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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Connections Between the TTL and Sea Surface Temperatures: Interannual Variability and Trends

Comprehensive chemistry climate models and satellite data are used to investigate the forcing of variability in the tropical lower stratosphere and upper troposphere. As this region is the origination region for air parcels which enter the stratosphere, it is important to understand variability in this region on timescales ranging from the seasonal to decadal. The warming trend in the tropical upper troposphere over the past 30 years is strongest near the Indo Pacific warm pool, while the warming trend in the western and central Pacific is much weaker. In the lower stratosphere, these trends are reversed: the historical cooling trend is strongest over the Indo Pacific warm pool and is weakest in the western and central Pacific. These zonal variations are stronger than the zonal mean response in boreal winter. Targeted experiments with a chemistry climate model are used to demonstrate that sea surface temperature trends are driving the zonal asymmetry in upper tropospheric and lower stratospheric tropical temperature trends. The anomalous circulation set up by the changing SSTs has led to zonal structure in the ozone and water vapor trends near the tropopause, and subsequently to less water vapor entering the stratosphere. Projected future sea surface temperatures appear to drive a temperature and water vapor response whose zonal structure is similar to the historical response. In the lower stratosphere, the changes in water vapor and temperature due to projected future sea surface temperatures is of similar strength to, though slightly weaker than, that due directly to projected future CO2, ozone, and methane. Finally, targeted experiments with a chemistry climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv.

Tropical Tropopause Layer↗
DOE OSTI2025

Report on the Atmospheric Temperature Changes and their Drivers (ATC) Activity 2025 Spring Meeting

The Atmospheric Temperature Change and their Drivers (ATC) Activity brings together experts interested in improving understanding of atmospheric temperature variability and trends and their representation in climate data records. ATC pursues this goal by fostering intercomparisons of atmospheric temperature datasets, providing and improving uncertainty information for climate data records, comparing observations with model simulations, assessing atmospheric temperature trends and their drivers, and documenting their efforts in review papers and assessment reports. The ATC activity convened at the Wegener Center for Climate and Global Change at the University of Graz in Graz, Austria over April 23 – 25. The purpose of the meeting was to provide updates on research and datasets related to atmospheric temperature change and variability, to identify areas that need further research, and to coordinate ongoing and future collaborations. Meeting themes included theoretical and simulated controls on atmospheric temperature, the development of new and improved atmospheric temperature datasets, and analysis of atmospheric temperature variability and trends. 18 activity members attended the meeting including 12 in-person attendees and 6 remote attendees. Four new early career activity members attended with support from APARC.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Leveraging Intramolecular π-Stacking to Access an Exceptionally Long-Lived 3 MC Excited State in an Fe(II) Carbene Complex

The ability to manipulate excited-state decay cascades using molecular structure is essential to the application of abundant-metal photosensitizers and chromophores. Ligand design has yielded some spectacular results elongating charge-transfer excited state lifetimes of Fe(II) coordination complexes, but triplet metal-centered ( 3 MC) excited states - recently demonstrated to be critical to the photoactivity of isoelectronic Co(III) polypyridyls - have to date remained elusive, with temporally isolable examples limited to the picosecond regime. Here, with this report, we show how strong-field donors and intramolecular π-stacking can conspire to stabilize a long-lived 3 MC excited state for a remarkable 4.1 ± 0.3 ns in fluid solution at ambient temperature. Analysis of variable-temperature time-resolved absorption data using theoretical models ranging from Arrhenius to semiclassical Marcus theory, combined with computational modeling and X-ray crystallography, reveal a Jahn−Teller stabilized excited state with a high activation barrier for ground-state recovery. The net result is a chromophore with a 3 MC excited-state lifetime that is orders of magnitude longer than anything yet observed for an Fe(II) complex.

carbene compounds↗
DOE OSTI2024

Rigidochromism of tetranuclear Cu( I )–pyrazolate macrocycles: steric crowding with trifluoromethyl groups

Macrocyclic Cu(I)–pyrazolate tetramers (Cu 4 pz 4 ) can fold into compact structures with luminescent Cu 4 cores whose emission wavelengths are sensitive to steric effects along the periphery of the macrocycle. Introducing CF 3 at the C 4 position of 3,5-di- t Bu-pyrazolate increases steric crowding that modifies the conformational behavior of the Cu 4 pz 4 complex, highlighted by a low-temperature martensitic transition. Variable-temperature analysis of solid-state luminescence reveal an unexpected blueshifting of emission with rising temperature.

Rajagopal, Shinaj K.↗
DOE OSTI2021

Distinct roles of land cover in regulating spatial variabilities of temperature responses to radiative effects of aerosols and clouds

Surface temperature responses to radiative perturbations due to aerosols and clouds are complicated by the land surface properties. To disentangle these complexities, this study, from a terrestrial surface energy budget perspective, isolates the underlying biophysical processes from the instantaneous radiative effects of aerosols and clouds on surface temperature using the National Center for Atmospheric Research Community Earth System Model version 1.2.1. It is found that in comparison with the global heterogeneous distributions of instantaneous radiative perturbations at the surface induced by aerosols and clouds, the spatial variations of the corresponding surface temperature responses to aerosol direct radiative effects (DRE) during the daytime and cloud radiative effects (CRE) during the nighttime are amplified. It is because of the consistent global distribution of the local surface climate sensitivity (a function of land cover properties such as surface roughness and Bowen ratio) with those of daytime DRE and nighttime CRE. By applying identical anthropogenic aerosol and precursor emissions over eight major past, present and projected future anthropogenic aerosol emitting regions (i.e. Brazil, China, East Africa, India, Indonesia, South Africa, United States and Western Europe), surface temperature responses to aerosol radiative cooling in the daytime and cloud radiative warming in the nighttime over these regions positively regulated by local surface climate sensitivities are prominent.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1971

Collisionless solar wind. II - Variable electron temperature.

Examination of a two-component ?model' for the solar wind, in which the protons become collisionless beyond a distance from the solar center equal to or greater than 10 solar radii, where they are already highly supersonic. The proton temperatures are found from the double adiabatic equation of state. The electrons are highly subsonic, and their temperature profile is prescribed ad hoc. The momentum equations for the electrons and protons are solved subject to the conditions of quasi-neutrality and zero charge efflux from the sun. Some of the principal results are: (1) the proton thermal anisotropy is substantially reduced when solar rotation is considered; (2) solar rotation leads to significantly lower mean proton temperatures; and (3) the electron temperature profile in the supersonic region is the primary parameter determining flow acceleration there.

Hollweg, J. V.↗
NASA NTRS1974

Turbulent transport of heat and momentum in a boundary layer subject to deceleration, suction and variable wall temperature

The relationship between the turbulent transport of heat and momentum in an adverse pressure gradient boundary layer was studied. An experimental study was conducted of turbulent boundary layers subject to strong adverse pressure gradients with suction. Near-equilibrium flows were attained, evidenced by outer-region similarity in terms of defect temperature and defect velocity profiles. The relationship between Stanton number and enthalpy thickness was shown to be the same as for a flat plate flow both for constant wall temperature boundary conditions and for steps in wall temperature. The superposition principle used with the step-wall-temperature experimental result was shown to accurately predict the Stanton number variation for two cases of arbitrarily varying wall temperature. The Reynolds stress tensor components were measured for strong adverse pressure gradient conditions and different suction rates. Two peaks of turbulence intensity were found: one in the inner and one in the outer regions. The outer peak is shown to be displaced outward by an adverse pressure gradient and suppressed by suction.

Orlando, A. F.↗
NASA NTRS1950

Altitude-chamber Performance of British Roll-royce Nene II Engine IV : Effect of Operational Variables on Temperature Distribution at Combustion-chamber Outlets

Temperature surveys were made at the combustion-chamber outlets of a British Rolls-Royce Nene II engine. The highest mean nozzle-vane and mean gas temperatures were found to occur at a radius approximately 75% of the nozzle-vane length from the inner ring of the nozzle-vane assembly. Variations in engine speed, jet-nozzle area, simulated altitude, and simulated flight speed altered the temperature level but did not materially affect the pattern of radial temperature distribution.

COMBUSTION - TURBINE ENGINES↗
NASA NTRS1997

America's Urban Forests: Keeping Our Cities Cool

The additional heating of the air over the city is the result of the replacement of naturally vegetated surfaces with those composed of asphalt, concrete, rooftops and other man-made materials. The temperatures of these artificial surfaces can be 20 to 40 C higher than vegetated surfaces. Materials such as asphalt store much of the sun's energy and remains hot long after sunset. This produces a dome of elevated air temperatures 5 to 8 C greater over the city, compared to the air temperatures over adjacent rural areas. This effect is called the "urban heat island". Tree canopies can reduce the urban heat island effect by dissipating the solar energy received by transpiring water from leaf surfaces which cools the air by taking "heat" from the air to evaporate the water and by shading surfaces like asphalt, roofs, and concrete parking lots which prevents initial heating and storage of heat. It is difficult to take enough temperature measurements over a large city area to characterize the surface temperature variability and quantify the temperature reduction effects of tree canopies. However, the use of remotely sensed thermal data from airborne scanners are ideal for the task. In a study funded by NASA, a series of flights over Huntsville AL were performed in September 1994 and over Atlanta in May 1997. In this article we will examine the techniques of analyzing remotely sensed data for measuring the effect of tree canopies in reducing the urban heat island effect.

Luvall, Jeffrey C.↗
NASA NTRS2000

Decadal Variability and Temperature Trends in the Middle Atmosphere From Historical Rocketsonde Data

Observational studies were performed using historical rocketsonde data to investigate long-term temperature trends, solar-cycle variations, and interactions between tropical and extratropical latitudes in the middle atmosphere. Evidence from tropical, subtropical, and midlatitude North American rocketsonde stations indicated a consistent downward trend over 25 years, with a solar cycle component superposed. The trend is about -1.4 to -2.0 K per decade and the amplitude of the decadal oscillation is about 1.1 K. Prior to trend derivation it was necessary for us to correct temperatures for aerodynamic heating in the early years. The empirically derived correction profile agrees well with a theoretical profile of Krumins and Lyons. A study was also performed of the correlation between equatorial winds and north polar temperatures in winter, showing that the entire stratospheric wind profile near the equator -- including the quasi-biennial oscillation (QBO) and stratopause semiannual oscillation (SAO) -- is important to the extratropical flow, not merely the QBO component as previously thought. A strong correlation was discovered between winter polar temperatures and equatorial winds in the upper stratosphere during the preceding September, suggesting a role for the second cycle of the SAO.

Dunkerton, Timothy J.↗
NASA NTRS2002

Prelaunch Instrument Calibration in the Real World: The GOES Example

The pre-launch ground infrared calibration of the Geostationary Operational Environmental Satellite (GOES) N-Q Imager and Sounder is presented. Ground calibration provides information necessary to the accurate on-orbit calibration of these radiometers. Infrared channels are calibrated in a thermal vacuum environment, under minimum and maximum mission operation temperatures, using a variable-temperature warm target to simulate the Earth scene and a cold target to simulate the space scene. Brightness temperatures derived from observation of the instrument internal calibration target, used for on-orbit calibration, are compared to brightness temperatures of the external calibration target as a check of relative accuracy using these two sources. Changes to the GOES N-Q specification from GOES I-M are highlighted, as well as results of noise, relative calibration accuracy, and spectral response performance to date. For completeness, results of spatial and pointing performance will be presented. Enhancements to test methodology and data processing techniques are highlighted throughout.

Murphy-Morris, J.↗
NASA NTRS1985

Modeling sea-surface temperature and its variability

A brief review is presented of the temporal scales of sea surface temperature variability. Progress in modeling sea surface temperature, and remaining obstacles to the understanding of the variability is discussed.

Sarachik, E. S.↗
NASA NTRS2001

The Low-Frequency Variability of the Tropical Atlantic Ocean

Upper ocean temperature variability in the tropical Atlantic is examined from the Comprehensive Ocean Atmosphere Data Set (COADS) as well as from an ocean model simulation forced by COADS anomalies appended to a monthly climatology. Our findings are as follows: Only the sea surface temperatures (SST) in the northern tropics are driven by heat fluxes, while the southern tropical variability arises from wind driven ocean circulation changes. The subsurface temperatures in the northern and southern tropics are found to have a strong linkage to buoyancy forcing changes in the northern North Atlantic. Evidence for Kelvin-like boundary wave propagation from the high latitudes is presented from the model simulation. This extratropical influence is associated with wintertime North Atlantic Oscillation (NAO) forcing and manifests itself in the northern and southern tropical temperature anomalies of the same sign at depth of 100-200 meters as result of a Rossby wave propagation away from the eastern boundary in the wake of the boundary wave passage. The most apparent association of the southern tropical sea surface temperature anomalies (STA) arises with the anomalous cross-equatorial winds which can be related to both NAO and the remote influence from the Pacific equatorial region. These teleconnections are seasonal so that the NAO impact on the tropical SST is the largest it mid-winter but in spring and early summer the Pacific remote influence competes with NAO. However, NAO appears to have a more substantial role than the Pacific influence at low frequencies during the last 50 years. The dynamic origin of STA is indirectly confirmed from the SST-heat flux relationship using ocean model experiments which remove either anomalous wind stress forcing or atmospheric forcing anomalies contributing to heat exchange.

Haekkinen, Sirpa↗
DOE OSTI2023

Decoupling of Arctic variability from the North Pacific in a warmer climate

The sea level pressure variability in the North Pacific modulates the climate of the Arctic and surrounding continents, substantially impacting ecosystems and indigenous communities. Our analysis based on data from the CESM2 Large Ensemble and different Model Intercomparison Project datasets reveals that the interannual variability of Arctic surface air temperature (SAT) gradually decouples from the contemporaneous atmospheric conditions over the North Pacific as external forcing increases in intensity in the future. Future projections show that the North Pacific-Arctic relationship during the fall season consistently weakens in magnitude until the end of this century, and in the 22nd and 23rd centuries, the relationship is negligible throughout the year. We show that under increased greenhouse gas emissions, the regional heat fluxes extensively control the Arctic temperature variability, and the strength of the projected North Pacific-Arctic relationship is strongly dependent on the Arctic sea ice extent. Our results suggest that under future warming, a strong coupling of Arctic SAT with the underlying ocean and a weakening of the meridional pressure gradient driven by an enhanced rate of sea ice retreat will weaken the interannual footprint of North Pacific variability on Arctic SAT. Therefore, we propose that the alarming rate of sea-ice decline over recent decades and projected in the near future could accelerate the rate of decoupling. Further, we suggest that mitigation strategies for the Arctic should focus on regional mechanisms operating on interannual and seasonal timescales.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

The effect of substrate temperature on the critical velocity in microparticle impact bonding

A number of nascent coating and micromanufacturing processes involve particles sprayed at a high velocity, which impact a substrate, deform, and adhere. Successful bonding between the particles and the substrate requires impact velocities higher than the so-called critical adhesion velocity. This critical velocity is influenced by the temperature of the substrate, a variable that we isolate in this work by conducting single-particle impacts on a variable-temperature substrate for three systems (Al–Al, Sn–Sn, and Ti–Ti) with particles individually selected within a narrow size distribution. Our results quantitatively connect the increase in substrate temperature to a significant lowering of the critical velocity, which we attribute to the lower dynamic strength of the thermally softened substrate. The data are generally consistent with expectations for bonding being controlled by a hydrodynamic process of jetting upon impact.

36 MATERIALS SCIENCE↗
NASA NTRS1985

Influence of spatial variability of hydraulic characteristics of soils on surface parameters obtained from remote sensing data in infrared and microwaves

The correct interpretation of thermal and hydraulic soil parameters infrared from remotely sensed data (thermal infrared, microwaves) implies a good understanding of the causes of their temporal and spatial variability. Given this necessity, the sensitivity of the surface variables (temperature, moisture) to the spatial variability of hydraulic soil properties is tested with a numerical model of heat and mass transfer between bare soil and atmosphere. The spatial variability of hydraulic soil properties is taken into account in terms of the scaling factor. For a given soil, the knowledge of its frequency distribution allows a stochastic use of the model. The results are treated statistically, and the part of the variability of soil surface parameters due to that of soil hydraulic properties is evaluated quantitatively.

Brunet, Y.↗