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Results for “ULTRAVIOLET SPECTROPHOTOMETRY”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

PW Vulpeculae - A nova with nearly solar abundances

Optical spectrophotometry of PW Vulpeculae is combined with ultraviolet data to estimate electron temperatures, densities, and abundances in the ejecta of this slow classical nova. The reddening, the distance, and the evolution of the ultraviolet spectrum are discussed. Abundances are nearly solar, with the exception of nitrogen, which is substantially higher. Although neon has been reported to be enhanced in several novae, it does not seem to be the case for PW Vul. Photoionization model calculations of the ejecta that give a reasonable match of the observed emission spectrum are presented. A strong featureless continuum shows that very hot, presumably shock-heated, gas plays a major role in determining the energetics of this nova. Emission from this hot gas is responsible for the ionization of the nebular gas. A calculation of the masses of both the hot coronal gas and the cooler nebular gas shows that the former may account for most of the mass of the ejecta.

Saizar, Pedro↗
DOE OSTI2024

Plutonium Speciation and Oxidation State Distributions in the Presence of Citrate

We explored the speciation and kinetics of the Pu(VI)-citrate and Pu(III)-citrate systems (pH m = 2.5–11.0, I = 0.1 M NaCl, T = 23 °C, O 2 (g) < 2 ppm) using ultraviolet–visible–near-infrared (UV–vis–NIR) spectrophotometry, solvent extraction, and PHREEQC modeling. Formation constants were determined for PuO 2 (HcitH)(aq) (log K° 1,1 = 1.09 ± 0.05) and PuO 2 (HcitH)(citH) 3– (log K° 1,2 = -0.20 ± 0.07), and evidence for (PuO 2 ) m (citH –k ) n (OH) x 2m(3+k)n–x was identified under alkaline conditions. Pu(VI) species were found to be less stable in the presence of citrate than in the absence of citrate (t ≤ 168 days); the rate of reduction increased with increasing pH. Further, the direct reduction of Pu(VI) to Pu(IV) was required to fit experimental data in the presence of citrate but did not improve the fit for Pu in the absence of citrate. We also observed increased Pu(III) stability in the presence of citrate (t ≤ 293 days), with higher concentrations of Pu(III) favored at lower pH. Finally, we provide evidence of a radiolysis-driven mechanism for the citrate-mediated reduction of plutonium that involves electron transfer from the oxidative breakdown of citrate. Our work highlights the need to investigate the redox effect of organic ligands on plutonium oxidation states under repository-relevant conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Ultraviolet and visible flare observations of EQ Pegasi B

EQ Peg AB (dM43+dM5.5e) was monitored in the visible at the Whipple Observatory and ultraviolet with IUE on September 2, 1981. In the visible spectrophotometry of EQ Peg B the H-beta emission strengthened by a factor of 2 relative to the nearby stellar continuum within a few minutes and decayed over an hour. This flare in EQ Peg B was coincident with the enhancement of ultraviolet emission lines of C IV 1550 A, He II 1640 A, and C II 1335 A in the combined light of EQ Peg AB. The ultraviolet fluxes during the flare can be interpreted as similar to those either in the thermal phases of large two-ribbon solor flares where radiative cooling balances thermal conduction or in gas cooling quickly from X-ray emitting temperatures. The appearance of the ultraviolet continuum at 1700-1900 A and ratio of H-alpha to H-beta fluxes during the flare are consistent with models producing these emissions in the chromosphere.

Baliunas, S. L.↗
NASA NTRS1992

Review of results from the Hopkins Ultraviolet Telescope aboard the Astro-1 mission

The Hopkins Ultraviolet Telescope (HUT), flown aboard the Space Shuttle Columbia in the Astro-1 mission, provided the first spectrophotometry in the sub Kyman alpha region for many astronomical sources. Observations of 77 sources were made throughout the far ultraviolet (912 to 1850 A, delta lambda approximately 3 A), and for a few objects in the extreme ultraviolet (415 to 912 A, delta lambda approximately 1.5 A). Among the objects observed were quasars, galaxy clusters, active and normal galaxies, cataclysmic variables, globular clusters, supernova remnants, planetary nebulae, and white dwarfs.

Davidsen, A. F.↗
NASA NTRS1981

The Johns Hopkins Ultraviolet Telescope for Shuttle astronomy

The Hopkins Ultraviolet Telescope (HUT) is a 90-cm f/2 prime focus telescope and spectrometer with a photon-counting microchannel plate detector designed to obtain moderate resolution (wavelength interval, approximately 4 A) spectrophotometry of faint (visual magnitude, less than approximately 17) objects in the far-ultraviolet spectral region (approximately 900-1700 A). The HUT will be mounted on the Spacelab Instrument Pointing System and will be operated by a Payload Specialist using a field acquisition TV system to assist in locating targets. The initial flight of the HUT, expected in 1984 or 1985, will be devoted primarily to the study of quasars and active galactic nuclei, emphasizing the 900-1200 A spectral region which is inaccessible with other existing or currently planned orbiting instruments.

Davidson, A. F.↗
NASA NTRS1979

The ultraviolet flux distribution of Alpha-2 Canum Venaticorum

Intermediate- and narrow-band UV spectrophotometry from Copernicus, OAO 2, the S2-68 experiment on TD 1, and a sounding-rocket experiment are combined with ground-based observations to define the absolute flux distribution of the bright magnetic Ap star Alpha-2 CVn over the wavelength range from 1030 to 7580 A. Two flux distributions are presented which coincide more or less with the rare-earth maximum and minimum in the star's cycle. The results are compared with those for two normal stars, the UV variability of Alpha-2 CVn is characterized as a function of wavelength, and non-LTE effects on the UV continua of C I and Si I are analyzed. Some physical properties of Alpha-2 CVn are estimated, and the evolutionary age of the star is estimated to be between 220 million and 300 million years. It is concluded that Alpha-2 CVn is old enough to have been magnetically braked to its current rotational velocity by either the centrifugal-wind or the accretion mechanism and to have developed its chemical peculiarities by either mechanism.

Leckrone, D. S.↗
NASA NTRS1983

Time-resolved ultraviolet and optical spectroscopy of the pulsating X-ray source H2252-035

UV spectrophotometry and and optical spectroscopy of H2252-035, a close binary featuring a spinning, magnetized star, were carried out with instrumentation on the IUE satellite, in addition to ground-based observations from the Lick Observatory. An excess reddening was determined, with E(B-V) equal to 0.10. The spectrum from 1200-22,000 A was decomposed into a blackbody with a temperature of 13,400 K and a power law wavelength component, where the exponent is 2.74, which fits the excess UV and IR excesses. The exponent value is noted to be amenable to a disk model with a slight curvature because of its finite extent. The emission-line intensities were found to vary by a factor of two, with some of the variations accountable by a modulation in-phase with the optical continuum binary modulation.

Cordova, F. A.↗
NASA NTRS1985

The ultraviolet excess of quasars 3: The highly polarized quasars PKS 0736+017 and PKS 1510-089

Ultraviolet/optical/infrared spectrophotometry of the highly-polarized quasars (HPQ's) PKS 0736+017 and PKS 1510-089 is analyzed. A blazar continuum component like that in BL Lac objects (e.g. with violent variability, high polarization, and a steep power-law shape) contributes about half the visual light of 1510-089, and at least three-quarters of that in 0736+017. The remaining light has the same spectrum as normal (low-polarization) quasars, including an ultraviolet excess or blue bump, which is easily detected in the IUE spectra of 1510-089, and weakly detected in 0736+017. The line fluxes do vary, but not as much as the continuum. The ratios of the broad emission lines, and the Balmer continuum are normal in both quasars.

Malkan, M. A.↗
NASA NTRS1986

The ultraviolet excess of quasars. III - The highly polarized quasars PKS 0736 + 017 and PKS 1510 - 089

Ultraviolet/optical/infrared spectrophotometry of the highly-polarized quasars (HPQ's) PKS 0736 + 047 and PKS 1510 089 is analyzed. A blazer continuum component like that in BL Lac objects (e.g. with violent variability, high polarization, and a steep power-law shape) contributes about half the visual light of 1510 - 089, and at least three-quarters of that in 0736 + 017. The remaining light has the same spectrum as normal (low-polarization) quasars, including an ultraviolet excess or blue bump, which is easily detected in the IUE spectra of 1510 - 089, and weakly detected in 0736 + 017. The line fluxes do vary, but not as much as the continuum. The ratios of the broad emission lines, and the Balmer continuum are normal in both quasars.

Malkan, M. A.↗
NASA NTRS2000

Preparation of Ion Exchange Films for Solid-Phase Spectrophotometry and Solid-Phase Fluorometry

Atomic spectroscopy has dominated the field of trace inorganic analysis because of its high sensitivity and selectivity. The advantages gained by the atomic spectroscopies come with the disadvantage of expensive and often complicated instrumentation. Solid-phase spectroscopy, in which the analyte is preconcentrated on a solid medium followed by conventional spectrophotometry or fluorometry, requires less expensive instrumentation and has considerable sensitivity and selectivity. The sensitivity gains come from preconcentration and the use of chromophore (or fluorophore) developers and the selectivity is achieved by use of ion exchange conditions that favor the analyte in combination with speciative chromophores. Little work has been done to optimize the ion exchange medium (IEM) associated with these techniques. In this report we present a method for making ion exchange polymer films, which considerably simplify the solid-phase spectroscopic techniques. The polymer consists of formaldehyde-crosslinked polyvinyl alcohol with polyacrylic acid entrapped therein. The films are a carboxylate weak cation exchanger in the calcium form. They are mechanically sturdy and optically transparent in the ultraviolet and visible portion of the spectrum, which makes them suitable for spectrophotometry and fluorometry.

Hill, Carol M.↗
NASA NTRS1999

The interstellar 4.62 micron band

We present new 4.5-5.1 micron (2210-1970 cm-1) spectra of embedded protostars, W33 A, AFGL 961 E, AFGL 2136, NGC 7538 IRS 9, and Mon R2 IRS 2, which contain a broad absorption feature located near 4.62 micron (2165 cm-1), commonly referred to in the literature as the "X-C triple bond N" band. The observed peak positions and widths of the interstellar band agree to within 2.5 cm-1 and 5 cm-1, respectively. The strengths of the interstellar 4.62 micrometers band and the ice absorption features in these spectra are not correlated, which suggests a diversity of environmental conditions for the ices we are observing. We explore several possible carriers of the interstellar band and review possible production pathways through far-ultraviolet photolysis (FUV), ion bombardment of interstellar ice analog mixtures, and acid-base reactions. Good fits to the interstellar spectra are obtained with an organic residue produced through ion bombardment of nitrogen-containing ices or with the OCN- ion produced either through acid-base reactions or FUV photolysis of NH3-containing ices.

NASA Center ARC↗
NASA NTRS1980

Colors and magnitudes predicted for high redshift galaxies

Ultraviolet observations of nearby galaxies with the ANS are used to derive ultraviolet spectra for different galaxy types. These spectra are used with existing visible spectrophotometry to calculate K-corrections, and to predict colors and magnitudes for various galaxy types as a function of redshifts, to z = 2. No evolutionary effects are considered. It appears that the first-ranked cluster galaxies on blue emulsions should be spirals for z greater than or approximately equal to 0.5.

Coleman, G. D.↗
NASA NTRS1982

ANS spectrophotometry - The bright X-ray binaries Hercules X-1 /HZ Herculis/ and Cygnus X-1 /HDE 226868/

Complete ultraviolet light curves for HZ Her immediately after a well-defined X-ray turn-on in 1975 are obtained. The features of the curve are found to correspond well with features seen in the optical. The absolute level of emission at maximum light at 1550 A is in good agreement with the calculations of the X-ray reflection effect of Milgrom and Salpeter (1975). It is found that at 1550 A approximately 20% of the light at maximum comes from the accretion disk. Similar observations of Cyg X-1 make it possible to determine the degree of reddening, equivalent to E(B-V) = 0.95 + or - 0.07, from the strength of the 2200 A interstellar absorption feature. The distance inferred from this amount of reddening requires that the optical star be luminous and, therefore, massive. Observations obtained during the May 1975 X-ray transition show ultraviolet excess when compared with the data obtained six months later.

Wu, C.-C.↗
NASA NTRS1987

Infrared-ultraviolet spectra of active galactic nuclei

Data from IRAS and IUE were combined with ground based optical and infrared spectrophotometry to derive emission line free spectral energy distributions (SEDs) for 29 active galactic nuclei (AGNs) between 0.1 and 100 microns. The IRAS data were scaled down to account for extended emission. These correction factors, determined by comparing small aperture ground based 10.6 micron data with large aperture IRAS 12 micron fluxes, were usually less than 25%. These corrected SEDs are shown.

Malkan, M. A.↗
NASA NTRS1993

Observations of stars with the Hopkins Ultraviolet Telescope

The Hopkins Ultraviolet Telescope (HUT) was flown aboard the space shuttle Columbia as part of the Astron-1 mission during December 1990. During the nine-day flight, HUT carried out 3 A resolution spectrophotometry of a wide variety of astronomical objects, including a number of stellar targets, in the 912-1860 A range of the far ultraviolet. A few nearby stars were observed in the 415-912 A range of the extreme ultraviolet as well. For nearly all of these targets, the spectra obtained by HUT are the first ever obtained in the spectroscopically rich region between Lyman-alpha (1216 A) and the Lyman limit (912 A). Here, we present highlights of the results obtained by HUT in a variety of areas of stellar astronomy.

Kimble, R. A.↗
NASA NTRS1984

Earth-Based Planetary Data

NASA sponsors Earth-based planetary astronomy to provide data needed for: planning future missions; supporting missions already in progress; and enhanching the scientific analysis of data returned by past missions. Such data complement spacecraft data by providing observational coverage of important planetary phenomena at epochs before and after spacecraft encounters, with time scales longer than a spacecraft encounter, and at wavelengths and spectral resolutions not covered by spacecraft instruments. Earth-based planetary data are defined here as: observations made with ground based telescopes, balloon-borne instruments, rocket-borne instruments, and Earth-orbiting spacecraft. Data in the last category differ somewhat in nature and availability from the other three. In all categories, planetary data are only a subset of the total astronomical observations on record. As a result part of the task is to identify and extract (or separately catalog) those observations which are planetary. The data cover wavelengths in the ultraviolet, the visual, and the infrared. The instrumental techniques addressed are: imaging, polarimetry, photometry, spectrophotometry, and spectroscopy.

Source record↗
NASA NTRS1992

Spectral synthesis in the ultraviolet. IV - A library of mean stellar groups

A library of mean UV stellar energy distributions is derived from IUE spectrophotometry of 218 stars. The spectra cover 1230-3200 A with a spectral resolution of about 6 A. They have been corrected for interstellar extinction and converted to a common flux and wavelength scale. Individual stars were combined into standard groups according to their continuum colors, observed UV spectral morphology, MK luminosity class, and metal abundance. The library consists of 56 groups: 21 dwarf(V), 8 subgiant(IV), 16 giant(III), and supergiant(I + II) groups, covering O3-M4 spectral types. A metal-poor sequence is included, containing four dwarf and two giant groups, as is a metal-enhanced sequence with a single dwarf, subgiant, and giant group. Spectral indices characterizing the continuum and several strong absorption features are examined as temperature, luminosity, and abundance diagnostics. The library is intended to serve as a basis for interpreting the composite UV spectra of a wide variety of stellar systems, e.g., elliptical galaxies, starburst systems, and high-redshift galaxies.

Fanelli, Michael N.↗