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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Photocarrier-induced persistent structural polarization in soft-lattice lead halide perovskites

The success of the lead halide perovskites in diverse optoelectronics has motivated considerable interest in their fundamental photocarrier dynamics. Here, in this work, we report the discovery of photocarrier-induced persistent structural polarization and local ferroelectricity in lead halide perovskites. Photoconductance studies of thin-film single-crystal CsPbBr 3 at 10 K reveal long-lasting persistent photoconductance with an ultralong photocarrier lifetime beyond 10 6 s. X-ray diffraction studies reveal that photocarrier-induced structural polarization is present up to a critical freezing temperature. Photocapacitance studies at cryogenic temperatures further demonstrate a systematic local phase transition from linear dielectric to paraelectric and relaxor ferroelectric under increasing illumination. Our theoretical investigations highlight the critical role of photocarrier–phonon coupling and large polaron formation in driving the local relaxor ferroelectric phase transition. Our findings show that this photocarrier-induced persistent structural polarization enables the formation of ferroelectric nanodomains at low temperature, which suppress carrier recombination and offer the possibility of exploring intriguing carrier–phonon interplay and the rich polaron photophysics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Cyberguardians Webinar

Robust solar industry growth is creating a shortage of U.S. workers who are knowledgeable in emerging Distributed Energy Resource (DER) technologies including networking, operational software, smart advanced inverters, smart advanced PV modules, and cybersecurity. Retraining military veterans and other qualified individuals to fill workforce gaps in those technologies is the project focus. The project leverages the experience and contributions of DER and cybersecurity experts, educational organizations offering accreditation, and groups serving our nation’s veterans to meet its goals. To bridge this workforce skills gap, the Cyberguardians and STEM Warriors project will establish a complete learning and career advancement system for veterans, transitioning military personnel and other qualified individuals into the DER workforce. The project will guide participants successfully through the process of program/vocation selection, curriculum enrollment, academic mentoring, degree or certificate attainment, job board enrollment, introduction to hiring managers at DER companies, and successful job acquisition. This webinar was used to promote the Cyberguardians program and to ensure ample news coverage to reach veterans, employers, and others that would benefit from this program.

14 SOLAR ENERGY↗

The Energy in Modular (EMOD) Buildings Method: A Guide to Energy-Efficient Design for Industrialized Construction of Modular Buildings

Industrialized construction has immense potential to address the growing need globally to build and upgrade the building stock to be affordable, energy-efficient, and resilient. It can also help achieve the United States' goal of a 50% reduction in U.S. greenhouse gas (GHG) emissions by 2030. Despite this potential, and the ever-increasing push for electrification and decarbonization of households in the United States, industrialized construction has not yet been leveraged specifically to help address these challenges and accelerate the pathway to meet these goals. The National Renewable Energy Laboratory (NREL) aims to claim this missed opportunity by focusing on delivering affordable, grid-efficient net-zero energy (NZE) modular buildings for underserved communities to ensure an equitable transition to the future of clean energy, accelerate decarbonization of the built environment, and support the development of a high-productivity construction and energy efficiency workforce. The Energy in Modular (EMOD) method is our approach to designing, producing, and delivering affordable, net-zero energy, low-carbon, and healthier buildings at scale. The following energy efficiency strategies are part of the scope of this guide: envelope thermal control, envelope infiltration control, mechanical, electrical, and plumbing systems, smart controls, and solar plus storage. We draw synergies between design for manufacturing and assembly, process optimization, retrofit technologies, and digitization. Our goal is to influence the improvement and production of buildings to increase performance, enhance energy efficiency, and reduce GHG emissions. This guide documents the research and development efforts initiated by a set of design objectives to "modularize" a set of energy efficiency and low-carbon strategies into a housing unit while preserving and enhancing energy efficiency benefits and decarbonization pathways. This guide is intended to serve as a framework for housing developers, housing agencies, architects, energy experts, and process engineers or factory operator personnel who are critical to today's modular builder teams. This guide focuses on specific energy efficiency strategies, decarbonization pathways, and associated processes as part of NREL's research efforts. Stakeholders may substitute other means, methods, and technologies for the ones evaluated in this study.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Analyzing Data Privacy for Edge Systems

Internet-of-Things (IoT)-based streaming applications are all around us. Currently, we are transitioning from IoT processing being performed on the cloud to the edge. While moving to the edge provides significant networking efficiency benefits, IoT edge computing creates significant data privacy concerns. We propose a methodology that can successfully privacy protect the continual data streams generated by sensors on the edge device. We implement local differential privacy on streaming data and incorporate Bayesian inference and Gaussian process to evaluate the privacy policy. We demonstrate our methodology on a real-world smart meter testbed and identify the optimal privacy protection settings.

Kotevska, Olivera↗

Chemo‐Mechanical Coupling in Hydrogels: Dynamics in the Diffusion‐Limited Regime

Hydrogels are characterized by substantial volume changes in response to external stimuli, making them promising candidates for developing smart materials with enhanced adaptability and responsiveness. By integrating chemical reactions, hydrogels acquire dynamic and tunable responsiveness to external stimuli through chemo‐mechanical coupling, expanding their potential in emerging applications. However, capturing their transient behavior remains challenging due to the complex interplay of chemical reactions, solvent transport, and polymer network deformation. Classical theories capture equilibrium swelling but fail to describe time‐dependent phenomena. To address this, a time‐dependent continuum model is developed that explicitly couples these processes. Volume phase transition in hydrogels with homogeneous chemical reactions is investigated, then the effects of reaction kinetics on these transitions are analyzed. The coupling of these mechanisms is further explored through a study of transient mechanical instabilities. To illustrate the impact of distinct reaction and diffusion timescales, a photo‐active gripper is studied for robotic applications. Finally, a photo‐active microswimmer that exhibits non‐reciprocal motion is proposed to highlight the solvent diffusion for locomotion at the micro‐ and nano‐ scales. The work establishes that transient dynamics of chemo‐mechanical hydrogels generate functions not accessible by steady state models and provides a predictive platform for designing adaptive materials in emerging applications.

chemo-mechanical coupling↗

Enabling Secure Grid Information Sharing through Hash Calendar-based Blockchain Infrastructures

The power grid is becoming increasingly interconnected, as information from grid operations must be accessible to an array of engineers, grid regulators, and market operators. However, there remain challenges ensuring the appropriate integrity and authenticity of the grid information. While traditional cryptographic protocols, like public key infrastructure, provide security for in-transit communication, they come with key exchanges and cost to get public key certificates from a centralized authority. To address these challenges, this paper demonstrates how a hash calendar-based blockchain can be used to provide improved security for communication with the use of distributed ledgers. It demonstrates the security requirements and threats to this communication, and then provides a theoretic definition of the process. Furthermore, it introduces a use-case of the proposed process within the WSU Smart City Testbed DMS with the Guardtime’s Keyless Signature Infrastructure (KSI) architecture.

Kaur, Kudrat J.↗

Hybrid Modeling of Three-Phase Grid-Supporting Inverters for Dynamic Studies

Grid technologies connected by power electronic converter (PEC) interfaces continually implement grid support functions mandated by grid codes and standards. The transition to converter-based generation demands precise PEC models to assess system dynamics, which have been previously overlooked in conventional power systems. This study proposes a hybrid method for analyzing grid-connected three-phase PEC dynamics with the IEEE standard 1547-2018 Volt-VAr mode that combines physics and data-driven techniques. The physics model reflects the PEC’s internal behavior, whereas the data-driven modeling technique evaluates the grid-supporting capabilities of the smart PEC. The system identification approach is used to generate dynamic PEC models based on changing grid voltage and measured current injected into the grid by the PEC. In the Volt-VAr support mode, a detailed topological model including switches is utilized to compare the goodness-of-fit of the extracted hybrid dynamic model. The results demonstrate that the hybrid PEC model in the Volt-VAr mode accurately matches the dynamics with the topological model.

Subedi, Sunil↗

Spatially Resolved Domicile Charging Demands for Light-, Medium-, and Heavy-Duty Electric Vehicles in Virginia

The use of plug-in electric vehicles (PEVs) and resulting grid impacts are likely to grow rapidly, and evaluation of optimal smart charge management and grid integration strategies is warranted now. Evaluating distribution grid impacts requires fine-grained models of PEV operations to estimate charging loads across diverse vehicles at high spatial resolution. We propose such a model and consider a high-electrification scenario in Richmond and Newport News, Virginia. Our framework considers four categories of vehicle that are amenable to early aggressive electrification: light-duty passenger vehicles (LDV), trucks and vans with a focus on delivery or other local operations, school buses, and transit buses. These vehicles have a relatively consistent domicile, reducing the need for public charging infrastructure rollout to electrify. We apply a recent LDV model and propose new models for each vocation of medium- and heavy-duty vehicle, leveraging telematics data. We demonstrate our framework in Virginia and find energy demands in the region may total 15 GWh day, with most consumed by LDV. However, considering power demand at high spatial resolution reveals a different trend: LDVs have relatively small peak loads at specific sites (peak site demand around 800 kW) compared to average and high demand medium- and heavy-duty vehicle charging sites (peak site demand around 6,000 kW at a transit bus depot, 1,500 kW at a local freight hub, and 1,000 kW at a school). Our framework yields insights on the relative impacts of each vocation and enables future work to tailor grid integration strategies to each vehicle category.

33 ADVANCED PROPULSION SYSTEMS↗

Ion Gating in Nanopore Electrode Arrays with Hierarchically Organized pH-Responsive Block Copolymer Membranes

Inspired by biological ion channels, artificial nanopore-based architectures have been developed for smart ion/molecular transport control with potential applications to iontronics and energy conversion. Advances in nanofabrication technology enable simple, versatile construction methods, and post-fabrication functionalization delivers nanochannels with unique ion transport-control attributes. Here, we characterize a pH-responsive, charge-selective dual-gating block copolymer (BCP) membrane composed of polystyrene-b-poly(4-vinylpyridine) (PS 48400 -b-P4VP 21300 ), capable of self-organizing into highly ordered nanocylindrical domains. Because the PS-b-P4VP membrane exhibits pH-dependent structural transitions, it is suitable for designing intelligent pH-gated biomimetic channels, for example, exhibiting on–off transport switching at pH values near the pK a of P4VP with excellent anion permselectivity at pH < pK a . Introducing the BCP membrane onto nanopore electrode arrays (BCP@NEAs) allows the BCP to serve as a pH-responsive gate controlling ion transfer into the NEA nanopores. Such selectively transported and confined ions are detected by using a 100 nm gap dual-ring nanoelectrode structure capable of enhancing current output by efficient redox cycling with an amplification factor >10 2 . In addition, BCP@NEAs exhibit extraordinary pH-gated ion selectivity, resulting in a 3380-fold current difference between anion and cation probes at pH 3.0. Furthermore, this hierarchically organized BCP-gated NEA system can serve as a template for the development of other stimulus-responsive ion gates, for example, those based on temperature and ligand gating, thus exploiting the intrinsic advantages of NEAs, such as enhanced sensitivity based on redox cycling, which may lead to technological applications such as engineered biosensors and iontronic devices.

36 MATERIALS SCIENCE↗

CIAM/NASA Mach 6.5 Scramjet Flight and Ground Test

The Russian Central Institute of Aviation Motors (CIAM) performed a flight test of a CIAM-designed, hydrogen-cooled/fueled dual-mode scramjet engine over a Mach number range of approximately 3.5 to 6.4 on February 12, 1998, at the Sary Shagan test range in Kazakhstan. This rocket-boosted, captive-carry test of the axisymmetric engine reached the highest Mach number of any scramjet engine flight test to date. The flight test and the accompanying ground test program, conducted in a CIAM test facility near Moscow, were performed under a NASA contract administered by the Dryden Flight Research Center with technical assistance from the Langley Research Center. Analysis of the flight and ground data by both CIAM and NASA resulted in the following preliminary conclusions. An unexpected control sensor reading caused non-optimal fueling of the engine, and flowpath modifications added to the engine inlet during manufacture caused markedly reduced inlet performance. Both of these factors appear to have contributed to the dual-mode scramjet engine operating primarily in a subsonic combustion mode. At the maximum Mach number test point, combustion caused transition from supersonic flow at the fuel injector station to primarily subsonic flow in the combustor. Ground test data were obtained at similar conditions to the flight test, allowing for a meaningful comparison between the ground and flight data. The results of this comparison indicate that the differences in engine performance are small.

Voland, R. T.↗

Prolate and oblate chiral liquid crystal spheroids

Liquid crystals are known to exhibit intriguing textures and color patterns, with applications in display and optical technologies. This work focuses on chiral materials and examines the palette of morphologies that arises when microdroplets are deformed into nonspherical shapes in a controllable manner. Specifically, geometrical confinement and mechanical strain are used to manipulate orientational order, phase transitions, and topological defects that arise in chiral liquid crystal droplets. Inspired by processes encountered in nature, where insects and animals often rely on strain and temperature to alter the optical appearance of dispersed liquid crystalline elements, chiral droplets are dispersed in polymer films and deformation induced by uniaxial or biaxial stretching. Our measurements are interpreted by resorting to simulations of the corresponding systems, thereby providing an in-depth understanding of the morphologies that arise in these materials. The reported structures and assemblies offer potential for applications in smart coatings, smart fabrics, and wearable sensors.

42 ENGINEERING↗

Control Surface and Afterbody Experimental Aeroheating for a Proposed Mars Smart Lander Aeroshell

Several configurations, having a Viking aeroshell heritage and providing lift-to-drag required for precision landing, have been considered for a proposed Mars Smart Lander. An experimental aeroheating investigation of two configurations, one having a blended tab and the other a blended shelf control surface, has been conducted at the NASA Langley Research Center in the 20-Inch Mach 6 Air Tunnel to assess heating levels on these control surfaces and their effects on afterbody heating. The proposed Mars Smart Lander concept is to be attached through its aeroshell to the main spacecraft bus, thereby producing cavities in the forebody heat shield upon separation prior to entry into the Martian atmosphere. The effects these cavities will have on the heating levels experienced by the control surface and the afterbody were also examined. The effects of Reynolds number, angle-of-attack, and cavity location on aeroheating levels and distributions were determined and are presented. At the highest angle-of-attack, blended tab heating was increased due to transitional reattachment of the separated shear layer. The placement of cavities downstream of the control surface greatly influenced aeroheating levels and distributions. Forebody heat shield cavities had no effect on afterbody heating and the presence of control surfaces decreased leeward afterbody heating slightly.

Liechty, Derek S.↗

GRO J1655-40: Early Stages of the 2005 Outburst

The black-hole X-ray binary transient GRO J1655-40 underwent an outburst beginning in early 2005. We present the results of our multi-wavelength observational campaign to study the early outburst spectral and temporal evolution, which combines data from X-ray (RXTE, INTEGRAL), radio (VLA) and optical (ROTSE, SMARTS) instruments. During the reported period the source left quiescence and went through four major accreting black hole states: low-hard, hard intermediate, soft intermediate and high-soft. We investigated dipping behavior in the RXTE band and compare our results to the 1996-1997 case, when the source was predominantly in the high-soft state, finding significant differences. We consider the evolution of the low frequency quasi-periodic oscillations and find that the frequency strongly correlates with the spectral characteristics, before shutting off prior to the transition to the high-soft state. We model the broad-band high-energy spectrum in the context of empirical models, as well as more physically motivated thermal and bulk-motion Comptonization and Compton reflection models. RXTE and INTEGRAL data together support a statistically significant high energy cut-off in the energy spectrum at approximately equal to 100 - 200 keV during the low-hard state. The RXTE data alone also show it very significantly during the transition, but cannot see one in the high-soft state spectra. We consider radio, optical and X-ray connections in the context of possible synchrotron and synchrotron self-Compton origins of X-ray emission in low-hard and intermediate states. In this outburst of GRO J1655-40, the radio flux does not rise strongly with the X-ray flux.

Shaposhnikov, N.↗

Validation of a Co-Optimized, Smart Hybrid Heat Pump Control

This study examines a residential dual fuel (DF) heating system that integrates heat pump and gas furnace technology with a home’s forced-air distribution ducts. Specifically, it explores a retrofit where an “add-on” heat pump replaces the air conditioning (A/C) system and is combined with the home’s existing furnace and air handler. The research team developed and validated an innovative control scheme for this integrated DF system that selected the more economical heating source (furnace or heat pump) while maintaining comfort in the home. The project’s field study and subsequent modeling analysis show that this control scheme can decrease energy use, cost, and emissions compared to a furnace-only system. As homes in mixed and cold climates transition to more electric space heating, furnace-to-dual fuel system retrofits offer a solution that can alleviate the retrofit costs, energy cost concerns, and peak load impacts of full electrification.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Aeroheating Environments for a Mars Smart Lander

A proposed Mars Smart Lander is designed to reach the surface via lifting-body atmospheric entry (alpha = 16 deg) to within 10 km of the target site. CFD (computational fluid dynamics) predictions of the forebody aeroheating environments are given for a direct entry from a 2005 launch. The solutions were obtained using an 8-species gas in thermal and chemical nonequilibrium with a radiative-equilibrium wall temperature boundary condition. Select wind tunnel data are presented from tests at NASA Langley Research Center. Turbulence effects are included to account for both smooth body transition and turbulence due to heatshield penetrations. Natural transition is based on a momentum-thickness Reynolds number value of 200. The effects of heatshield penetrations on turbulence are estimated from wind tunnel tests of various cavity sizes and locations. Both natural transition and heatshield penetrations are predicted to cause turbulence prior to the nominal trajectory peak heating time. Laminar and turbulent CFD predictions along the trajectory are used to estimate heat rates and loads. The predicted peak turbulent heat rate of 63 W/sq cm on the heatshield leeward flank is 70% higher than the laminar peak. The maximum integrated heat load for a fully turbulent heat pulse is 38% higher than the laminar load on the heatshield nose. The predicted aeroheating environments with uncertainty factors will be used to design a thermal protection system.

Edquist, Karl T.↗

Conformer-Dependent Chemistry: Experimental Product Branching of the Vinyl Alcohol + OH + O 2 Reaction

The concentration of formic acid in Earth's tropo-sphere is underestimated by detailed chemical models compared to field observations. Phototautomerization of acetaldehyde to its less stable tautomer vinyl alcohol, followed by the OH-initiated oxidation of vinyl alcohol, has been proposed as a missing source of formic acid that improves the agreement between models and field measurements. Theoretical investigations of the OH + vinyl alcohol reaction in excess O 2 conclude that OH addition to the alpha carbon of vinyl alcohol produces formaldehyde + formic acid + OH, whereas OH addition to the β site leads to glycoaldehyde + HO 2 . Furthermore, these studies predict that the conformeric structure of vinyl alcohol controls the reaction pathway, with the anti-conformer of vinyl alcohol promoting α OH addition, whereas the syn-conformer promotes β addition. However, the two theoretical studies reach different conclusions regarding which set of products dominate. We studied this reaction using time-resolved multiplexed photoionization mass spectrometry to quantify the product branching fractions. Our results, supported by a detailed kinetic model, conclude that the glycoaldehyde product channel (arising mostly from syn-vinyl alcohol) dominates over formic acid production with a 3.6:1.0 branching ratio. Additionally, this result supports the conclusion of Lei et al. that conformer-dependent hydrogen bonding at the transition state for OH-addition controls the reaction outcome. As a result, tropospheric oxidation of vinyl alcohol creates less formic acid than recently thought, increasing again the discrepancy between models and field observations of Earth's formic acid budget.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamic Line Rating Models and Their Potential for a Cost‐Effective Transition to Carbon‐Neutral Power Systems

Most transmission system operators (TSOs) currently use seasonally steady-state models considering limiting weather conditions that serve as reference to compute the transmission capacity of overhead power lines. The use of dynamic line rating (DLR) models can avoid the construction of new lines, market splitting, false congestions, and the degradation of lines in a cost-effective way. DLR can also be used in the long run in grid extension and new power capacity planning. In the short run, it should be used to help operate power systems with congested lines. The operation of the power systems is planned to have the market trading into account; thus, it computes transactions hours ahead of real-time operation, using power flow forecasts affected by large errors. In the near future, within a “smart grid” environment, in real-time operation conditions, TSOs should be able to rapidly compute the capacity rating of overhead lines using DLR models and the most reliable weather information, forecasts, and line measurements, avoiding the current steady-state approach that, in many circumstances, assumes ampacities above the thermal limits of the lines. Here, this work presents a review of the line rating methodologies in several European countries and the United States. Furthermore, it presents the results of pilot projects and studies considering the application of DLR in overhead power lines, obtaining significant reductions in the congestion of internal networks and cross-border transmission lines.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Distributed Wind-Hybrid Microgrids with Autonomous Controls and Forecasting

Distributed wind-hybrid microgrids have the potential to provide key resilience and economic benefits to both the customers they serve and the utility grids they are connected to. Such microgrids will likely be a key part of the grid of the future, whether connected to large utility grids or linked together in multi-microgrid systems. Through the hybridization of distributed wind and solar photovoltaics, autonomous device-level and system-level controls, battery energy storage systems with smart inverters, and forecasting, these microgrids could maintain local stability and provide grid services - all with renewable power. In the literature, these elements have been considered individually. However, they have not been combined and demonstrated at a high fidelity, which is essential to prove the concept's operation before moving to hardware-in-the-loop and physical demonstrations. In this work, we develop a high-fidelity MATLAB-Simulink model of a real distributed wind-hybrid microgrid that includes all these elements. We demonstrate the microgrid maintaining stability and production in a variety of islanded, grid-connected, and transition scenarios. This includes riding through faults and grid transitions, handling resource variability, and providing grid services. The results demonstrate, at a high fidelity, how distributed wind-hybrid microgrids can operate in an economic and resilient fashion. Finally, we provide recommendations for future research to move advanced distributed wind-hybrid microgrids toward deployment.

ancillary services↗