Characteristics of a thermionic converter with a chloride-vapor-deposited tungsten emitter and a nickel collector.
Characteristics of thermionic converter with chloride vapor deposited tungsten emitter and nickel collector
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Characteristics of thermionic converter with chloride vapor deposited tungsten emitter and nickel collector
Numerical analysis of relationship between current, voltage, emitter temperature, and collector temperature of cesiated thermionic converter
Current-voltage characteristics of variable spaced thermionic converter with tungsten emitter and niobium collector
Thermionic converter with fluorine vapor deposited tungsten emitter etched to expose crystal planes
Thermionic converter operation with 112 to 114 oriented tungsten emitter and niobium collector with oxygen
Approximate expressions are presented which correlate experimental performance data from a CVD tungsten-niobium, planar thermionic converter. The current voltage characteristics are given as functions of emitter and collector temperatures and cesium pressure for currents below the knee in the ignited mode. The correlation covers the temperature ranges of 1700 to 1950 K for the emitter, 900 to 1050 K for the collector, and 580 to 645 K for the cesium reservoir.
Surprisingly few data are available on the variation of thermionic converter output with collector temperature. In this study the output power density has been measured as a function of collector temperature (at a fixed emitter temperature of 1650 K) for six converters with different electrode combinations. Collector temperatures ranged from 750 to 1100 K. For collector temperatures below 900 K, converters built with sublimed molybdenum oxide collectors gave the best performance.
Variable spacing planar thermionic converter with tungsten emitter, niobium collector and niobium guard ring
Performance prediction for planar and cylindrical electrode geometry fixed spacing thermionic converters
Design documentation for solar thermionic generator containing six energy converters
It is shown that it is possible to controllably and continuously elevate the electron temperature in the plasmatron thermionic energy converter from the emitter temperature to the maintenance electron temperature for the diode arc mode. This ability and the apparent validity of an elementary analytical model of the plasma should make possible the optimization and evaluation of operation under strong ionization conditions for which the plasma resistance should be acceptably low. Measurement of the vacuum space charge arising from the emission from a surface in cesium vapor indicates the presence of a substantial negative ion emission current. Apparatus has been constructed for identifying and directly measuring the flux of positive, negative and neutral species emitted from an electrode surface in a cesium vapor diode. The primary purpose of the investigation is to determine the influence of negative ion emission on the effective work function of thermionic converter electrodes. Initial data indicate the presence of H(-), Cs(-) and possibly C(-) and CH(-).
Performance characteristics of parallel plane, variable spaced thermionic converter with tungsten emitter and molybdenum-niobium collector
A metal/ceramic Marchuk tube was used to measure work functions of oxygen-doped tantalum, to determine applicability of the material to plasma-mode thermionic converters. Oxygen-doped tantalum was shown to increase in work function monotonically with oxygen doping in the range 0.1 to 0.3 atomic percent. Oxygenated test emitters were run at an average temperature of 2165 K and a T/T sub Cs ratio -5.8 to observe the influence of oxygen depletion. Bare work function decreased with outgassing of oxygen. Projections were made based on outgassing kinetics and area/volume ratios to calculate the longevity of oxygen doping in a practical converter. Calculations indicated that the program goal of 10,000 hr could be achieved at 1800 K with an initial oxygen doping of 1 atomic percent and a practical emitter area/volume ratio.
The techniques of fabricating and characterizing the surface properties of electrode materials were investigated. The basic surface properties of these materials were studied with respect to their utilization as thermionic energy converter electrodes. Emphasis was placed on those factors (e.g, cesium disorption kinetic and mechanisms of low work function production) which are of primary concern to thermionic converter performance.
Reexamination of designs of nuclear thermionic space power systems with the converter outside the reactor in the perspective of recent advances in heat-transfer methods, materials, converter performance, and radiation design. The 40- to 70-kW(e) power range is treated. The configuration is found to meet the constraints of readily available launch vehicles. It allows for off-design operation including startup, shutdown, and possible emergency conditions; provides tolerance of failure by extensive use of modular, redundant elements; incorporates and uses heat pipes in a fashion that reduces the need for extensive in-pile testing of system components; and uses thermionic converters, nuclear fuel elements, and heat-transfer devices in a geometrical form adapted from existing incore thermionic system designs.
The effect of collector, guard-ring potential imbalance on the observed collector-current-density J, collector-to-emitter voltage V characteristic was evaluated in a planar, fixed-space, guard-ringed thermionic converter. The J,V characteristic was swept in a period of 15 msec by a variable load. A computerized data acquisition system recorded test parameters. The results indicate minimal distortion of the J,V curve in the power output quadrant for the nominal guard-ring circuit configuration. Considerable distortion, along with a lowering of the ignited-mode striking voltage, was observed for the configuration with the emitter shorted to the guard ring. A limited-range performance map of an etched-rhenium, niobium, planar converter was obtained by using an improved computer program for the data acquisition system.
Density, dc electrical resistivity, thermal conductivity, and linear thermal expansion are measured for arc-melted rod-shaped samples of binary eutectics of Zr, Hf, Ru, Nb, Ir, Mo, Ta, Os, Re, and W selected as very-low-pressure braze fillers for thermionic converters. The first two properties are measured at 296 K for Zr-21.7 at% Ru, Zr-13 wt% W, Zr-19 wt% W, Zr-22.3 at% Nb, Nb-66.9 at% Ru, Hf-25.3 wt% Re, Zr-25.7 at% Ta, Hf-22.5 at% W, and Nb-35 wt% Mo. The last property is measured from 293 K to 2/3 melting point for specified alloys of different compositions. Resistivities of 0.000055 to 0.000181 ohm-cm are observed with the alloys having resistivities about ten times that of the less resistive constituent metal and about three times that of the more resistive constituent metal, except for Zr-19 wt% W and Nb-35 wt% Mo (greater resistivities). Thermal expansion coefficients vary from 0.000006 to 0.0000105/K. All brazes exhibit linear thermal expansion near that of their constituent metals.
A 25.4-cm long externally configured converter was performance tested by electrically heating the emitter to simulate reactor thermal power input. The measured maximum output power was limited by the maximum input power available from the electric RF induction heater. With maximum heater input power, the converter electric output was 178 W (1.95 W/sq cm) at an emitter temperature of 1946 K. This electric output power was smaller than expected. A reactor-core-length (25.4-cm long) cylindrical thermionic converter power and maintaining the emitter-to-collector gap without shorting are of major importance to the feasibility of a 25.4-cm-long reactor fuel element. The emitter of the converter is located externally to the collector to increase the fuel-volume fraction and to allow redundant collector cooling in a reactor configuration.