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At least 127 records · Page 7

UV blocking filters for polymeric films

The concept of incorporating UV screening agents in silicone resins as a means of protecting underlying solar cell covers and adhesives from UV degradation is presented. A silicone hard-coat resin incorporating a UV screening agent was selected as a suitable coating material for PFA Teflon solar cell covers. Consideration is given to fabrication procedures and techniques for introduction of the UV screening agents into silicone resins and application of these UV-inhibited coatings to the Teflons. Some preliminary environmental tests, such as thermal shock and temperature humidity, were conducted.

Rayl, G. J.↗

Quasi-simultaneous observations of BL Lac object Mrk 501 in X-ray, UV, visible, IR, and radio frequencies

Observations in the X-ray, UV, visible, IR and radio regions of the BL Lac object Mrk 501 made over the course of two months are reported. The measurements were made with the A2 experiment on HEAO 1 (X-ray), the SWP and LWR cameras on IUE (UV), the 5-m Hale telescope (visible), the 2.5-m telescope at Mount Wilson (IR), the NRAO 92-m radio telescope at Green Bank (4750 MHz) and the 46-m radio telescope at the Algonquin Observatory (10275 and 10650 MHz). The quasi-simultaneously observed spectral slope is found to be positive and continuous from the X-ray to the UV, but to gradually flatten and possibly turn down from the mid-UV to the visible; the optical-radio emission cannot be accounted for by a single power law. The total spectrum is shown to be compatible with a synchrotron self-Compton emission mechanism, while the spectrum from the visible to the X-ray is consistent with synchrotron radiation or inverse-Compton scattering by a hot thermal electron cloud. The continuity of the spectrum from the UV to the X-ray is noted to imply a total luminosity greater than previous estimates by a factor of 3-4.

Kondo, Y.↗

Temporal Variations of Solar UV Spectral Irradiance Caused by Solar Rotation and Active Region Evolution

Variations in the solar 100 to 400 nm UV spectral irradiance caused by solar rotation and active region evolution, are discussed as a function of UV wavelength, CMD dependence, and in relation to the temporal variations in the total solar irradiance, 10.7 cm radio flux, sunspot number and Ca K plage data. Active region radiation at cm wavelengths includes a component proportional to the magnetic field. Active region evolution involves a more rapid growth, peak and decay of sunspots and their strong magnetic fields than the Ca K plages and their related UV enhancements. Major plages often last a rotation or more longer than the active region's sunspots. Large active regions, including those associated with major dips in the total solar irradiance, tend to produce the strongest peaks in 10.7 cm and sunspot numbers on their first rotation, while the Ca K plages and UV enhancements peak on the next rotation and decay more slowly on subsequent rotations. Differences in CMD dependencies cause temporal differences including the stronger presence of 13 day variations in the UV flux.

Donnelly, R. F.↗

Differences in the temporal variations of solar UV flux, 10.7-cm solar radio flux, sunspot number, and Ca-K plage data caused by solar rotation and active region evolution

Attention is given to two types of temporal variations in the solar UV spectral irradiance caused by solar rotation and active region evolution. It is noted that the first type of dissimilar temporal behavior occurs when concentrations of solar active regions evolve at solar longitudes nearly 180 deg apart. Both the UV observations and modeled UV fluxes based on Ca-K plage data then exhibit pronounced 13-day periodicity, whereas the 10.7-cm solar radio flux and sunspot number exhibit quite dissimilar temporal variations. This type of dissimilarity is related to the modeled UV flux and has a dependence on the solar central meridian distance that is narrower than that for the 10.7-cm radio flux or for sunspot numbers. A second case of marked dissimilarity is seen when major new solar active regions arise and dominate the full-disk fluxes for several rotations. It is found that the strongest peaks in 10.7 cm and sunspot numbers tend to occur on their first rotation, for example, during major dips in the total solar irradiance, whereas the Ca-K plages and UV enhancements peak on the next rotation and then decay more slowly on subsequent rotations.

Donnelly, R. F.↗

Correlated observations of impulsive UV and hard X-ray bursts in solar flares from the solar maximum mission

An investigation is conducted of the temporal and spatial structures of UV and hard X-ray bursts in a disk and a limb flare observed with instruments on the Solar Maximum Mission satellite. Attention is given to the transient UV brightening before the flare, the impulsive enhancement of UV continuum emission, the relationship between emission source region and particle acceleration region, and large scale excitations. The most active part of the active region appears to be the most flare-productive region. These regions exhibit high UV activities with numerous UV transient bursts occurring in many small kernels.

Cheng, C.-C.↗

Temporal characteristics of the solar UV flux and He I line at 1083 nm

It is pointed out that the solar UV flux in the 170- to 210-nm range is important because it photodissociates O2 in the terrestrial atmosphere and thereby initiates the production of ozone and other odd-oxygen chemistry in the stratosphere. The 210- to 290-nm solar UV flux heats the stratosphere. There is consequently a great interest in the temporal variations of the solar UV flux and its relation to ground-based measures of solar activity which may be useful in estimating the UV flux variations. The present investigation is concerned with daily values of 205-nm solar UV flux data measured with the aid of the Nimbus 7 satellite during the period from November 1978 to November 1982, taking into account also measurements of the equivalent width of the He I solar absorption line at 1083 at the National Solar Observatory. Attention is given to an analysis of the data, episodes of activity, and long-term variations.

Donnelly, R. F.↗

Solar UV radiation variations and their stratospheric and climatic effects

Nimbus-7 SBUV measurements of the short-term solar UV variations caused by solar rotation and active-region evolution have determined the amplitude and wavelength dependence for the active-region component of solar UV variations. Intermediate-term variations lasting several months are associated with rounds of major new active regions. The UV flux stays near the peak value during the current solar cycle variation for more than two years and peaks about two years later than the sunspot number. Nimbus-7 measurements have observed the concurrent stratospheric ozone variations caused by solar UV variations. There is now no doubt that solar UV variations are an important cause of short- and long-term stratospheric variations, but the strength of the coupling to the troposphere and to climate has not yet been proven.

Donnelly, R. F.↗

Interpretation of Voyager UVS observations of occultations by the atmosphere of Neptune

We propose to continue our investigation of the upper atmosphere of Neptune based primarily on the solar occultation measurements made by the Voyager Ultraviolet Spectrometer (UVS). The ultimate goal of this research is to understand the structure and composition of Neptune's upper atmosphere as encoded in the data base obtained by the UVS during the Voyager 2 encounter with Neptune. The UVS occultations provide information essential to studies of atmospheric composition and structure, energy balance, photochemistry, global transport, ionospheric structure, and airglow production mechanisms. In conjunction with other research in progress at the University of Arizona and by our colleagues at other institutions, we not only analyze and interpret individual measurements or observations by the UVS, but also construct models of the upper atmosphere which are consistent with all available data obtained by the UVS. We derive constraints from measurements of the atmospheric emissions and we combine these with constraints derived from the occultation measurements. Principal sources for the atmospheric emissions include dayglow, resonance scattering and, at long wavelengths, the reflected solar spectrum. On the dark side of the planet, a weak H Ly alpha emission is due to resonance scattering of the sky background and perhaps another source. Thus a wide range of physical processes are at work, and each provides its own constraints on the atmosphere.

Sandel, Bill R.↗

The response of middle atmospheric ozone to solar UV irradiance variations with a period of 27 days

A one-dimensional photochemical-dynamical-radiative time-dependent model was used to study the response of middle atmospheric temperature and ozone to solar UV irradiance variations with the period of 27 days. The model solar UV O(x), HO(x), NO(x), and CIO(x)families and modeled solar UV variations. The amplitude of the primary temperature response to the solar UV variation is plus 0.4 K at 85-90 km with a phase lag of about 6 days. A secondary maximum response of plus 0.3 K at 45-50 km appears with a phase lag of 1 day. There is a maximum positive ozone response to the 27-day solar UV oscillation of 2.5 percent at 80-90 km with a phase lag of about 10 days after the solar irradiance maximum. At 70 km the ozone response is about 1.2 percent and is out of phase with the solar variation. In the upper stratosphere (40-50 km) the relative ozone variation is small, about 0.2 percent to 0.3 percent, and there is a negative phase of about 4 days between the ozone and solar oscillations. These oscillations are in phase in the middle stratosphere (35-40 km) where there is again a maximum relative response of about 0.6 percent. The reasons for these ozone amplitude and phase variations are discussed.

Chen, LI↗

UV-observations with a Brewer spectrophotometer at Hohenpeissenberg

Regular spectral UV-B measurements with a Brewer spectrophotometer have been performed at Hohenpeissenberg since 1990. Intercomparison of the Brewer instrument with other UV-B monitoring devices have shown agreement to within plus or minus 10 percent. Comparisons of UV-B spectra measured on fair weather days reveal the well known increasing influence of ozone on UV-B irradiance with decreasing wavelengths. The integral amplification factor the erythemal irradiance reaches values up to 2.8, which can be diminished by increasing turbidity. The influence of cirrus cloud on the UV-B is also shown.

Vandersee, Winfried↗

Comparison of UV-B measurements performed with a Brewer spectrophotometer and a new UVB-1 broad band detector

Measurements of the UV-B erythemal dose, based on solar spectra acquired with a Brewer spectrophotometer at Thessaloniki, Greece, are compared to measurements performed with the recently introduced, by the Yankee Environmental Systems, (Robertson type) broad band solar UV-B detector. The spectral response function of this detector, when applied to the Brewer spectral UV-B measurements, results in remarkably comparable estimates of the erythemal UV-B dose. The two instruments provide similar information on the UV-B dose when they are cross-examined under a variety of meteorological and atmospheric conditions and over the a large range of solar zenith angles and total ozone.

Bais, Alkiviadis F.↗

The effect of simulated low earth orbit radiation on polyimides (UV degradation study)

UV degradation of polyimide films in air and vacuum were studied using UV-visible, ESR, FTIR, and XPS spectroscopies. The UV-visible spectra of polyimide films showed a blue shift in the absorption compared to Kapton. This behavior was attributed to the presence of bulky groups and kinks along the polymer chains which disrupt the formation of a charge transfer complex. The UV-visible spectra showed also that UV irradiation of polyimides result extensively in surface degradation, leaving the bulk of the polymer intact. ESR spectra of polyimides irradiated in vacuum revealed the formation of stable carbon-centered radicals which give a singlet ESR spectrum, while polyimides irradiated in air produced an asymmetric signal shifted to a lower magnetic field, with a higher g value and line width. This signal was attributed to oxygen-cenetered radicals of peroxy and/or alkoxy type. The rate of radical formation in air was two fold higher than for vacuum irradiation, and reached a plateau after a short time. This suggests a continuous depletion of radicals on the surface via an ablative degradation process. FTIR, XPS, and weight loss studies supported this postulate. An XPS study of the surface indicated a substantial increase in the surface oxidation after irradiation in air. The sharp increase in the C-O binding energy peak relative to the C-C peak was believed to be associated with an aromatic ring opening reaction.

Forsythe, John S.↗

Determination of hydrocarbon abundances and the strength of eddy mixing in the stratosphere of Neptune: Analysis of UVS solar occultation lightcurves

Work on completing our analysis of the Voyager UVS solar occultation data acquired during Neptune encounter is essentially complete, as testified by the attached poster materials. The photochemical modeling addresses the recent revision in branching ratios for radical production in the photolysis of methane at H Lyman alpha implied by the lab measurements of Mordaunt et al. (1993). The software generated in this effort has been useful for checking the degree to which photochemical models addressing other datasets (mainly infrared) are consistent with the UVS data. This work complements the UVS modeling results in that the IR data refer to deeper pressure levels; as regards the modeling of UVS data, the most significant result is the convincing support for the presence of a stagnant lower stratosphere. Evidence for strong dynamical (mixing) transport of minor constituents at shallower pressures is provided by the UVS data analysis.

Bishop, James↗

UV-A/Blue-Light responses in algae

All life on earth depends on light. A variety of photoreceptors capture the light for a wide range of reactions. Photosynthetic organisms absorb the light necessary for energy transformation and charge separation facilitating photosynthesis. In addition to the bulk pigments there is a great diversity of photoreceptors present in minute concentrations that control development, metabolism and orientation of plants and microorganisms. Based on its spectral absorbance, the well-studied phytochrome system acts in the RL (red light) region as well as in the UV-A/BL (blue light) region where the above mentioned reactions are mediated by a variety of photoreceptors whose natures are largely unknown. Phyllogenetically the UV-A/BL photoreceptors seem to be more ancient pigments that eventually were replaced by the phytochrome system. However, there are many reports that suggest a coaction between the UV-A/BL receptors and the phytochrome system. In several cases the UV-A/BL activation is the prerequisite for the phytochrome reaction. Historically it was the German botanist Julius Sachs who first discovered in 1864 that phototropism in plants was due to BL reactions. It took over 70 years until Bunning (1937) and Galston and Baker (1949) rediscovered the BL response. Since then, an ever-increasing attention has been paid to this effect. In this contribution, the general aspect of UV-A/BL responses and especially the responsiveness of algae will be covered.

Senger, Horst↗

Its a Wind, Its a Wave, Its Two Phenomena in One: Jerry Schubert, Superrotation, and the UV Markings on Venus

In the early 1970's, ground-based astronomers had already discovered that Ultraviolet (UV) cloud markings on Venus reappeared every 4 days. When radar evidence later revealed a 243-day rotation period for the solid planet, planetary scientists were faced with a quandary: Could the Venus atmosphere really move 60 times as fast as the planet below, or were the apparent movements of the UV features just an illusion caused by propagating waves? The former explanation seemed unlikely - a planet that hardly rotates should generate only a very sluggish circulation. The historical impact of Jerry Schubert's moving flame theory was twofold: It was the forerunner of current thermal tide explanations of the cloud-level superrotation, but it was also the first plausible mechanism for explaining a seemingly inconsistent set of observations. In 1974, Mariner 10 acquired UV images of the Venus clouds at unprecedented levels of detail. Although few have noted it, this began the shift of planetary atmospheric research primarily from the domain of astronomy to that of meteorology. Jerry was among the first scientists to apply terrestrial meteorology to the analysis of planetary data. At that time a young UCLA graduate student with plans to do research on mantle convection, but having flunked the solid earth geophysics section of his departmental comprehensive exam, was gently invited by Jerry to switch to atmospheric science. Jerry suggested that the Venus UV features could be revealing both superrotating winds and planetary-scale waves at the same time, and that we could distinguish the two by looking at motions on different spatial scales. This was my first science research lesson - the complexity of real geophysical systems. Over the next couple of years I was inculcated with Jerry's philosophy of a comprehensive, rigorous approach to research, which manifested itself as a scouring of the literature and the UCLA meteorology faculty to learn about every possible type of planetary-scale wave. The resulting identification of large-scale UV features on Venus as the product of Kelvin and Rossby-type wave motions was validated by extensive Pioneer Venus observations a decade later and remains one of the best examples of the use of terrestrial knowledge to understand other planets.

DelGenio, Anthony↗

Production of High Intracavity UV Power From a CW Laser Source

The goal of this research project is to create a prototype high power CW source of ultraviolet (UV) photons for photon-electron scattering at the Thomas Jefferson National Accelerator Facility (TJNAF), Hall B. The facility will use optical resonant cavities to produce a high photon flux. The technical approach will be to frequency-double the 514.5 mn light from an Argon-Ion Laser to create 0.1 to 1.0 watt in the UV. The produced UV power will be stored in a resonant cavity to generate an high intracavity UV power of 102 to 103 watts. The specific aim of this project is to first design and construct the low-Q doubling cavity and lock it to the Argon-Ion wavelength. Secondly, the existing 514.5 nm high-Q build-up cavity and its locking electronics will be modified to create high intracavity UV power. The entire system will then be characterized and evaluated for possible beam line use.

David, R. T.↗

UV-Visible Spectroscopic Method and Models for Assessment and Monitoring of Harmful Algal Blooms

The development of an enhanced predictive and early warning capability for the occurrence and impact of harmful algal blooms (HABs) would be of great benefit to coastal communities. A critical issue for early detection and monitoring of HABs is the need to detect harmful algal species within a mixed-species phytoplankton assemblage. Possession of UV-absorbing compounds called mycosporine-like amino acids (MAAs) may be one factor that allows HAB species to out-compete their phytoplankton neighbors. Possession of MAAs, which we believe can be inferred from strong UV-absorption signals in phytoplankton absorption coefficients, can be used as a flag for potential HAB outbreak. The goal of this project was to develop a solar simulating UV-visible incubator to grow HAB dinoflagellates, to begin MAA analysis of samples collected on global cruises, and to carry out initial experiments on HAB dinoflagellate species in pure culture. Our scientific objectives are to quantify MAA production and spectral induction mechanisms in HAB species, to characterize spectral absorption of MAAs, and to define the ecological benefit of MAAs (i.e. photoprotection). Data collected on cruises to the global oceans will be used to parameterize phytoplankton absorption in the UV region, and this parameterization could be incorporated into existing models of seawater optical properties in the UV spectral region. Data collected in this project were used for graduate fellowship applications by Elizabeth Frame. She has been awarded an EPA STAR fellowship to continue the work initiated by this project.

Mitchell, B. Greg↗

Limits on the UV Photodecomposition of Carbonates on Mars

The effect of UV (ultraviolet) light on the stability of calcium carbonate in a simulated martian atmosphere was experimentally investigated. Sample cells containing C-13 labeled calcite were irradiated with a Xe arc lamp in 10 mbar of simulated martian atmosphere and a quadrupole mass spectrometer was used to monitor the headspace gases for the production of (13)CO2. We found no experimental evidence of the UV photodecomposition of calcium carbonate in a simulated martian atmosphere. Extrapolating the lower limit of detection of our experimental system to an upper limit of carbonate decomposition on Mars yields a quantum efficiency of 3.5 x 10(exp -8) molecules/photon over the wavelength interval of 190-390 nm and a maximum UV photodecomposition rate of 1.2 x 10(exp -13) kg m(exp -2) s(exp -1) from a calcite surface. The maximum loss of bulk calcite due to this process would be 2.5 nm yr(exp -1). However, calcite is expected to be thermodynamically stable on the surface of Mars and potential UV photodecomposition reaction mechanisms indicate that while calcium carbonate may decompose under vacuum, it would be stable in a CO2 atmosphere. Given the expected stability of carbonate on Mars and our inability to detect carbonate decomposition, we conclude that it is unlikely that the apparent absence of carbonate on the martian surface is due to UV photo decomposition of calcite in the current environment.

Quinn, Richard↗