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Results for “SURFACE LAYER”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Thermal stability of the surface layer and its relation to the dispersion of primary pollutants in St. Louis

The present investigation is concerned with the applicability of the vertical temperature gradient, DT, as a dispersion parameter for urban area sources. Data on DT were tabulated from temperature measurements at 5 m and 30 m obtained on 30 m towers at 12 stations. DT was obtained by subtracting the value at 5 m from that at 30 m. Positive DT values represent an inversion. Accuracy of the DT data is 0.1 K. Hourly measurements of DT along with concentrations of the primary pollutants, CO, NO, and total hydrocarbons (THC), are available from the 1976 RAPS data base for St. Louis. Linear correlations between a given pollutant species concentration and DT are developed from that data set. It could be confirmed that a strong positive correlation exists at night between the thermal stability of the lowest part of the boundary layer and the urban concentration of the primary pollutants CO, NO, and hydrocarbons.

Remsberg, E. E.↗
NASA NTRS1983

Stability of the surface layer and its relation to the dispersion of primary pollutants in St. Louis

The effects of atmospheric stability on the dispersion of primary pollutants such as CO, total hydrocarbons (THC), and NO were examined in St. Louis. The pollutant levels were measured at 25 stations, temperature at 12 stations at 5 and 30 m height, and wind speed and direction at the 30 m level at 12 stations. Correlation coefficients were generated for pairs of the vertical temperature differences, the log of the mean wind speed reciprocal, the bulk Richardson number, and specific pollutant concentrations. A high correlation was obtained between the thermal stability and the urban concentration of the primary pollutants in the lowest part of the boundary layer. A restricted nighttime dispersion of the pollutants was observed, indicating near-ground increased concentrations at times when the source emissions actually decrease.

Remsberg, E. E.↗
NASA NTRS1994

Use of acoustic wave travel-time measurements to probe the near-surface layers of the Sun

The variation of solar p-mode travel times with cyclic frequency nu is shown to provide information on both the radial variation of the acoustic potential and the depth of the effective source of the oscillations. Observed travel-time data for waves with frequency lower than the acoustic cutoff frequency for the solar atmosphere (approximately equals 5.5 mHz) are inverted to yield the local acoustic cutoff frequency nu(sub c) as a function of depth in the outer convection zone and lower atmosphere of the Sun. The data for waves with nu greater than 5.5 mHz are used to show that the source of the p-mode oscillations lies approximately 100 km beneath the base of the photosphere. This depth is deeper than that determined using a standard mixing-length calculation.

Jefferies, S. M.↗
NASA NTRS2000

Size Scales for Thermal Inhomogeneities in Mars' Atmosphere Surface Layer: Mars Pathfinder

Atmospheric temperature measurement at three heights with thin wire thermocouples on the 1.1 m Mars Pathfinder meteorology must allow estimates of the integral scale of the atmospheric thermal turbulence during an 83 sol period that begins in the summer. The integral scale is a measure for regions of perturbations. In turbulent media that roughly characterizes locations where the perturbations are correlated. Excluding some to intervals with violent excursions of the mean temperatures, integral scale values are found that increase relatively rapidly from a few tenths meters or less near down to several meters by mid-morning. During mid-morning, the diurnal and shorter time scale wind direction variations often place the meteorology mast in the thermal wake of the Lander.

Mihalov, John D.↗
DOE OSTI2023

Low refractive index surface layers and related methods

The disclosure relates to a method for forming a low refractive index layer on a substrate. The method generally includes (a) applying a block copolymer layer on a substrate, the block copolymer including a polar polymeric block and a non-polar polymeric block; (b) swelling the block copolymer layer with a solvent to increase the block copolymer layer thickness; (c) depositing a metal oxide or metalloid oxide layer on polar polymeric blocks of the block copolymer layer; and (d) removing the block copolymer layer from the substrate, thereby forming a porous metal oxide or metalloid oxide layer on the substrate.

Shevchenko, Elena↗
DOE OSTI2022

Exceptional Mineral Scaling Resistance from the Surface Gas Layer: Impacts of Surface Wetting Properties and the Gas Layer Charging Mechanism

Mineral scaling is a phenomenon that occurs on submerged surfaces in contact with saline solutions. In membrane desalination, heat exchangers, and marine structures, mineral scaling reduces process efficiency and eventually leads to process failure. Therefore, achieving long-term scaling resistance is beneficial to enhancing process performance and reducing operating and maintenance costs. While evidence shows that superhydrophobic surfaces may reduce mineral scaling kinetics, prolonged scaling resistance is limited due to the finite stability of the entrained gas layer present in a Cassie–Baxter wetting state. Additionally, superhydrophobic surfaces are not always feasible for all applications, but strategies for long-term scaling resistance with smooth or even hydrophilic surfaces are often overlooked. In this study, we elucidate the role of interfacial nanobubbles on the scaling kinetics of submerged surfaces of varied wetting properties, including those that do not entrain a gas layer. We show that both solution conditions and surface wetting properties that promote interfacial bubble formation enhances scaling resistance. In the absence of interfacial bubbles, scaling kinetics decrease as surface energy decreases, while the presence of bulk nanobubbles enhances the scaling resistance of the surface with any wetting property. The findings in this study allude to scaling mitigation strategies that are enabled by solution and surface properties that promote the formation and stability of interfacial gas layers and provide insights to surface and process design for greater scaling resistance.

calcite↗
NASA NTRS1977

Optical polarimetry: Instrumentation and applications; Proceedings of the Seminar, San Diego, Calif., August 23, 24, 1977

Instrumentation used in optical polarimetry is discussed with reference to high-resolution spectropolarimetry, an orbiter cloud photopolarimeter, X-ray polarimeters, and the design of a self-nulling ellipsometer. Consideration is given to surface and thin-film ellipsometry noting studies of electrochemical surface layers, surface anisotropy, polish layers on infrared window materials, and anodic films. Papers on biological, chemical, and physical polarimetry are presented including birefringence in biological materials, vibrational optical activity, and the optical determination of the thermodynamic phase diagram of a metamagnet. Remote sensing is discussed in terms of polarization imagery, the optical polarimetry of particulate surfaces, and techniques and applications of elliptical polarimetry in astronomy and atmospheric studies.

Azzam, R. M. A.↗
DOE OSTI2022

Sensitivity of the Arctic Sea Ice Cover to the Summer Surface Scattering Layer

Here, the ‘surface scattering layer’ (SSL) is the highly-scattering, coarse-grained ice layer that forms on the surface of melting, drained sea ice during spring and summer. Ice of sufficient thickness with an SSL has an observed persistent broadband albedo of ~0.65, resulting in a strong influence on the regional solar partitioning. Experiments during the MOSAiC expedition showed that the SSL re-forms in approximately one day following manual removal. Coincident spectral albedo measurements provide insight into the SSL evolution, where albedo increased on sunny days with higher solar insolation. Comparison with experiments in radiative transfer and global climate models show that the sea ice albedo is greatly impacted by the SSL thickness. The presence of SSL is a significant component of the ice-albedo feedback, with an albedo impact of the same order as melt ponds. Changes in SSL and implications for Arctic sea ice within a warming climate are uncertain.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

2023 National Offshore Wind data set (NOW-23)

The 2023 National Offshore Wind data set (NOW-23) is the latest wind resource data set for offshore regions in the United States, which supersedes, for its offshore component, the Wind Integration National Dataset (WIND) Toolkit, which was published about a decade ago and is currently one of the primary resources for stakeholders conducting wind resource assessments in the continental United States. The NOW-23 data set was produced using the Weather Research and Forecasting Model (WRF) version 4.2.1. A regional approach was used: for each offshore region, the WRF setup was selected based on validation against available observations. The WRF model was initialized with the European Centre for Medium Range Weather Forecasts 5 Reanalysis (ERA-5) data set, using a 6-hour refresh rate. The model is configured with an initial horizontal grid spacing of 6 km and an internal nested domain that refined the spatial resolution to 2 km. The model is run with 61 vertical levels, with 12 levels in the lower 300m of the atmosphere, stretching from 5 m to 45 m in height. The MYNN planetary boundary layer and surface layer schemes were used the North Atlantic, Mid Atlantic, Great Lakes, Hawaii, and North Pacific regions. On the other hand, using the YSU planetary boundary layer and MM5 surface layer schemes resulted in a better skill in the South Atlantic, Gulf of Mexico, and South Pacific regions. A more detailed description of the WRF model setup can be found in the WRF namelist files linked at the bottom of this page. For all regions, the NOW-23 data set coverage starts on January 1, 2000. For Hawaii and the North Pacific regions, NOW-23 goes until December 31, 2019. For the South Pacific region, the model goes until 31 December, 2022. For all other regions, the model covers until December 31, 2020. Outputs are available at 5 minute resolution, and for all regions we have also included output files at hourly resolution. The NOW-23 data are provided here as HDF5 files. Examples of how to use the HSDS Service to Access the NOW-23 files are linked below. A list of the variables included in the NOW-23 files is also linked below. No filters have been applied to the raw WRF output.

Array↗
NASA NTRS2000

Satellite and Skin Layer Effects on the Accuracy of Sea Surface Temperature Measurements from the GOES Satellites

The latest Geostationary Operational Environmental Satellites (GOES) have facilitated significant improvements in our ability to measure sea surface temperature (SST) from geostationary satellites. Nonetheless, difficulties associated with sensor calibration and oceanic near-surface temperature gradients affect the accuracy of the measurements and our ability to estimate and interpret the diurnal cycle of the bulk SST. Overall, measurements of SST from the GOES Imagers on the GOES 8-10 satellites are shown to have very small bias (less than 0.02 K) and rms differences of between 0.6 and 0.9 K relative to buoy observations. Separate consideration of individual measurement times, however, demonstrates systematic bias variations of over 0.6 K with measurement hour. These bias variations significantly affect both the amplitude and shape of estimates of the diurnal SST cycle. Modeled estimates of the temperature difference across the oceanic cool skin and diurnal thermocline show that bias variations up to 0.3 K can result from variability in the near-surface layer. Oceanic near-surface layer and known "satellite midnight" calibration effects, however, explain only a portion of the observed bias variations, suggesting other possible calibration concerns. Methods of explicitly incorporating skin layer and diurnal thermocline effects in satellite bulk SST measurements were explored in an effort to further improve the measurement accuracy. While the approaches contain more complete physics, they do not yet significantly improve the accuracy of bulk SST measurements due to remaining uncertainties in the temperature difference across the near-surface layer.

Wick, Gary A.↗
DOE OSTI2022

A Gauss’s law analysis of redox active adsorbates on semiconductor electrodes: The charging and faradaic currents are not independent

A detailed framework for modeling and interpreting the data in totality from a cyclic voltammetric measurement of adsorbed redox monolayers on semiconductor electrodes has been developed. A three-layer model consisting of the semiconductor space-charge layer, a surface layer, and an electrolyte layer is presented that articulates the interplay between electrostatic, thermodynamic, and kinetic factors in the electrochemistry of a redox adsorbate on a semiconductor. Expressions are derived that describe the charging and faradaic current densities individually, and an algorithm is demonstrated that allows for the calculation of the total current density in a cyclic voltammetry measurement as a function of changes in the physical properties of the system (e.g., surface recombination, dielectric property of the surface layer, and electrolyte concentration). The most profound point from this analysis is that the faradaic and charging current densities can be coupled. That is, the common assumption that these contributions to the total current are always independent is not accurate. Their interrelation can influence the interpretation of the charge-transfer kinetics under certain experimental conditions. More generally, this work not only fills a long-standing knowledge gap in electrochemistry but also aids practitioners advancing energy conversion/storage strategies based on redox adsorbates on semiconductor electrodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

An In Situ Formed Surface Coating Layer Enabling LiCoO 2 with Stable 4.6 V High‐Voltage Cycle Performances

Abstract The development of high‐voltage LiCoO 2 is essential for achieving lithium‐ion batteries with high volumetric energy density, however, it faces a great deal of challenges owing to the materials, structure and interfacial instability issues. In this work, a strategy is developed, through heat annealing a precoated surface layer to in situ form a high‐voltage‐stable surface coating layer, which is demonstrated to be highly effective to improve the high‐voltage performance of LiCoO 2 . It is discovered that LiCoO 2 reacts with Li 1.5 Al 0.5 Ti 1.5 (PO 4 ) 3 (LATP) at 700 °C to form exclusively spinel phases in addition to Li 3 PO 4 , which are structurally coherent to the layered lattice of LiCoO 2 . The heat annealing of the precoated thin layer of LATP enables the formation of a high‐quality surface layer. Spinel phases possess high‐voltage‐stable structures with much weaker oxidizing ability of lattice oxygen than layered structure. In addition, the Li 3 PO 4 is a good lithium‐ion conductor with excellent chemical stability at high voltages. All these benefits contribute to the construction of a uniform and conformal high‐voltage‐stable surface layer with favorable lithium conducting kinetics at the LiCoO 2 surface. The modified LiCoO 2 shows excellent 4.6 V high‐voltage cycle performance at both room temperature and 45 °C. The thermal stability is greatly enhanced as well.

Wang, Yi↗
DOE OSTI2020

Chalcogen back surface field layer

Kesterite photovoltaic devices having a back surface field layer are provided. In one aspect, a method of forming a photovoltaic device includes: forming a complete photovoltaic device having a substrate, an electrically conductive layer on the substrate, an absorber layer on the electrically conductive layer, a buffer layer on the absorber layer, and a transparent front contact on the buffer layer; removing the substrate and the electrically conductive layer from the complete photovoltaic device to expose a backside surface of the absorber layer; forming a passivating layer on the backside surface of the absorber layer; and forming a high work function back contact on the passivating layer. A photovoltaic device having a passivating layer is also provided.

14 SOLAR ENERGY↗