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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Regulating the Third Metal to Design and Engineer Multilayered NiFeM (M: Co, Mn, and Cu) Nanofoam Anode Catalysts for Anion-Exchange Membrane Water Electrolyzers

In this study, alkaline anion-exchange membrane water electrolyzers (AEMWEs) for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant platinum group metal (PGM)-free catalysts. Herein, the third metal is incorporated into NiFe-based catalysts to regulate their electronic structures and morphologies, aiming to achieve sufficient oxygen evolution reaction (OER) activity and performance in AEMWEs. The ternary NiFeM (M: Cu, Co, or Mn) catalysts are featured with multiple layered structures and nanofoam network morphologies, consisting of highly OER-active amorphous Ni-rich oxide shells and electrically conductive metallic alloy cores. The physical and electronic perturbations to the NiFe induced by a third element lead to a fine-tuning of the redox ability of the metal sites at the reaction centers, which breaks the scaling relationship between OH* and O* intermediates at the reaction centers. Thus, the unique structural configuration and electronic regulation simultaneously benefit catalytic activity and performance improvements. These NiFeM nanofoam catalysts demonstrated promising anode performance in actual AEMWEs, comparable to the IrO 2 reference, especially at high current densities. Notably, using various electrolytes (e.g., KOH solution or pure water) for AEMWEs exhibited a different performance trend among studied NiFeM catalysts, likely due to dynamic changes of catalysts under various OER environments.

25 ENERGY STORAGE↗
DOE OSTI2026

Electron–Ion Covariance Reveals Geometry-Resolved Inner-Shell Spectra in CS 2 Photodissociation

The chemical shifts of inner-shell atomic orbitals are highly sensitive to chemical bonding and molecular structure. In evolving systems, however, the spectra of distinct molecular species and geometries overlap, obscuring the underlying chemical dynamics. Here we demonstrate the use of electron–ion covariance analysis to combine the structural sensitivity of Coulomb explosion imaging with inner-shell spectroscopy, yielding geometry-specific spectra of transient and product species. We apply this approach to the excited state dynamics of CS 2 probed by ionization above the S 2p edge. Electron–ion covariance with time- and momentum-selected S + and S 2+ ions isolates distinct S 2p photoelectron spectra for ground-state CS 2 , bent photoexcited CS 2 , the CS photoproduct, and bare atomic sulfur ─ species whose spectra overlap strongly in the channel-averaged measurement. Clear chemical shifts are observed in the covariance photoelectron spectrum for each of these species, all of which are consistent with high-level calculations. Here, by extracting the atomic S contribution to the photoelectron spectrum in a finely time-resolved manner we can disentangle this contribution to the overall time-resolved photoelectron spectrum as the photodissociation proceeds. These results demonstrate the promise of electron–ion covariance as a general approach to geometry-resolved inner-shell spectroscopy, opening a route to tracking structural evolution through chemical shifts in complex photoexcited molecules.

Ionization↗
DOE OSTI2022

Few-femtosecond resolved imaging of laser-driven nanoplasma expansion

Abstract The free expansion of a planar plasma surface is a fundamental non-equilibrium process relevant for various fields but as-yet experimentally still difficult to capture. The significance of the associated spatiotemporal plasma motion ranges from astrophysics and controlled fusion to laser machining, surface high-harmonic generation, plasma mirrors, and laser-driven particle acceleration. Here, we show that x-ray coherent diffractive imaging can surpass existing approaches and enables the quantitative real-time analysis of the sudden free expansion of laser-heated nanoplasmas. For laser-ionized SiO 2 nanospheres, we resolve the formation of the emerging nearly self-similar plasma profile evolution and expose the so far inaccessible shell-wise expansion dynamics including the associated startup delay and rarefaction front velocity. Our results establish time-resolved diffractive imaging as an accurate quantitative diagnostic platform for tracing and characterizing plasma expansion and indicate the possibility to resolve various laser-driven processes including shock formation and wave-breaking phenomena with unprecedented resolution.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1975

Evolution of the moon between 4.6 and 3.3 AE

A model of lunar evolution is proposed. At 4.6 AE an outer shell 60-100 km thick of an initially homogeneous moon was totally molten following accretion. 'Highland basalt' represents remnants of the chilled crust of this molten layer and, therefore, the mean lunar composition. Melt from the partially molten region below the outer shell intruded into it, enriching it in FeO, SiO2, radiogenic, and trivalent trace LIL (large ion lithop) elements. Fractional crystallization of the outer shell produced toward its base a mafic cumulate zone less than 40 km thick, the upper 60 km being anorthosite. The radiogenic elements concentrated together with dense residual melt in the upper parts pf the mafic cumulate zone. Between 4.6 and 4.3 AE a second differentiation led to localized enrichment from below of radiogenic elements in the plagioclase-rich, high-Mg/Mg + Fe residuum below the outer 100-km-thick shell. Melting at these enriched sites at about 4.0 AE produced to KREEP basalts. Later melting at sites of radiogenic element enrichment in the outer 100-km-thick shell produced the mare basalts.

Hollister, L. S.↗
NASA NTRS1985

Spectrophotometry at 10 microns of T Tauri stars

New 8-13 micron spectra of 32 T Tau, or related young, stars are presented. Silicate emission features are commonly seen. Absorptions occur less frequently but also match the properties of silicate materials. The shape of the emission feature suggests that a more crystalline grain is responsible in the T Tau stars than those of the Trapezium region. The evolution of the silicate component of the circumstellar shell around T Tau stars, and its dependence upon stellar wind activity, visual linear polarization, and extinction are investigated. Several correlations suggest that the shells are likely to be flattened, disklike structures rather than spherical.

Cohen, M.↗
NASA NTRS1986

Volatile components and continental material of planets

It is shown that the continental material of the terrestrial planets varies in composition from planet to planet according to the abundances and composition of true volatiles (H20, CO2, etc.) in the outer shells of the planets. The formation of these shells occurs very early in a planet's evolution when the role of endogenous processes is indistinct and continental materials are subject to melting and vaporizing in the absence of an atmosphere. As a result, the chemical properties of continental materials are related not only to fractionation processes but also to meltability and volatility. For planets retaining a certain quantity of true volatile components, the chemical transformation of continental material is characterized by a close interaction between impact melting vaporization and endogeneous geological processes.

Florenskiy, K. P.↗
NASA NTRS1994

The conductive propagation of nuclear flames. 2: Convectively bounded flames in C + O and O + Ne + Mg cores

We determine the speeds, and many other physical properties, of flame fronts that propagate inward into degenerate and semidegenerate cores of carbon and oxygen (CO) and neon and oxygen (NeOMg) white dwarfs when such flames are bounded on their exterior by a convective region. Combustion in such fronts, per se, is incomplete, with only a small part of the initial mass function burned. A condition of balanced power is set up in the star where the rate of energy emitted as neutrinos from the convective region equals the power available from the unburned fuel that crosses the burning front. The propagation of the burning front itself is in turn limited by the temperature at the base of the convective shell, while cannot greatly exceed the adiabatic value. Solving for consistency between these two conditions gives a unique speed for the flame. Typical values for CO white dwarfs are a few hundredths of a centimeter per second. Flames in NeOMg mixtures are slower. Tables are presented in a form that can easily be implemented in stellar evolution codes and yield the rate at which the convective shell advances into the interior. Combining these velocities with the local equations for stellar structure, we find a minimum density for each gravitational potential below with the local equations for stellar structure, we find a minimum density for each gravitational potential below which the flame cannot propagate, and must die. Although detailed stellar models will have to be constructed to reslove some issues conclusively, our results that a CO white dwarf inginted at its edge will not burn carbon all the way to its center unless the mass of the white dwarf exceeds 0.8 solar mass. On the other hand, it is difficult to ignite carbon burning by compression alone anywhere in a white dwarf whose mass does not exceed 1.0 solar mass. Thus, compressionally ignited shell carbon burning in an accerting CO dwarf almost certainly propagates all the way to the center of the star. Implications for neutron star formation, and Type Ia supernova models, are briefly discussed. These are also applicable to massive stars in the about 10-12 solar mass range which ignite neon burning off center.

Timmes, F. X.↗
NASA NTRS2023

Origin and Evolution of Enceladus’s Tidal Dissipation

Enceladus possesses a subsurface ocean beneath a conductive ice shell. Based on shell thickness models, the estimated total conductive heat loss from Enceladus is 25–40 GW; the measured heat output from the South Polar Terrain (SPT) is 4–19 GW. The present-day SPT heat flux is of order 100 mWm -21 −, comparable to estimated paleo-heat fluxes for other regions of Enceladus. These regions have nominal ages of about 2 Ga, but the estimates are uncertain because the impactor flux in the Saturnian system may not resemble that elsewhere. Enceladus’s measured rate of orbital expansion implies a low dissipation factor Q p for Saturn, with Q p ≈3×10 -3 (neglecting the role of Dione). This value implies that Enceladus’s present-day equilibrium tidal heat production (roughly 50 GW, but with large uncertainties) is in approximate balance with its heat loss. If Q p is constant, Enceladus cannot be older than 1.5 Gyr (because otherwise it would have migrated more than is permissible). However, Saturn’s dissipation may be better described by the “resonance-locking” theory, in which case Enceladus’s orbit may have only evolved outwards by about 35% over the age of the Solar System. In the constant-Q p scenario, any ancient tidal heating events would have been too energetic to be consistent with the observations. Because resonance-locking makes capture into earlier mean-motion orbital resonances less likely, the inferred ancient heating episodes probably took place when the current orbital resonance was already established. In the resonance-locking scenario, tidal heating did not change significantly over time, allowing for a long-lived ocean and a relatively stable ice shell. If so, Enceladus is an attractive target for future exploration from a habitability standpoint.

Satellites of Saturn↗
DOE OSTI2024

Evolution of the nuclear spin-orbit splitting explored via the 32 Si( d,p ) 33 Si reaction using SOLARIS

The spin-orbit splitting between neutron 1p orbitals at 33 Si has been deduced using the single-neutron-adding (d,p) reaction in inverse kinematics with a beam of 32 Si, a long-lived radioisotope. Reaction products were analyzed by the newly implemented SOLARIS spectrometer at the reaccelerated-beam facility at the National Superconducting Cyclotron Laboratory. The measurements show reasonable agreement with shell-model calculations that incorporate modern cross-shell interactions, but they contradict the prediction of proton density depletion based on relativistic mean-field theory. The evolution of the neutron 1p-shell orbitals is systematically studied using the present and existing data in the isotonic chains of N = 17, 19, and 21. In each case, a smooth decrease in the separation of the 1p 3/2 - 1p 1/2 orbitals is seen as the respective p-orbitals approach zero binding, suggesting that the finite nuclear potential strongly influences the evolution of nuclear structure in this region.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2014

The Rapid Evolution of the Exciting Star of the Stingray Nebula

Context: SAO244567, the exciting star of the Stingray nebula, is rapidly evolving. Previous analyses suggested that it has heated up from an effective temperature of about 21 kK in 1971 to over 50 kK in the 1990s. Canonical post-asymptotic giant branch evolution suggests a relatively high mass while previous analyses indicate a low-mass star. Aims: A comprehensive model-atmosphere analysis of UV and optical spectra taken during 1988-2006 should reveal the detailed temporal evolution of its atmospheric parameters and provide explanations for the unusually fast evolution. Methods: Fitting line profiles from static and expanding non-LTE model atmospheres to the observed spectra allowed us to study the temporal change of effective temperature, surface gravity, mass-loss rate, and terminal wind velocity. In addition, we determined the chemical composition of the atmosphere. Results: We find that the central star has steadily increased its effective temperature from 38 kK in 1988 to a peak value of 60 kK in 2002. During the same time, the star was contracting, as concluded from an increase in surface gravity from log g = 4.8 to 6.0 and a drop in luminosity. Simultaneously, the mass-loss rate declined from log(M/M (solar mass) yr (exp −1)) = −9.0 to −11.6 and the terminal wind velocity increased from v (infinity) = 1800 km s (exp −1) to 2800 km s (exp −1). Since around 2002, the star stopped heating and has cooled down again to 55 kK by 2006. It has a largely solar surface composition with the exception of slightly subsolar carbon, phosphorus, and sulfur. The results are discussed by considering different evolutionary scenarios. Conclusions: The position of SAO244567 in the log T (sub eff) -log g plane places the star in the region of sdO stars. By comparison with stellar-evolution calculations, we confirm that SAO244567 must be a low-mass star (M < 0.55 solar mass). However, the slow evolution of the respective stellar evolutionary models is in strong contrast to the observed fast evolution and the young planetary nebula with a kinematical age of only about 1000 years. We speculate that the star could be a late He-shell flash object. Alternatively, it could be the outcome of close-binary evolution. Then SAO244567 would be a low-mass (0.354 solar mass) helium pre-white dwarf after the common-envelope phase, during which the planetary nebula was ejected.

Stingray↗
NASA NTRS1994

Ion Chemistry in Atmospheric and Astrophysical Plasmas

There are many differences and also remarkable similarities between the ion chemistry and physics of planetary ionospheres and the ion chemistry and physics of astronomical environments beyond the solar system. In the early Universe, an expanded cooling gas of hydrogen and helium was embedded in the cosmic background radiation field and ionized by it. As the Universe cooled by adiabatic expansion, recombination occurred and molecular formation was driven by catalytic reactions involving the relict electrons and protons. Similar chemical processes are effective in the ionized zones of gaseous and planetary nebulae and in stellar winds where the ionization is due to radiation from the central stars, in the envelopes of supernovae where the ionization is initiated by the deposition of gamma-rays, in dissociative shocks where the ionization arises from electron impacts in a hot gas and in quasar broad-line region clouds where the quasar is responsible for the ionization. At high altitudes in the atmospheres of the Jovian planets, the main constituents are hydrogen and helium and the ion chemistry and physics is determined by the same processes, the source of the ionization being solar ultraviolet radiation and cosmic rays. After the collapse of the first distinct astronomical entities to emerge from the uniform flow, heavy elements were created by nuclear burning in the cores of the collapsed objects and distributed throughout the Universe by winds and explosions. The chemistry and physics became more complicated. Over 90 distinct molecular species have been identified in interstellar clouds where they are ionized globally by cosmic ray impacts and locally by radiation and shocks associated with star formation and evolution. Complex molecules have also been found in circumstellar shells of evolved stars. At intermediate and low altitudes in the Jovian atmospheres, the ion chemistry is complicated by the increasing abundance of heavy elements such as carbon, and an extensive array of complex molecules has been predicted. Reactions involving heavy elements dominate the structure of the ionspheres of the terrestrial planets and the satellites Titan and Triton.

Dalgarno, A.↗
NASA NTRS1992

Formation of shells in major mergers

Numerical simulations are used to study the fate of disks in mergers between equal-mass galaxies. Contrary to popular belief, mergers between equal-mass galaxies can form shells, loops, and ripples. Material that was originally in the outer disk of the premerger spirals falls into the remnant late in the merger event, long after the inner region of the remnant has relaxed. Thus, its evolution is similar to that of an accreted dwarf satellite that forms shells through 'phase wrapping'. However, the mechanism described in this letter avoids a number of difficulties with the accretion model; specifically, it can explain the observed correlation between properties of the host galaxies and shell alignments and luminosities. In view of this, we argue that many shell systems may have originated through 'major' mergers of comparable-mass galaxies rather than via 'minor' mergers or accretions. In particular, the shell elliptical NGC 3923 appears to be a good candidate for shell formation by a major merger.

Hernquist, Lars↗
DOE OSTI2020

Chromium Nucleosynthesis and Silicon–Carbon Shell Mergers in Massive Stars

In this work, we analyze the production of the element Cr in galactic chemical evolution (GCE) models using the NuGrid nucleosynthesis yields set. We show that the unusually large [Cr/Fe] abundance at [Fe/H] ≈ 0 reported by previous studies using those yields and predicted by our Milky Way model originates from the merging of convective Si-burning and C-burning shells in a 20 ${M}_{\odot }$ model at metallicity Z = 0.01, about an hour before the star explodes. This merger mixes the incomplete burning material in the Si shell, including 51 V and 52 Cr, out to the edge of the carbon/oxygen (CO) core. The adopted supernova model ejects the outer 2 ${M}_{\odot }$ of the CO core, which includes a significant fraction of the Cr-rich material. When including this 20 M⊙ model at Z = 0.01 in the yields interpolation scheme of our GCE model for stars between 15 and 25 ${M}_{\odot }$, we overestimate [Cr/Fe] by an order of magnitude at [Fe/H] ≈ 0 relative to observations in the Galactic disk. This raises a number of questions regarding the occurrence of Si–C shell mergers in nature, the accuracy of different simulation approaches, and the impact of such mergers on the presupernova structure and explosion dynamics. According to the conditions in this 1D stellar model, the substantial penetration of C-shell material into the Si shell could launch a convective–reactive global oscillation if a merger does take place. In any case, GCE provides stringent constraints on the outcome of this stellar evolution phase.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1984

Thermal evolution of Venus

A modification of the Boussinesq fluid assumption is the basis of the present theory of three-dimensional and finite amplitude convection in a viscous spherical shell with temperature- and pressure-dependent physical parameters. The theory is applied to the definition of thermal evolution models for Venus which emphasize the effects of certain physical parameters on thermal evolution, rather than the specific thermal history of the planet. It is suggested that a significant portion of the present temperature in the mantle and surface heat flux of Venus is due to the decay of a high temperature that was established in the planet at the completion of its core formation, and that Venus has been highly convective over the course of its history, until about 0.5 Ga ago.

Arkani-Hamed, J.↗
NASA NTRS1989

IUE investigations of SN 1987A

IUE observations of the SN 1987A began shortly after the discovery and have been frequent through 1988 and 1989, using the fine error sensor for photometry, low dispersion spectra for the supernova spectrum, and high dispersion observations for the interstellar medium when the supernova was bright and for circumstellar gas surrounding the supernova as the initial event faded. The UV data were very useful in determining which star exploded, assessing the ionizing pulse produced as the shock hit the surface of the star, and in constraining the stellar evolution that preceded the explosion through observations of a circumstellar shell.

Kirshner, Robert P.↗
NASA NTRS1991

Observing SN 1987A with the International Ultraviolet Explorer

The International Ultraviolet Explorer (IUE) satellite played a leading role in elucidating the nature of SN 1987A, providing a unique ultraviolet perspective on the brightest supernova since 1604. IUE observations of SN 1987A began promptly after discovery and were frequent through 1988 and 1989, using the FES (Fine Error Sensor) for photometry, low dispersion spectra for the supernova spectrum, high dispersion observations for the interstellar medium when the supernova was bright, and for circumstellar gas surrounding the supernova as the initial event faded. The UV data were especially useful in determining which star exploded, assessing the ionizing pulse produced as the shock hit the surface of the star, and in constraining the stellar evolution that preceded the explosion through observation of a circumstellar shell.

Kirshner, Robert P.↗
NASA NTRS1979

Helium runaways in white dwarfs

The long term evolution of an accreting carbon white dwarf was studied from the onset of accretion to the ignition of helium. The variations in the details of the helium shell flash examined with respect to variations in mass accretion rate. For intermediate rates the helium flash is potentially explosive whereas for high rates the shell flash is relatively weak. The results are discussed in the context of the long term evolution of novae.

Taam, R. E.↗