Shock tube kinetics by atomic absorption in the vacuum ultraviolet.
Shock tube chemical kinetics of H dissociation by atomic resonance absorption spectrophotometry in far UV
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Shock tube chemical kinetics of H dissociation by atomic resonance absorption spectrophotometry in far UV
The Hopkins Ultraviolet Telescope (HUT), flown aboard the Space Shuttle Columbia in the Astro-1 mission, provided the first spectrophotometry in the sub Kyman alpha region for many astronomical sources. Observations of 77 sources were made throughout the far ultraviolet (912 to 1850 A, delta lambda approximately 3 A), and for a few objects in the extreme ultraviolet (415 to 912 A, delta lambda approximately 1.5 A). Among the objects observed were quasars, galaxy clusters, active and normal galaxies, cataclysmic variables, globular clusters, supernova remnants, planetary nebulae, and white dwarfs.
The Hopkins Ultraviolet Telescope (HUT) is a 90-cm f/2 prime focus telescope and spectrometer with a photon-counting microchannel plate detector designed to obtain moderate resolution (wavelength interval, approximately 4 A) spectrophotometry of faint (visual magnitude, less than approximately 17) objects in the far-ultraviolet spectral region (approximately 900-1700 A). The HUT will be mounted on the Spacelab Instrument Pointing System and will be operated by a Payload Specialist using a field acquisition TV system to assist in locating targets. The initial flight of the HUT, expected in 1984 or 1985, will be devoted primarily to the study of quasars and active galactic nuclei, emphasizing the 900-1200 A spectral region which is inaccessible with other existing or currently planned orbiting instruments.
Intermediate- and narrow-band UV spectrophotometry from Copernicus, OAO 2, the S2-68 experiment on TD 1, and a sounding-rocket experiment are combined with ground-based observations to define the absolute flux distribution of the bright magnetic Ap star Alpha-2 CVn over the wavelength range from 1030 to 7580 A. Two flux distributions are presented which coincide more or less with the rare-earth maximum and minimum in the star's cycle. The results are compared with those for two normal stars, the UV variability of Alpha-2 CVn is characterized as a function of wavelength, and non-LTE effects on the UV continua of C I and Si I are analyzed. Some physical properties of Alpha-2 CVn are estimated, and the evolutionary age of the star is estimated to be between 220 million and 300 million years. It is concluded that Alpha-2 CVn is old enough to have been magnetically braked to its current rotational velocity by either the centrifugal-wind or the accretion mechanism and to have developed its chemical peculiarities by either mechanism.
UV spectrophotometry and and optical spectroscopy of H2252-035, a close binary featuring a spinning, magnetized star, were carried out with instrumentation on the IUE satellite, in addition to ground-based observations from the Lick Observatory. An excess reddening was determined, with E(B-V) equal to 0.10. The spectrum from 1200-22,000 A was decomposed into a blackbody with a temperature of 13,400 K and a power law wavelength component, where the exponent is 2.74, which fits the excess UV and IR excesses. The exponent value is noted to be amenable to a disk model with a slight curvature because of its finite extent. The emission-line intensities were found to vary by a factor of two, with some of the variations accountable by a modulation in-phase with the optical continuum binary modulation.
Ultraviolet/optical/infrared spectrophotometry of the highly-polarized quasars (HPQ's) PKS 0736+017 and PKS 1510-089 is analyzed. A blazar continuum component like that in BL Lac objects (e.g. with violent variability, high polarization, and a steep power-law shape) contributes about half the visual light of 1510-089, and at least three-quarters of that in 0736+017. The remaining light has the same spectrum as normal (low-polarization) quasars, including an ultraviolet excess or blue bump, which is easily detected in the IUE spectra of 1510-089, and weakly detected in 0736+017. The line fluxes do vary, but not as much as the continuum. The ratios of the broad emission lines, and the Balmer continuum are normal in both quasars.
Ultraviolet/optical/infrared spectrophotometry of the highly-polarized quasars (HPQ's) PKS 0736 + 047 and PKS 1510 089 is analyzed. A blazer continuum component like that in BL Lac objects (e.g. with violent variability, high polarization, and a steep power-law shape) contributes about half the visual light of 1510 - 089, and at least three-quarters of that in 0736 + 017. The remaining light has the same spectrum as normal (low-polarization) quasars, including an ultraviolet excess or blue bump, which is easily detected in the IUE spectra of 1510 - 089, and weakly detected in 0736 + 017. The line fluxes do vary, but not as much as the continuum. The ratios of the broad emission lines, and the Balmer continuum are normal in both quasars.
Atomic spectroscopy has dominated the field of trace inorganic analysis because of its high sensitivity and selectivity. The advantages gained by the atomic spectroscopies come with the disadvantage of expensive and often complicated instrumentation. Solid-phase spectroscopy, in which the analyte is preconcentrated on a solid medium followed by conventional spectrophotometry or fluorometry, requires less expensive instrumentation and has considerable sensitivity and selectivity. The sensitivity gains come from preconcentration and the use of chromophore (or fluorophore) developers and the selectivity is achieved by use of ion exchange conditions that favor the analyte in combination with speciative chromophores. Little work has been done to optimize the ion exchange medium (IEM) associated with these techniques. In this report we present a method for making ion exchange polymer films, which considerably simplify the solid-phase spectroscopic techniques. The polymer consists of formaldehyde-crosslinked polyvinyl alcohol with polyacrylic acid entrapped therein. The films are a carboxylate weak cation exchanger in the calcium form. They are mechanically sturdy and optically transparent in the ultraviolet and visible portion of the spectrum, which makes them suitable for spectrophotometry and fluorometry.
We present new 4.5-5.1 micron (2210-1970 cm-1) spectra of embedded protostars, W33 A, AFGL 961 E, AFGL 2136, NGC 7538 IRS 9, and Mon R2 IRS 2, which contain a broad absorption feature located near 4.62 micron (2165 cm-1), commonly referred to in the literature as the "X-C triple bond N" band. The observed peak positions and widths of the interstellar band agree to within 2.5 cm-1 and 5 cm-1, respectively. The strengths of the interstellar 4.62 micrometers band and the ice absorption features in these spectra are not correlated, which suggests a diversity of environmental conditions for the ices we are observing. We explore several possible carriers of the interstellar band and review possible production pathways through far-ultraviolet photolysis (FUV), ion bombardment of interstellar ice analog mixtures, and acid-base reactions. Good fits to the interstellar spectra are obtained with an organic residue produced through ion bombardment of nitrogen-containing ices or with the OCN- ion produced either through acid-base reactions or FUV photolysis of NH3-containing ices.
Ultraviolet observations of nearby galaxies with the ANS are used to derive ultraviolet spectra for different galaxy types. These spectra are used with existing visible spectrophotometry to calculate K-corrections, and to predict colors and magnitudes for various galaxy types as a function of redshifts, to z = 2. No evolutionary effects are considered. It appears that the first-ranked cluster galaxies on blue emulsions should be spirals for z greater than or approximately equal to 0.5.
Complete ultraviolet light curves for HZ Her immediately after a well-defined X-ray turn-on in 1975 are obtained. The features of the curve are found to correspond well with features seen in the optical. The absolute level of emission at maximum light at 1550 A is in good agreement with the calculations of the X-ray reflection effect of Milgrom and Salpeter (1975). It is found that at 1550 A approximately 20% of the light at maximum comes from the accretion disk. Similar observations of Cyg X-1 make it possible to determine the degree of reddening, equivalent to E(B-V) = 0.95 + or - 0.07, from the strength of the 2200 A interstellar absorption feature. The distance inferred from this amount of reddening requires that the optical star be luminous and, therefore, massive. Observations obtained during the May 1975 X-ray transition show ultraviolet excess when compared with the data obtained six months later.
Data from IRAS and IUE were combined with ground based optical and infrared spectrophotometry to derive emission line free spectral energy distributions (SEDs) for 29 active galactic nuclei (AGNs) between 0.1 and 100 microns. The IRAS data were scaled down to account for extended emission. These correction factors, determined by comparing small aperture ground based 10.6 micron data with large aperture IRAS 12 micron fluxes, were usually less than 25%. These corrected SEDs are shown.
The Hopkins Ultraviolet Telescope (HUT) was flown aboard the space shuttle Columbia as part of the Astron-1 mission during December 1990. During the nine-day flight, HUT carried out 3 A resolution spectrophotometry of a wide variety of astronomical objects, including a number of stellar targets, in the 912-1860 A range of the far ultraviolet. A few nearby stars were observed in the 415-912 A range of the extreme ultraviolet as well. For nearly all of these targets, the spectra obtained by HUT are the first ever obtained in the spectroscopically rich region between Lyman-alpha (1216 A) and the Lyman limit (912 A). Here, we present highlights of the results obtained by HUT in a variety of areas of stellar astronomy.
NASA sponsors Earth-based planetary astronomy to provide data needed for: planning future missions; supporting missions already in progress; and enhanching the scientific analysis of data returned by past missions. Such data complement spacecraft data by providing observational coverage of important planetary phenomena at epochs before and after spacecraft encounters, with time scales longer than a spacecraft encounter, and at wavelengths and spectral resolutions not covered by spacecraft instruments. Earth-based planetary data are defined here as: observations made with ground based telescopes, balloon-borne instruments, rocket-borne instruments, and Earth-orbiting spacecraft. Data in the last category differ somewhat in nature and availability from the other three. In all categories, planetary data are only a subset of the total astronomical observations on record. As a result part of the task is to identify and extract (or separately catalog) those observations which are planetary. The data cover wavelengths in the ultraviolet, the visual, and the infrared. The instrumental techniques addressed are: imaging, polarimetry, photometry, spectrophotometry, and spectroscopy.
A library of mean UV stellar energy distributions is derived from IUE spectrophotometry of 218 stars. The spectra cover 1230-3200 A with a spectral resolution of about 6 A. They have been corrected for interstellar extinction and converted to a common flux and wavelength scale. Individual stars were combined into standard groups according to their continuum colors, observed UV spectral morphology, MK luminosity class, and metal abundance. The library consists of 56 groups: 21 dwarf(V), 8 subgiant(IV), 16 giant(III), and supergiant(I + II) groups, covering O3-M4 spectral types. A metal-poor sequence is included, containing four dwarf and two giant groups, as is a metal-enhanced sequence with a single dwarf, subgiant, and giant group. Spectral indices characterizing the continuum and several strong absorption features are examined as temperature, luminosity, and abundance diagnostics. The library is intended to serve as a basis for interpreting the composite UV spectra of a wide variety of stellar systems, e.g., elliptical galaxies, starburst systems, and high-redshift galaxies.
Low-resolution ultraviolet International Ultraviolet Explorer spectra of the DA white dwarf Case 1 are presented. The spectra show the presence of the 1400 A feature, already discovered in several other DA stars, and of a shallower trough in the 1550-1700 A range. A model atmosphere analysis of the ultraviolet energy distribution of the Ly-alpha red wing yields T(e) = 13,000 + or - 500 K. Possible interpretations of the 1400 A feature are reviewed. Case 1 is the coolest white dwarf found in a short-period, detached white dwarf-red dwarf binary, and its cooling time is consistent with estimates of the efficiency of angular momentum removal mechanisms in the phases subsequent to common envelope binary evolution.
High signal-to-noise ratio optical spectrophotometry of a sample of field subluminous B stars drawn largely from the Palomar Green ultraviolet-excess survey is analyzed with a new grid of model atmospheres and synthetic spectra. The stellar effective temperatures, surface gravities, and photospheric helium abundances are determined simultaneously from a detailed analysis of hydrogen and helium absorption line profiles. The derived temperatures and gravities place the subluminous B stars in the theoroetical Hertzsprung-Russell (H-R) diagram along and bounded below by theoretical sequences of the zero-age extended horizontal branch, lending strong support to the hypothesis that these stars are composed of helium-burning cores of approximately 0.5 solar mass overlain by very thin layers of hydrogen (approximately less than 0.02 solar mass). Various scenarios for their past evolutionary history are examined in the context of their probable future evolution into white dwarfs of lower than average mass.
Methods for classifying B stars in the visible region by examining low reslution spectra; broadband colors; intermidiate band colors and H beta; absolute magnitude as a function of H beta and H gamma strength and of luminosity class; and the BCD system and its relation to the MK system are examined. The use of OAO-2 spectrophotometry; objective prism and objective grating spectra; and observations from the TD1 satellite for classifying B stars in the ultraviolet region are also discussed. Infrared and radio observations of these stars are reviewed as well as information available concerning masses, radii and velocity of escape.