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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Thermochemical water decomposition processes

Thermochemical processes which lead to the production of hydrogen and oxygen from water without the consumption of any other material have a number of advantages when compared to other processes such as water electrolysis. It is possible to operate a sequence of chemical steps with net work requirements equal to zero at temperatures well below the temperature required for water dissociation in a single step. Various types of procedures are discussed, giving attention to halide processes, reverse Deacon processes, iron oxide and carbon oxide processes, and metal and alkali metal processes. Economical questions are also considered.

Chao, R. E.↗
NASA NTRSDate not supplied

Modeling Electrolytic O2 Recovery from Metabolic CO2 for Advanced Closed Loop Life Support Systems in Extraterrestrial Human Missions

The International Space Station (ISS) is currently equipped with a complex, heavy, and power consuming system that recovers approximately 50% of O2 from metabolic CO2. Future long duration human missions to the Moon and Mars will necessitate a sustainable and highly efficient metabolic oxygen recovery system capable of yielding a minimum of 75% O2 recovery. A Macrofluidic Electrochemical Reactor (MFECR) technology development effort is currently underway at NASA Marshall Space Flight Center (MSFC) to significantly increase current metabolic O2 recovery efficiency, expand mission sustainability, and reduce complexity of the system. The novel design combines CO2 conversion to O2 along with C2H4 as byproduct and water electrolysis (currently conducted in two separate units) into a single compact unit that runs at standard conditions and is theoretically capable of generating O2 with a theoretical maximum metabolic CO2 conversion of 73% while consuming less than metabolic water. This paper presents a comprehensive multi-physic 3D model developed at MSFC on CO2 conversion to O2 and C2H4 at standard conditions via MFECR. The 3D spatial domain of the model is a replica of the actual MFECR’s 3D drawing generated for the MFECR fabrication and operated to recover O2 from CO2 yielding C2H4 as byproduct. Electrochemical (EC) physics that includes EC multicomponent reaction mechanisms, mass transport, and electrical current density distributions is coupled in the model with all the other physics phenomena involved in the MFECR’s process, such as two-phase flow, free and porous fluid regimes, multicomponent mass transfer, heat transfer, and DC electrical current generation along with Joule heating effect. The EC reaction sections of the MFECR consists of two porous gas diffusion electrodes (GDE) and an electrolyte serpentine channel sandwiched in the middle. The CO2 feeds the cathode serpentine channel and part of the O2 product is fed back to the anode serpentine chamber. An alkaline solution feeds the electrolyte serpentine chamber wetting the GDEs of both, the anode and cathode allowing the OH- ionic transport between them. The EC reactions in the cathode’s GDE yield C2H4 from CO2 and H2 from water while the EC reaction in the anode’s GDE yields O2. The authors will present in this paper the validation of the model using experimental data and the utilization of the validated model in building a reliable simulator that will not only assist the authors on the MFECR design but also the optimization of its operation in the ISS and future spatial human missions.

Jesus A Dominguez↗
NASA NTRS1975

Thermochemical production of hydrogen via multistage water splitting processes

This paper presents and reviews the fundamental thermodynamic principles underlying thermochemical water splitting processes. The overall system is considered first and the temperature limitation in process thermal efficiency is developed. The relationship to an ideal water electrolysis cell is described and the nature of efficient multistage reaction processes is discussed. The importance of the reaction entropy change and the relation of the reaction free energy change to the work of separation is described. A procedure for analyzing thermochemical water splitting processes is presented and its use to calculate individual stage efficiency is demonstrated. A number of processes are used to illustrate the concepts and procedures.

Funk, J. E.↗
NASA NTRS1983

Integrated atmosphere revitalization system description and test results

The design and operation of several air revitalization subsystems are described, along with the testing of these subsystems separately and integrated in an air revitalization system for use in space stations. The subsystems are: one that generates O2 by water electrolysis, one that removes and concentrates CO2 using an electrochemical technique, and one that reduces concentrated CO2 by the Sabatier process. Results of the integrated testing include the observations that liquid cooling should be baselined for recovery of the CO2 reduction subsystem product water, continuous CO2 injection into the air supply unit is preferable, small changes in the current CO2 removal subsystem inlet PCO2 are detectable as changes in the CO2 reduction subsystem reactor temperatures, and hardwired shutdown of critical parameters is vital if computer-based controllers are not redundant. Several block diagrams are provided.

Martin, R. B.↗
NASA NTRS1987

Space station onboard propulsion system: Technology study

The objective was to prepare for the design of the space station propulsion system. Propulsion system concepts were defined and schematics were developed for the most viable concepts. A dual model bipropellant system was found to deliver the largest amount of payload. However, when resupply is considered, an electrolysis system with 10 percent accumulators requires less resupply propellant, though it is penalized by the amount of time required to fill the accumulators and the power requirements for the electrolyzer. A computer simulation was prepared, which was originally intended to simulate the water electrolysis propulsion system but which was expanded to model other types of systems such as cold gas, monopropellant and bipropellant storable systems.

Mcallister, J. G.↗
NASA NTRSDate not supplied

Lunar Water Pilot Plant Conceptual Design

A study was conducted to determine mass, power, and concept of operations for a polar water pilot plant that can produce 1000 kg of oxygen in a year from 1125 kg of water extracted from the icy regolith in a permanently shadowed region(PSR). Icy regolith in the PSR is excavated and delivered to a stationary dryer that extracts the water which is frozen in an ice tanker and delivered up to the ridge for further processing into oxygen and hydrogen. This study assumed a previously landed nuclear reactor was available in the PSR to provide power for the water extraction, which requires 2.4 kW of power, including a 30 percent margin. At 325 kg, the ISRU system mass in the PSR, including the excavator, should be deliverable by one of the Commercial Lunar Payload Services (CLPS) landers, and the packaging and concept of operations are shown using one specific CLPS lander. The mass and power of the ISRU system components on the ridge for water electrolysis and liquefaction and storage of the oxygen and hydrogen are estimated at 840 kg and 4.3 kW.

Lunar↗
NASA NTRS1976

Nuclear driven water decomposition plant for hydrogen production

The conceptual design of a hydrogen production plant using a very-high-temperature nuclear reactor (VHTR) to energize a hybrid electrolytic-thermochemical system for water decomposition has been prepared. A graphite-moderated helium-cooled VHTR is used to produce 1850 F gas for electric power generation and 1600 F process heat for the water-decomposition process which uses sulfur compounds and promises performance superior to normal water electrolysis or other published thermochemical processes. The combined cycle operates at an overall thermal efficiency in excess of 45%, and the overall economics of hydrogen production by this plant have been evaluated predicated on a consistent set of economic ground rules. The conceptual design and evaluation efforts have indicated that development of this type of nuclear-driven water-decomposition plant will permit large-scale economic generation of hydrogen in the 1990s.

Parker, G. H.↗
NASA NTRS2004

Development of a Self-calibrating Dissolved Oxygen Microsensor Array for the Monitoring and Control of Plant Growth in a Space Environment

Plant experiments in space will require active nutrient delivery concepts in which water and nutrients are replenished on a continuous basis for long-term growth. The goal of this study is to develop a novel microsensor array to provide information on the dissolved oxygen environment in the plant root zone for the optimum control of plant cultivation systems in the space environment. Control of water and oxygen is limited by the current state-of-the-art in sensor technology. Two capabilities of the new microsensor array were tested. First, a novel in situ self-diagnosis/self-calibration capability for the microsensor was explored by dynamically controlling the oxygen microenvironment in close proximity to an amperometric dissolved oxygen microsensors. A pair of integrated electrochemical actuator electrodes provided the microenvironments based on water electrolysis. Miniaturized thin film dissolved oxygen microsensors on a flexible polyimide (Kapton(Registered Trademark)? substrate were fabricated and their performances were tested. Secondly, measurements of dissolved oxygen in two representative plant growth systems were made, which had not been performed previously due to lack of proper sensing technology. The responses of the oxygen microsensor array on a flexible polymer substrate properly reflected the oxygen contents on the surface of a porous tube nutrient delivery system and within a particulate substrate system. Additionally, we demonstrated the feasibility of using a 4-point thin film microprobe for water contents measurements for both plant growth systems. mechanical flexibility, and self-diagnosis. The proposed technology is anticipated to provide a reliable sensor feedback plant growth nutrient delivery systems in both terrestrial environment and the microgravity environment during long term space missions. The unique features of the sensor include small size and volume, multiple-point sensing,

Kim, Chang-Soo↗
NASA NTRS1989

Sensitivity of propulsion system selection to Space Station Freedom performance requirements

The selection of the propulsion system for the Space Station (SS) is reassessed. The propulsion system consists of two distinct elements. The first of these combusts gaseous oxygen and hydrogen produced from water electrolysis, to maintain the SS altitude and perform higher thrust maneuvers for backup attitude control, collision avoidance, and other contingencies. The second consists of gas resistojets, which augment altitude maintenance. The results of a parametric comparison of the life cycle costs of this electrolysis/resistojet propulsion with those of other system options, carried out over a range of probable performance requirements, confirmed the baseline superiority of the SS propulsion system for most anticipated conditions. However, relative costs among impulse requirements vary so much that major changes in the design conditions may warrant implementation of another system (such as hydrazine with water resistojets).

Schmidt, George R.↗
NASA NTRS1988

Alkaline static feed electrolyzer based oxygen generation system

In preparation for the future deployment of the Space Station, an R and D program was established to demonstrate integrated operation of an alkaline Water Electrolysis System and a fuel cell as an energy storage device. The program's scope was revised when the Space Station Control Board changed the energy storage baseline for the Space Station. The new scope was aimed at the development of an alkaline Static Feed Electrolyzer for use in an Environmental Control/Life Support System as an oxygen generation system. As a result, the program was divided into two phases. The phase 1 effort was directed at the development of the Static Feed Electrolyzer for application in a Regenerative Fuel Cell System. During this phase, the program emphasized incorporation of the Regenerative Fuel Cell System design requirements into the Static Feed Electrolyzer electrochemical module design and the mechanical components design. The mechanical components included a Pressure Control Assembly, a Water Supply Assembly and a Thermal Control Assembly. These designs were completed through manufacturing drawing during Phase 1. The Phase 2 effort was directed at advancing the Alkaline Static Feed Electrolyzer database for an oxygen generation system. This development was aimed at extending the Static Feed Electrolyzer database in areas which may be encountered from initial fabrication through transportation, storage, launch and eventual Space Station startup. During this Phase, the Program emphasized three major areas: materials evaluation, electrochemical module scaling and performance repeatability and Static Feed Electrolyzer operational definition and characterization.

Noble, L. D.↗
NASA NTRS1971

Spacecraft oxygen recovery system

Spacecraft closed loop oxygen recovery system using electrochemical carbon dioxide concentrator, Sabatier reactor and water electrolysis subsystem

Quattrone, P. D.↗
NASA NTRS1972

Atmosphere revitalization in the space station prototype.

The atmosphere revitalization group (ARG) for the space station prototype (SSP) environmental/thermal control and life support system (ETC/LSS) has been designed to meet a comprehensive set of requirements and constraints for a flight type mission. Design definition is for a modular vehicle temperature and humidity control subsystem, contaminant control equipment, a hydrogen depolarized cell CO2 concentrator, a water electrolysis oxygen generation subsystem, CO2 reduction equipment, and a pressure and composition control subsystem. Performance requirements are for support of a crew of six. Realistic leakage rates and metabolic activity cycles, cabin temperature selectability, and controlled cabin relative humidities are specified for the design. Operational aspects of the subsystem are discussed with emphasis given to the influence of a 180-day, maintainable requirement on system design. Consideration of flight vehicle type packaging, in flight maintenance, data management systems interface and fault detection capability, and electrical supply constraints is covered.

Trusch, R. B.↗
NASA NTRS1973

Cost analysis of oxygen recovery systems

Report is made of the cost analysis of four leading oxygen recovery subsystems which include two carbon dioxide reduction subsystems and two water electrolysis subsystems, namely, the solid polymer electrolyte and the circulating KOH electrolyte. The four oxygen recovery systems were quantitatively evaluated. System characteristics, including process flows, performance, and physical characteristics were also analyzed. Additionally, the status of development of each of the systems considered and the required advance technology efforts required to bring conceptual and/or pre-prototype hardware to an operational prototype status were defined. Intimate knowledge of the operations, development status, and capabilities of the systems to meet space mission requirements were found to be essential in establishing the cost estimating relationships for advanced life support systems.

Yakut, M. M.↗
NASA NTRS1973

Cost analysis of oxygen recovery systems

The design and development of equipment for flight use in earth-orbital programs, when optimally approached cost effectively, proceed through the following logical progression: (1) bench testing of breadboard designs, (2) the fabrication and evaluation of prototype equipment, (3) redesign to meet flight-imposed requirements, and (4) qualification and testing of a flight-ready system. Each of these steps is intended to produce the basic design information necessary to progress to the next step. The cost of each step is normally substantially less than that of the following step. An evaluation of the cost elements involved in each of the steps and their impact on total program cost are presented. Cost analyses of four leading oxygen recovery subsystems which include two carbon dioxide reduction subsystem, Sabatier and Bosch, and two water electrolysis subsystems, the solid polymer electrolyte and the circulating KOH electrolyte are described.

Yakut, M. M.↗
NASA NTRS1973

Electrolytic hydrogen fuel production with solid polymer electrolyte technology.

A water electrolysis technology based on a solid polymer electrolyte (SPE) concept is presented for applicability to large-scale hydrogen production in a future energy system. High cell current density operation is selected for the application, and supporting cell test performance data are presented. Demonstrated cell life data are included to support the adaptability of the SPE system to large-size hydrogen generation utility plants as needed for bulk energy storage or transmission. The inherent system advantages of the acid SPE electrolysis technology are explained. System performance predictions are made through the year 2000, along with plant capital and operating cost projections.

Titterington, W. A.↗