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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Tunable UV ∼ IR frequency comb generation via high-order sideband generation

Abstract We propose the generation of a widely tunable UV-to-IR frequency comb by high-order sideband generation (HSB) spectrum emitted from semiconductors. In our theoretical simulations, we demonstrate the high-order sideband signals of two series (2m Ω seed + (2n + 1) ω driver , and (2m + 1) Ω seed + 2 n ω driver ), wheremandnare integers of a seed pulse and a driver laser frequency, respectively. The simulations also reveal the intensity of HSB scale with the driver laser power, both perturbatively and non-perturbatively. We find that the harmonic position and spacing of the high-order sideband emission can be controlled by varying the seed pulse and driver photon energies. In the experiment, we applied a visible ( ℏ Ω seed = 3.1 eV, ∼400 nm) seed pulse and mid-infrared (MIR, ℏ ω driver = 0.4 eV, 3.1 μm) driver pulses to ZnSe target. Our experimental observations confirmed the UV (4.7 eV, 263 nm and 3.9 eV, 317 nm) HSB generation.

Physics↗
DOE OSTI2023

Beyond n-dopants for organic semiconductors: use of bibenzo[ d ]imidazoles in UV-promoted dehalogenation reactions of organic halides

2,2’-Bis(4-dimethylaminophenyl)- and 2,2'-dicyclohexyl-1,1',3,3'-tetramethyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[ d ]imidazole ((N-DMBI) 2 and (Cyc-DMBI) 2 ) are quite strong reductants with effective potentials of ca. −2 V vs ferrocenium/ferrocene, yet are relatively stable to air due to the coupling of redox and bond-breaking processes. Here, we examine their use in accomplishing electron transfer-induced bond-cleavage reactions, specifically dehalogenations. The dimers reduce halides that have reduction potentials less cathodic than ca. −2 V vs ferrocenium/ferrocene, especially under UV photoexcitation (using a 365 nm LED). In the case of benzyl halides, the products are bibenzyl derivatives, whereas aryl halides are reduced to the corresponding arenes. The potentials of the halides that can be reduced in this way, quantum-chemical calculations, and steady-state and transient absorption spectroscopy suggest that UV irradiation accelerates the reactions via cleavage of the dimers to the corresponding radical monomers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Into the UV: A Precise Transmission Spectrum of HAT-P-41b Using Hubble’s WFC3/UVIS G280 Grism

The ultraviolet–visible wavelength range holds critical spectral diagnostics for the chemistry and physics at work in planetary atmospheres. To date, time-series studies of exoplanets to characterize their atmospheres have relied on several combinations of modes on the Hubble Space Telescope’s STIS/COS instruments to access this wavelength regime. Here for the first time, we apply the Hubble WFC3/UVIS G280 grism mode to obtain exoplanet spectroscopy from 200 to 800 nm in a single observation. We test the G280 grism mode on the hot Jupiter HAT-P-41b over two consecutive transits to determine its viability for the characterization of exoplanet atmospheres. We obtain a broadband transit depth precision of 29–33 ppm and a precision of on average 200 ppm in 10 nm spectroscopic bins. Spectral information from the G280 grism can be extracted from both the positive and negative first-order spectra, resulting in a 60% increase in the measurable flux. Additionally, the first Hubble Space Telescope orbit can be fully utilized in the time-series analysis. We present detailed extraction and reduction methods for use by future investigations with this mode, testing multiple techniques. We find the results to be fully consistent with STIS measurements of HAT-P-41b from 310 to 800 nm, with the G280 results representing a more observationally efficient and precise spectrum. HAT-P-41b’s transmission spectrum is best fit with a model with T {sub eq} = 2091 K, high metallicity, and significant scattering and cloud opacity. With these first-of-their-kind observations, we demonstrate that WFC3/UVIS G280 is a powerful new tool to obtain UV–optical spectra of exoplanet atmospheres, adding to the UV legacy of Hubble and complementing future observations with the James Webb Space Telescope.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Astrometric Membership Tests for the Zinn–Newell–Gibson UV-bright Stars in Galactic Globular Clusters

In 1972, Zinn, Newell, & Gibson (ZNG) published a list of 156 candidate UV-bright stars they had found in 27 Galactic globular clusters (GCs), based on photographs in the U and V bands. UV-bright stars lie above the horizontal branch (HB) and blueward of the asymptotic giant branch (AGB) and red giant branch in the clusters’ color–magnitude diagrams. They are in rapid evolutionary phases—if they are members and not unrelated bright foreground stars. The ZNG list has inspired numerous follow-up studies, aimed at understanding late stages of stellar evolution. However, the ZNG candidates were presented only in finding charts, and celestial coordinates were not given. Using my own collection of CCD frames in u and V, I have identified all of the ZNG objects, and have assembled their coordinates, parallaxes, and proper motions from the recent Gaia Early Data Release 3 (EDR3). Based on the Gaia astrometry, I have determined which objects are probable cluster members (45% of the sample). For the members, using photometry from EDR3, I have assigned the stars to various evolutionary stages, including luminous post-AGB stars, and stars above the HB. I point out several ZNG stars of special interest that have still, to my knowledge, never been studied in detail. This study is an adjunct to a forthcoming survey of the Galactic GCs in the uBVI photometric system, designed for detection of low-gravity stars with large Balmer discontinuities.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

BVR{sub c}I{sub c} Observations, Third-body Orbital Study, and Analysis of the UV Leo-type, Pre-W UMA Binary V642 Virginis

V642 Vir is a polar spotted, well-detached, UV Leo-type, low-mass, pre-WUMa (T1 ~ 4250K, ~K6V) eclipsing binary. It was observed in 2020 April, May, and June at the Dark Sky Observatory in North Carolina, USA with the 0.81 m reflector of Appalachian State University. A total of 88 timings were used in our 22-year period study which included 12 Transiting Exoplanet Survey Satellite (TESS) timings. The O - C plots show a low-amplitude oscillation of residuals that points to the existence of an orbiting third body, a dwarf of minimum mass, 0.15 M {sub ⊙} in an eccentric orbit (e = 0.41), with an orbital period of 20.07 yr. The odd light curves of V642 Virginis indicate that it has polar spots similar to UV Leo and the recently published V1023 Per. Its present large polar spot region indicates that it must have a strong magnetic field and that it is synchronously rotating. The BVR{sub c}I{sub c} simultaneous Wilson–Devinney Program solution gives a detached binary (primary and secondary components are underfilling their respective Roche Lobes, with 76% and 78% fill outs respectively). The cool spot region models near the pole of the primary component (centered at 10° colatitude) and is angled toward the secondary component. Its large radius (68°) and T-fact (T{sub spot}/T{sub surface} = 0.69) also attest to the conclusion of the strength of the magnetic field. The small ΔT in the components (~318 K) and mass ratio near unity (0.9542 ± 0.0005) show that the stars are similar in spectral type (secondary ~K9V). The inclination is high, ~86.87 ± 0.04°, yet there is no time of constant light due to the two stars’ essentially equal radii.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

New Determinations of the UV Luminosity Functions from z ~ 9 to 2 Show a Remarkable Consistency with Halo Growth and a Constant Star Formation Efficiency

Here we provide the most comprehensive determinations of the rest-frame UV luminosity function (LF) available to date with the Hubble Space Telescope (HST) at z ~ 2–9. Essentially all of the noncluster extragalactic legacy fields are utilized, including the Hubble Ultra Deep Field, the Hubble Frontier Fields parallel fields, and all five CANDELS fields, for a total survey area of 1136 arcmin{sup 2}. Our determinations include galaxies at z ~ 2–3 leveraging the deep HDUV, UVUDF, and ERS WFC3/UVIS observations available over an ~150 arcmin{sup 2} area in the GOODS-North and GOODS-South regions. All together, our collective samples include >24,000 sources, >2.3× larger than previous selections with HST. We identify 5766, 6332, 7240, 3449, 1066, 601, 246, and 33 sources at z ~ 2, 3, 4, 5, 6, 7, 8, and 9, respectively. Combining our results with an earlier z ~ 10 LF determination by Oesch et al., we quantify the evolution of the UV LF. Our results indicate that there is (1) a smooth flattening of the faint-end slope α from α ~ -2.4 at z ~ 10 to α ~ -1.5 at z ~ 2, (2) minimal evolution in the characteristic luminosity M* at z ≥ 2.5, and (3) a monotonic increase in the normalization log{sub 10}ϕ* from z ~ 10 to 2, which can be well described by a simple second-order polynomial, consistent with an “accelerated” evolution scenario. We find that each of these trends (from z ~ 10 to 2.5 at least) can be readily explained on the basis of the evolution of the halo mass function and a simple constant star formation efficiency model.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

HST PanCET Program: A Complete Near-UV to Infrared Transmission Spectrum for the Hot Jupiter WASP-79b

We present a new optical transmission spectrum of the hot Jupiter WASP-79b. We observed three transits with the STIS instrument mounted on the Hubble Space Telescope (HST), spanning 0.3–1.0 μm. Combining these transits with previous observations, we construct a complete 0.3–5.0 μm transmission spectrum of WASP-79b. Both HST and ground-based observations show decreasing transit depths toward blue wavelengths, contrary to expectations from Rayleigh scattering or hazes. We infer atmospheric and stellar properties from the full near-UV to infrared transmission spectrum of WASP-79b using three independent retrieval codes, all of which yield consistent results. Our retrievals confirm previous detections of H{sub 2}O (at 4.0σ confidence) while providing moderate evidence of H{sup -} bound–free opacity (3.3σ) and strong evidence of stellar contamination from unocculted faculae (4.7σ). The retrieved H{sub 2}O abundance (~1%) suggests a superstellar atmospheric metallicity, though stellar or substellar abundances remain consistent with present observations (O/H = 0.3–34× stellar). All three retrieval codes obtain a precise H{sup -} abundance constraint: log(X{sub H{sup -}}) ≈ -8.0 ± 0.7. The potential presence of H{sup -} suggests that James Webb Space Telescope observations may be sensitive to ionic chemistry in the atmosphere of WASP-79b. The inferred faculae are ~500 K hotter than the stellar photosphere, covering ~15% of the stellar surface. Our analysis underscores the importance of observing UV–optical transmission spectra in order to disentangle the influence of unocculted stellar heterogeneities from planetary transmission spectra.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

A New Member of the Fast and Furious Family: A Relativistic and Time-variable UV Outflow in a Luminous Quasar

We report the fastest quasar outflow first detected in the ultraviolet, via variable C IV and Si IV absorption at outflow velocities −77,000 km s −1 to at least −90,000 km s −1 , in the radio-quiet quasar SDSS J231854.31+243954.2 (J2318). J2318 is a weak-lined quasar in the rest-frame ultraviolet, but Gemini GNIRS spectroscopy reveals an Hα redshift of z = 2.6781 ± 0.0004. A 20 yr photometric time series shows peak-to-peak variability of 0.5 mag in the g band. The C IV outflow strengthened monotonically over three epochs spanning ∼2.2 rest-frame years. The existence of such a high-velocity outflow implies that models of quasar outflows must be able to either accelerate gas to 0.3c while still preserving C IV and Si IV ions, or enable the formation of C IV and Si IV ions in gas, which has been accelerated to 0.3c. Virial estimates reveal a black-hole mass of 1.65 × 10 9 M ⊙ , which leads to an Eddington luminosity and Eddington ratio of 2.4 × 10 47 erg s −1 and 0.45, respectively. Using very conservative assumptions, the UV-absorbing outflow alone has an estimated mass loss of >0.82 M ⊙ yr −1 and a kinetic luminosity ratio L kin /L bol ≥ 0.75%. The lower limit is just above the threshold usually cited for significant feedback on the host galaxy. Comparison to PDS 456, the only other known quasar with a UV-absorbing outflow at 0.3c, suggests that the true $\dot{M}$ and Lkin/Lbol could be up to 2 orders of magnitude larger.

Seaton, Lucas M. [York University] (ORCID:00090006↗
DOE OSTI2020

Hollow fiber mid-ID spectrometer with UV laser ablation sampling for fine spatial reoslution of isotope ratios in solids

We describe a system that combines isotope ratio analysis via mid-infrared (Mid-IR) laser absorption spectroscopy with fine spatial resolution sampling using a UV pulsed laser. The UV laser ablates a pit in a solid on the order of 10 microns in diameter. The sample-derived particulates resulting from laser ablation pass through a micro-combustor, and the resulting gas is analyzed using Mid-IR laser absorption spectroscopy in a capillary absorption spectrometer (CAS). The CAS uses a hollow fiber optic waveguide with a reflective inner coating and a small internal volume on the order of 1ml. The hollow fiber both guides the laser light from source to detector and contains the gas sample at reduced pressure. Near unity overlap between the laser beam and sample enables sensitive analysis with ultra-small sample size. A prototype system has been demonstrated to enable stable carbon isotopic analysis (d13C) with 1 per mil precision using <1 picomole of carbon and is currently being used to study nutrient exchange in soil/root/microbial rhizosphere studies. The smaller sample size of this system is enabling fine spatial resolution analysis (on the order of 10 microns), which is roughly an order of magnitude smaller than was possible with an isotope ratio mass spectrometer (IRMS). In addition to rhizosphere studies, the system can provide a useful tool for fine scale isotope analysis with applications in biological, forensic, and environmental science.

capillary absorption spectroscopy, laser ablation,↗
DOE OSTI2023

Metal-semiconductor-metal structured p-i-n GaN/AlGaN ultrafast detectors for deep-UV photodetection

We report the productive outcome of the design, fabrication, and testing of a new class of GaN/AlGaN-based ultrafast, sensitive photodiodes for deep-UV solar blind photodetection. Pt was employed as the interdigitated metal electrode to establish that while a Schottky contact was formed at the metal/semiconductor heterojunction, it was the quantum wells in the p-i-n vertical structure that produced the diode characteristics of the detectors. The metal–semiconductor–metal design retained its ultrafast property as expected in the p-i-n structure because the spacing between the interdigitated fingers was asymmetrically implemented to optimize the photogenerated carriers’ transit time from the quantum well to the external circuitry. Also, the vertical p-i-n structure provided its renowned efficient photocarrier generation, which was significantly enhanced by the delta quantum well architecture of the vertical epitaxial structure. The active area of the device was 300 μm × 300 μm with 5-μm finger width, and asymmetric electrode spacing of 2 μm, 3 μm, and 5 μm. Here, the best device had peak responsivity of 3.5 A/W under 262-nm illumination with full width half maximum of 337.2-ps and 37.5-ps rise times when biased with 20 V.

efficient↗
DOE OSTI2023

Self-diagnosis of model suitability for continuous measurements of stream-dissolved organic carbon derived from in situ UV–visible spectroscopy

Application of high-frequency monitoring of dissolved organic carbon (DOC) is difficult in instances where training datasets are challenging to develop (e.g., remote locations) and the relationship between optical features and DOC concentration changes due to environmental or landscape shifts (e.g., climate or land-use change). We developed and compared three partial least squares (PLS) models using in situ water level measurements, conductivity, and UV–Vis spectral attenuation to predict DOC. Two site-specific models were developed using data from a hillslope-dominated forest or a low-relief wetland-pond-dominated stream catchment. The third model, using data from both sites, exhibited the best performance (DOC range = 4–15.5 mg C L −1 , mean = 8.38 mg C L −1 , training RMSE = 0.34 mg C L −1 , internal validation RMSE = 0.50 mg C L −1 , external validation RMSE = 2.43 mg C L −1 ). We further demonstrate using PLS model statistics to monitor performance and elucidate when and how models should be updated. These statistics, Hotelling's T 2 and squared prediction errors, are useful consistency checks for the predictions made and detect underlying inconsistencies that, if undetected, can reduce the robustness of DOC prediction. For example, via the T 2 statistic, we identified the summer–autumn transition as a period when DOC composition differed from what was represented in the training dataset. We also determined that elevated SUVA 254 values contributed to the overall bias observed in predictions made during the subsequent year as part of the external validation. This enabled the application of a bias correction that reduced the RMSE from 2.43 to 0.89 mg C L −1 . The method presented here could be applied to future monitoring programs enabling model updates to monitor DOC fluxes accurately from optical datasets (e.g., attenuance or fluorescence) in the face of developing datasets in remote locations or environmental change. In conclusion, implementation of this approach may also identify possible regime shifts or landscape and hydrologic change associated with climate and other environmental changes relevant to terrestrial to aquatic fluxes.

UV-VIS spectroscopy↗
DOE OSTI2022

Investigation on the AgPt and AgPd hybrid alloy nanoparticles (HANPs) for the hybrid MoS 2 /ZnO/HANP UV photodetector application

We report hybrid photodetectors made of two or more nanomaterial components can offer the high potential for advanced photodetection applications with enhanced light absorption, improved efficiency and structural tunability. A hybrid UV photodetector (PD) configuration incorporating the plasmonic hybrid alloy nanoparticles (HANP), ZnO quantum dots (QDs) and MoS 2 nanoflakes, namely MoS2/ZnO/HANP PD, is demonstrated. The optimized MoS 2 /ZnO/HANP PD exhibits a high photocurrent of 5.66 mA at 0.34 mW/mm 2 under 385 nm illumination with two orders of improvement from the bare ZnO, which is one of the highest photocurrents by the ZnO-based PDs. It also demonstrates high figure-of-merits with the responsivity of 14,523 mA/W, detectivity of 8.13 x 10 11 jones, and external quantum efficiency (EQE) of 4,680 %, outperforming most of the ZnO-based hybrid architectures. The enhanced photoresponse is primarily attributed to the significantly enhanced hot electron generation by the AgPd HANPs and photocarrier collection through the ZnO QD layer. MoS 2 nanoflakes also provide additional photon absorption sites and boost the photo-carrier transfer process. HANPs are grown by adapting a dual-step solid-state dewetting process (SSD) approach and the superiority of AgPd HANPs is confirmed by systematic investigation, FDTD simulation and comparison of AgPt and AgPd HANPs.

MoS2↗
DOE OSTI2020

Structural Dynamics in UV Curable Resins Resolved by In Situ 3D Printing X-ray Photon Correlation Spectroscopy

Additive manufacturing (AM) is a promising technique to rapidly produce polymeric materials into complex 3-dimensional (3D) geometries. While AM is widespread and relevant for a range of applications, implementation in industry has outpaced our fundamental understanding of polymer dynamics and structure development during the printing process. Characterization and quantification of such dynamics is necessary to optimize final material properties and design future materials and processes for 3D printing. Here, we utilize X-ray photon correlation spectroscopy (XPCS) to measure spatial and time-resolved, out-of-equilibrium dynamics during direct ink write (DIW) 3D printing. Specifically, we investigate the progression of structural dynamics in a dual cure (UV/thermal) nanocomposite during and directly after printing. As the filament is printed and cured in situ, the relaxation processes of the cross-linking network are measured through the dynamics of inorganic filler particles. The characteristic relaxation time of the dynamics is calculated through the intensity–intensity autocorrelation function g 2 and directly correlated to the printing process parameters, such as printhead velocity and UV light intensity. The time-resolved evolution of nanoscale dynamics follows a power-law dependence as the filament is cured. Additionally, bulk rheological characterizations reveal the macroscopic solidification of the resin, providing correlation of material properties across a wide range of length and time scales. Overall, the measurement of multiscale, out-of-equilibrium dynamics provides insight into the development of structure in polymer nanocomposite filaments during 3D printing and is used to further understand the influence of such parameters on the AM process.

36 MATERIALS SCIENCE↗
DOE OSTI2024

UV-Vis spectrophotometric determination of rare earth elements (REE) speciation at near-neutral to alkaline pH. Part I: m-cresol purple properties from 25-75 °C and Er hydrolysis

The speciation and mobility of rare earth elements (REE) strongly depends on pH which controls the formation of charged aqueous hydroxyl species. The latter potentially play an important role in controlling heavy REE adsorption on clay minerals in near-neutral to alkaline waters such as in regolith-hosted REE mineral deposits. However, accurate REE hydrolysis constants are needed for developing geochemical models that can predict the role of these charged species in natural systems. Here, we develop a robust experimental UV-Vis spectrophotometric method using m-cresol purple to determine in situ pH from 25 to 75 °C. This method is used to derive the average ligand number and hydrolysis constants of erbium (Er) at 25 °C in aqueous solutions with low ionic strength (≤ 0.001 mol/L) at pH from ~7 to 9.5 and in the presence of Er concentrations from 0 to 0.057 mM. The average ligand number ranges between 1 and 3 indicating that Er(OH) 2+ , Er(OH) 2 + and Er(OH) 3 0 control speciation in the experiments. The logarithm of the Er hydrolysis constants (log*β n ° , n= 1 to 3) derived at infinite dilution for the reaction Er 3+ + nH 2 O = Er(OH) n 3-n + nH + are: *β 1 ° = –7.22 ± 0.10, *β 2 ° = –14.52 ± 0.08, *β 3 ° = –23.24 ± 0.04. Implementation of these experimental data into a geochemical model indicates that the Er(OH) 2 + and Er(OH) 3 0 species are both stable in a much wider pH range than previously predicted. Consequently, the positively charged REE hydroxyl complexes can potentially control the fractionation of light vs. heavy REE via adsorption as observed in the formation of certain regolith-hosted REE deposits.

58 GEOSCIENCES↗
DOE OSTI2020

Ultrafast UV AlGaN Metal–Semiconductor–Metal Photodetector With a Response Time Below 25 ps

Here, aluminum-gallium-nitride photodetectors were successfully fabricated with micrometer-scale metal–semiconductor–metal structures and tested with ultrafast, UV laser pulses. The measurements were performed with single-shot oscilloscopes. Pulse-broadening effects caused by the measurement system were systematically evaluated and reduced to resolve the intrinsic response time of the detector. The best-performing devices showed a response time of below 25 ps and dark currents below 20 pA. The devices showed linear response with the bias voltage and the laser energy

42 ENGINEERING↗
DOE OSTI2022

Interdigitated electrode geometry variation and external quantum efficiency of GaN/AlGaN-based metal-semiconductor-metal UV photodetectors

Aluminum gallium-nitride (Al x Ga 1–x N)-based metal–semiconductor–metal (MSM) ultraviolet photodetectors photodetectors (PD’s) have been successfully designed and fabricated using conventional photolithography techniques and tested experimentally to study their spectral sensitivity across different Al content, x, with x varying from 0 to 0.3. (Al)GaN-based UV PD’s have wide and tunable direct band gaps. The ability to easily select the photodetected wavelength by simply varying the aluminum content of GaN thin film (Al x Ga 1–x N) is a significant advantage of these group III–V compounds. Typically, MSM PD’s grown on (Al)GaN thin films result in ultrafast photodetection because of their highly mobile carriers. These devices are limited by the carrier transit time due to the negligible capacitance presented by the interdigitated fingers. Various electrode geometries were fabricated to investigate the influence of metal contact shapes on the devices’ performance indices with emphasis on the response speed and bias-voltage–independent efficiency. Here, coupled with the independently measured Hall mobility and electric field, we computed the carrier transit time of the devices to be as short as 1.31 ps and the bias-voltage–independent external quantum efficiencies were as high as 70% at 60 V for n-doped and intrinsic devices when operated in the reverse bias regime. Here, (Al x )Ga 1–x N photodetectors were designed to explore spectral sensitivity by altering x from 0 to 0.3.

42 ENGINEERING↗
DOE OSTI2021

Conformational Control of DNA Origami by DNA Oligomers, Intercalators and UV Light

DNA origami has garnered great attention due to its excellent programmability and precision. It offers a powerful means to create complex nanostructures which may not be possible by other methods. The macromolecular structures may be used as static templates for arranging proteins and other molecules. They are also capable of undergoing structural transformation in response to external signals, which may be exploited for sensing and actuation at the nanoscale. Such on-demand reconfigurations are executed mostly by DNA oligomers through base-pairing and/or strand displacement, demonstrating drastic shape changes between two different states, for example, open and close. Recent studies have developed new mechanisms to modulate the origami conformation in a controllable, progressive manner. Here we present several methods for conformational control of DNA origami nanostructures including chemical adducts and UV light as well as widely applied DNA oligomers. The detailed methods should be useful for beginners in the field of DNA nanotechnology.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Anion-tethered Single Lithium-ion Conducting Polyelectrolytes through UV-induced Free Radical Polymerization for Improved Morphological Stability of Lithium Metal Anodes

Single Li + ion conducting polyelectrolytes (SICs), which feature covalently tethered counter-anions along their backbone, have the potential to mitigate dendrite formation by reducing concentration polarization and preventing salt depletion. However, due to their low ionic conductivity and complicated synthetic procedure, the successful validation of these claimed advantages in lithium metal (Li 0 ) anode batteries remains limited. In this study, we fabricated a SIC electrolyte using a single-step UV polymerization approach. The resulting electrolyte exhibited a high Li + transference number (t + ) of 0.85 and demonstrated good Li + conductivity (6.3×10 -5 S/cm at room temperature), which is comparable to that of a benchmark dual ion conductor (DIC, 9.1×10 -5 S/cm). Benefitting from the high transference number of SIC, it displayed a three-fold higher critical current density (2.4 mA/cm 2 ) compared to DIC (0.8 mA/cm 2 ) by successfully suppressing concentration polarization-induced short-circuiting. Additionally, the t + significantly influenced the deposition behavior of Li0, with SIC yielding a uniform, compact, and mosaic-like morphology, while the low t + DIC resulted in a porous morphology with Li 0 whiskers. Using the SIC electrolyte, Li 0 ||LiFePO 4 cells exhibited stable operation for 4500 cycles with 70.5 % capacity retention at 22 °C.

25 ENERGY STORAGE↗