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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Stability Of A Carbon-Dioxide-Removing Resin

Report describes experiments determing long-term chemical stability of IRA-45, commerical ion-exchange resin candidate for use in removing CO2 from atmosphere of Space Station. In proposed system, cabin air passes through resin, and acidic CO2 absorbed by weakly-basic hydrated diethylenetriamine bonded to porous resin substrate. When resin absorbs all CO2, disconnects from airstream and heated with steam to desorb CO2. Resin reuseable. Removed by post-treating process air with phosphoric acid on charcoal. Other chemicals removed by trace-contaminant-control subsystem of Space Station.

Wydeven, Theodore↗

Medical Lessons Learned from the Exploration Atmospheres Study

Background: The National Aeronautics and Space Administration’s (NASA) Exploration Atmospheres study (EA) was done to evaluate alternative cabin atmospheres for future spacecraft designs and planetary surface exploration of the Moon, Mars and beyond. Deep space exploration involves creating habitats and environments safe for human occupancy and means to explore the outside environment (extravehicular activities, EVA). In order to validate alternative atmospheres and pre-spacewalk procedures, the EA study was conducted to evaluate factors such as hypoxia risks, denitrogenation protocols, food limitations, medications, and the impact of other factors on human performance. Overview: Space travel is constrained by mass, volume, power and the cost of vehicle development, which creates tradeoffs in various capabilities, including breathing gasses. Higher atmospheric pressure in a vehicle means more gas, and a stronger containment vessel/habitat; while lower pressure requires higher oxygen partial pressure, which may increase fire risk. NASA’s EA study evaluated a proposed alternative cabin environment (8.2 psia, 34% Oxygen), for future spacecraft habitat, and planetary EVAs. EA included both a 3-day and a 11-day trial. These trials included a depressurization and saturation to 8.2psi at 34% O2 with additional depresses to 4.3 psia at 85% O2 for simulated EVAs, (1 EVA during the 3-day and 5 during the 11-day trials). Discussion: Planning for and executing the medical monitoring and response plan for a trial of this scope was a huge undertaking with no prior practice to fall back on. Food obstacles, sleeping issues, medications, joint injury, equipment limitations, medical privacy, multiple cases of decompression sickness, and even a COVID outbreak among the support team proved challenging. Conclusion: Testing of this nature is an essential part NASA’s preparation for the upcoming Lunar Artemis missions. As spaceflight transitions beyond low earth orbit, to planetary, even more trials of this nature will be required to learn what are the optimal atmospheric and associated operational constraints to maintain the optimal health of the crew and achieve mission objectives.

R Sanders↗

Effects of Atmospheric Environment on Flammability of Fabrics and Carbonaceous Solids

In this chapter and in the others to follow, an attempt will be made to outline empirical studies which shed some light on the effects of internal atmospheric conditions on the fire hazard in space cabins. The results of these experiments will be interpreted, whenever possible, in light of the theoretical considerations outlined in Chapter 1.

Roth, Emanuel M.↗

Performance Evaluation of Staged Bosch Process for CO2 Reduction to Produce Life Support Consumables

Utilizing carbon dioxide to produce water and hence oxygen is critical for sustained manned missions in space, and to support both NASA's cabin Atmosphere Revitalization System (ARS) and In-Situ Resource Utilization (ISRU) concepts. For long term missions beyond low Earth orbit, where resupply is significantly more difficult and costly, open loop ARS, like Sabatier, consume inputs such as hydrogen. The Bosch process, on the other hand, has the potential to achieve complete loop closure and is hence a preferred choice. However, current single stage Bosch reactor designs suffer from a large recycle penalty due to slow reaction rates and the inherent limitation in approaching thermodynamic equilibrium. Developmental efforts are seeking to improve upon the efficiency (hence reducing the recycle penalty) of current single stage Bosch reactors which employ traditional steel wool catalysts. Precision Combustion, Inc. (PCI), with support from NASA, has investigated the potential for utilizing catalysts supported over short-contact time Microlith substrates for the Bosch reaction to achieve faster reaction rates, higher conversions, and a reduced recycle flows. Proof-of-concept testing was accomplished for a staged Bosch process by splitting the chemistry in two separate reactors, first being the reverse water-gas-shift (RWGS) and the second being the carbon formation reactor (CFR) via hydrogenation and/or Boudouard. This paper presents the results from this feasibility study at various operating conditions. Additionally, results from two 70 hour durability tests for the RWGS reactor are discussed.

Vilekar, Saurabh A.↗

Virtual Design of a Four-Bed Molecular Sieve for Exploration

Aboard the International Space Station, CO2 is removed from the cabin atmosphere by a four-bed molecular sieve (4BMS) process called the Carbon Dioxide Removal Assembly (CDRA).1 This 4BMS process operates by passing the CO2-laden air through a desiccant bed to remove any humidity and then passing the dried air through a sorbent bed to remove the CO2. While one pair of beds is in use, the other pair is thermally regenerated to allow for continuous CO2 removal.

Giesy, T. J.↗

Dynamic Sampling of Cabin VOCs during the Mission Operations Test of the Deep Space Habitat

The atmospheric composition inside spacecraft is dynamic due to changes in crew metabolism and payload operations. A portable FTIR gas analyzer was used to monitor the atmospheric composition of four modules (Core lab, Veggie Plant Atrium, Hygiene module, and Xhab loft) within the Deep Space Habitat '(DSH) during the Mission Operations Test (MOT) conducted at the Johnson Space Center. The FTIR was either physically relocated to a new location or the plumbing was changed so that a different location was monitored. An application composed of 20 gases was used and the FTIR was zeroed using N2 gas every time it was relocated. The procedures developed for operating the FTIR were successful as all data was collected and the FTIR worked during the entire MOT mission. Not all the 20 gases in the application sampled were detected and it was possible to measure dynamic VOC concentrations in each DSH location.

Monje, Oscar↗

On-Orbit Measurements of the ISS Atmosphere by the Vehicle Cabin Atmosphere Monitor

We report on trace gas and major atmospheric constituents results obtained by the Vehicle Cabin Atmosphere Monitor (VCAM) during operations aboard the International Space Station (ISS). VCAM is an autonomous environmental monitor based on a miniature gas chromatograph/mass spectrometer. It was flown to the ISS on shuttle mission STS-131 and commenced operations on 6/10/10. VCAM provides measurements of ppb-to-ppm levels of volatile trace-gas constituents, and of the atmospheric major constituents (nitrogen, oxygen, argon, and carbon dioxide) in a space vehicle or station. It is designed to operate autonomously and maintenance-free, approximately once per day, with a self-contained gas supply sufficient for a one-year lifetime. VCAM is designed to detect and identify 90% of the target compounds at their 180-day Spacecraft Maximum Allowable Concentration levels.

cabin atmosphere↗

Rationale and Methods for Archival Sampling and Analysis of Atmospheric Trace Chemical Contaminants On Board Mir and Recommendations for the International Space Station

Collection and analysis of spacecraft cabin air samples are necessary to assess the cabin air quality with respect to crew health. Both toxicology and engineering disciplines work together to achieve an acceptably clean cabin atmosphere. Toxicology is concerned with limiting the risk to crew health from chemical sources, setting exposure limits, and analyzing air samples to determine how well these limits are met. Engineering provides the means for minimizing the contribution of the various contaminant generating sources by providing active contamination control equipment on board spacecraft and adhering to a rigorous material selection and control program during the design and construction of the spacecraft. A review of the rationale and objectives for sampling spacecraft cabin atmospheres is provided. The presently-available sampling equipment and methods are reviewed along with the analytical chemistry methods employed to determine trace contaminant concentrations. These methods are compared and assessed with respect to actual cabin air quality monitoring needs. Recommendations are presented with respect to the basic sampling program necessary to ensure an acceptably clean spacecraft cabin atmosphere. Also, rationale and recommendations for expanding the scope of the basic monitoring program are discussed.

Perry, J. L.↗

Automation of closed environments in space for human comfort and safety

The development of Environmental Control and Life Support Systems (ECLSS) for Space Station Freedom, future colonization of the Moon, and Mars missions presents new challenges for present technologies. ECLSS that operate during long-duration missions must be semi-autonomous to allow crew members environmental control without constant supervision. A control system for the ECLSS must address these issues as well as being reliable. The Kansas State University Advanced Design Team is in the process of researching and designing controls for the automation of the ECLSS for Space Station Freedom and beyond. The ECLSS for Freedom is composed of six subsystems. The temperature and humidity control (THC) subsystem maintains the cabin temperature and humidity at a comfortable level. The atmosphere control and supply (ACS) subsystem insures proper cabin pressure and partial pressures of oxygen and nitrogen. To protect the space station from fire damage, the fire detection and suppression (FDS) subsystem provides fire-sensing alarms and extinguishers. The waste management (WM) subsystem compacts solid wastes for return to Earth, and collects urine for water recovery. The atmosphere revitalization (AR) subsystem removes CO2 and other dangerous contaminants from the air. The water recovery and management (WRM) subsystem collects and filters condensate from the cabin to replenish potable water supplies, and processes urine and other waste waters to replenish hygiene water supplies. These subsystems are not fully automated at this time. Furthermore, the control of these subsystems is not presently integrated; they are largely independent of one another. A fully integrated and automated ECLSS would increase astronauts' productivity and contribute to their safety and comfort.

Source record↗

A regenerable solid amine CO2 concentrator for space station

A regenerable solid amine CO2 control system, which employs water vapor for desorption, is being developed for potential use on long duration space missions. During cyclic operation, CO2 is first absorbed from the cabin atmosphere onto the granular amine. Steam is then used to heat the solid amine bed and desorb the CO2. This paper describes the solid amine system operation and application to the Shuttle Orbiter, Manned Space Platform (MSP) and Space Operations Center (SOC). The importance and interplay of system performance parameters are presented together with supporting data and design characteristics.

Boehm, A. M.↗

Flight prototype CO2 and humidity control system

A regenerable CO2 and humidity control system is presently being developed for potential use on the space shuttle as an alternative to the baseline lithium hydroxide system. The system utilizes a sorbent material (designated HS-C) to adsorb CO2 and water vapor from the cabin atmosphere and desorb the CO2 and water vapor overboard when exposed to a space vacuum. Continuous operation is achieved by utilizing two beds which are alternately cycled between adsorption and desorption. A shuttle vehicle integration study showed that the HS-C system offers substantial weight advantages compared to the baseline shuttle orbiter expendable lithium hydroxide CO2 removal system for extended missions beyond the nominal design of four men for seven days. This study defined a system packaging envelope in the area presently occupied by the LiOH cartridges.

Rudy, K. M.↗

Breadboard CO2 and humidity control system

A regenerable CO2 and humidity control system is being developed for potential use on shuttle as an alternate to the baseline lithium hydroxide (LiOH)/condensing heat exchanger system. The system utilizes a sorbent material, designated HS-C, to adsorb CO2 and water vapor from the cabin atmosphere. The material is regenerated by exposing it to space vacuum. A half-size breadboard system, utilizing a flight representative HS-C canister, was designed, built, and performance tested to shuttle requirements for total CO2 and total humidity removal. The use of a new chemical matrix material allowed significant optimization of the system design by packing the HS-C chemical into the core of a heat exchanger which is manifolded to form two separate and distinct beds. Breadboard system performance was proven by parametric testing and simulated mission testing over the full range of shuttle crew sizes and metabolic loadings. Vacuum desorption testing demonstrated considerable savings in previously projected shuttle vacuum duct sizing.

Boehm, A. M.↗

Automation of closed environments in space for human comfort and safety

The Environmental Control and Life Support System (ECLSS) for the Space Station Freedom and future colonization of the Moon and Mars presents new challenges for present technologies. Current plans call for a crew of 8 to live in a safe, shirt-sleeve environment for 90 days without ground support. Because of these requirements, all life support systems must be self-sufficient and reliable. The ECLSS is composed of six subsystems. The temperature and humidity control (THC) subsystem maintains the cabin temperature and humidity at a comfortable level. The atmosphere control and supply (ACS) subsystem insures proper cabin pressure and partial pressures of oxygen and nitrogen. To protect the space station from fire damage, the fire detection and suppression (FDS) subsystem provides fire sensing alarms and extinguishers. The waste management (WM) subsystem compacts solid wastes for return to Earth, and collects urine for water recovery. Because it is impractical, if not impossible, to supply the station with enough fresh air and water for the duration of the space station's extended mission, these elements are recycled. The atmosphere revitalization (AR) subsystem removes CO2 and other dangerous contaminants from the air. The water recovery and management (WRM) subsystem collects and filters condensate from the cabin to replenish potable water supplies, and processes urine and other waste waters to replenish hygiene water supplies. These subsystems are not fully automated at this time. Furthermore, the control of these subsystems is not presently integrated; they are largely independent of one another. A fully integrated and automated ECLSS would increase astronauts' productivity and contribute to their safety and comfort. The Kansas State University Advanced Design Team is in the process of researching and designing controls for the automation of the ECLSS for Space Station Freedom and beyond. The approach chosen to solve this problem is to divide the design into three phases. The first phase is to research the ECLSS as a whole system and then concentrate efforts on the automation of a single subsystem. The AR subsystem was chosen for our focus. During the second phase, the system control process will then be applied to the AR subsystem.

Source record↗

Space Clinical Medicine.

Book on space clinical medicine covering hypoxia, ebullism, decompression, aerotitis, dehydration, hypothermia, cabin atmosphere contamination, urinary calculus, etc

Busby, D. E.↗

Toxicological evaluation of the Columbia spacecraft

The toxicology procedures developed for the Space Shuttle program to evaluate and eliminate contaminants in the cabin atmosphere characterized, and results from STS missions 1-5 are reviewed. Shuttle maximum-allowable-concentration standards (SMAC) equal to 10-50 percent of those established for normal 40-h work weeks on the ground have been established for a broad range of substances, and outgassing data are employed in choosing spacecraft construction materials. Gases are removed by the atmospheric revitalization system (CO2-removal bed, catalytic oxidizer, and dehumidifier). Whole-gas and adsorbed-gas samples are employed in ground-based and inflight measurements of contaminants: results are presented in tables. A total of 152 substances, of which 64 were well defined, were detected in STS-1-5. Only the toluene contamination on STS-2 (17 ppm compared to the SMAC of 20 ppm) was considered serious.

Rippstein, W. J., Jr.↗

In-space Biomanufacturing Using CO2 with Methylobacterium Extorquens

Long duration missions to deep space will require new approaches for supplying astronauts. In-space microbial manufacturing could generate many important compounds (such as nutrients, pharmaceuticals and fuels) but there are significant barriers to deploying reliable bioproduction platforms to space. These include ensuring adequate production and proper purification of the desired product, especially in the unique radiation and microgravity environment. Here we are focused on developing methods and technologies to feed microbial factories using the resources available in space. CO2, found in abundance in spacecraft cabins and the Mars atmosphere, can be sequestered and converted into bioproducts. While autotrophic organisms can use CO2 directly, they are generally slow growing and have less-developed biotechnology toolkits. Therefore we are developing an alternative paradigm in which CO2 is first reduced to more energetic carbon compounds that can support more rapid growth of workhorse biotechnology platforms (E. coli, S. cerevisiae, P. pastoris).Various technologies exist or are being developed to convert CO2. For example, the Sabatier system currently installed on the ISS, reacts CO2 and H2 to generate CH4 and H2O. This methane could be consumed by engineered methanotrophic bacteria. Alternatively, electrochemical systems can convert CO2 into formate (CHO2) which could be consumed by formatotrophic bacteria. In either case, synthetic biology techniques allow these microbes to serve as reprogrammable biofactories capable of producing a vast number or products.

Synthetic biology; Formate metabolism↗