of the Lunar Exosphere and the Mercurian Tail

The sodium in the lunar exosphere is a marker species for studying the lunar exosphere because the element possesses two strong resonance transitions from the ground state whose wavelengths fall in the visible spectrum near 590 nm. Emissions at these wavelengths are thus, observable from Earth. Observations have shown that the exosphere responds in a complex way to the external processes (impact vaporization, sputtering, and photon stimulated desorption) that weather the lunar regolith to produce the sodium. Unraveling the sodium production allows us to study the processes that weather the regolith. Obtaining the extensive time sequence of observations required to unravel the sources of sodium using conventional observatories is impractical, and too expensive. Effectively imaging the lunar sodium exosphere dose to the Moon requires an off-axis rejection of scattered light that can only be obtained with a coronagraph. A related problem. the observation of the sodium tail of Mercury, can be addressed as well only by coronagraphic observations. We present here a concept for a small, rugged coronagraph sited at an observatory dedicated to remote robotic observing (the Winer Observatory in Sonoita Arizona) that can obtain the quality and quantity of lunar sodium observations needed to answer these questions. The design uses Commercial Off the Shelf Technology (COTS). If this facility is operational by 2013. the observations will be concurrent with the Lunar Atmosphere and Dust Environment Explorer (LADEE) mission.

Morgan, T. H.↗
NASA NTRS1976

Toward more environmentally resistant gas turbines: Progress in NASA-Lewis programs

A wide range of programs are being conducted for improving the environmental resistance to oxidation and hot corrosion of gas turbine and power system materials. They range from fundamental efforts to delineate attack mechanisms, allow attack modeling and permit life prediction, to more applied efforts to develop potentially more resistant alloys and coatings. Oxidation life prediction efforts have resulted in a computer program which provides an initial method for predicting long time metal loss using short time oxidation data by means of a paralinear attack model. Efforts in alloy development have centered on oxide-dispersion strengthened alloys based on the Ni-Cr-Al system. Compositions have been identified which are compromises between oxidation and thermal fatigue resistance. Fundamental studies of hot corrosion mechanisms include thermodynamic studies of sodium sulfate formation during turbine combustion. Information concerning species formed during the vaporization of Na2SO4 has been developed using high temperature mass spectrometry.

Lowell, C. E.↗
NASA NTRS1984

Measuring Trace Hydrocarbons in Silanes

Technique rapid and uses standard analytical equipment. Silane gas containing traces of hydrocarbons injected into carrier gas of moist nitrogen having about 0.2 percent water vapor. Carrier, water and silane pass through short column packed with powdered sodium hydroxide which combines moisture and silane to form nonvolatile sodium silicate. Carrier gas free of silane but containing nonreactive hydrocarbons, pass to silica-gel column where chromatographic separation takes place. Hydrocarbons measured by FID.

Lesser, L. A.↗
DOE OSTI2025

Benchmark Exercise Report for Experimental Study of Bubble Scrubbing in Sodium Pool

Mechanistic source term (MST) analyses are likely to be an important part of advanced reactor licensing applications. For the purpose, an MST analysis code applicable to newly introduced advanced reactors, called SRT (Simplified Radionuclide Transport) code, has been developed by Argonne National Laboratory. SRT can track overall behaviors of radionuclides especially in metal fuel-based sodium fast reactors (SFRs) and microreactors. Throughout the simulation, migration inside fuel pins before failure, interaction with coolant (for SFR), removal/leakage in cover gas and containment (or confinement), and environmental dose impacts are considered alongside radioactive decay for short-lived nuclides. Among the postulated process, pool scrubbing phenomenon, especially under sodium pool condition, has been identified as high importance with limited supportive data. The phenomenon plays a crucial role in assessing the degree of radiological impacts as radioactive aerosols or vapors are efficiently and effectively removed during the process. To provide validation basis for SRT in assessing pool scrubbing performance inside sodium pools, the University of Wisconsin-Madison performed tests including extensive parametric effects. Separate effect tests were conducted to directly evaluate the SRT models and to estimate degree of contribution by each contributing factor. Specifically, bubble size, aerosol size, aerosol density, aerosol concentration, pool depth, system temperature, and bubble swarm effects were considered. According to the parametric effects, decontamination performance enhances with decreasing bubble size, large density, and deeper pool height. Aerosol concentration provides no effect for the whole range of interest, and pool temperature variation shows minor effects under the considered temperature condition. When multiple bubbles are injected generating a bubble swarm condition, DF performance further enhances by bubble interactions and turbulence characteristics. The measurement shows the exceptional importance of aerosol size range considered, with the lowest decontamination, where most radionuclides are expected to escape.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1977

A high pressure modulated molecular beam mass spectrometric sampling system

The current state of understanding of free-jet high pressure sampling is critically reviewed and modifications of certain theoretical and empirical considerations are presented. A high pressure, free-jet expansion, modulated molecular beam, mass spectrometric sampling apparatus was constructed and this apparatus is described in detail. Experimental studies have demonstrated that the apparatus can be used to sample high temperature systems at pressures up to one atmosphere. Condensible high temperature gaseous species have been routinely sampled and the mass spectrometric detector has provided direct identification of sampled species. System sensitivity is better than one tenth of a part per million. Experimental results obtained with argon and nitrogen beams are presented and compared to theoretical predictions. These results and the respective comparison are taken to indicate acceptable performance of the sampling apparatus. Results are also given for two groups of experiments related to hot corrosion studies. The formation of gaseous sodium sulfate in doped methane-oxygen flames was characterized and the oxidative vaporization of metals was studied in an atmospheric pressure flowing gas system to which gaseous salt partial pressures were added.

Stearns, C. A.↗
NASA NTRS2012

Monte Carlo Model Insights into the Lunar Sodium Exosphere

Sodium in the lunar exosphere is released from the lunar regolith by several mechanisms. These mechanisms include photon stimulated desorption (PSD), impact vaporization, electron stimulated desorption, and ion sputtering. Usually, PSD dominates; however, transient events can temporarily enhance other release mechanisms so that they are dominant. Examples of transient events include meteor showers and coronal mass ejections. The interaction between sodium and the regolith is important in determining the density and spatial distribution of sodium in the lunar exosphere. The temperature at which sodium sticks to the surface is one factor. In addition, the amount of thermal accommodation during the encounter between the sodium atom and the surface affects the exospheric distribution. Finally, the fraction of particles that are stuck when the surface is cold that are rereleased when the surface warms up also affects the exospheric density. In [1], we showed the "ambient" sodium exosphere from Monte Carlo modeling with a fixed source rate and fixed surface interaction parameters. We compared the enhancement when a CME passes the Moon to the ambient conditions. Here, we compare model results to data in order to determine the source rates and surface interaction parameters that provide the best fit of the model to the data.

Hurley, Dana M.↗
DOE OSTI2022

On the nature of droplet production in DC glows with a liquid anode: mechanisms and potential applications

The interactions between plasma and liquid solutions give rise to the formation of chemically reactive species useful for many applications, but the mass transport in the interfacial region is usually limited and not fully understood. In this work, we report on the observation and explanation of droplet ejection at the plasma–liquid interface of a one-atmosphere glow discharge with the liquid anode. The impact of droplets emission on plasma properties is also analyzed by spectroscopy. The process, which is an efficient mass and charge transport mechanism, apparently occurs during discharge operation and thus constitutes a feedback vehicle between the discharge and the liquid. Distinctive from the well-known Talyor cone droplets associated with liquid cathodes, the observed droplets originate from the bubbles due to electrolysis and solvated air which does not require strong electric field at liquid surface. Instead, the droplets are ejected by bubble cavity rupture at the plasma–liquid interface and their size, initial speed are strongly dependent on the gravity, inertia and capillarity. Further, the droplets emerge near the plasma attachment and are subsequently vaporized, emitting intense UV and visible light, which originated from excited OH radicals and sodium derived from the liquid electrolyte. Spectroscopy analysis confirmed that the bursting droplets generally reduce the gas temperature while their effects on electron density depend on the composition of the liquid anode. Results also show that droplets from NaCl solution increase the plasma electron density due to the lower ionization potential of sodium. These findings reveal a new mechanism for discharge maintenance and mass transport as well as suggest a simple approach to dispersing plasma-activated liquid into the gas phase and thus enhancing plasma–liquid interaction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗