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At least 127 records · Page 7

Interplay of superconducting, metallic, and crystalline states of composite fermions at 𝜈 = $\frac{1}{6}$ in wide quantum wells

Evidence for developing fractional quantum Hall effect (FQHE) at filling fraction 𝜈 = 1/6 and 1/8 was recently reported in wide GaAs quantum wells [Wang et al., Phys. Rev. Lett. 134, 046502 (2025)]. In this article, we theoretically investigate the nature of the state at 𝜈 = 1/6 as a function of the quantum well width and the density by considering composite-fermion (CF) crystals, CF Fermi sea, and various kinds of paired CF states. The 𝑓-wave paired state has the lowest energy among the paired CF states. However, for parameters of interest, the energies of the CF crystal, the CF Fermi liquid, and the 𝑓-wave paired CF state are too close to distinguish. We, therefore, predict that 𝑖𝑓 the FQHE at 𝜈 = 1/6 is experimentally confirmed, this state would be an 𝑓-wave paired state of CFs, which can be verified by measurement of its thermal Hall conductance. Exact diagonalization studies on clean systems with up to eight electrons show that the ground states at 𝜈 = 𝑛/(6⁢𝑛 ± 1) are incompressible for all widths and densities we have considered, and are well described by the corresponding Laughlin and Jain states. We propose a phase diagram for large quantum well widths and densities in which at zero disorder, incompressible FQHE states are stabilized at 𝜈 = 𝑛/(6⁢𝑛 ± 1) and 𝜈 = 1/6, but in between these fillings the CF crystal is stabilized. We also present a qualitative discussion on the effects of disorder and propose a schematic phase diagram based on it. With disorder, which creates a spatial variation in the filling factor, two regimes are identified: (i) for small disorder, when the incompressible states percolate at the special fillings, FQHE with quantized Hall plateaus and vanishing longitudinal resistance should occur; and (ii) for larger disorder, when the CF crystal percolates, the longitudinal resistance rises with decreasing temperature but the domains of FQHE liquid produce minima at the special filling factors. Here, experiments are consistent with the latter scenario. We also mention a possible connection of the phase diagram presented here to a puzzling behavior observed for the fractional quantum anomalous Hall effect in pentalayer graphene.

Composite fermions↗

Large Nernst Effect and Thermodynamics Properties in Weyl Antiferromagnet

The noncollinear antiferromagnet Mn3Sn exhibits a large anomalous Hall effect (AHE) driven by a large Berry curvature despite the vanishingly small magnetization. Theoretically, the large Berry curvature in antiferromagnets is predicted to be induced by the time-reversal breaking Weyl state in momentum space. Here, we comprehensively study the thermal conductivity, specific heat, thermoelectric power S(T), and thermomagnetic power S ji (T) in single crystals of Mn 3 Sn. Mn 3 Sn exhibited a large spontaneous anomalous Nernst effect (ANE) at room temperature; in particular, the signal magnitude of Mn 3 Sn exceeded 0.6 µV/K, which is comparable to that of ordinary ferromagnets. The large ANE results from the magnetic Weyl states near the Fermi level E F and likely shares its origin with the AHE. Moreover, the possibility of Nernst-type thermoelectric modules was evaluated by analyzing the basic thermal and electric physical properties.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Propulsion Instruments for Small Hall Thruster Integration

Planning and development are underway for the propulsion instrumentation necessary for the next AFRL electric propulsion flight project, which includes both a small Hall thruster and a micro-PPT. These instruments characterize the environment induced by the thruster and the associated data constitute part of a 'user's manual' for these thrusters. Several instruments probe the back-flow region of the thruster plume, and the data are intended for comparison with detailed numerical models in this region. Specifically, an ion probe is under development to determine the energy and species distributions, and a Langmuir probe will be employed to characterize the electron density and temperature. Other instruments directly measure the effects of thruster operation on spacecraft thermal control surfaces, optical surfaces, and solar arrays. Specifically, radiometric, photometric, and solar-cell-based sensors are under development. Prototype test data for most sensors should be available, together with details of the instrumentation subsystem and spacecraft interface.

ion probes↗

12.5kW Advanced Electric Propulsion System Thruster Development Testing

Since 2012, NASA has been developing the12.5kW Hall Effect Rocket with Magnetic Shielding (HERMeS)thruster to serve the need for deep space propulsion. Aerojet Rocketdyne (AR)is developing the HERMeS Hall Current Thruster (HCT)into a flight capable design through the Advanced Electric Propulsion System (AEPS) program. In execution of this program, Aerojet Rocketdyne has designed, built and begun test of two Engineering Test Unit (ETU)HCTs, designated ETU-1 and ETU-2. This paper presents some of the preliminary results from theETU-1 thruster and draws comparisons to previous HERMeS Technology Demonstration Units (TDUs)and theETU-2 characterization unit. The ETU-1 thruster serves to evaluate the ETU design against dynamic and thermal environments while ETU-2 undergoes operational characterization and wear testing. The thruster has been exposed to acceptance and qualification-level vibration and shock testing and has undergone acceptance and characterization hot-firing to evaluate thruster performance after exposure to dynamic environments. The results have demonstrated that the dynamic environments have not had an adverse effect on performance and demonstrated that stability and operating characteristics remain unaffected. Together, ETU-1 and ETU-2 HCTs have demonstrated operating performance and characteristics in-family with each other and with the NASA HERMeS Technology Demonstration Units.

AEPS↗

Environmental Testing of the HERMeS TDU-2 Hall Thruster

The Hall Effect Rocket with Magnetic Shielding (HERMeS) is a 12.5 kW magnetically shielded Hall thruster presently under development for deep-space missions. A development model HERMeS thruster, TDU-2, with borosilicate channel walls, has successfully undergone proto-qualification testing including random vibration and thermal-vacuum, demonstrating the thruster can survive critical launch and operational environmental requirements. The three-axis random vibrational tests were performed with the thruster body mounted directly to the shaker table using a modified loading schedule to compensate for the vibration isolation dampers under design for the flight thruster. Initial random vibration testing revealed issues with fragmentation of magnetic coil potting material and thruster spool mount fabrication weaknesses that were addressed with an alternate potting material and fabrication revisions that were then successfully retested with an additional round of random vibration tests. Thermal-vacuum testing involved three cycles of full-power 600 V 12.5 kW thruster operation from -121°C to +373°C which included eight hours at peak temperature as well as a hot restart. A thermal model of the test configuration was developed and validated with the experiment results within an average difference of 5°C. Before and after the random vibrational and thermal-vacuum tests, the thruster performance, plasma plume, thrust vector angle, discharge characteristics, and magnetic field profile were measured. The thruster performance, magnetic field, and most other parameters remained invariant throughout the environmental testing campaign. During the thermal testing, an increase in the discharge oscillation amplitude of 11% was observed as well as subtle thrust vector changes of ±0.2° as the thruster warmed from -121°C to +373°C.

Sorenson, Ryan↗

In Situ Characterization of Surface Recombination in p-Si/SiO x Based Photoelectrochemical Cells

Time-resolved infrared (TRIR) and electrochemical impedance spectroscopy (EIS) were utilized to quantify surface states present at silicon oxide (SiO x ) protected crystalline p-Si electrolyte interfaces. The primary goal was to identify p-Si/SiO x photoelectrodes with both low surface recombination rates and efficient multi-electron transfer to an acceptor present in the external electrolyte. Three SiO x layers were investigated: native oxide (nOx), chemical oxide (cOx), and rapid thermal annealed (RTA) thermal oxide (tOx). Comparative study with [Ru(bpy) 3 ](PF 6 ) 2 as the electron acceptor indicated that tOx was most optimal with a small effective recombination rate, multi-electron transfer capability, and photovoltage of 500 ± 50 mV. A secondary goal was to analyze the surface recombination rates with the Shockley–Read–Hall (SRH) kinetic model. Two surface states were identified from this analysis, one closer to the CB edge (V t,1 ) and the other near the midgap (V t,2 ). EIS and SRH analyses revealed that a forming gas (5% H 2 /N 2 ) anneal (FGA) decreased surface recombination for tOx and nOx through a lower density of surface states. In the case of tOx, the infrared data indicated that V t,2 was completely removed. Here, the energetic positions of the band edges were correlated with the surface state density; low densities corresponded to more favorable potentials for inversion layer formation, which is expected to be most optimal for photocatalysis. Collectively this study indicates that the free carrier dynamics provided by TRIR represent a powerful in situ probe of the band edge and the surface state energetics in silicon based photoelectrochemical cells.

Electrochemical Impedance Spectroscopy↗

Fourier Transform Spectrometer observations of solar carbon monoxide. I - The fundamental and first overtone bands in the quiet sun

Measurements of the 2200/cm fundamental and 4300/cm first overtone vibration-rotation band systems of solar carbon monoxide, were obtained with the Fourier Transform Spectrometer of the McMath telescope at Kitt Peak. The overtone measurements were taken at the east, north, and west heliocentric limbs, and at disk center. Observations of the strong fundamental bands were obtained at disk center and near the north limb. The low core brightness temperatures of the strongest fundamental carbon monoxide lines near the limb, reported previously by Noyes (1972) and Hall (1974), are confirmed. The possibility that thermal inhomogeneities might be responsible for the unusual behavior of the fundamental carbon dioxide lines have been examined. The somewhat discordant behavior of the fundamental lines at disk center compared with the north limb seems to favor a limb shadowing effect. The first overtone limb equivalent widths and the best-fit thermal and microvelocity models indicate a solar carbon abundance of 0.004 (on the scale with A sub H = 1) for an oxygen-to-carbon abundance ratio of 2.

Ayres, T. R.↗

Multi-Mission Radioisotope Thermoelectric Generator Experience on Mars

The Mars Science Laboratory (MSL) Curiosity rover has been operating on Mars using the F1 Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) for over one and one-half Mars years (over three Earth years). During this extended period, Curiosity has provided a wealth of information about operating with a MMRTG in the Mars surface environment. This paper discusses MMRTG performance over the life of the mission as affected not only by expected radioisotope degradation, but also by the thermal environment, including seasonal, wind, and time-of-sol effects. Additionally, issues related to MMRTG internal shorts will be discussed including detection, impacts on operations, and clearing the shorts.

RTG↗

Electromagnetic Thermocouple (TC) Anomaly Mechanisms During Atmospheric Entry

Thermocouples (TCs) are a critical diagnostic sensor for high enthalpy environments including Thermal Protection Systems (TPS) for atmospheric entry, hypersonic wind tunnels, and arc jet test facilities. They are used for both evaluating facility environmental conditions (enthalpy, and heat flux) as well as for measuring in-situ material thermal response under test conditions (thermal conductivity, heat capacity, etc.). Consequently, accurate TC measurements are fundamental for both material and facility Verification and Validation (V&V). However, a number of electromagnetic TC anomalies have been observed in both ground tests and flight instrumentations. These anomalies are caused via various coupling mechanisms: surface voltage coupling, Hall effect currents, and RF rectification. All of these mechanisms can, if unaddressed, result in obviously compromised results or worse, non-physical measurements which appear reasonable. This talk will provide an overview of each of these anomaly mechanisms and discuss ongoing efforts to quantify and mitigate them.

Magnus Haw↗

Infrared nano-imaging of Dirac magnetoexcitons in graphene

Magnetic fields can have profound effects on the motion of electrons in quantum materials. Two-dimensional electron systems subject to strong magnetic fields are expected to exhibit quantized Hall conductivity, chiral edge currents and distinctive collective modes referred to as magnetoplasmons and magnetoexcitons. Generating these propagating collective modes in charge-neutral samples and imaging them at their native nanometre length scales have thus far been experimentally elusive. Here we visualize propagating magnetoexciton polaritons at their native length scales and report their magnetic-field-tunable dispersion in near-charge-neutral graphene. Imaging these collective modes and their associated nano-electro-optical responses allows us to identify polariton-modulated optical and photo-thermal electric effects at the sample edges, which are the most pronounced near charge neutrality. Our work is enabled by innovations in cryogenic near-field optical microscopy techniques that allow for the nano-imaging of the near-field responses of two-dimensional materials under magnetic fields up to 7 T. In conclusion, this nano-magneto-optics approach allows us to explore and manipulate magnetopolaritons in specimens with low carrier doping via harnessing high magnetic fields.

36 MATERIALS SCIENCE↗

Manipulation of the van der Waals Magnet Cr 2 Ge 2 Te 6 by Spin–Orbit Torques

In this work, we report measurements of current-induced thermoelectric and spin-orbit torque effects within devices in which multilayers of the semiconducting 2-dimensional van der Waals magnet Cr 2 Ge 2 Te 6 (CGT) are integrated with Pt and Ta metal overlayers. We show that the magnetic orientation of the CGT can be detected accurately either electrically (using an anomalous Hall effect) or optically (using magnetic circular dichroism) with good consistency. The samples exhibit large thermoelectric effects, but nevertheless the spin-orbit torque can be measured quantitatively using the angle-dependent second harmonic Hall technique. For CGT/Pt we measure the spin-orbit torque efficiency to be similar to conventional metallic-ferromagnet/Pt devices with the same Pt resistivity. The interfacial transparency for spin currents is therefore similar in both classes of devices. Our results demonstrate the promise of incorporating semiconducting 2D magnets within spin-orbitronic and magneto-thermal devices.

2D magnets↗

Crystal Growth of CdTe by Gradient Freeze in Universal Multizone Crystallizator (UMC)

In the case of unsealed melt growth of an array of II-VI compounds, namely, CdTe, CdZnTe and ZnSe, there is a tremendous amount of experimental data describing the correlations between melt conditions and crystal quality. The results imply that the crystallinity quality can be improved if the melt was markedly superheated or long-time held before growth. It is speculated that after high superheating the associated complex dissociate and the spontaneous nucleation is retarded. In this study, crystals of CdTe were grown from melts which have undergone different thermal history by the unseeded gradient freeze method using the Universal Multizone Crystallizator (UMC). The effects of melt conditions on the quality of grown crystal were studied by various characterization techniques, including Synchrotron White Beam X-ray Topography (SWSXT), infrared microscopy, chemical analysis by glow discharge mass spectroscopy (GDMS), electrical conductivity and Hall measurements.

Su, Ching-Hua↗

Effects of 5-Ion Beam Irradiation and Hindlimb Unloading on Metabolic Pathways in Plasma and Brain of Behaviorally Tested WAG/Rij Rats

A limitation of simulated space radiation studies is that radiation exposure is not the only environmental challenge astronauts face during missions. Therefore, we characterized behavioral and cognitive performance of male WAG/Rij rats 3 months after sham-irradiation or total body irradiation with a simplified 5-ion mixed beam exposure in the absence or presence of simulated weightlessness using hindlimb unloading (HU) alone. Six months following behavioral and cognitive testing or 9 months following sham-irradiation or total body irradiation, plasma and brain tissues (hippocampus and cortex) were processed to determine whether the behavioral and cognitive effects were associated with long-term alterations in metabolic pathways in plasma and brain. Sham HU, but not irradiated HU, rats were impaired in spatial habituation learning. Rats irradiated with 1.5 Gy showed increased depressive-like behaviors. This was seen in the absence but not presence of HU. Thus, HU has differential effects in sham-irradiated and irradiated animals and specific behavioral measures are associated with plasma levels of distinct metabolites 6 months later. The combined effects of HU and radiation on metabolic pathways in plasma and brain illustrate the complex interaction of environmental stressors and highlights the importance of assessing these interactions.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Uncertainty analysis of steady-state measurements with a hot-filament type calorimetric emissometer

Calorimetric emissometers measure total hemispherical emissivity by measuring the heat transferred from a heated sample to its surroundings under a vacuum. The accuracy of emissometers standardized by the ASTM C835-06 are well understood. This work uses the Guide to the Evaluation of Uncertainty in Measurement (GUM) for the propagation uncertainties for an ASTM compliant emissometer. The GUM method was able to develop a measurement model and expressions to determine the uncertainty for other emissometers of this type. Data on ‘as-received’ Hastelloy X was used to develop a detailed uncertainty analysis of the emissivity measurement. Data on ‘as-received’ SS 347 and sandblasted A387 Gr. 91 and previous data by the group on A508/A533B were used to determine uncertainty over the ranges 0.16 to 0.81. For all samples, relative uncertainties in emissivities varied from 0.77% to 2.5% when using a fluxgate magnetometer sensor (FMS) to measure the DC heating current. Data on Hastelloy X using a Hall-effect sensor for DC current and low alloy steel showed the DC current and voltage across the test section to be dominate sources of uncertainty. When these sources were reduced, the specimen temperature and the surface area of the test sections were main sources of uncertainty in the emissivity, especially at higher temperatures. As thermal expansion of the surface was considered in the calculations, correlation between specimen temperature and surface area was examined. It was found to be a small contribution to emissivity's uncertainty despite the differences in linear CTE and its uncertainty for the materials analyzed in this study. For low temperatures, the chamber temperature can be a significant source of uncertainty if not sufficiently cooled. The GUM was also briefly compared to uncertainty from the 2nd and 3rd expansions of the Taylor series. We found that the results were the same when rounding to two significant figures.

42 ENGINEERING↗

Hardware in the Loop Testing of an Iodine-Fed Hall Thruster

CUBESATS are relatively new spacecraft platforms that are typically deployed from a launch vehicle as a secondary payload,1 providing low-cost access to space for a wide range of end-users. These satellites are comprised of building blocks having dimensions of 10x10x10 cm cu and a mass of 1.33 kg (a 1-U size). While providing low-cost access to space, a major operational limitation is the lack of a propulsion system that can fit within a CubeSat and is capable of executing high delta v maneuvers. This makes it difficult to use CubeSats on missions requiring certain types of maneuvers (i.e. formation flying, spacecraft rendezvous). Recently, work has been performed investigating the use of iodine as a propellant for Hall-effect thrusters (HETs) 2 that could subsequently be used to provide a high specific impulse path to CubeSat propulsion. Iodine stores as a dense solid at very low pressures, making it acceptable as a propellant on a secondary payload. It has exceptionally high ρIsp (density times specific impulse), making it an enabling technology for small satellite near-term applications and providing the potential for systems-level advantages over mid-term high power electric propulsion options. Iodine flow can also be thermally regulated, subliming at relatively low temperature ( less than100 C) to yield I2 vapor at or below 50 torr. At low power, the measured performance of an iodine-fed HET is very similar to that of a state-of-the-art xenon-fed thruster. Just as importantly, the current-voltage discharge characteristics of low power iodine-fed and xenon-fed thrusters are remarkably similar, potentially reducing development and qualifications costs by making it possible to use an already-qualified xenon-HET PPU in an iodine-fed system. Finally, a cold surface can be installed in a vacuum test chamber on which expended iodine propellant can deposit. In addition, the temperature doesn't have to be extremely cold to maintain a low vapor pressure in the vacuum chamber (it is under 10(exp -6) torr at -75 C), making it possible to 'cryopump' the propellant with lower-cost recirculating refrigerant-based systems as opposed to using liquid nitrogen or low temperature gaseous helium cryopanels. In the present paper, we describe testing performed using an iodine-fed 200 W Hall thruster mounted to a thrust stand and operated in conjunction with MSFCs Small Projects Rapid Integration and Test Environment (SPRITE) Portable Hardware In the Loop (PHIL) hardware. This work is performed in support of the iodine satellite (iSAT) project, which aims to fly a 200-W iodine-fed thruster on a 12-U CubeSat. The SPRITE PHIL hardware allows a given vehicle to do a checkout of its avionics algorithm by allowing it to monitor and feed data to simulated sensors and effectors in a digital environment. These data are then used to determine the attitude of the vehicle and a separate computer is used to interpret the data set and visualize it using a 3D graphical interface. The PHIL hardware allows the testing of the vehicles bus by providing 'real' hardware interfaces (in the case of this test a real RS422 bus) and specific components can be modeled to show their interactions with the avionics algorithm (e.g. a thruster model). For the iSAT project the PHIL is used to visualize the operating cycle of the thruster and the subsequent effect this thrusting has on the attitude of the satellite over a given period of time. The test is controlled using software running on an Andrews Space Cortex 160 flight computer. This computer is the current baseline for a full iSAT mission. While the test could be conducted with a lab computer and software, the team chose to exercise the propulsion system with a representative CubeSat-class computer. For purposes of this test, the "flight" software monitored the propulsion and PPU systems, controlled operation of the thruster, and provided thruster state data to the PHIL simulation. Commands to operate the thruster were initiated from an operator's workstation outside the vacuum chamber and passed through the Cortex 160 to exercise portions of the flight avionics. Two custom-designed pieces of electronics hardware have been designed to operate the propellant feed system. One piece of hardware is an auxiliary board that controls a latch valve, proportional flow control valves (PFCVs) and valve heaters as well as measuring pressures, temperatures and PFCV feedback voltage. An onboard FPGA provides a serial link for issuing commands and manages all lower level input-output functions. The other piece of hardware is a power distribution board, which accepts a standard bus voltage input and converts this voltage into all the different current-voltage types required to operate the auxiliary board. These electronics boards are located in the vacuum chamber near the thruster, exposing this hardware to both the vacuum and plasma environments they would encounter during a mission, with these components communicating to the flight computer through an RS-422 interface. The auxiliary board FPGA provides a 28V MOSFET switch circuit with a 20ms pulse to open or close the iodine propellant feed system latch valve. The FPGA provides a pulse width modulation (PWM) signal to a DC/DC boost converter to produce the 12-120V needed for control of the proportional flow control valve. There are eight MOSFET-switched heating circuits in the system. Heaters are 28V and located in the latch valve, PFCV, propellant tank and propellant feed lines. Both the latch valve and PFCV have thermistors built into them for temperature monitoring. There are also seven resistance temperature device (RTD) circuits on the auxiliary board that can be used to measure the propellant tank and feedline temperatures. The signals are conditioned and sent to an analog to digital converter (ADC), which is directly commanded and controlled by the FPGA.

Polzin, Kurt A.↗

Status and Mission Applicability of NASA's In-Space Propulsion Technology Project

The In-Space Propulsion Technology (ISPT) project develops propulsion technologies that will enable or enhance NASA robotic science missions. Since 2001, the ISPT project developed and delivered products to assist technology infusion and quantify mission applicability and benefits through mission analysis and tools. These in-space propulsion technologies are applicable, and potentially enabling for flagship destinations currently under evaluation, as well as having broad applicability to future Discovery and New Frontiers mission solicitations. This paper provides status of the technology development, near-term mission benefits, applicability, and availability of in-space propulsion technologies in the areas of advanced chemical thrusters, electric propulsion, aerocapture, and systems analysis tools. The current chemical propulsion investment is on the high-temperature Advanced Material Bipropellant Rocket (AMBR) engine providing higher performance for lower cost. Investments in electric propulsion technologies focused on completing NASA's Evolutionary Xenon Thruster (NEXT) ion propulsion system, a 0.6-7 kW throttle-able gridded ion system, and the High Voltage Hall Accelerator (HiVHAC) thruster, which is a mid-term product specifically designed for a low-cost electric propulsion option. Aerocapture investments developed a family of thermal protections system materials and structures; guidance, navigation, and control models of blunt-body rigid aeroshells; atmospheric models for Earth, Titan, Mars and Venus; and models for aerothermal effects. In 2009 ISPT started the development of propulsion technologies that would enable future sample return missions. The paper describes the ISPT project's future focus on propulsion for sample return missions. The future technology development areas for ISPT is: Planetary Ascent Vehicles (PAV), with a Mars Ascent Vehicle (MAV) being the initial development focus; multi-mission technologies for Earth Entry Vehicles (MMEEV) needed for sample return missions from many different destinations; propulsion for Earth Return Vehicles (ERV), transfer stages to the destination, and Electric Propulsion for sample return and low cost missions; and Systems/Mission Analysis focused on sample return propulsion. The ISPT project is funded by NASA's Science Mission Directorate (SMD).

Anderson, David J.↗

Experimental Results for Titan Aerobot Thermo-Mechanical Subsystem Development

This paper presents experimental results on a set of 4 thermo-mechanical research tasks aimed at Titan and Venus aerobots: 1. A cryogenic balloon materials development program culminating in the fabrication and testing of a 4.6 m long blimp prototype at 93K. 2. A combined computational and experimental thermal analysis of the effect of radioisotope power system (RPS) waste heat on the behavior of a helium filled blimp hull. 3. Aerial deployment and inflation testing using a blimp 4. A proof of concept experiment with an aerobot-mounted steerable high gain antenna These tasks were supported with JPL internal R&D funds and executed by JPL engineers with substantial industry collaboration for Task #1, the cryogenic balloon materials

blimps↗

Synthesis and Optimization of Thermoelectric Properties of Zn(x)Sb3

High-performance thermoelectric materials are studied to investigate their abilities to optimize electrical and minimize thermal conductivities. A stoichiometric range of p-type zinc antimonide compounds was synthesized to analyze the trends in their thermoelectric properties. Zn(x)Sb3 (x=3.80, 3.85, 3.90, 3.95, 4.00, 4.05, 4.10) was reacted at 750 C and annealed at 300 C for 24 hours at each temperature. Electronic transport properties such as Seebeck and Hall Effect were measured to analyze possible trends in the set of compositions. SEM, EDS, and XRD were used to quantify both ingots and hot-pressed samples to confirm that they were single-phase and of the expected stoichiometries. Recent SEM data indicated that Zn(3.90)Sb3 and Zn(4.00)Sb3 samples were actually Zn3Sb2. In hopes of further improving the figure-of-merit (ZT) of the binary system, V, Cr, Mn, Fe, Co, In, and Sn were used to dope (Zn(0.95)M(0.05))(3.95)Sb3.

Doan-Nguyen, Vicky V.↗