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At least 127 records · Page 7

Low Earth orbit thermal control coatings exposure flight tests: A comparison of U.S. and Russian results

Both the United States (US) and Russia have conducted a variety of space environment effects on materials (SEEM) flight experiments in recent years. A prime US example was the Long Duration Exposure Facility (LDEF), which spent 5 years and 9 months in low Earth orbit (LEO) from April 1984 to January 1990. A key Russian experiment was the Removable Cassette Container experiment, (RCC-1), flown on the Mir Orbital Station from 11 January 1990 to 26 April 1991. This paper evaluates the thermal control coating materials data generated by these two missions by comparing: environmental exposure conditions, functionality and chemistry of thermal control coating materials, and pre- and post-flight analysis of absorptance, emittance, and mass loss due to atomic oxygen erosion. It will be seen that there are noticeable differences in the US and Russian space environment measurements and models, which complicates comparisons of environments. The results of both flight experiments confirm that zinc oxide and zinc oxide orthotitanate white thermal control paints in metasilicate binders (Z93, YB71, TP-co-2, TP-co-11, and TP-co-12), are the most stable upon exposure to the space environment. It is also seen that Russian flight materials experience broadens to the use of silicone and acrylic resin binders while the US relies more heavily on polyurethane.

Tribble, A. C.↗

Investigation of conductive thermal control coatings by a contactless method in vacuo

A technique for determining the conductance per unit area of thermal control coatings for electrostatically clean spacecraft is described. In order to simulate orbital conditions more closely, current-density-voltage (j-V) curves are obtained by a contactless method in which the paint on an aluminum substrate is the anode of a vacuum diode configuration with a tungsten filament cathode. Conductances per unit area which satisfy the International Sun Earth Explorer (ISEE) requirement were observed on black paints containing carbon and in white and green paints filled with zinc oxide which were fired in order to induce defect conductivity. Because of surface effects and the nonhomogeneous nature of paints, large discrepancies were found between measurements with the contactless method and measurements employing metallic contacts, particularly at low current densities. Therefore, measurements with metallic contacts are considered to be of questionable value in deciding the suitability of coatings for electrostatic charge control.

Viehmann, W.↗

Porcelain enamel passive thermal control coatings

This paper discusses the development and evaluation of a highly adherent, low solar absorptance, porcelain enamel thermal control coating applied to 6061 and 1100 aluminum for space vehicle use. The coating consists of a low index of refraction, transparent host frit and a high volume fraction of titania as rutile, crystallized in-situ, as the scattering medium. Solar absorptance is 0.21 at a coating thickness of 0.013 cm. Hemispherical emittance is 0.88. The change in solar absorptance is 0.03, as measured in-situ, after an exposure of 1000 equivalent sun hours in vacuum.

Leggett, H.↗

Space environmental effects on spacecraft thermal control coatings

A large portion of the space based applications in the near future are for low Earth orbit (LEO) including the Space Station Freedom (SSF). The lifetime needs for materials on the SSF is 30 years. Materials must be selected which can withstand the deleterious effects of LEO. Environmental effects in the LEO include atomic oxygen, UV, ionizing radiation, and hypervelocity impact. These effects can adversely affect the surface properties of materials. This is particularly critical in the case of thermal control materials where the efficiency of the thermal control is dependent on the stability of the surface properties. The current baseline thermal coating for the SSF radiators is Ag Teflon. The surface property requirements for the coatings are a solar absorptance of 0.2 and an infrared emittance of 0.8. The effects of atomic oxygen and UV radiation on the baseline coating and several other candidate thermal control materials were studied. The thermal control radiator materials included Ag and Al backed Teflon, H2SO4 anodized Al, sputter deposited SiO2 on Al, and Ag and Al backed polychloro trifluoroethylene. The simulation of several of the LEO environment constituents provided a data base to aid in the selection of the radiator thermal control material to meet the life requirements of the SSF. The effects are illustrated of the environment on thermal control coatings and the importance of this factor in the selection process for long life spacecraft materials.

Bartosik, L. G.↗

Damage of thermal control coating properties by energetic mercury ion bombardment.

The thermophysical properties (absorptance and emittance) of five commonly used spacecraft thermal control coatings have been measured in situ after exposure to 1.5 and 3 KeV mercury ions. Sample temperature was varied from 20 to 150 C. The results showed negligible change in emittance but significant degradation of the solar absorptance at fluences of 10 to the 17th power ions/sq cm. Plots of absorptance as a function of ion fluence are presented, along with pre- and post-exposure ex situ spectral absorptance measurements. The widely used Z93 white paint exhibited quantitative degradation from mercury ions similar to that reported by other experimenters for hydrogen and helium ions.

Kelley, L. R.↗

Development of Silane Hydrolysate Binder for Thermal-Control Coatings

Technical report describes theoretical and experimental development of methyltriethoxysilane (MTES) hydrolysate binder for white, titanium dioxidepigmented thermal-control coatings often needed on satellites. New coating is tougher and more abrasion-resistant than conventional coating, S-13G, which comprises zinc oxide in hydroxyl-therminated dimethylsiloxane binder.

Patterson, W. J.↗

LDEF's contribution to the selection of thermal control coatings for the Space Station

The design of the Space Station presented new challenges in the selection and qualification of thermal control materials that would survive in low Earth orbit for a duration of up to 30 years. Prior to LDEF, flight data were obtained from Orbiting Solar Observatory (OSO) satellites, a number of Orbiter flights, and limited ground tests. The excellent data obtained from the OSO satellites were based on calorimetry and temperature measurements which were transmitted to Earth; these satellites were not recovered. For some of these flight experiments it was difficult to distinguish between changes due to contamination, atomic oxygen (AO), ultraviolet radiation (UV), particle radiation and the synergistic effects between them. The data from Shuttle flights were primarily focused on developing a better understanding of atomic oxygen (AO) effects. Although UV and AO were present, the relatively short duration of the Orbiter flights, about one week, was viewed as too short to show the effects from UV or possible synergistic interactions with AO and contamination. At the beginning of the program in 1989 there was no established design data base for AO resistant thermal control coatings for the Space Station. Then came the Long Duration Exposure Facility (LDEF). It provided the first long life data for materials exposed and recovered from space with a characterized environment. Post flight analysis proved data on the effects of contamination on optical properties in the ram (velocity) and wake directions and the erosion of Teflon and multilayer insulation (MLI) covers. The results from LDEF confirmed and, in some cases, modified the approach used for the Space Station, as well as helped to focus our development activities. These development activities resulted in a number of new technical solutions which are applicable to many spacecraft surfaces and missions. LDEF also showed the detrimental effects that could occur from silicone contamination, an issue that has not been completely resolved. An investigation was initiated in 1993 on the effects of silicone contamination and was continuing at the time this paper was prepared.

Babel, Henry W.↗

Optical properties of thermal control coatings contaminated by MMH/N2O4 5-pound thruster in a vacuum environment with solar simulation.

Cat-a-lac Black and S13G thermal control coatings were exposed to the exhaust of a thrustor in a simulated space environment. Vacuum was maintained at less than 10 microtorr during thrustor firing in the liquid helium cooled facility. The thrustor was fired in a 50-millisecond pulse mode, and the accumulated firing time was 224 seconds. Solar absorptance and thermal emittance of the coatings were measured in-situ at intervals of 300 pulses, using a calorimetric technique. The Cat-a-lac Black coatings showed no change in solar absorptance or thermal emittance. The S13G showed up to 25% increase in solar absorptance but no change in thermal emittance.

Sommers, R. D.↗

Optical properties of thermal control coating contaminated by MMH/N2O4 5-pound thruster in a vacuum environment with solar simulation

Cat-a-lac Black, and S13G thermal control coatings were exposed to the exhaust of a thruster in a simulated space environment. Vacuum was maintained at less than 10 to the minus 5th power torr during thruster firing in the liquid helium cooled facility. The thruster was fired in a 50-millisecond pulse mode and the accumulated firing time was 224 seconds. Solar absorptance (alpha sub s) and thermal emittance (sigma) of the coatings were measured in-situ at intervals of 300 pulses. A calorimetric technique was used to measure alpha sub s and sigma. The tests, technique, and test results are presented. The Cat-a-lac Black coatings showed no change in alpha sub s or sigma. The S13G showed up to 25 percent increase in alpha sub s but no change in sigma.

Sommers, R. D.↗